CN104872270A - Preservative for maritime iced preservation of shrimps and preparation method and application thereof - Google Patents

Preservative for maritime iced preservation of shrimps and preparation method and application thereof Download PDF

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Publication number
CN104872270A
CN104872270A CN201410824402.3A CN201410824402A CN104872270A CN 104872270 A CN104872270 A CN 104872270A CN 201410824402 A CN201410824402 A CN 201410824402A CN 104872270 A CN104872270 A CN 104872270A
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China
Prior art keywords
preservative
preservation
shrimps
extra large
iced
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CN201410824402.3A
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CN104872270B (en
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张小军
梅光明
李铁军
严忠雍
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Zhejiang Marine Fisheries Research Institute
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Zhejiang Marine Fisheries Research Institute
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  • Freezing, Cooling And Drying Of Foods (AREA)

Abstract

The invention discloses a preservative for maritime iced preservation of shrimps. The preservative is composed of the following ingredients, by weight, 0.5-1% of glucose oxidase, 1-3% of glucose, 10-15% of dithiothreitol, 0.75-1% of nisin, 20-30% of sodium caseinate, 3-5% of metallothionein, 20-30% of sodium fumarate and the rest being rosmarinic acid. The formula of the preservative is scientific, reasonable and low-cost. Through synergism of the ingredients, the preservative has excellent antibacterial, fresh-keeping and anti-blackening effects. By the use of the preservative, freshness lifetime of shrimps can be prolonged, quality of shrimps is good, and the problem that freshness lifetime of shrimps is short, shrimp bodies are easy to dehydrate and quality is easy to reduce during the iced preservation process of shrimps is effectively solved. The preservative provided by the invention has a wide application prospect. The invention also discloses a preparation method of the preservative for maritime iced preservation of shrimps. The preservative can be obtained by uniformly mixing the ingredients after weighing in proportion. The preparation steps are simple; investment in equipment is less; and cost is low. The preservative is suitable for large-scale industrial production.

Description

Marine ice preservation antistaling agent of a kind of extra large shrimping and preparation method thereof, application
Technical field
The present invention relates to aquatic products technical field of preservation of fresh, especially relate to marine ice preservation antistaling agent of a kind of extra large shrimping and preparation method thereof, application.
Background technology
Sea shrimp body is little, moisture is high, musculature is soft, catch and treat that fishing boat returns port and generally needs 3 ~ 5d, at this moment had the part serious blackening of shrimp body of catching, especially 1 ~ 2d shrimp closely corruption of catching, edible quality and commodity value reduce greatly, but also obstruction affects fishing boat working days further, directly affects productivity effect.
The preservation method at current extra large shrimping sea mainly contains cold sea water preservation, preservation by partial and ice preservation, wherein cold sea water preservation be carry out in the pure seawater extra large shrimping being dipped in about 0 DEG C fresh-keeping, shrimp body can be made directly not contact with the oxygen in air, prevent black change, but the long-time immersion in water of shrimp body can be expanded, build deliquescing poor flexibility, quality appearance is poor, is only suitable for processing peeled shrimp product; Preservation by partial can make shrimp body substantially be in micro-ly to freeze state, can the breeding of anti-bacteria and the activity of tyrosinase in various degree, but can not suppress completely shrimp Ti ?become, and preservation by partial cost is high, be not suitable for the needs of mass transit, application remains in certain difficulty; Ice preservation is that preservation on the rocks of casing is carried out in extra large shrimping, its because of cost low, and the needs of suitable mass transit, it is still one sea shrimping preservation method the most conventional at present, but the fresh keeping time of ice preservation is short, maximum duration is 5 days, and easily causes shrimp body dewater and cause quality to decline.Therefore, the fresh keeping time and the fresh-keeping effect that improve extra large shrimping ice preservation seem particularly important.
Summary of the invention
The present invention is that the fresh keeping time of extra large shrimping ice preservation in order to solve prior art is short, and the problem easily causing shrimp body to dewater and cause quality to decline, provide a kind of scientific formulation reasonable, cost is low, there is excellent antibacterial, fresh-keeping and anti-black change effect, freshness date when can extending extra large shrimping ice preservation and the extra large shrimping sea ice preservation antistaling agent of shrimp body quality better.
Present invention also offers the preparation method of the marine ice preservation antistaling agent of a kind of extra large shrimping, preparation process is simple, and equipment investment is few, and cost is low, is applicable to large-scale industrial production.
To achieve these goals, the present invention is by the following technical solutions:
The marine ice preservation antistaling agent of a kind of extra large shrimping, be made up of the component of following mass percent: 0.5 ~ 1% glucose oxidase, 1 ~ 3% glucose, 10 ~ 15% dithiothreitol (DTT)s, 0.75 ~ 1% nisin, 20 ~ 30% casein sodiums, 3 ~ 5% metallothioneins, 20 ~ 30% fumaric acid sodiums, surplus is Rosmarinic acid.Antistaling agent prescription of the present invention is scientific and reasonable, each component is easy to get, cost is low, wherein, glucose oxidase plays deoxidation, and the oxygen under the effect of glucose oxidase around shrimp body can react with glucose and remove, be conducive to suppressing Xia Ti ?become, glucose also can maintain color and the gloss of shrimp body, is conducive to improving exterior quality; The metal ion (copper core) of the rapid chelating tyrosinase activity point position of dithiothreitol (DTT) energy, reaches the object suppressing enzymatic ?to become; Nisin has very excellent biocidal property, and security is good, can extend the freshness date of shrimp body; Rosmarinic acid can suppress the activity of various metabolic enzyme in shrimp body, delays the putrid and deteriorated of shrimp, and in addition, Rosmarinic acid also has bacteriostasis, and with nisin coordinated, fungistatic effect improves greatly; Casein sodium can improve retentiveness and the stability of shrimp body, the components such as the lipid in shrimp, moisture and musculature can also be combined securely, form compact texture, to reduce the loss of moisture, nutriment and flavor substance in preserving process, efficiently solve extra large shrimping and easily dewater at ice preservation process Prawn body and the problem causing quality to decline; Metallothionein has very strong demetalization ability, especially have very strong selective to copper ion, with dithiothreitol (DTT) coordinated, the activity of the thorough restraint of tyrosinase of energy, suppress black change successful, in addition metallothionein can reduce the accumulation of oxygen in shrimp body, impels bis-phenol to be transformed into colourless compound, thus suppress further Xia Ti ?become; Fumaric acid sodium plays the effect of the black change of antioxygen chemoprevention.The mutual Synergistic of each component in antistaling agent of the present invention, has excellent antibacterial, fresh-keeping and anti-black change effect, can extend the freshness date of shrimp and shrimp body quality better, have broad application prospects.
The preparation method of the marine ice preservation antistaling agent of a kind of extra large shrimping, key step is: after taking glucose oxidase, glucose, dithiothreitol (DTT), nisin, casein sodium, metallothionein, fumaric acid sodium and Rosmarinic acid respectively by said ratio, each component mixed.Mix after each component being weighed by proportioning and can obtain antistaling agent of the present invention, preparation process is simple, and equipment investment is few, and cost is low, is applicable to large-scale industrial production.
The application of the marine ice preservation antistaling agent of a kind of extra large shrimping when extra large shrimping is marine fresh-keeping.
Therefore, the present invention has following beneficial effect: (1) provides the marine ice preservation antistaling agent of a kind of extra large shrimping, scientific formulation is reasonable, cost is low, by the mutual Synergistic of each component, there is excellent antibacterial, fresh-keeping and anti-black change effect, the freshness date of shrimp can be extended and shrimp body quality better, efficiently solve the problem that the short and extra large shrimping of the fresh keeping time of extra large shrimping ice preservation is easily dewatered at ice preservation process Prawn body and caused quality to decline, have broad application prospects;
(2) mix after each component being weighed by proportioning and can obtain antistaling agent of the present invention, preparation process is simple, and equipment investment is few, and cost is low, is applicable to large-scale industrial production.
Detailed description of the invention
Below by detailed description of the invention, the present invention will be further described.
In the present invention, if not refer in particular to, all percentage is unit of weight, and all devices and raw material all can be buied from market or the industry is conventional, and the method in following embodiment, if no special instructions, is this area conventional method.
Embodiment 1
The marine ice preservation antistaling agent of a kind of extra large shrimping, is made up of the component of following mass percent: 0.8% glucose oxidase, 2% glucose, 12% dithiothreitol (DTT), 0.8% nisin, 25% casein sodium, 4% metallothionein, 25% fumaric acid sodium, surplus is Rosmarinic acid.
This antistaling agent obtains by the following method: after taking glucose oxidase, glucose, dithiothreitol (DTT), nisin, casein sodium, metallothionein, fumaric acid sodium and Rosmarinic acid respectively by said ratio, each component mixed.
Embodiment 2
The marine ice preservation antistaling agent of a kind of extra large shrimping, is made up of the component of following mass percent: 1% glucose oxidase, 3% glucose, 15% dithiothreitol (DTT), 1% nisin, 30% casein sodium, 5% metallothionein, 30% fumaric acid sodium, surplus is Rosmarinic acid.
This antistaling agent obtains by the following method: after taking glucose oxidase, glucose, dithiothreitol (DTT), nisin, casein sodium, metallothionein, fumaric acid sodium and Rosmarinic acid respectively by said ratio, each component mixed.
Embodiment 3
The marine ice preservation antistaling agent of a kind of extra large shrimping, is made up of the component of following mass percent: 0.5% glucose oxidase, 1% glucose, 10% dithiothreitol (DTT), 0.75% nisin, 20% casein sodium, 3% metallothionein, 20% fumaric acid sodium, surplus is Rosmarinic acid.
This antistaling agent obtains by the following method: after taking glucose oxidase, glucose, dithiothreitol (DTT), nisin, casein sodium, metallothionein, fumaric acid sodium and Rosmarinic acid respectively by said ratio, each component mixed.
Embody rule:
The general step of sea shrimping ice preservation is: ice → refrigeration is mixed in fresh extra large shrimping cleaning → precooling → vanning, antistaling agent of the present invention is applied in the vanning of pre-cold-peace and mixes between ice step, embody rule method is: antistaling agent being dissolved in temperature is obtain fresh-keeping solution in the seawater of 0 ~ 2 DEG C, the addition of antistaling agent is 2 ~ 4% of seawer quality, then the extra large shrimping after precooling is put into fresh-keeping liquid and soak 2 ~ 5min, pick up and drain laggard luggage case and mix ice.
Antistaling agent of the present invention is adopted to carry out ice preservation to extra large shrimping, the basic Mei You of preservation 7d time shrimp body ?become occur, shrimp body colour pool and good springiness, without de-head, smell is normal, and VBN is at about 25mg/100g, illustrate that antistaling agent of the present invention effectively can extend the fresh keeping time of the marine ice preservation of shrimp body, and shrimp body quality better, the productivity effect for the commodity value and operation on the sea that improve extra large shrimping is significant, is applicable to large-scale promotion application.
Above-described embodiment is one of the present invention preferably scheme, not does any pro forma restriction to the present invention, also has other variant and remodeling under the prerequisite not exceeding the technical scheme described in claim.

Claims (3)

1. the marine ice preservation antistaling agent of extra large shrimping, it is characterized in that, be made up of the component of following mass percent: 0.5 ~ 1% glucose oxidase, 1 ~ 3% glucose, 10 ~ 15% dithiothreitol (DTT)s, 0.75 ~ 1% nisin, 20 ~ 30% casein sodiums, 3 ~ 5% metallothioneins, 20 ~ 30% fumaric acid sodiums, surplus is Rosmarinic acid.
2. the preparation method of the marine ice preservation antistaling agent of extra large shrimping as claimed in claim 1, it is characterized in that, key step is: after taking glucose oxidase, glucose, dithiothreitol (DTT), nisin, casein sodium, metallothionein, fumaric acid sodium and Rosmarinic acid respectively by said ratio, each component mixed.
3. the application of the marine ice preservation antistaling agent of extra large shrimping as claimed in claim 1 when the marine ice preservation of extra large shrimping.
CN201410824402.3A 2014-12-26 2014-12-26 A kind of sea shrimping sea ice preservation antistaling agent and preparation method thereof, application Active CN104872270B (en)

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CN105475469A (en) * 2015-11-26 2016-04-13 浙江海洋学院 Preparation method and use of local flavor antimicrobial microemulsion

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CN102389151A (en) * 2011-11-09 2012-03-28 上海海洋大学 Preparation method of biological preservative for Penaeus vannamei
CN102423100A (en) * 2011-11-09 2012-04-25 上海海洋大学 Penaeus Vannamei ice temperature fresh keeping method combining with ice cube refrigeration
CN104054802A (en) * 2014-05-12 2014-09-24 浙江海洋学院 Fresh shrimp coating preservation composite film forming liquid and preparation method thereof

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CN105475469A (en) * 2015-11-26 2016-04-13 浙江海洋学院 Preparation method and use of local flavor antimicrobial microemulsion

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