CN104849784A - Light storage film without white reflective layer and manufacturing technology - Google Patents

Light storage film without white reflective layer and manufacturing technology Download PDF

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Publication number
CN104849784A
CN104849784A CN201510215749.2A CN201510215749A CN104849784A CN 104849784 A CN104849784 A CN 104849784A CN 201510215749 A CN201510215749 A CN 201510215749A CN 104849784 A CN104849784 A CN 104849784A
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CN
China
Prior art keywords
layer
photosphere
film
store
light storage
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Pending
Application number
CN201510215749.2A
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Chinese (zh)
Inventor
任旭林
罗荣祥
程明
李本都
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SICHUAN ZHONGKE BETTER TECHNOLOGY Co Ltd
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SICHUAN ZHONGKE BETTER TECHNOLOGY Co Ltd
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Priority to CN201510215749.2A priority Critical patent/CN104849784A/en
Publication of CN104849784A publication Critical patent/CN104849784A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/0808Mirrors having a single reflecting layer
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F13/00Illuminated signs; Luminous advertising
    • G09F13/20Illuminated signs; Luminous advertising with luminescent surfaces or parts

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Optics & Photonics (AREA)
  • Laminated Bodies (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

The invention relates to a light storage film without a white reflective layer, comprising a surface layer (1), a light storage layer (2), a reflective layer (3) and a release layer (5), wherein the surface layer (1) is arranged on the upper surface of the light storage layer (2), the reflective layer (3) is plated on the lower surface of the light storage layer (2), the release layer (5) is arranged on the lower side of the reflective layer (3), a back glue layer (4) is arranged between the release layer (5) and the reflective layer (3), and the reflective layer (3) is an aluminum film of which the thickness is 200-1200 tenthmeters. The manufacturing steps include: S1, pre-preparation; S2, preparing the light storage layer (2); S3, vacuum aluminum plating; and S4, final forming. The light storage film has the following advantages: the reflective layer is formed by vacuum aluminum plating which is a physical method, so that the light storage film is more environment-friendly; the processing speed can reach 80-200m/min; and the cost is 0.15-0.4yuan/square meter, and the production cost is low.

Description

A kind ofly store light film and manufacturing process thereof without white Reflection layer
Technical field
The present invention relates to and store light film production technical field, particularly a kind ofly store light film and manufacturing process thereof without white Reflection layer.
Background technology
Storing light film is that macromolecular material and light-accumulating powder combine, and adopts the technique extruded or be coated with, becomes certain thickness film.Wide sending out is applied to the fields such as subway, market, high building escape way, number, plays the effect of expressing, instructing in the dark.Popularly at present store light film, primary structure is: surface layer, stores photosphere, reflection horizon, adhesive layer and backing paper.According to the difference of use occasion, what have does not have surface layer, and some adhesive layers are storing before photosphere, forms anti-subsides and stores light film.But storing photosphere and reflection horizon is form the most basic structure storing light film.The composition storing photosphere comprises macromolecular material and light-accumulating powder, can be manufactured by the mode extruded or be coated with, reflection horizon is then passed through at the back side storing photosphere, coating or laminating one deck 10 ~ 50 μm white film and formed, what reflection horizon adopted is white inorganic material and high molecule plastic, the effect in reflection horizon is to reflect the twilight sunset storing photosphere, increases brightness.
Above explained hereafter store light film, have a white reflecting layer significantly formed by the mode being coated with or bonding, propose the brightness of high performance film.The inorganic material of the general adularescent in reflection horizon of white, such as titanium dioxide etc., mix with macromolecular material.As storing the requisite structure composition of light film, certain thickness must be had, just can play the effect of reflection of being in the light; The mode of the white layer that coating or bonding have been extruded can form certain organic solvent volatilization, does not meet the trend of current environmental protection, and finite rate, speed of production is at 5 ~ 15m/min, and material cost is also higher, and cost is at 1 ~ 5 yuan/square metre.
Summary of the invention
The object of the invention is to the shortcoming overcoming prior art, provide that a kind of environmental protection, production efficiency are high, production cost is low without white Reflection layer stores light film and manufacturing process thereof.
Object of the present invention is achieved through the following technical solutions: a kind ofly store light film without white Reflection layer, it comprises surface layer, store photosphere, reflector layer and release layer, described surface layer is arranged at the upper surface storing photosphere, described reflector layer is plated on and stores on the lower surface of photosphere, the downside of reflector layer is provided with release layer, is also provided with gum layer between described release layer and reflector layer.
Described reflector layer is the aluminium film of thickness between 200 ~ 1200.
Without the manufacturing process storing light film of white Reflection layer, comprise the following steps:
S1, front preparation: apply surface layer on the surface in PET base material, the thickness of surface layer is 0 ~ 70 μm;
S2, preparation store photosphere: by long persistence light storage powder and resin according to the ratio of 0.1 ~ 10:1, mix, by extrude or coating processes obtain on surface layer thickness be 10 ~ 500 μm store photosphere;
S3, vacuum aluminum-coated: to move to take-up type vacuum aluminize in the sealed chamber of equipment by storing photosphere, be pumped into 0.01 ~ 0.1 atmospheric vacuum, by evaporation boat heated high-purity aluminium wire, aluminium wire is made to form gasification aluminium, and be deposited on to be wound in chill roll cylinder stores on the film surface of photosphere, form the aluminium film that thickness is 200 ~ 1200, what obtain being coated with reflector layer stores photosphere;
S4, final molding: on release layer 5, glue-spreading layer 4, is compounded in after drying on the back side of reflector layer 3, obtains product.
In step S2, described resin is one or more the potpourri in acrylate resin, Corvic, vibrin, vinyl chloride-vinyl acetate resin, urethane resin.
In step S2, the specification of described long persistence light storage powder is between 100 ~ 450 orders.
In described step S4, after compound release layer, also comprise the step of a stripping PET base material.
The present invention has the following advantages:
1, to be aluminized equipment by take-up type vacuum, in sealed chamber, be pumped into 0.01 ~ 0.1 following vacuum of atmospheric pressure, by evaporation boat heated high-purity aluminium wire, form gasification aluminium, be deposited on and store photosphere film surface by chill roll, belong to physical method, pollution-free, the more environmental protection when producing and use.
2, high-purity aluminium wire directly melts and forms gasification aluminium by vacuum aluminium plating process, is deposited on and stores photosphere surface, store photosphere and reflection horizon faster in conjunction with speed, better, process velocity can reach 80 ~ 200m/min, can increase substantially the production efficiency storing light film.
3, storing production reflection horizon on photosphere by vacuum aluminum-coated membrane process, its cost, between 0.15 ~ 0.4 yuan/square metre, reduces by more than 10 times compared to the cost of traditional handicraft.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
In figure: 1-surface layer, 2-stores photosphere, 3-reflector layer, 4-gum layer, 5-release layer.
Embodiment
Below in conjunction with drawings and Examples, the present invention will be further described, but protection scope of the present invention is not limited to the following stated.
[embodiment 1]:
As shown in Figure 1, a kind ofly store light film without white Reflection layer, it comprises surface layer 1, store photosphere 2, reflector layer 3 and release layer 5, described surface layer 1 is arranged at the upper surface storing photosphere 2, described reflector layer 3 be plated on store photosphere 2 lower surface on, the downside of reflector layer 3 is provided with release layer 5, is also provided with gum layer 4 between described release layer 5 and reflector layer 3.
Described reflector layer 3 is the aluminium film of thickness between 200 ~ 1200.
Without the manufacturing process storing light film of white Reflection layer, comprise the following steps:
S1, front preparation: apply surface layer 1 on the surface in PET base material, the thickness of surface layer 1 is 70 μm;
S2, preparation store photosphere 2: by long persistence light storage powder and the resin ratio according to 0.1:1, the specification of described long persistence light storage powder is 100 orders, described resin is one or more the potpourri in acrylate resin, Corvic, vibrin, vinyl chloride-vinyl acetate resin, urethane resin, mix, by extrude or coating processes obtain on surface layer 1 thickness be 10 μm store photosphere 2;
S3, vacuum aluminum-coated: to move to take-up type vacuum aluminize in the sealed chamber of equipment by storing photosphere 2, be pumped into 0.01 atmospheric vacuum, by evaporation boat heated high-purity aluminium wire, aluminium wire is made to form gasification aluminium, and be deposited on the film surface storing photosphere 2 that is wound on chill roll cylinder, form the aluminium film that thickness is 200, what obtain being coated with reflector layer 3 stores photosphere 2;
S4, final molding: on release layer 5, glue-spreading layer 4, is compounded on the back side of reflector layer 3 after drying, peel off PET base material, obtain product.
That is produced by this embodiment stores light film, and speed of production is 90m/min, reflector layer 3 production cost about 0.4 yuan/square metre.
[embodiment 2]:
Its structure is with embodiment 1.
Without the manufacturing process storing light film of white Reflection layer, comprise the following steps:
S1, front preparation: apply surface layer 1 on the surface in PET base material, the thickness of surface layer 1 is 35 μm;
S2, preparation store photosphere 2: by long persistence light storage powder and the resin ratio according to 5:1, the specification of described long persistence light storage powder is 250 orders, described resin is one or more the potpourri in acrylate resin, Corvic, vibrin, vinyl chloride-vinyl acetate resin, urethane resin, mix, by extrude or coating processes obtain on surface layer 1 thickness be 250 μm store photosphere 2;
S3, vacuum aluminum-coated: to move to take-up type vacuum aluminize in the sealed chamber of equipment by storing photosphere 2, be pumped into 0.06 atmospheric vacuum, by evaporation boat heated high-purity aluminium wire, aluminium wire is made to form gasification aluminium, and be deposited on the film surface storing photosphere 2 that is wound on chill roll cylinder, form the aluminium film that thickness is 650, what obtain being coated with reflector layer 3 stores photosphere 2;
S4, final molding: on release layer 5, glue-spreading layer 4, is compounded on the back side of reflector layer 3 after drying, peel off PET base material, obtain product.
That is produced by this embodiment stores light film, and speed of production is 200m/min, reflector layer 3 production cost about 0.15 yuan/square metre.
[embodiment 3]:
Its structure is with embodiment 1.
Without the manufacturing process storing light film of white Reflection layer, comprise the following steps:
S1, front preparation: apply surface layer 1 on the surface in PET base material, the thickness of surface layer 1 is 0 μm, does not namely apply surface layer 1 on the surface in PET base material;
S2, preparation store photosphere 2: by long persistence light storage powder and the resin ratio according to 10:1, the specification of described long persistence light storage powder is 450 orders, described resin is one or more the potpourri in acrylate resin, Corvic, vibrin, vinyl chloride-vinyl acetate resin, urethane resin, mix, by extrude or coating processes obtain in PET base material thickness be 500 μm store photosphere 2;
S3, vacuum aluminum-coated: to move to take-up type vacuum aluminize in the sealed chamber of equipment by storing photosphere 2, be pumped into 0.1 atmospheric vacuum, by evaporation boat heated high-purity aluminium wire, aluminium wire is made to form gasification aluminium, and be deposited on the film surface storing photosphere 2 that is wound on chill roll cylinder, form the aluminium film that thickness is 1200, what obtain being coated with reflector layer 3 stores photosphere 2;
S4, final molding: on release layer 5, glue-spreading layer 4, is compounded on the back side of reflector layer 3 after drying, peel off PET base material, obtain product.
That is produced by this embodiment stores light film, and speed of production is 80m/min, reflector layer 3 production cost about 0.3 yuan/square metre.
[embodiment 4]:
Its structure is with embodiment 1.
Without the manufacturing process storing light film of white Reflection layer, comprise the following steps:
S1, front preparation: apply surface layer 1 on the surface in PET base material, the thickness of surface layer 1 is 0 μm, does not namely apply surface layer 1 on the surface in PET base material;
S2, preparation store photosphere 2: by long persistence light storage powder and the resin ratio according to 10:1, the specification of described long persistence light storage powder is 450 orders, described resin is one or more the potpourri in acrylate resin, Corvic, vibrin, vinyl chloride-vinyl acetate resin, urethane resin, mix, by extruding or coating processes, by PET base material as surface layer 1, directly obtain in PET base material thickness be 500 μm store photosphere 2;
S3, vacuum aluminum-coated: to move to take-up type vacuum aluminize in the sealed chamber of equipment by storing photosphere 2, be pumped into 0.1 atmospheric vacuum, by evaporation boat heated high-purity aluminium wire, aluminium wire is made to form gasification aluminium, and be deposited on the film surface storing photosphere 2 that is wound on chill roll cylinder, form the aluminium film that thickness is 1200, what must be coated with reflector layer 3 stores photosphere 2;
S4, final molding: on release layer 5, glue-spreading layer 4, is compounded in after drying on the back side of reflector layer 3, does not peel off PET base material, obtain product.
That is produced by this embodiment stores light film, and speed of production is 80m/min, reflector layer 3 production cost about 0.3 yuan/square metre.

Claims (6)

1. one kind stores light film without white Reflection layer, it is characterized in that: it comprises surface layer (1), stores photosphere (2), reflector layer (3) and release layer (5), described surface layer (1) is arranged at the upper surface storing photosphere (2), described reflector layer (3) be plated on store photosphere (2) lower surface on, the downside of reflector layer (3) is provided with release layer (5), is also provided with gum layer (4) between described release layer (5) and reflector layer (3).
2. according to claim 1ly a kind ofly store light film without white Reflection layer, it is characterized in that: described reflector layer (3) is the aluminium film of thickness between 200 ~ 1200.
3. a kind of manufacturing process storing light film without white Reflection layer as claimed in claim 1, is characterized in that: it comprises the following steps:
S1, front preparation: apply surface layer (1) on the surface in PET base material, the thickness of surface layer (1) is 0 ~ 70 μm;
S2, preparation store photosphere (2): by long persistence light storage powder and resin according to the ratio of 0.1 ~ 10:1, mix, by extrude or coating processes obtain on surface layer (1) thickness be 10 ~ 500 μm store photosphere (2);
S3, vacuum aluminum-coated: photosphere (2) will to be stored and move to take-up type vacuum and aluminize in the sealed chamber of equipment, be pumped into 0.01 ~ 0.1 atmospheric vacuum, by evaporation boat heated high-purity aluminium wire, aluminium wire is made to form gasification aluminium, and be deposited on the film surface storing photosphere (2) that is wound on chill roll cylinder, form the aluminium film that thickness is 200 ~ 1200, what obtain being coated with reflector layer (3) stores photosphere (2);
S4, final molding: on release layer 5, glue-spreading layer 4, is compounded in after drying on the back side of reflector layer 3, obtains product.
4. according to claim 3ly a kind ofly store light film and manufacturing process thereof without white Reflection layer, it is characterized in that: in step S1, described resin is one or more the potpourri in acrylate resin, Corvic, vibrin, vinyl chloride-vinyl acetate resin, urethane resin, amino resins, isocyanate resin.
5. according to claim 3ly a kind ofly store light film and manufacturing process thereof without white Reflection layer, it is characterized in that: in step S1, the specification of described long persistence light storage powder is between 100 ~ 450 orders.
6. according to claim 3ly a kind ofly store light film and manufacturing process thereof without white Reflection layer, it is characterized in that: in described step S4, after compound release layer (5), also comprise the step of a stripping PET base material.
CN201510215749.2A 2015-04-30 2015-04-30 Light storage film without white reflective layer and manufacturing technology Pending CN104849784A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107272263A (en) * 2017-08-23 2017-10-20 京东方科技集团股份有限公司 A kind of array base palte, display panel and display device
CN110033716A (en) * 2019-04-26 2019-07-19 泉州市夜景辉反光材料有限公司 A kind of light storage film and preparation method thereof
CN111511541A (en) * 2017-12-19 2020-08-07 鹤卷京彦 Sheet member
CN112259014A (en) * 2020-11-23 2021-01-22 国网江苏省电力有限公司泰州供电分公司 Self-adhesive light-storing luminous label for high-voltage bare wire

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CN103149613A (en) * 2013-03-28 2013-06-12 四川中科倍特尔技术有限公司 Novel lens-embedded type reflective membrane and manufacturing method thereof
CN103592707A (en) * 2013-11-13 2014-02-19 浙江方远夜视丽反光材料有限公司 Light-storage flame-retardant reflective stripe
JP2014232157A (en) * 2013-05-28 2014-12-11 コニカミノルタ株式会社 Reflection member, manufacturing method of the same, and surface light emission unit
CN204705734U (en) * 2015-04-30 2015-10-14 四川中科倍特尔技术有限公司 A kind ofly store light film without white Reflection layer

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CN204705734U (en) * 2015-04-30 2015-10-14 四川中科倍特尔技术有限公司 A kind ofly store light film without white Reflection layer

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107272263A (en) * 2017-08-23 2017-10-20 京东方科技集团股份有限公司 A kind of array base palte, display panel and display device
CN107272263B (en) * 2017-08-23 2021-01-22 京东方科技集团股份有限公司 Array substrate, display panel and display device
CN111511541A (en) * 2017-12-19 2020-08-07 鹤卷京彦 Sheet member
CN110033716A (en) * 2019-04-26 2019-07-19 泉州市夜景辉反光材料有限公司 A kind of light storage film and preparation method thereof
CN112259014A (en) * 2020-11-23 2021-01-22 国网江苏省电力有限公司泰州供电分公司 Self-adhesive light-storing luminous label for high-voltage bare wire

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Application publication date: 20150819