CN104845502A - Coating composition for wear-resistant and scratch-resistant coating - Google Patents

Coating composition for wear-resistant and scratch-resistant coating Download PDF

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Publication number
CN104845502A
CN104845502A CN201510269986.7A CN201510269986A CN104845502A CN 104845502 A CN104845502 A CN 104845502A CN 201510269986 A CN201510269986 A CN 201510269986A CN 104845502 A CN104845502 A CN 104845502A
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parts
formic acid
coating
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CN104845502B (en
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李亮军
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Jiangmen Dongyang Ink Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/103Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/08Oxygen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/10Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/16Solid spheres
    • C08K7/18Solid spheres inorganic
    • C08K7/20Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a coating composition for a wear-resistant and scratch-resistant coating. The coating composition contains specific modified nano-aluminium oxide powder and modified nano-titanium dioxide powder; by using the surface-modified nano powder, the strength and the toughness of the coating can be effectively improved; in addition, the coating also contains potassium titanate whisker and silicon carbide whisker; by combining the potassium titanate whisker and the silicon carbide whisker, the hardness, the strength and the wear resistance of the coating can be effectively improved; the coating composition disclosed by the invention has the advantages of being convenient for construction, and obvious social benefit and economic benefit; properties of coatings formed on the surfaces of timber, a density board, metal, glass and ceramic are excellent.

Description

A kind of wear-resisting scratch-resistant coating material composition
Technical field
The present invention relates to a kind of wear-resisting scratch-resistant coating material composition and method of making the same, be specifically related to comprise modified Nano aluminium sesquioxide and nano titanium oxide, and the coating composition of potassium titanate crystal whisker and silicon carbide whisker and preparation method thereof.
Background technology
Ultraviolet-curing paint is a kind of pollution-free, resource-saving, less energy-consumption, safe and reliable high-tech green environment friendly coating, its society and environmental benefit huge.Under day by day harsh environmental requirement, this technology obtains unprecedented development, has been widely used in the industries such as electronic material encapsulation, plastic part surface protection, timber floor glazing, the repairing of automobile small area.This product meets world's material technology trend, is coating circle new growth point, and huge fund research and development are just competitively thrown in countries in the world.China's application for floor coating material solidified more than the UV of 70% sales volume, and also there is many problems in the wear resistance of current ultra-violet curing Floor paint, study a kind of ultraviolet-curing paint being applied to the surfaces such as timber, density board, pottery, be the target that domestic and international coating circle is pursued to improve the wear resistance on the surfaces such as timber, density board, pottery comprehensively always.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of UV curable is provided and there is excellent scratch resistant, the coating of rub.
The present invention is achieved through the following technical solutions above-mentioned purpose:
A kind of wear-resisting scratch-resistant coating material composition, this coating is prepared from by following steps:
A aluminium sesquioxide powder that () gets 20-50nm adds in container, then add the mixing solutions of Virahol and toluene, wherein the mass ratio of toluene and Virahol is 13:7, dispersed with stirring 60 minutes at 25 DEG C, then add 3-(methacryloxy) propyl trimethoxy silicane and formic acid, 50 DEG C of stirring reaction 2h, then add ethyl triethoxysilane and formic acid again, 50 DEG C of stirring reaction 2h, 3-(methacryloxy) propyl trimethoxy silicane wherein added, the mol ratio of ethyl triethoxysilane and total formic acid is 1:1:2, be cooled to room temperature, filter, obtain modified Nano aluminium sesquioxide powder,
B titanium dioxide powder that () gets 20-50nm adds in container, then add the mixing solutions of Virahol and toluene, wherein the mass ratio of toluene and Virahol is 10:7, dispersed with stirring 30 minutes at 30 DEG C, then add 3-(methacryloxy) propyl trimethoxy silicane and formic acid, 50 DEG C of stirring reaction 1h, then add ethyl triethoxysilane and formic acid again, 50 DEG C of stirring reaction 2h, 3-(methacryloxy) propyl trimethoxy silicane wherein added, the mol ratio of ethyl triethoxysilane and total formic acid is 1:1:2, be cooled to room temperature, filter, obtain modified nano-titanium dioxide powder,
C () is with weight parts, get vinyl ester resin 30 parts, neopentylglycol diacrylate 20 parts, thioxanthone 5 parts of mix and blend 1-2 hour, then add the modified Nano aluminium sesquioxide powder 7 parts that step a) is obtained successively, the modified nano-titanium dioxide powder 7 parts that step b) is obtained, potassium titanate crystal whisker 2 parts, silicon carbide whisker 1 part, urn glass microballon 2 parts, dispersion agent 2 parts, defoamer 2 parts, flow agent, 1.5 parts, anti-settling agent 2 parts, and appropriate solvent, dispersed with stirring is even, and packaging, obtains coating composition finished product.
Wherein, the filtration in described step (a) adopts paint filter to filter.
Wherein, the aluminium sesquioxide granularity in described step (a) is 25-40nm, and in step (b), titanium dioxide coarseness is 25-40nm.
Wherein, the consumption of the solvent in described step (c) is 25 weight parts.
beneficial effect
Specific modified Nano aluminium sesquioxide powder and modified nano-titanium dioxide powder is comprised in coating of the present invention, intensity and the toughness of coating effectively can be improved through the above-mentioned nano-powder of surface modification, in addition, also comprise potassium titanate crystal whisker and silicon carbide whisker in coating, the combination of the two effectively can improve the hardness of coating, intensity and wear resistance.Coating composition easy construction of the present invention, the coating performance formed at timber, density board, metal, glass, ceramic surface is excellent, has obvious social benefit and economic benefit.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated, but embodiments of the present invention are not limited thereto.
embodiment 1
The aluminium sesquioxide powder getting 30-40nm adds in container, then add the mixing solutions of Virahol and toluene, wherein the mass ratio of toluene and Virahol is 13:7, dispersed with stirring 60 minutes at 25 DEG C, then add 3-(methacryloxy) propyl trimethoxy silicane and formic acid, 50 DEG C of stirring reaction 2h, then add ethyl triethoxysilane and formic acid again, 50 DEG C of stirring reaction 2h, 3-(methacryloxy) propyl trimethoxy silicane wherein added, the mol ratio of ethyl triethoxysilane and total formic acid is 1:1:2, be cooled to room temperature, filter, obtain modified Nano aluminium sesquioxide powder.
The titanium dioxide powder getting 30-40nm adds in container, then add the mixing solutions of Virahol and toluene, wherein the mass ratio of toluene and Virahol is 10:7, dispersed with stirring 30 minutes at 30 DEG C, then add 3-(methacryloxy) propyl trimethoxy silicane and formic acid, 50 DEG C of stirring reaction 1h, then add ethyl triethoxysilane and formic acid again, 50 DEG C of stirring reaction 2h, 3-(methacryloxy) propyl trimethoxy silicane wherein added, the mol ratio of ethyl triethoxysilane and total formic acid is 1:1:2, be cooled to room temperature, filter, obtain modified nano-titanium dioxide powder.
With weight parts, get vinyl ester resin 30 parts, neopentylglycol diacrylate 20 parts, thioxanthone 5 parts mixing, then adds the modified Nano aluminium sesquioxide powder 7 parts that step a) is obtained successively, the modified nano-titanium dioxide powder 7 parts that step b) is obtained, potassium titanate crystal whisker 2 parts, silicon carbide whisker 1 part, urn glass microballon 2 parts, dispersion agent 2 parts, defoamer 2 parts, flow agent, 1.5 parts, anti-settling agent 2 parts, and solvent 25 parts, dispersed with stirring is even, and packaging, obtains coating composition finished product.
comparative example 1
With weight parts, get vinyl ester resin 30 parts, neopentylglycol diacrylate 20 parts, thioxanthone 5 parts mixing, then adds nano-aluminium oxide powder 7 parts successively, nano-titanium dioxide powder 7 parts, potassium titanate crystal whisker 2 parts, silicon carbide whisker 1 part, urn glass microballon 2 parts, dispersion agent 2 parts, defoamer 2 parts, flow agent, 1.5 parts, anti-settling agent 2 parts, and solvent 25 parts, dispersed with stirring is even, and packaging, obtains coating composition finished product.
comparative example 2
With weight parts, get vinyl ester resin 30 parts, neopentylglycol diacrylate 20 parts, thioxanthone 5 parts mixing, then adds the modified Nano aluminium sesquioxide powder 7 parts that step a) is obtained successively, the modified nano-titanium dioxide powder 7 parts that step b) is obtained, urn glass microballon 2 parts, dispersion agent 2 parts, defoamer 2 parts, flow agent, 1.5 parts, anti-settling agent 2 parts, and solvent 25 parts, dispersed with stirring is even, and packaging, obtains coating composition finished product.
Measurement of hardness carries out according to GB/T6739-1996 herein.Shock-resistance measures according to GB/T1720-1993.Snappiness is tested according to GB/T6742-86.
Test each film, result is as follows:
Test item Thickness (μm) Pencil hardness Shock resistance Snappiness
Embodiment 1 15 6H Pass through ≤3mm
Comparative example 1 15 5H Do not pass through ≤5mm
Comparative example 2 15 4H Do not pass through ≤3mm

Claims (4)

1. a wear-resisting scratch-resistant coating material composition, it is characterized in that, this coating is prepared from by following steps:
A aluminium sesquioxide powder that () gets 20-50nm adds in container, then add the mixing solutions of Virahol and toluene, wherein the mass ratio of toluene and Virahol is 13:7, dispersed with stirring 60 minutes at 25 DEG C, then add 3-(methacryloxy) propyl trimethoxy silicane and formic acid, 50 DEG C of stirring reaction 2h, then add ethyl triethoxysilane and formic acid again, 50 DEG C of stirring reaction 2h, 3-(methacryloxy) propyl trimethoxy silicane wherein added, the mol ratio of ethyl triethoxysilane and total formic acid is 1:1:2, be cooled to room temperature, filter, obtain modified Nano aluminium sesquioxide powder,
B titanium dioxide powder that () gets 20-50nm adds in container, then add the mixing solutions of Virahol and toluene, wherein the mass ratio of toluene and Virahol is 10:7, dispersed with stirring 30 minutes at 30 DEG C, then add 3-(methacryloxy) propyl trimethoxy silicane and formic acid, 50 DEG C of stirring reaction 1h, then add ethyl triethoxysilane and formic acid again, 50 DEG C of stirring reaction 2h, 3-(methacryloxy) propyl trimethoxy silicane wherein added, the mol ratio of ethyl triethoxysilane and total formic acid is 1:1:2, be cooled to room temperature, filter, obtain modified nano-titanium dioxide powder,
C () is with weight parts, get vinyl ester resin 30 parts, neopentylglycol diacrylate 20 parts, thioxanthone 5 parts waits mix and blend 1-2 hour, then adds the modified Nano aluminium sesquioxide powder 7 parts that step a) is obtained successively, the modified nano-titanium dioxide powder 7 parts that step b) is obtained, potassium titanate crystal whisker 2 parts, silicon carbide whisker 1 part, urn glass microballon 2 parts, dispersion agent 2 parts, defoamer 2 parts, flow agent, 1.5 parts, anti-settling agent 2 parts, and appropriate solvent, dispersed with stirring is even, and packaging, obtains coating composition finished product.
2. wear-resisting scratch-resistant coating material composition as claimed in claim 1, is characterized in that: filter described in step (a) and adopt paint filter to filter.
3. wear-resisting scratch-resistant coating material composition as claimed in claim 1, is characterized in that: the granularity of aluminium sesquioxide described in step (a) is about 25-40nm, and in step (b), titanium dioxide coarseness is about 25-40nm.
4. wear-resisting scratch-resistant coating material composition as claimed in claim 1, is characterized in that: the consumption of solvent described in step (c) is 25 weight parts.
CN201510269986.7A 2015-05-26 2015-05-26 Coating composition for wear-resistant and scratch-resistant coating Expired - Fee Related CN104845502B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105924381A (en) * 2015-12-18 2016-09-07 重庆两江药物研发中心有限公司 Method for preparing pimavanserin crystal form C
CN105967661A (en) * 2016-04-22 2016-09-28 宁波高新区夏远科技有限公司 Antibacterial ceramic coating layer for non-stick pan and preparation method thereof, and non-stick pan
CN107216727A (en) * 2017-06-14 2017-09-29 南京工业大学 A kind of normal temperature cure FEVE fluorocarbon resin wear-resistant paints and preparation method thereof
CN107446407A (en) * 2017-09-26 2017-12-08 广东昭信照明科技有限公司 A kind of method of ceramic powder surface modification
CN110549437A (en) * 2019-10-09 2019-12-10 上海如晶新材料科技有限公司 production process of yellowing-resistant wood veneer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1772820A (en) * 2004-11-10 2006-05-17 比亚迪股份有限公司 Ultraviolet cured paint for plastics and its production process
WO2011152404A1 (en) * 2010-06-01 2011-12-08 リケンテクノス株式会社 Composition for use as coating material and adhesive, method for adhesive bonding, and laminated products
CN103483890A (en) * 2013-09-12 2014-01-01 西安交通大学 Polymer ice-coating-preventing coating containing modified nano particles and preparing method thereof
CN104231917A (en) * 2014-10-13 2014-12-24 北京国泰瑞华精藻硅特种材料有限公司 Nanometer high temperature resistant thermal insulation and prevention coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1772820A (en) * 2004-11-10 2006-05-17 比亚迪股份有限公司 Ultraviolet cured paint for plastics and its production process
WO2011152404A1 (en) * 2010-06-01 2011-12-08 リケンテクノス株式会社 Composition for use as coating material and adhesive, method for adhesive bonding, and laminated products
CN103483890A (en) * 2013-09-12 2014-01-01 西安交通大学 Polymer ice-coating-preventing coating containing modified nano particles and preparing method thereof
CN104231917A (en) * 2014-10-13 2014-12-24 北京国泰瑞华精藻硅特种材料有限公司 Nanometer high temperature resistant thermal insulation and prevention coating

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105924381A (en) * 2015-12-18 2016-09-07 重庆两江药物研发中心有限公司 Method for preparing pimavanserin crystal form C
CN105924381B (en) * 2015-12-18 2019-04-16 重庆两江药物研发中心有限公司 A kind of preparation method of piperazine Ma Selin crystal form C
CN105967661A (en) * 2016-04-22 2016-09-28 宁波高新区夏远科技有限公司 Antibacterial ceramic coating layer for non-stick pan and preparation method thereof, and non-stick pan
CN107216727A (en) * 2017-06-14 2017-09-29 南京工业大学 A kind of normal temperature cure FEVE fluorocarbon resin wear-resistant paints and preparation method thereof
CN107446407A (en) * 2017-09-26 2017-12-08 广东昭信照明科技有限公司 A kind of method of ceramic powder surface modification
CN107446407B (en) * 2017-09-26 2021-04-16 广东昭信照明科技有限公司 Method for modifying surface of ceramic powder
CN110549437A (en) * 2019-10-09 2019-12-10 上海如晶新材料科技有限公司 production process of yellowing-resistant wood veneer

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