CN104862812A - Antibiosis-functionalized PTT polyester fibers and preparation method therefor - Google Patents
Antibiosis-functionalized PTT polyester fibers and preparation method therefor Download PDFInfo
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- CN104862812A CN104862812A CN201410531585.XA CN201410531585A CN104862812A CN 104862812 A CN104862812 A CN 104862812A CN 201410531585 A CN201410531585 A CN 201410531585A CN 104862812 A CN104862812 A CN 104862812A
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Abstract
The invention discloses antibiosis-functionalized PTT polyester fibers and a preparation method therefor. The PTT polyester fibers comprise the following ingredients, by weight, 70%-90% of PTT, 2%-10% of nanokaolin, 5%-8% of MBS, 2%-5% of antibacterial agents, 0.5%-2% of antistatic agent, 0.5%-2% of ultraviolet ray absorbers, 0.1%-0.5% of anti-oxidants and 0.1%-1% of lubricants. The antistatic agent is one selected from silver ion calcium phosphate, silver ion antibacterial zeolite, silica modified organic antibacterial agent and phosphonium salt antibacterial agent. The beneficial effects are that the PTT polyester fibers have good elasticity and toughness, the flexibility is good, the glossiness is strong, antibacterial, antistatic and aging resistant modification effects are good, and the PTT polyester fibers are suitable for fields of indoor textures, decorations, fabrics and the like.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of antibacterial functionalized PTT polyester fiber and preparation method thereof.
Background technology
PTT fiber (PTT polyester fiber) has excellent soft feel, attractive in appearance, dynamic drapability and excellent performance lasting, and pollution resistance is good, and cost is low.PTT polyester fiber has the advantage of spandex class elastic fabric, lower than spandex class elastic fabric cost again, and the good stability of the dimension of fabric, anti-fold increases, therefore PTT is integrated in one the excellent wearability of various fiber, is highly suitable for producing knitting and woven stretch fabric, wears fit, flexible clothes and is just being applicable to the tendency of the day that contemporary mankind advocates a sexual liberation, thus become always run dress, leisure wear fabric, the first-selection of knitted underwear and dark doting on by people.
Summary of the invention
The object of the present invention is to provide a kind of antibacterial functionalized PTT polyester fiber and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of antibacterial functionalized PTT polyester fiber, and its component by mass percent proportioning is: PTT 70% ~ 90%, nano kaoline 2% ~ 10%, MBS 5% ~ 8%, antiseptic 2% ~ 5%, antistatic additive 0.5% ~ 2%, ultra-violet absorber 0.5% ~ 2%, antioxidant 0.1% ~ 0.5%, lubricant 0.1% ~ 1%.
Described PTT is the polytrimethylene terephthalate of intrinsic viscosity 0.7 ~ 1.5dL/g, fusing point 245 DEG C ~ 258 DEG C, relative density 1.30 ~ 1.35g/cm3.
Described nano kaoline be surface through silane coupler modified process and longitudinal thickness at 20 ~ 50nm, the lamella size kaolin nano particle within the scope of 300 ~ 500nm.
Described MBS is MBS block copolymer.
Described antiseptic is the one in silver ion calcium phosphate, silver-ion antibiotic zeolite, silica modified organic antibacterial agent, quaternary alkylphosphonium salt antiseptic.
Described antistatic additive is commercially available antistatic additive HKD-510 or antistatic additive HKD-912.
Described ultra-violet absorber is the one in Hydroxyphenyltriazines ultra-violet absorber, bisphenol a disalicylate ultra-violet absorber, 2-hydroxyl-4 n-octyloxies-benzophenone, 2,4-DihydroxyBenzophenone.
Described antioxidant is the one in the compound of antioxidant 1010, antioxidant 1076, antioxidant 1010 or antioxidant 1076 and irgasfos 168.
Described lubricant is the one in silicone powder, calcium stearate, ethylene bis stearamide, pentaerythritol stearate.
The preparation method of above-mentioned a kind of antibacterial functionalized PTT polyester fiber is: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, through blended, the melting of screw machine extruding, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, winding speed controls at 500 ~ 3000m/min, heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 5 times, namely obtains a kind of antibacterial functionalized PTT polyester fiber of the present invention.
The invention has the beneficial effects as follows, the present invention has good elasticity and toughness, and flexibility is good, and glossiness is strong, and antibacterial, antistatic and ageing-resistant modified effect is good, is suitable for the fields such as indoor fabric, ornaments, fabric.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below in conjunction with concrete preferred embodiment.
Embodiment 1:
A kind of antibacterial functionalized PTT polyester fiber, its component by mass percent proportioning is: PTT 75%, nano kaoline 10%, MBS 8%, silver ion calcium phosphate 3%, antistatic additive HKD-510 2%, Hydroxyphenyltriazines ultra-violet absorber 1.5%, antioxidant 1010 0.2%, silicone powder 0.3%, described PTT is intrinsic viscosity 0.7 ~ 1.5dL/g, fusing point 245 DEG C ~ 258 DEG C, the polytrimethylene terephthalate of relative density 1.30 ~ 1.35g/cm3, described nano kaoline is that surface is through silane coupler modified process, and longitudinal thickness is at 20 ~ 50nm, the kaolin nano particle of lamella size within the scope of 300 ~ 500nm.
Preparation method: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, through blended, the melting of screw machine extruding, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, and winding speed controls at 500 ~ 3000m/min, and heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 5 times, namely obtains a kind of antibacterial functionalized PTT polyester fiber of the present invention.
Embodiment 2:
A kind of antibacterial functionalized PTT polyester fiber, its component by mass percent proportioning is: PTT 86%, nano kaoline 5%, MBS 5%, silver-ion antibiotic zeolite 2%, antistatic additive HKD-912 0.5%, 2, 4-dihydroxy benaophenonel 1%, the compound 0.1% of antioxidant 1076 and irgasfos 168, pentaerythritol stearate 0.4%, described PTT is intrinsic viscosity 0.7 ~ 1.5dL/g, fusing point 245 DEG C ~ 258 DEG C, the polytrimethylene terephthalate of relative density 1.30 ~ 1.35g/cm3, described nano kaoline is that surface is through silane coupler modified process, and longitudinal thickness is at 20 ~ 50nm, the kaolin nano particle of lamella size within the scope of 300 ~ 500nm.
Preparation method: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, through blended, the melting of screw machine extruding, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, and winding speed controls at 500 ~ 3000m/min, and heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 5 times, namely obtains a kind of antibacterial functionalized PTT polyester fiber of the present invention.
Claims (6)
1. an antibacterial functionalized PTT polyester fiber, it is characterized in that, its component by mass percent proportioning is: PTT 70% ~ 90%, nano kaoline 2% ~ 10%, MBS 5% ~ 8%, antiseptic 2% ~ 5%, antistatic additive 0.5% ~ 2%, ultra-violet absorber 0.5% ~ 2%, antioxidant 0.1% ~ 0.5%, lubricant 0.1% ~ 1%.
2. a kind of antibacterial functionalized PTT polyester fiber according to claim 1, it is characterized in that, described nano kaoline be surface through silane coupler modified process and longitudinal thickness at 20 ~ 50nm, the lamella size kaolin nano particle within the scope of 300 ~ 500nm.
3. a kind of antibacterial functionalized PTT polyester fiber according to claim 1, is characterized in that, described antiseptic is the one in silver ion calcium phosphate, silver-ion antibiotic zeolite, silica modified organic antibacterial agent, quaternary alkylphosphonium salt antiseptic.
4. a kind of antibacterial functionalized PTT polyester fiber according to claim 1, is characterized in that, described antistatic additive is commercially available antistatic additive HKD-510 or antistatic additive HKD-912.
5. a kind of antibacterial functionalized PTT polyester fiber according to claim 1, it is characterized in that, described ultra-violet absorber is the one in Hydroxyphenyltriazines ultra-violet absorber, bisphenol a disalicylate ultra-violet absorber, 2-hydroxyl-4 n-octyloxies-benzophenone, 2,4-DihydroxyBenzophenone.
6. the preparation method of a kind of antibacterial functionalized PTT polyester fiber according to claim 1, it is characterized in that, comprise the following steps: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, blended through screw machine extruding, melting, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, winding speed controls at 500 ~ 3000m/min, heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 5 times, namely a kind of antibacterial functionalized PTT polyester fiber of the present invention is obtained.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105755616A (en) * | 2016-04-15 | 2016-07-13 | 安踏(中国)有限公司 | Double-component biomass yarn, shell fabric and clothes |
CN105876953A (en) * | 2016-04-15 | 2016-08-24 | 安踏(中国)有限公司 | Fabric and clothes |
CN106222846A (en) * | 2016-08-24 | 2016-12-14 | 深圳全视觉市场策划有限公司 | Cleaning cloth and preparation method thereof |
CN107475809A (en) * | 2017-08-05 | 2017-12-15 | 广西筑梦三体科技有限公司 | Good 3D printing clothing materials of a kind of antibacterial effect and preparation method thereof |
CN112358675A (en) * | 2020-09-09 | 2021-02-12 | 武汉金发科技有限公司 | Polypropylene composition and preparation method thereof |
CN115287824A (en) * | 2022-06-29 | 2022-11-04 | 惠州市普林摩斯无纺布有限公司 | Antibacterial anti-mite non-woven fabric for mattress lining and preparation process thereof |
CN116005288A (en) * | 2022-12-09 | 2023-04-25 | 罗莱生活科技股份有限公司 | Antibacterial antistatic polyester fiber and preparation method and application thereof |
CN116121930A (en) * | 2023-02-27 | 2023-05-16 | 亿吉万(深圳)新材料科技有限公司 | Moisture-absorbing antibacterial textile |
-
2014
- 2014-10-11 CN CN201410531585.XA patent/CN104862812A/en active Pending
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105755616A (en) * | 2016-04-15 | 2016-07-13 | 安踏(中国)有限公司 | Double-component biomass yarn, shell fabric and clothes |
CN105876953A (en) * | 2016-04-15 | 2016-08-24 | 安踏(中国)有限公司 | Fabric and clothes |
CN105755616B (en) * | 2016-04-15 | 2018-02-02 | 安踏(中国)有限公司 | A kind of biomass two-component yarn, fabric and clothes |
CN106222846A (en) * | 2016-08-24 | 2016-12-14 | 深圳全视觉市场策划有限公司 | Cleaning cloth and preparation method thereof |
CN107475809A (en) * | 2017-08-05 | 2017-12-15 | 广西筑梦三体科技有限公司 | Good 3D printing clothing materials of a kind of antibacterial effect and preparation method thereof |
CN112358675A (en) * | 2020-09-09 | 2021-02-12 | 武汉金发科技有限公司 | Polypropylene composition and preparation method thereof |
CN112358675B (en) * | 2020-09-09 | 2023-08-22 | 武汉金发科技有限公司 | Polypropylene composition and preparation method thereof |
CN115287824A (en) * | 2022-06-29 | 2022-11-04 | 惠州市普林摩斯无纺布有限公司 | Antibacterial anti-mite non-woven fabric for mattress lining and preparation process thereof |
CN116005288A (en) * | 2022-12-09 | 2023-04-25 | 罗莱生活科技股份有限公司 | Antibacterial antistatic polyester fiber and preparation method and application thereof |
CN116121930A (en) * | 2023-02-27 | 2023-05-16 | 亿吉万(深圳)新材料科技有限公司 | Moisture-absorbing antibacterial textile |
CN116121930B (en) * | 2023-02-27 | 2023-11-03 | 亿吉万(深圳)新材料科技有限公司 | Moisture-absorbing antibacterial textile |
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Application publication date: 20150826 |