CN104844891A - Extruded colored segmentation line for building scaffold skirting lines and preparation method thereof - Google Patents

Extruded colored segmentation line for building scaffold skirting lines and preparation method thereof Download PDF

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Publication number
CN104844891A
CN104844891A CN201510170949.0A CN201510170949A CN104844891A CN 104844891 A CN104844891 A CN 104844891A CN 201510170949 A CN201510170949 A CN 201510170949A CN 104844891 A CN104844891 A CN 104844891A
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China
Prior art keywords
parts
building scaffold
skirting board
antioxidant
color segmentation
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Pending
Application number
CN201510170949.0A
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Chinese (zh)
Inventor
邢元进
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JIANGSU TAYE NEW MATERIAL TECHNOLOGY Co Ltd
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JIANGSU TAYE NEW MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201510170949.0A priority Critical patent/CN104844891A/en
Publication of CN104844891A publication Critical patent/CN104844891A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/22Halogen free composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses an extruded colored segmentation line for building scaffold skirting lines and a preparation method thereof. The segmentation line comprises the following components: 20-35 parts of polyethylene resin, 10-20 parts of a light stabilizer, 10-25 parts of a filler, 3-5 parts of a compatilizer, 1-2 parts of an antioxidant, 15-25 parts of a flame retardant, 1-2 parts of a coupling agent, 0.5-1 part of a plasticizer, 3-5 parts of an anti-aging agent, 10-15 parts of a pigment, 5-8 parts of an antistatic agent, and 2-4 parts of a dispersing agent. The preparation method includes: blending the components by weight ratio, then adding the mixture into a high-speed mixer or ultrasonic generator to conduct mixing, then adding the well mixed materials into a double-screw extruder to carry out melt blending, extrusion and packaging. The line provided by the invention has clear color, low smoke and no halogen, no toxicity and no odor, a specification of 250mm*0.2mm and arbitrary length, and has the advantages of recyclability, excellent flame retardance, aging resistance, anti-static performance, and simple preparation process.

Description

Building scaffold skirting board is with extruding Color Segmentation lines and preparation method thereof
Technical field
The present invention relates to a kind of preparation method splitting lines, being specifically related to a kind of building scaffold skirting board with extruding Color Segmentation lines and preparation method thereof.
Background technology
Generally to carry out above building scaffold pasting red, white or black, the yellow alternate isolation colour bar of plank, warn and mark effect.Current colour bar generally adopts the colour bar of adhesive type to carry out being pasted onto on scaffolding skirting board, and because duration of service is elongated, this stickup is not too strong, is easy to drop and aging, has a strong impact on work-ing life.
Summary of the invention
Goal of the invention: the present invention is directed to deficiency of the prior art, proposes the good and building scaffold skirting board that can be recycled of a kind of ageing resistance with extruding Color Segmentation lines and preparation method thereof.
Technical scheme: a kind of building scaffold skirting board of the present invention, with extruding Color Segmentation lines, comprises the component of following mass parts:
Polyvinyl resin 20-35 part
Photostabilizer 10-20 part
Weighting agent 10-25 part
Compatilizer 3-5 part
Oxidation inhibitor 1-2 part
Fire retardant 15-25 part
Coupling agent 1-2 part
Softening agent 0.5-1 part
Antiaging agent 3-5 part
Pigment 10-15 part
Static inhibitor 5-8 part
Dispersion agent 2-4 part.
As optimization, described photostabilizer is 2-hydroxyl-4-methoxy benzophenone or hindered amine as light stabilizer.
As optimization, described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.
As optimization, described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethene-methyl acrylate-glycidyl methacrylate terpolymer (E-MA-GMA).
As optimization, described oxidation inhibitor is the compound of hindered phenol antioxygen 1010 or 1076 and phosphite ester kind antioxidant 168.
As optimization, described fire retardant is the compound of poly-silicon borine fire retardant 50wt%, polyphosphoric acid amine (PPA) 30wt% and aluminium hydroxide 20wt% three mixing.
As optimization, described pigment is Rutile type Titanium Dioxide, or Rutile type Titanium Dioxide and nano level barium sulfate mixture, and in Rutile type Titanium Dioxide and nano level barium sulfate mixture, nano level barium sulfate is no more than 20%.
As optimization, described antiaging agent is made up of antioxidant 1010 or oxidation inhibitor 225, antioxidant 1076, auxiliary antioxidant DSTP and photostabilizer UV-327, and the weight percent of its each component is: antioxidant 1010 or oxidation inhibitor 225: 20 ~ 40%; Antioxidant 1076: 10 ~ 30%; Auxiliary antioxidant DSTP: 10 ~ 30%; Photostabilizer UV-327:20 ~ 40%.
As optimization, described static inhibitor of stating is stearylamine polyoxyethylene (2) ether, or amino dodecane polyoxyethylene (2) ether, or stearylamine polyoxyethylene (2) ether and amino dodecane polyoxyethylene (2) ether mixture.
The invention also discloses a kind of building scaffold skirting board preparation method extruding Color Segmentation lines, each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mixing temperature 120 DEG C ~ 140 DEG C mixing 10 ~ 20 minutes, again the material mixed is added twin screw extruder melt blending, melt temperature controls at 160 DEG C ~ 190 DEG C, after being extruded by twin screw extruder, through overcooling, drying, slitting, packaging.
Beneficial effect: lines color and luster of the present invention is clear, low smoke and zero halogen, nonpoisonous and tasteless road, specification is 250mm*0.2mm, and length is random, and can recycle, and flame retardant properties, anti-aging, antistatic performance is excellent, and preparation technology is simple.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
A kind of building scaffold skirting board, with extruding Color Segmentation lines, comprises the component of following mass parts:
Polyvinyl resin 20 parts
Photostabilizer 10 parts
Weighting agent 10 parts
Compatilizer 3 parts
1 part, oxidation inhibitor
Fire retardant 15 parts
Coupling agent 1 part
0.5 part, softening agent
Antiaging agent 3 parts
Pigment 10 parts
5 parts, static inhibitor
Dispersion agent 2 parts.
As the further optimization of technique scheme, described photostabilizer is 2-hydroxyl-4-methoxy benzophenone or hindered amine as light stabilizer.Described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.Described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethene-methyl acrylate-glycidyl methacrylate terpolymer (E-MA-GMA).Described oxidation inhibitor is the compound of hindered phenol antioxygen 1010 or 1076 and phosphite ester kind antioxidant 168.Described fire retardant is the compound of poly-silicon borine fire retardant 50wt%, polyphosphoric acid amine (PPA) 30wt% and aluminium hydroxide 20wt% three mixing.Described pigment is Rutile type Titanium Dioxide, or Rutile type Titanium Dioxide and nano level barium sulfate mixture, and in Rutile type Titanium Dioxide and nano level barium sulfate mixture, nano level barium sulfate is no more than 20%.Described antiaging agent is made up of antioxidant 1010 or oxidation inhibitor 225, antioxidant 1076, auxiliary antioxidant DSTP and photostabilizer UV-327, and the weight percent of its each component is: antioxidant 1010 or oxidation inhibitor 225: 20 ~ 40%; Antioxidant 1076: 10 ~ 30%; Auxiliary antioxidant DSTP: 10 ~ 30%; Photostabilizer UV-327:20 ~ 40%.Described static inhibitor of stating is stearylamine polyoxyethylene (2) ether, or amino dodecane polyoxyethylene (2) ether, or stearylamine polyoxyethylene (2) ether and amino dodecane polyoxyethylene (2) ether mixture.
The above-mentioned building scaffold skirting board preparation method extruding Color Segmentation lines, each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mixing temperature 120 DEG C mixing 10 minutes, again the material mixed is added twin screw extruder melt blending, melt temperature controls at 160 DEG C, after being extruded by twin screw extruder, through overcooling, drying, slitting, packaging.
Embodiment 2
A kind of building scaffold skirting board, with extruding Color Segmentation lines, comprises the component of following mass parts:
Polyvinyl resin 35 parts
Photostabilizer 20 parts
Weighting agent 25 parts
Compatilizer 5 parts
2 parts, oxidation inhibitor
Fire retardant 25 parts
Coupling agent 2 parts
1 part, softening agent
Antiaging agent 5 parts
Pigment 15 parts
8 parts, static inhibitor
Dispersion agent 4 parts.
As the further optimization of technique scheme, described photostabilizer is 2-hydroxyl-4-methoxy benzophenone or hindered amine as light stabilizer.Described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.Described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethene-methyl acrylate-glycidyl methacrylate terpolymer (E-MA-GMA).Described oxidation inhibitor is the compound of hindered phenol antioxygen 1010 or 1076 and phosphite ester kind antioxidant 168.Described fire retardant is the compound of poly-silicon borine fire retardant 50wt%, polyphosphoric acid amine (PPA) 30wt% and aluminium hydroxide 20wt% three mixing.Described pigment is Rutile type Titanium Dioxide, or Rutile type Titanium Dioxide and nano level barium sulfate mixture, and in Rutile type Titanium Dioxide and nano level barium sulfate mixture, nano level barium sulfate is no more than 20%.Described antiaging agent is made up of antioxidant 1010 or oxidation inhibitor 225, antioxidant 1076, auxiliary antioxidant DSTP and photostabilizer UV-327, and the weight percent of its each component is: antioxidant 1010 or oxidation inhibitor 225: 20 ~ 40%; Antioxidant 1076: 10 ~ 30%; Auxiliary antioxidant DSTP: 10 ~ 30%; Photostabilizer UV-327:20 ~ 40%.Described static inhibitor of stating is stearylamine polyoxyethylene (2) ether, or amino dodecane polyoxyethylene (2) ether, or stearylamine polyoxyethylene (2) ether and amino dodecane polyoxyethylene (2) ether mixture.
The above-mentioned building scaffold skirting board preparation method extruding Color Segmentation lines, each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mixing temperature 140 DEG C mixing 20 minutes, again the material mixed is added twin screw extruder melt blending, melt temperature controls at 190 DEG C, after being extruded by twin screw extruder, through overcooling, drying, slitting, packaging.
Embodiment 3
A kind of building scaffold skirting board, with extruding Color Segmentation lines, comprises the component of following mass parts:
Polyvinyl resin 25 parts
Photostabilizer 15 parts
Weighting agent 15 parts
Compatilizer 4 parts
1.5 parts, oxidation inhibitor
Fire retardant 20 parts
Coupling agent 1.5 parts
0.7 part, softening agent
Antiaging agent 4 parts
Pigment 12 parts
6 parts, static inhibitor
Dispersion agent 3 parts.
As the further optimization of technique scheme, described photostabilizer is 2-hydroxyl-4-methoxy benzophenone or hindered amine as light stabilizer.Described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.Described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethene-methyl acrylate-glycidyl methacrylate terpolymer (E-MA-GMA).Described oxidation inhibitor is the compound of hindered phenol antioxygen 1010 or 1076 and phosphite ester kind antioxidant 168.Described fire retardant is the compound of poly-silicon borine fire retardant 50wt%, polyphosphoric acid amine (PPA) 30wt% and aluminium hydroxide 20wt% three mixing.Described pigment is Rutile type Titanium Dioxide, or Rutile type Titanium Dioxide and nano level barium sulfate mixture, and in Rutile type Titanium Dioxide and nano level barium sulfate mixture, nano level barium sulfate is no more than 20%.Described antiaging agent is made up of antioxidant 1010 or oxidation inhibitor 225, antioxidant 1076, auxiliary antioxidant DSTP and photostabilizer UV-327, and the weight percent of its each component is: antioxidant 1010 or oxidation inhibitor 225: 20 ~ 40%; Antioxidant 1076: 10 ~ 30%; Auxiliary antioxidant DSTP: 10 ~ 30%; Photostabilizer UV-327:20 ~ 40%.Described static inhibitor of stating is stearylamine polyoxyethylene (2) ether, or amino dodecane polyoxyethylene (2) ether, or stearylamine polyoxyethylene (2) ether and amino dodecane polyoxyethylene (2) ether mixture.
The above-mentioned building scaffold skirting board preparation method extruding Color Segmentation lines, each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mixing temperature 130 DEG C mixing 15 minutes, again the material mixed is added twin screw extruder melt blending, melt temperature controls at 175 DEG C, after being extruded by twin screw extruder, through overcooling, drying, slitting, packaging.

Claims (10)

1. building scaffold skirting board is with extruding Color Segmentation lines, it is characterized in that: the component comprising following mass parts:
Polyvinyl resin 20-35 part
Photostabilizer 10-20 part
Weighting agent 10-25 part
Compatilizer 3-5 part
Oxidation inhibitor 1-2 part
Fire retardant 15-25 part
Coupling agent 1-2 part
Softening agent 0.5-1 part
Antiaging agent 3-5 part
Pigment 10-15 part
Static inhibitor 5-8 part
Dispersion agent 2-4 part.
2. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described photostabilizer is 2-hydroxyl-4-methoxy benzophenone or hindered amine as light stabilizer.
3. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.
4. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethene-methyl acrylate-glycidyl methacrylate terpolymer (E-MA-GMA).
5. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described oxidation inhibitor is the compound of hindered phenol antioxygen 1010 or 1076 and phosphite ester kind antioxidant 168.
6. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described fire retardant is the compound of poly-silicon borine fire retardant 50wt%, polyphosphoric acid amine (PPA) 30wt% and aluminium hydroxide 20wt% three mixing.
7. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described pigment is Rutile type Titanium Dioxide, or Rutile type Titanium Dioxide and nano level barium sulfate mixture, in Rutile type Titanium Dioxide and nano level barium sulfate mixture, nano level barium sulfate is no more than 20%.
8. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described antiaging agent is made up of antioxidant 1010 or oxidation inhibitor 225, antioxidant 1076, auxiliary antioxidant DSTP and photostabilizer UV-327, and the weight percent of its each component is: antioxidant 1010 or oxidation inhibitor 225: 20 ~ 40%; Antioxidant 1076: 10 ~ 30%; Auxiliary antioxidant DSTP: 10 ~ 30%; Photostabilizer UV-327:20 ~ 40%.
9. a kind of building scaffold skirting board according to claim 1 is with extruding Color Segmentation lines, it is characterized in that: described in state static inhibitor be stearylamine polyoxyethylene (2) ether, or amino dodecane polyoxyethylene (2) ether, or stearylamine polyoxyethylene (2) ether and amino dodecane polyoxyethylene (2) ether mixture.
10. a kind of building scaffold skirting board preparation method extruding Color Segmentation lines according to claim 1-9 any one, it is characterized in that: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mixing temperature 120 DEG C ~ 140 DEG C mixing 10 ~ 20 minutes, again the material mixed is added twin screw extruder melt blending, melt temperature controls at 160 DEG C ~ 190 DEG C, after being extruded by twin screw extruder, through overcooling, drying, slitting, packaging.
CN201510170949.0A 2015-04-13 2015-04-13 Extruded colored segmentation line for building scaffold skirting lines and preparation method thereof Pending CN104844891A (en)

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CN201510170949.0A CN104844891A (en) 2015-04-13 2015-04-13 Extruded colored segmentation line for building scaffold skirting lines and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201510170949.0A CN104844891A (en) 2015-04-13 2015-04-13 Extruded colored segmentation line for building scaffold skirting lines and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105778244A (en) * 2016-05-24 2016-07-20 苏州新区特氟龙塑料制品厂 Novel polyethylene
CN107265927A (en) * 2017-07-05 2017-10-20 肥西县碧涛建材有限公司 A kind of construction material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005002154A (en) * 2003-06-10 2005-01-06 Kuraray Plast Co Ltd Sheet or film excellent in high-frequency gluing property and its use
CN101792975A (en) * 2010-02-26 2010-08-04 四川大学 Ageing-resistant heat-insulation tarpaulin and production method thereof
CN102756526A (en) * 2012-06-21 2012-10-31 青岛供八方塑料有限公司 Production method of waterproof anti-flaming ultraviolet ray-resistant plastic tarpaulin
CN103756095A (en) * 2014-01-15 2014-04-30 佛山市南方包装有限公司 High-barrier colorful plastic product capable of retarding moisture and air

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005002154A (en) * 2003-06-10 2005-01-06 Kuraray Plast Co Ltd Sheet or film excellent in high-frequency gluing property and its use
CN101792975A (en) * 2010-02-26 2010-08-04 四川大学 Ageing-resistant heat-insulation tarpaulin and production method thereof
CN102756526A (en) * 2012-06-21 2012-10-31 青岛供八方塑料有限公司 Production method of waterproof anti-flaming ultraviolet ray-resistant plastic tarpaulin
CN103756095A (en) * 2014-01-15 2014-04-30 佛山市南方包装有限公司 High-barrier colorful plastic product capable of retarding moisture and air

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105778244A (en) * 2016-05-24 2016-07-20 苏州新区特氟龙塑料制品厂 Novel polyethylene
CN107265927A (en) * 2017-07-05 2017-10-20 肥西县碧涛建材有限公司 A kind of construction material and preparation method thereof

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Application publication date: 20150819