CN104857662A - Foam extinguishing agent - Google Patents

Foam extinguishing agent Download PDF

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Publication number
CN104857662A
CN104857662A CN201510274054.1A CN201510274054A CN104857662A CN 104857662 A CN104857662 A CN 104857662A CN 201510274054 A CN201510274054 A CN 201510274054A CN 104857662 A CN104857662 A CN 104857662A
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CN
China
Prior art keywords
percent
grams
foam
fire
betaine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510274054.1A
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Chinese (zh)
Inventor
杨松
彭旻
薛学安
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xiamen Ongoing Fire Technology Co Ltd
Original Assignee
Xiamen Ongoing Fire Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xiamen Ongoing Fire Technology Co Ltd filed Critical Xiamen Ongoing Fire Technology Co Ltd
Priority to CN201510274054.1A priority Critical patent/CN104857662A/en
Publication of CN104857662A publication Critical patent/CN104857662A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • A62D1/0085Foams containing perfluoroalkyl-terminated surfactant

Abstract

The invention discloses a foam extinguishing agent. The foam extinguishing agent is composed of the following components in percentage by mass: 0.5-2.5 percent of perfluoro betaine, 1.7-2.3 percent of fluoroalkyl betaine, 3.2-5.9 percent of urea, 5.1-15.5 percent of modified succinate, 10-15 percent of n-octyl alcohol ether sulfonate, 10-16 percent of alkyl glycoside (0810), 10-20 percent of ethylene glycol, 0.25-0.45 percent of xanthan gum and the balance of water. The invention further discloses application of the foam extinguishing agent. A film generated by the foam extinguishing agent is larger in thickness and higher in stability, the fire extinguishing speed is high, and the fire extinguishing effect is better.

Description

A kind of fire foam
Technical field
The present invention relates to a kind of fire foam.
Background technology
Fire foam can be divided into eggwhite type foam extinguishing chemical and synthetic foam extinguishing chemical by the matrix of synthetic foam.Eggwhite type foam extinguishing chemical mainly contains general proteins fire foam, fluoroprotein foam extinguishing agent, film forming fluoroprotein foam extinguishing agent, anti-molten and membrane proteins alcohol foam extinguishing chemical; Synthetic foam extinguishing chemical mainly contains high-expansion foam extinguishing agent, high, medium and low times of universal foam extinguishing chemical, aqueous film-forming foam extinguishing agent, anti-molten MJPZ extinguishing chemical, category-A fire foam.
In prior art, the thickness of the film that fire foam produces and stability are not strong, will decompose, not reach covering power, and cooling rate is excessively slow 300 DEG C-400 DEG C time, and make blow-off velocity slow, extinguishing effect is poor, easy resume combustion.
Summary of the invention
The object of the present invention is to provide a kind of fire foam, the thickness of its film produced and stability are comparatively strong, and blow-off velocity is fast, and extinguishing effect is better.
For reaching above-mentioned purpose, solution of the present invention is:
A kind of fire foam, be made up of by mass percentage following component: perfluor betaine 0.5%-2.5%, fluorinated alkyl betaine 1.7%-2.3%, urea 3.2%-5.9%, modification succinate 5.1%-15.5%, n-octyl alcohol ether sulfonate 10%-15%, APG (0810) 10%-16%, ethylene glycol 10%-20%, xanthans 0.25%-0.45%, surplus is water.
A kind of application of fire foam, will by mass distribution ratio perfluor betaine 0.5%-2.5%, fluorinated alkyl betaine 1.7%-2.3%, urea 3.2%-5.9%, modification succinate 5.1%-15.5%, n-octyl alcohol ether sulfonate 10%-15%, APG (0810) 10%-16%, ethylene glycol 10%-20%, xanthans 0.25%-0.45%, surplus is that the extinguishing chemical of water composition is mixed with the aqueous solution that mass fraction is 3%.
After adopting such scheme, the thickness of the film that the present invention produces and stability are comparatively strong, and blow-off velocity is fast, and extinguishing effect is better.
Because perfluor betaine, fluorinated alkyl betaine have excellent water and oil repellence and very low surface tension, therefore, when the foam coverage produced is at the pasta burnt, these two materials can drive and spread over equably on pasta rapidly, and these two materials can form thin film, tightly cover on pasta, reach the effect of fire smothering.Its two, perfluor betaine is a kind of amphoteric surfactant, and heat endurance is fine, and have excellent compatibility, 600 DEG C also can not be decomposed, and therefore, the thin film stability that this material is formed is extremely strong.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment one
Take 5 grams of perfluor betaines respectively, 17 grams of fluorinated alkyl betaines, 32 grams of urea, 51 grams of modification succinates, 100 grams of n-octyl alcohol ether sulfonates, 100 grams of APGs (0810), 100 grams of ethylene glycol, 2.5 grams of xanthans, be dissolved in 592.5 grams of running water, high-speed stirred, making it mix and obtaining mass fraction is 3% fire foam, and freezing point AFFF is-32 DEG C.
Described fire foam is mixed with the polymer solution in water that mass fraction is 3%, filling in MSJ950 water base fire extinguishing device, the gasoline fire of the 13B that goes out.Described extinguishing chemical by fire extinguishing device jet to pasta, dense smoke become at once white steam, the intensity of a fire in 6 seconds in controlled, only had very little flare in 8 seconds, extinguished completely in 14 seconds.
Embodiment two
Take 25 grams of perfluor betaines respectively, 23 grams of fluorinated alkyl betaines, 59 grams of urea, 155 grams of modification succinates, 150 grams of n-octyl alcohol ether sulfonates, 160 grams of APGs (0810), 200 grams of ethylene glycol, 4.5 grams of xanthans, be dissolved in 223.5 grams of running water, high-speed stirred, making it mix and obtaining mass fraction is 3% fire foam, and freezing point AFFF is-32 DEG C.
Described fire foam is mixed with the polymer solution in water that mass fraction is 3%, filling in MSJ950 water base fire extinguishing device, the gasoline fire of the 13B that goes out.Described extinguishing chemical by fire extinguishing device jet to pasta, dense smoke become at once white steam, the intensity of a fire in 5 seconds in controlled, only had very little flare in 9 seconds, extinguished completely in 13 seconds.
Embodiment three
Take 15 grams of perfluor betaines respectively, 20 grams of fluorinated alkyl betaines, 44 grams of urea, 105 grams of modification succinates, 120 grams of n-octyl alcohol ether sulfonates, 130 grams of APGs (0810), 140 grams of ethylene glycol, 3.5 grams of xanthans, be dissolved in 422.5 grams of running water, high-speed stirred, making it mix and obtaining mass fraction is 3% fire foam, and freezing point AFFF is-32 DEG C.
Described fire foam is mixed with the polymer solution in water that mass fraction is 3%, filling in MSJ950 water base fire extinguishing device, the gasoline fire of the 8B that goes out.Described extinguishing chemical by fire extinguishing device jet to pasta, dense smoke become at once white steam, the intensity of a fire in 4 seconds in controlled, only had very little flare in 8 seconds, extinguished completely in 10 seconds.
Embodiment four
Take 10 grams of perfluor betaines respectively, 18 grams of fluorinated alkyl betaines, 38 grams of urea, 85 grams of modification succinates, 140 grams of n-octyl alcohol ether sulfonates, 140 grams of APGs (0810), 170 grams of ethylene glycol, 4 grams of xanthans, be dissolved in 395 grams of running water, high-speed stirred, making it mix and obtaining mass fraction is 3% fire foam, and freezing point AFFF is-32 DEG C.
Described fire foam is mixed with the polymer solution in water that mass fraction is 3%, in filling foam maker, by GB15308-2006 requirement go out 144B solvent naphtha fire.Described extinguishing chemical is ejected on the pasta of burning by foam maker, the intensity of a fire in 48 seconds in controlled, only had very little flare in 78 seconds, extinguished completely in 115 seconds.
Fluorinated alkyl betaine uses Shanghai Jiu Shicheng Chemical Co., Ltd., and model is JSC-2168 product; Modification succinate uses the alkyl phenol ether sulfosuccinic acid ester sodium salt of haian Guoli Chemical Co., Ltd. of Jiangsu Province.N-octyl alcohol ether sulfonate uses Guangdong Ming Da Scientific and Technical Industry Co., Ltd, model MD-503 product.Perfluor betaine uses Hubei You Shida Science and Technology Ltd., and model is YF-003.
Be below performance test results of the present invention:
The foregoing is only the preferred embodiments of the present invention, not to the restriction of this case design, all equivalent variations done according to the design key of this case, all fall into the protection domain of this case.

Claims (2)

1. a fire foam, it is characterized in that: be made up of by mass percentage following component: perfluor betaine 0.5%-2.5%, fluorinated alkyl betaine 1.7%-2.3%, urea 3.2%-5.9%, modification succinate 5.1%-15.5%, n-octyl alcohol ether sulfonate 10%-15%, APG (0810) 10%-16%, ethylene glycol 10%-20%, xanthans 0.25%-0.45%, surplus is water.
2. the application of a fire foam, it is characterized in that: will by mass distribution ratio perfluor betaine 0.5%-2.5%, fluorinated alkyl betaine 1.7%-2.3%, urea 3.2%-5.9%, modification succinate 5.1%-15.5%, n-octyl alcohol ether sulfonate 10%-15%, APG (0810) 10%-16%, ethylene glycol 10%-20%, xanthans 0.25%-0.45%, surplus is that the extinguishing chemical of water composition is mixed with the aqueous solution that mass fraction is 3%.
CN201510274054.1A 2015-05-26 2015-05-26 Foam extinguishing agent Pending CN104857662A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510274054.1A CN104857662A (en) 2015-05-26 2015-05-26 Foam extinguishing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510274054.1A CN104857662A (en) 2015-05-26 2015-05-26 Foam extinguishing agent

Publications (1)

Publication Number Publication Date
CN104857662A true CN104857662A (en) 2015-08-26

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Family Applications (1)

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CN201510274054.1A Pending CN104857662A (en) 2015-05-26 2015-05-26 Foam extinguishing agent

Country Status (1)

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CN (1) CN104857662A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105797301A (en) * 2016-04-20 2016-07-27 四川瑞思可消防科技有限公司 Pollution-free water-series extinguishant
CN106492394A (en) * 2016-10-17 2017-03-15 张书源 A kind of extinguishing chemical and preparation method thereof and application
CN107899173A (en) * 2017-11-24 2018-04-13 靖江市新东机械零部件制造有限公司 A kind of alcohol foam extinguishing chemical of continuous-stable
CN108211192A (en) * 2018-03-29 2018-06-29 李波 A kind of environment-friendly high-efficiency extinguishing chemical and preparation method thereof
CN111420339A (en) * 2020-03-24 2020-07-17 杭州辚萧科技有限公司 Anti-dissolution foam extinguishing agent and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1413749A (en) * 2002-12-04 2003-04-30 中国石油化工股份有限公司 Foam extingusher with covering function
CN101366999A (en) * 2007-08-15 2009-02-18 中瑞华特(北京)高新技术开发有限公司 Water system extinguishing agent
CN103380208A (en) * 2011-02-24 2013-10-30 巴斯夫欧洲公司 Compositions comprising alkylalkoxysulfonates for the production of high temperature stable foams
CN103520870A (en) * 2013-10-17 2014-01-22 中国人民武装警察部队学院 Multifunctional water-based extinguishing agent and preparation method thereof
CN104606837A (en) * 2015-02-16 2015-05-13 杨光 Universal fire extinguishing agent and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1413749A (en) * 2002-12-04 2003-04-30 中国石油化工股份有限公司 Foam extingusher with covering function
CN101366999A (en) * 2007-08-15 2009-02-18 中瑞华特(北京)高新技术开发有限公司 Water system extinguishing agent
CN103380208A (en) * 2011-02-24 2013-10-30 巴斯夫欧洲公司 Compositions comprising alkylalkoxysulfonates for the production of high temperature stable foams
CN103520870A (en) * 2013-10-17 2014-01-22 中国人民武装警察部队学院 Multifunctional water-based extinguishing agent and preparation method thereof
CN104606837A (en) * 2015-02-16 2015-05-13 杨光 Universal fire extinguishing agent and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105797301A (en) * 2016-04-20 2016-07-27 四川瑞思可消防科技有限公司 Pollution-free water-series extinguishant
CN105797301B (en) * 2016-04-20 2019-01-29 四川瑞思可消防科技有限公司 A kind of pollution-free water-based extinguishing agent
CN106492394A (en) * 2016-10-17 2017-03-15 张书源 A kind of extinguishing chemical and preparation method thereof and application
CN107899173A (en) * 2017-11-24 2018-04-13 靖江市新东机械零部件制造有限公司 A kind of alcohol foam extinguishing chemical of continuous-stable
CN108211192A (en) * 2018-03-29 2018-06-29 李波 A kind of environment-friendly high-efficiency extinguishing chemical and preparation method thereof
CN111420339A (en) * 2020-03-24 2020-07-17 杭州辚萧科技有限公司 Anti-dissolution foam extinguishing agent and application thereof

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Application publication date: 20150826