CN104844044B - Manufacturing method of ceramsite enhanced foam concrete self-insulation building block - Google Patents

Manufacturing method of ceramsite enhanced foam concrete self-insulation building block Download PDF

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CN104844044B
CN104844044B CN201510264525.0A CN201510264525A CN104844044B CN 104844044 B CN104844044 B CN 104844044B CN 201510264525 A CN201510264525 A CN 201510264525A CN 104844044 B CN104844044 B CN 104844044B
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building block
haydite
foam concrete
ceramsite
sludge ceramsite
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CN104844044A (en
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王江豪
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Hunan Hongjingchen New Material Technology Co ltd
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Abstract

The invention discloses a sludge ceramsite and ceramsite enhanced foam concrete self-insulation building block and a preparation method of the building block. Sludge ceramsite is obtained through puffing under high temperature after at least one of building rubbish, coal ash and mountain flour is mixed with sludge for granulating, the obtained sludge ceramsite has the characteristics of low density, high strength, low heat conductivity coefficient and high corrosion resistance, the ceramsite enhanced foam concrete self-insulation building block with low density, high strength, good heat insulation performance, low shrinking percentage, low water absorption rate, high impervious performance, good freezing resistance, good waterproof performance and durability, good sound insulation effect and good shock resistance and damping performance can be prepared by the obtained sludge ceramsite taken as an aggregate as well as sludge ceramsite, low calcium secondary coal ash, ordinary portland cement, detrital saltpetre, microcrystal inorganic materials, water, auxiliaries and the like through a physical foaming method; the preparation method is simple and low in cost, and meets industrial production.

Description

Prepare the method that haydite strengthens foam concrete heat insulation building block
Technical field
The present invention relates to a kind of sludge ceramsite and haydite strengthen the preparation method of foam concrete heat insulation building block and building block, Belong to green construction material preparing technical field.
Background technology
The task of China environmental protection is extremely arduous, wherein as thermal power generation, the trade waste of mining industry, rivers and lakes mud All extremely thorny with the process of municipal sludge, architectural engineering waste residue.On the other hand, economic development, Development of China's Urbanization plus Fast and living standards of the people raisings are expanded rapid to the demand of building construction.And in building industry, brick mix structure and frame are cut Frame structure is still main building system, clay solid brick and other light materials.Materials for wall is still in seize by force Main status, not only shock resistance is low for this kind of building masonry material, infiltration, cracking, hollowing easily, and expends man-hour, makes Valency is high, and heat insulation effect is poor, also will consume the clay resource of preciousness and coal-fired in a large number cause the pollution to environment.In order to solve state These significant problems in the meter people's livelihood, building energy conservation reducing energy consumption is an extremely important task, building row during 11th Five-Year Industry energy consumption accounts for the 45%~50% of whole society's total energy consumption, and with the development of market economy, China cities and towns are by newly-built 50~6,000,000,000 Square metre building, propose strictly mandatory by the building energy-saving standard reaching 65% in the whole country to country during 12 Execution, and on market, light wall material undoubtedly meets this index, it can provide excellent having self-heat conserving, sound insulation, resist The product of the good endurance such as shake, fire prevention, water-impervious, high-strength light, and not fully up to expectations it is therefore desirable to innovation and change further Enter, and the product that the inventive method makes is entirely capable of reaching existing country and local building energy-saving design code requirement.China Patent (Publication No. cn 104556859 a) discloses a kind of light wall material processing technology containing regeneration aggregate, this technique It is that waste ceramic etc. is pulverized as aggregate mainly using discarded concrete, discarded brick, for preparing a kind of lightweight, thermal insulation separation of material Hot property is excellent, strength durable is good, less to energy resource consumption, the materials for wall of environmentally safe.But its regeneration aggregate Actually solid material, density is relatively large, at least in 800kg/m3More than, the light wall material quality made is relatively Greatly, heat insulation effect does not include ideal.
Content of the invention
The defect existing for light wall material of the prior art, it is an object of the invention to be by mud And construction waste material etc. by a kind of low cost of expanded acquisition, density is little, intensity is high, heat conductivity is low, corrosion resistance is strong Sludge ceramsite.
Another object of the present invention is to be to provide that a kind of density obtaining based on modified haydite is little, intensity is high, heat-insulated Heat-insulating property is excellent, shrinkage factor is little, water absorption rate is low, anti-permeability performance is strong, frost resistance is good, fire prevention and durability is excellent, sound insulating and absorbing effect The haydite good, antidetonation shock attenuation is good strengthens foam concrete heat insulation building block.
A further object of the invention is to be that providing a kind of process is simple, low cost to prepare described haydite enhancing foam mixes The method of solidifying soil heat insulation building block.
In order to realize the above-mentioned purpose of the present invention, the invention provides a kind of sludge ceramsite, this sludge ceramsite is by building rubbish Expanded under 1100 DEG C~1300 DEG C high temperature after at least one in rubbish, flyash and stone powder and mud mixing granulation obtain.
Preferably sludge ceramsite by least one in building waste, flyash and stone powder and mud in mass ratio 20~ After the mixing granulation of 40:30~50, high temperature puffing obtains;Wherein, the water content of building waste, flyash and stone powder and mud all exists Between 20wt%~45wt%.
Preferably sludge ceramsite particle diameter is 15~25mm.
Preferably sludge ceramsite density is 250~300kg/m3.
The mud that the present invention adopts can be domestic sewage sludge, industrial wastewater sludge or copper water-supply pipe according to source, this The main component of a little mud is substantially the same and all meets the preparation of haydite of the present invention and require.
The preparation of the sludge ceramsite of the present invention has to control temperature conditionss, under suitable hot conditionss, on the one hand Be conducive to quick volatilization and the expansion of moisture, carry out internal pore-creating, so that sludge ceramsite raw material is closed under the high temperature conditions Hole, forms and closes microcellular structure, imparts haydite light weight, the feature that high-strength, heat conductivity is low.Under high temperature action, sludge ceramsite Raw material Outside surface glass matter, leads to appearance hard, and under the surface tension effects of itself, carries out shrinking closed pore.Using this The 40% of the haydite enhancing foam concrete heat insulation building block density only normal concrete stripping and slicing density that bright haydite is made~ 50%;Heat conductivity is the 1/5~1/3 of normal concrete stripping and slicing.
The preparation of the sludge ceramsite of the present invention has to coordinate building waste, flyash and stone powder etc. to use in mud, dirty Mud plays good cementation, effectively strengthens the intensity of sludge ceramsite, substantially reduces the density of sludge ceramsite simultaneously.
The sludge ceramsite that the present invention obtains has the more elliposoidal of standard or spherical or gravel, and color is brown or brown Color.
The construction waste crushing of the present invention is to reuse in the range of 2~5mm to particle diameter.
The granularity of the flyash of the present invention and stone powder is all in the range of 70~90 mesh.
Preferably sludge ceramsite is prepared via a method which to obtain: by least in building waste, flyash and stone powder Plant and mix with mud, after equilibrium moisture content to 30wt%~45wt%, by granulator granulation, pelletize gained particulate matter is placed in In Expanded Clay Rotary Kilns, expanded at a temperature of 1100 DEG C~1300 DEG C, obtain final product.
The preparation of the sludge ceramsite of the present invention preferably controls the moisture of sludge ceramsite raw material in 30wt%~45wt% Between, can effective conditioning of mud haydite pore structure, moisture under the high temperature conditions quickly volatilization, expand, make in sludge ceramsite Portion forms the hole series structure of prosperity.
The invention provides a kind of haydite strengthens foam concrete heat insulation building block, this haydite strengthens foam concrete self-insurance Warm building block, by the raw material including following mass percent component, is obtained by physical blowing, mould molding: sludge ceramsite 20%~30%, low calcium second class powered coal ash 15%~25%, Portland cement 15%~25%, broken nitre 3%~8%, micro- Brilliant inorganic material 3%~8%, water 20%~30%.More preferably composition of raw materials is: sludge ceramsite 25%~30%, low calcium two Level flyash 18%~20%, Portland cement 20%~25%, broken nitre 3%~8%, microcrystalline inorganic material 3%~ 8%, water 25%~30%.
Preferably haydite strengthens broken nitre granularity in foam concrete heat insulation building block is 25~35 mesh.
Preferably haydite strengthens microcrystalline inorganic material granularity in foam concrete heat insulation building block is 70~100 mesh.
Preferably the raw material described in haydite enhancing foam concrete heat insulation building block includes active toughening auxiliary agent, nanometer Strengthen accelerator and water-retaining agent.
More preferably in haydite enhancing foam concrete heat insulation building block, raw material also includes active toughening auxiliary agent, nanometer strengthens Accelerator and water-retaining agent.
More preferably haydite strengthens raw material activity toughening auxiliary agent, nanometer in foam concrete heat insulation building block and strengthens accelerator It is 0.5~1.5:0.5~1.5:0.5~1.5:30 with the consumption of water-retaining agent and the mass ratio of water.
It is all commercially available normal auxiliary agent that the active toughening auxiliary agent of the present invention, nanometer strengthen accelerator and water-retaining agent.As toughness reinforcing in activity The commercially available modified pe m-521 in Dongguan City Lignum cinnamomi camphorae Tou Dansheng plastic material business department of auxiliary agent, that nanometer strengthens accelerator is commercially available Reach Chemical Engineering Technology company limited and the commercially available cmc in Shandong one rattan of water-retaining agent in Shang Haihan.The present invention is not limited to these factories The product that family produces, other activity toughening auxiliary agents of this area, nanometer enhancing accelerator and water-retaining agent are also applied for the present invention.
The Portland cement that the present invention adopts is Portland cement 325r/425r.
Present invention also offers a kind of prepare the method that described haydite strengthens foam concrete heat insulation building block, the method Comprise the following steps:
Step one: prepare sludge ceramsite
At least one in building waste, flyash and stone powder is mixed with mud, equilibrium moisture content to 30wt%~ After 45wt%, by granulator granulation, pelletize gained particulate matter is placed in Expanded Clay Rotary Kilns, at a temperature of 1100 DEG C~1300 DEG C Expanded, obtain final product sludge ceramsite;
Step 2: prepare haydite and strengthen foam concrete heat insulation building block
After step one gained sludge ceramsite is mixed homogeneously with other raw materials, it is placed in stir speed (S.S.) and maintains 40~70r/ Carry out stirring at low speed in blender in the range of min, pass through high-pressure pump carrier to defeated in the mixed material in blender simultaneously Gases at high pressure are sent so that mixed material is foamed, control gas release is 35~45 seconds/m3;After the completion of foaming, mixed material passes through Die casting molding, then sequentially pass through maintenance, the demoulding, cutting, obtain final product haydite and strengthen foam concrete heat insulation building block.
Preferably control presetting period > 35min, final setting time < 8h during mould moulding by casting in preparation method.
Preferably in preparation method, particulate matter accelerates into Expanded Clay Rotary Kilns from Expanded Clay Rotary Kilns top, particulate matter under Fall 1100 DEG C~1300 DEG C of high-temperature areas in Expanded Clay Rotary Kilns when, carry out moment boiling and volatilization moisture, expand.
Preferably in preparation method, foamed time is 2~3min.
Preferably in preparation method, foaming temperature is 3 DEG C~36 DEG C, typically can be foamed at room temperature.
It is 0.08kpa that the present invention foams with high-pressure air pressure.
Preferably in preparation method, maintenance includes heating foster and/or steam is foster and/or rests.Described rest for: in the summer Season daily water spray two to three times, then need not spray water in the winter time, 2~3 days will be extended in time of resting in winter than summer.Described adds Heat is supported and/or steam supports the time for 6~8h.The haydite of the present invention strengthens in foam concrete heat insulation building block preparation process, After die casting molding, first can adopt heating or stream mode maintenance 6~8 hours, then after resting 24 hours, the demoulding, cutting, Further rest 7 days, now, the intensity of haydite enhancing foam concrete heat insulation building block can reach is rested with conventional concrete 28 days identical intensity effects.
The haydite of the present invention strengthens foam concrete heat insulation building block and can make solid class and hollow class as needed, point It is not applied to bearing building block body and non-bearing building block body.Different shape can also be designed to as needed.Prepared haydite strengthens Foam concrete heat insulation building block can use directly as fragment of brick.
Preferably in preparation method, sludge ceramsite preferably preparing raw material is mud cooperation building waste, flyash, stone powder In at least one use.At least one in mass ratio 30 more preferably in mud and building waste, flyash, stone powder ~50:20~40 use cooperatively (water content of each component is all between 20wt%~45wt%).Most preferably mud and building rubbish Rubbish, flyash, stone powder are used in mixed way, and wherein, the butt quality of mud is 30~50 parts, building waste, flyash and stone powder Gross mass is 20~40 parts;Building waste, flyash and stone powder mass ratio are 1:0.5~1.5:0.5~1.5.
Preferably in preparation method the equilibrium water conten process of haydite granular precursor thing can by the regulation humidity that adds water, or The waste heat air inducing of Expanded Clay Rotary Kilns kiln hood is reclaimed by person, using hot-air, particulate matter is dried.
Hinge structure, the beneficial effect that the present invention brings:
1st, the present invention obtains by specific process by mud and construction waste material etc. that a kind of density is little, intensity is high, outer Table is hard, heat conductivity is low, the sludge ceramsite of corrosion resistance and good.Have inside sludge ceramsite abundant independently close micropore, assign Sludge ceramsite light weight, the high-strength and low characteristic of heat conductivity are given.The density of the concrete stripping and slicing that sludge ceramsite is prepared is to be only The 40%~50% of the normal concrete stripping and slicing density of identical label, heat conductivity is the 1/5~1/3 of normal concrete stripping and slicing; The haydite of sludge ceramsite preparation strengthens foam concrete heat insulation building block (mpa/a5.0b07) -700kg unit weight, sludge ceramsite system Standby haydite concrete many rounds brick intensity is (5.0mpa) unit weight is 1200kg.Sludge ceramsite can extensively apply with concrete, The fields such as building materials, gardening, oil, chemical industry, flame-proof thermal insulation material.
2nd, the raw material sources of sludge ceramsite are wide, and the overwhelming majority is mud and Solid construction rubbish, solves existing solid rubbish The reluctant difficult problem of rubbish;And the preparation method of sludge ceramsite is simple, low production cost.
3rd, sludge ceramsite combines as aggregate and strengthens foam concrete and use, and can obtain that density is light, intensity is high, heat-insulation and heat-preservation Performance is excellent, shrinkage factor is little, water absorption rate is low, anti-permeability performance is strong, frost resistance is good, fire prevention and durability is excellent, sound insulating and absorbing effect is good, anti- The good haydite of shake damping property strengthens foam concrete heat insulation building block.And sludge ceramsite uses as aggregate can be by adjusting The bulk density of Superlight ceramsites and volume can obtain the haydite Concrete Structure heat insulation building block of varying strength and density.This is cut Block can be widely applied in industry and all types of pre-members and cast-in-place concrete of civil buildings, significantly mitigates building lotus Carry, be not required to do inside and outside wall thermal insulation and external wall waterproof, completely solve the trouble and worry of exterior-wall heat insulation and waterproof.
The haydite of the present invention strengthens the construction featuress based on sludge ceramsite for the foam concrete self-heat conserving block, and sludge ceramsite combines Cement strengthens cement bond effect using collaborative, strengthens foam concrete heat insulation building block in haydite and condenses the initial stage, haydite can be inhaled Receive the part moisture in cement mortar so as to the ratio of mud reduces, effectively increase the early strength that cement strengthens foam mortar, and Afterwards with the prolongation strengthening foam concrete age, the moisture of concrete constantly evaporation and gradually hydropenia, now absorb saturation Fleeing from of moisture can start to gush moisture, is cement mortar gradually aquation, maintenance, that is, be conducive to improving the intensity of cement mortar, It is also beneficial to improve density and the intensity that cement strengthens foam mortar and haydite interface;The haydite of the present invention strengthens foam coagulation Native heat insulation building block after heating or steam curing 7 hours, then after resting within 24 hours can the demoulding, resting 7 days intensity after cutting can Reach and 28 days corresponding effects of conventional concrete.
The fine aggregate that the haydite of the present invention strengthens in foam concrete heat insulation building block adopt broken nitre, microcrystalline inorganic material with And low calcium second class powered coal ash, it is effectively reduced the blended amount of cement, mitigate density of building block, improve heat preservation and insulation.
Inside the haydite Concrete Structure heat insulation building block of the present invention, there is the micropore that closes independent in a large number (to be carried by sludge ceramsite For), close micropore and effectively reduce water absorption rate, also improve lightweight, heat-insulation and heat-preservation and anti-freezing property.Haydite strengthens foam concrete The Binder Materials adopting in heat insulation building block are cement, have the characteristics that intensity stabilization.The haydite of preparation strengthens foam concrete Heat insulation building block heat conductivity is low, heat conductivity 0.158w/ (m.k), low 3~5 times of (normal concrete strippings and slicings than normal concrete Heat conductivity 1.0~1.2w/m.k);Radioactivity External Exposure Index is less than ira0.2, Outreach services are less than ira0.6;Frost resistance Intensity mpa5.4 after jelly, drying shrinkage value mm/m0.17;Fire resistance is normal concrete more than 5 times.
4th, haydite strengthen foam concrete heat insulation building block preparation method adopt physical blowing method, have process is simple, The low series of advantages of easy to operate, production cost, and do not use foaming agent, and the chemical blowing material such as aluminium powder, hydrogen peroxide.Solve Existing chemical foaming technology has that foam performance is unstable, and cost is high and the defect that is harmful to health not environmentally.And this Bright haydite strengthens foam concrete heat insulation building block formula and is not suitable for chemical blowing process preparation, and CBA is to building block Intensity has large effect.
The bright book of accompanying drawing
[Fig. 1] is the sludge ceramsite outside drawing of the embodiment of the present invention 1 preparation.
[Fig. 2] is the outside drawing of the haydite enhancing foam concrete heat insulation building block of the embodiment of the present invention 1 preparation.
[Fig. 3] is that the haydite of the embodiment of the present invention 1 preparation strengthens the body of wall that foam concrete heat insulation building block is built into.
[Fig. 4] is that the haydite of the embodiment of the present invention 1 preparation strengthens the fishpond that foam concrete heat insulation building block is built into.
Specific embodiment
Following examples are intended to further illustrate present invention, rather than the protection model limiting the claims in the present invention Enclose.
Embodiment 1
Moisture content is about 70% river sludge, is dried to moisture content 40%, takes 50 parts, then be 3mm with particle mean size 10 parts of the building waste (moisture content 30% about) of left and right, 10 parts of 80 mesh flyash (moisture content 30% about), 80 mesh stone powders (contain Water rate 25% about) after 10 parts of mixing, through by humidification and drying and processing, controlling mixed material moisture control about 40%, lead to Cross granulator pelletize, make small particle, small particle is directly sent into from Expanded Clay Rotary Kilns top, small particle is from running up Rotor on moment crash into Expanded Clay Rotary Kilns, fall in kiln 1200 DEG C of small particle are thermal zone, formed at once boiling and Transpiring moisture, is expanded, expanded after granule rotated outside Expanded Clay Rotary Kilns kiln body, define brown, shape close to circle The sludge ceramsite (shape is as shown in Figure 1) of spherical.Prepared river sludge haydite sample characterization: density is 292.7kg/m3, Cylindrical compress strength is 0.35mpa, and, in the range of 15mm~25mm, its alkali resistant aggregate reaction ability is excellent for particle diameter distribution.Haydite anti- Alkali ability is according to railway concrete aggregate in People's Republic of China's railroad industry standard tb/t2922.5-2002 Basic active test method: quick mortar bars method test.
Experimental raw: cement: normal silicate 42.5 cement.Naoh: concentration is 1mol/l.
Equipment: jaw crusher;Square hole screen: aperture be 4.75mm, 2.36mm, 1.18mm, 600 μm, 300 μm and 150 μm Sieve each a set of;Balance;Die trial: die trial is metal manufacture, can dismantle, inner wall size is 25mmx25mmx280mm;Survey length Instrument: range 275mm~300mm, precision 0.01mm;Maintenance container: the lidded container being made up of corrosion-resistant and high-temperature resistant material, in it It is provided with test-piece stand, water-tight, airtight after adding a cover, highly it is not less than 350mm;Water bath with thermostatic control or baking oven: temperature is 80 DEG C ± 2 ℃.
The method of sample preparation: 1, with quartering, sample is reduced to 5.0kg, then sample is all crushed to 5mm with Under.2nd, above-mentioned sample is sieved, with clear water by sieves at different levels to tail over sample wash clean, in 105 DEG C ± 5 DEG C of baking oven Middle baking 3h-4h, then leaves in standby as sample in exsiccator respectively.
Molding: apply last layer machine oil inside die trial, side head is carefully loaded the center in the hole of die trial termination.To be stirred Slurry divide two-layer load die trial in.The depth that ground floor slurry loads is about the 2/3 of die trial height.First drawn even back and forth with pocket knife Glue sand, especially side head both sides should many strokes several times, then sequentially come and gone in die trial with tamper and respectively smash pressure 20 times, notes that side head is all Enclose and carefully consolidate.Then reinstall second layer slurry.After die trial filled by second layer slurry, still with pocket knife, the second layer is starched Material is drawn even back and forth, and this time pocket knife puts the surface that depth should pass through ground floor slurry under.Come and gone in pulp surface again with tamper and respectively smash Pressure 20 times.Smash pressure to finish, remaining slurry is filled up die trial, then by floating for surface of test piece, numbering, and indicate mensure direction.
The precuring of test specimen: the preparation of conditioning solutions: weigh 40.00g sodium hydroxide, be dissolved in equipped with 900ml distilled water In 1l volumetric flask, then to Deca distilled water in bottle, make liquor capacity reach 1.0l, thus join 1n sodium hydroxide solution.
The test specimen band mould of forming is put into standard curing interior maintenance 24h ± 2h.After taking out die trial the careful demoulding, fast Speed puts into test specimen in the test-piece stand of maintenance container.With water by water by whole for test specimen submergences, cover maintenance container cover, maintenance is held Device is placed in 80 DEG C ± 2 DEG C of water-bath or baking oven places 24h ± 2h.
Long mensure at the beginning of test specimen: maintenance container is taken out one at a time from water-bath or baking oven, turns on maintenance container cover, One at a time takes out test specimen from container, dries surface of test piece and side head surface with rag rapidly, and tests test specimen with horizontal metroscope Length.This length is just long.Test specimen is fetched at the beginning of test specimen length from water and runs through the experienced time and should control in 15s ± 5s Interior.The test specimen grown at the beginning of being run through with wet rag covers, till the first length of remaining test specimen runs through.
The maintenance of test specimen: the maintenance container that will be equipped with enough curing fluids is placed in 80 DEG C ± 2 DEG C of water-bath or baking oven, extremely supports Till the temperature of the curing fluid in shield container reaches when 80 DEG C ± 1 DEG C.The test specimen having surveyed just long is vertically put into maintenance container In test-piece stand, and test specimen is made to be totally immersed in curing fluid.In maintenance container the volume ratio of the volume of curing fluid and test specimen be (4 ± 0.5): 1., after covering and sealing, again maintenance container is put back in 80 DEG C ± 2 DEG C of water bath with thermostatic control or baking oven.
The test of piece lengths change: be put in 80 DEG C of curing fluids from test specimen and count, maintenance to age is 14d ± 2h, adopts With just long identical method measures the length when this age for the test specimen with test test specimen, and note should be by test specimen and horizontal metroscope Same position when relative position is adjusted to and measures first long.Meanwhile, the situation of change of each surface of test piece should be examined, Including deformation, crackle, surface deposits or exudate etc., make a record.
Table 1 haydite level joins table
The quick mortar bars method of table 2 tests the alkali result of haydite
Result calculates and processes
Length expansion rate is calculated as follows:
ξ = l t - l 0 l 0 - 2 δ
The expansion rate (%) when 14d age for the ξ --- --- test specimen, is accurate to 0.01%;lt--- --- test specimen is in 14d Length (mm) during age;l0The first length (mm) of --- --- test specimen;The length (mm) of δ --- --- side head;
When the length expansion rate of single test specimen, average value difference meets following one of two things with 3 piece lengths expansion rates Requirement when, take 3 piece lengths expansion rate volume arithmetic mean of instantaneous values as length expansion rate:
1st, when meansigma methodss are less than or equal to 0.05%, single piece lengths expansion rate is equal with the absolute value of the difference of meansigma methodss Less than 0.01%;2nd, when meansigma methodss are more than 0.05%, single piece lengths expansion rate is respectively less than meansigma methodss with the difference of meansigma methodss 20%.When not meeting above-mentioned requirements, remove 3 piece lengths expansion rate minima, take remaining 2 piece lengths expansion rates Arithmetic mean of instantaneous value as length expansion rate.When 14d age length expansion rate is less than 0.10%, aggregate is assessed as non- Alkali --- silica reaction active aggregates;Otherwise, aggregate is assessed as alkali --- silicate reaction active aggregates.Note: work as length expansion When rate is more than or equal to 0.10% and is less than 0.20%, tb/t2922.3 may also be employed and test further, thus finally determining The Plant ecology of aggregate.
Embodiment 2
Moisture content is about 50% industrial wastewater sludge, is dried to moisture content 40%, takes 40 parts, then 80 mesh flyash After the mixing of 15 parts of 15 parts of (moisture content 30% about), 80 mesh stone powders (moisture content 25% about), through by humidification and drying and processing, Control mixed material moisture control about 35%, by granulator pelletize, make small particle, small particle directly returns from haydite Rotary kiln top is sent into, and small particle moment from the rotor running up crashes into Expanded Clay Rotary Kilns, and small particle falls through kiln Interior 1150 DEG C are thermal zone, at once form boiling and transpiring moisture, expanded, expanded after granule rotated haydite revolution Outside kiln kiln body, define brown, shape is close to the sludge ceramsite of the ball bodily form.Prepared sludge ceramsite sample characterization: density is 300.2kg/m3, cylindrical compress strength be 0.37mpa, particle diameter distribution in the range of 15mm~25mm, its alkali resistant aggregate reaction ability root According to railway concrete aggregate basic active test method in People's Republic of China's railroad industry standard tb/t2922.5-2002 (method of testing of embodiment 1), result is excellent.
Embodiment 3
By moisture content be about 60% mud, be dried to moisture content 40%, take 50 parts, then with 80 mesh flyash (moisture content 30% about) after 20 parts of mixing, through by humidification and drying and processing, controlling mixed material moisture control about 40%, by system Grain machine pelletize, makes small particle, and small particle is directly sent into from Expanded Clay Rotary Kilns top, and small particle is from turning of running up Sub upper moment crashes into Expanded Clay Rotary Kilns, and fall in kiln 1250 DEG C of small particle are thermal zone, form boiling and evaporation at once Moisture, is expanded, expanded after granule rotated outside Expanded Clay Rotary Kilns kiln body, define brown, shape is close to spherosome The sludge ceramsite of shape.Prepared river sludge haydite sample characterization: density is 289.7kg/m3, cylindrical compress strength is 0.32mpa, grain Footpath is distributed in the range of 15mm~25mm, and its alkali resistant aggregate reaction ability is excellent;Its alkali resistant aggregate reaction ability according in Chinese In people republic railroad industry standard tb/t2922.5-2002, railway concrete aggregate basic active test method is (by embodiment 1 Method of testing), result be excellent.
Embodiment 4
Moisture content is about 70% river sludge, is dried to moisture content 40%, takes 50 parts, then be 3mm with particle mean size After 10 parts of the building waste (moisture content 30% about) of left and right, 20 parts of mixing of 80 mesh stone powders (moisture content 25% about), through passing through Humidification and drying and processing, control mixed material moisture control about 40%, by granulator pelletize, make small particle, little Grain thing is directly sent into from Expanded Clay Rotary Kilns top, and small particle moment from the rotor running up crashes into Expanded Clay Rotary Kilns, little In kiln 1200 DEG C of dropout are thermal zone, form boiling and transpiring moisture at once, expanded, expanded after granule Rotated outside Expanded Clay Rotary Kilns kiln body, defined brown, shape is close to sludge ceramsite (shape such as Fig. 1 institute of the ball bodily form Show).Prepared river sludge haydite sample characterization: density is 291kg/m3, cylindrical compress strength is 0.33mpa, and particle diameter distribution exists In the range of 15mm~25mm, its alkali resistant aggregate reaction ability is according to People's Republic of China's railroad industry standard tb/t2922.5- In 2002, with aggregate basic active test method (by the method for testing of embodiment 1), result is excellent to railway concrete.
Embodiment 5
Sludge ceramsite is obtained as aggregate using embodiment 1, by the screening mud in the range of 15~20mm for the particle diameter that sieves Haydite, 25 parts of consumption, with 18 parts of low calcium second class powered coal ash, Portland cement 325r/425r22 part, 5 parts of the broken nitre of 30 mesh, 80 After 3 parts of mesh microcrystalline inorganic material is dry mixed uniformly, sends in frequency conversion numerical control double Luo band blender, add 25 at normal temperatures while stirring Part water and 0.7 part of active toughening auxiliary agent pe m-521,0.7 part of nanometer strengthen accelerator, and (can be purchased from Shang Haihan and reach Chemical Engineering Technology has Limit company), 0.6 part of water-retaining agent cmc, control the double stir speed (S.S.) with blender for the Luo of frequency conversion numerical control to be 60r/min, continue stirring 2 Minute, control gas release in 40 seconds/m3Left and right, die casting molding, control presetting period 60min, final setting time 6h, steam is supported Shield is after 7 hours, then after resting by 24 hours, mechanical stripping, cut after, then 7 days intensity of resting can reach and conventional concrete 28 days corresponding effects;During use, haydite can be strengthened foam concrete heat insulation building block as constructing brick or building block Using.Prepared stripping and slicing, as shown in Fig. 2 the tangent plane after as can be seen from Figure 2 cutting presents a large amount of circles, is physics The sectional view of haydite is it can be clearly seen that hole series structure within haydite, and has and independently close microcellular structure.Stripping and slicing is permissible Directly it is built into the routine buildings such as body of wall (as shown in Figure 3), fishpond (as shown in Figure 4), elegant in appearance.
Strengthen foam concrete heat insulation building block to the haydite that embodiment 5 is obtained to be sampled detecting (80 pieces of quantity): survey Test result is as shown in table 3:
Table 3 haydite strengthens the quality inspection report of foam concrete heat insulation building block
Embodiment 6
Sludge ceramsite is obtained as aggregate using embodiment 1, by the screening mud in the range of 15~20mm for the particle diameter that sieves Haydite, 22 parts of consumption, with 20 parts of low calcium second class powered coal ash, Portland cement 325r/425r22 part, 5 parts of the broken nitre of 30 mesh, 80 After 5 parts of mesh microcrystalline inorganic material is dry mixed uniformly, sends in frequency conversion numerical control double Luo band blender, add 24 at normal temperatures while stirring Part water and 0.7 part of active toughening auxiliary agent pe m-521,0.7 part of nanometer strengthen accelerator, and (can be purchased from Shang Haihan and reach Chemical Engineering Technology has Limit company), 0.6 part of water-retaining agent cmc, control the double stir speed (S.S.) with blender for the Luo of frequency conversion numerical control to be 50r/min, continue stirring 2 Minute, control gas release in 40 seconds/m3Left and right, die casting molding, control presetting period 50min, final setting time 6h, steam is supported Shield is after 7 hours, then after resting by 24 hours, mechanical stripping, cut after, then 7 days intensity of resting can reach and conventional concrete 28 days corresponding effects;During use, haydite can be strengthened foam concrete heat insulation building block as constructing brick or building block Using.
Strengthen foam concrete heat insulation building block to the haydite that embodiment 6 is obtained to be sampled detecting (80 pieces of quantity): survey Test result is as shown in table 4:
Table 4 haydite strengthens the quality inspection report of foam concrete heat insulation building block
Embodiment 7
Sludge ceramsite is obtained as aggregate using embodiment 2, by the screening mud in the range of 15~20mm for the particle diameter that sieves Haydite, 28 parts of consumption, with 15 parts of low calcium second class powered coal ash, Portland cement 325r/425r19 part, 4 parts of the broken nitre of 30 mesh, 80 After 4 parts of mesh microcrystalline inorganic material is dry mixed uniformly, sends in frequency conversion numerical control double Luo band blender, add 28 at normal temperatures while stirring Part water and 0.7 part of active toughening auxiliary agent pe m-521,0.7 part of nanometer strengthen accelerator, and (can be purchased from Shang Haihan and reach Chemical Engineering Technology has Limit company), 0.6 part of water-retaining agent cmc, control the double stir speed (S.S.) with blender for the Luo of frequency conversion numerical control to be 65r/min, continue stirring 2 Minute, control gas release in 40 seconds/m3Left and right, die casting molding, control presetting period 40min, final setting time 5h, steam is supported Shield is after 7 hours, then after resting by 24 hours, mechanical stripping, cut after, then 7 days intensity of resting can reach and conventional concrete 28 days corresponding effects;During use, haydite can be strengthened foam concrete heat insulation building block as constructing brick or building block Using.
Strengthen foam concrete heat insulation building block to the haydite that embodiment 7 is obtained to be sampled detecting (80 pieces of quantity): survey Test result is as shown in table 5:
Table 5 haydite strengthens the quality inspection report of foam concrete heat insulation building block
Embodiment 8
Sludge ceramsite is obtained as aggregate using embodiment 4, by the screening mud in the range of 15~20mm for the particle diameter that sieves Haydite, 30 parts of consumption, with 15 parts of low calcium second class powered coal ash, Portland cement 325r/425r16 part, 5 parts of the broken nitre of 30 mesh, 80 After 5 parts of mesh microcrystalline inorganic material is dry mixed uniformly, sends in frequency conversion numerical control double Luo band blender, add 27 at normal temperatures while stirring Part water and 0.6 part of active toughening auxiliary agent pe m-521,0.6 part of nanometer strengthen accelerator, and (can be purchased from Shang Haihan and reach Chemical Engineering Technology has Limit company), 0.8 part of water-retaining agent cmc, control the double stir speed (S.S.) with blender for the Luo of frequency conversion numerical control to be 50r/min, continue stirring 2 Minute, control gas release in 40 seconds/m3Left and right, die casting molding, control presetting period 60min, final setting time 6h, steam is supported Shield is after 7 hours, then after resting by 24 hours, mechanical stripping, cut after, then 7 days intensity of resting can reach and conventional concrete 28 days corresponding effects;During use, haydite can be strengthened foam concrete heat insulation building block as constructing brick or building block Using.
Strengthen foam concrete heat insulation building block to the haydite that embodiment 8 is obtained to be sampled detecting (80 pieces of quantity): survey Test result is as shown in table 3:
Table 3 haydite strengthens the quality inspection report of foam concrete heat insulation building block

Claims (3)

1. prepare haydite and strengthen the method for foam concrete heat insulation building block it is characterised in that comprising the following steps:
Step one: prepare sludge ceramsite
At least one in building waste, flyash and stone powder and mud are that 20~40:30~50 mix in mass ratio, To 30wt%~45wt%, by granulator granulation, pelletize gained particulate matter is placed in Expanded Clay Rotary Kilns equilibrium moisture content, Expanded at a temperature of 1100 DEG C~1300 DEG C, obtaining final product particle diameter is 15~25mm, and density is 250~300kg/m3Sludge ceramsite;
Step 2: prepare haydite and strengthen foam concrete heat insulation building block
After step one gained sludge ceramsite is mixed homogeneously with other raw materials, it is placed in stir speed (S.S.) and maintains 40~70r/min model Carry out stirring at low speed in blender in enclosing, pass through high-pressure pump carrier to conveying high-pressure in the mixed material in blender simultaneously Gas makes mixed material be foamed, and control gas release is 35~45 seconds/m3;After the completion of foaming, mixed material is poured by mould Injection forming, then sequentially pass through maintenance, the demoulding, cutting, obtain final product haydite and strengthen foam concrete heat insulation building block;
Described haydite strengthens foam concrete heat insulation building block by the raw material including following mass percent component, by thing Haircut bubble, mould molding obtain:
Sludge ceramsite 20%~30%,
Low calcium second class powered coal ash 15%~25%,
Portland cement 15%~25%,
Broken nitre 3%~8%,
Microcrystalline inorganic material 3%~8%,
Water 20%~30%;
Described broken nitre granularity is 25~35 mesh;Described microcrystalline inorganic material granularity is 70~100 mesh;
Described raw material includes active toughening auxiliary agent, nanometer strengthens accelerator and water-retaining agent;Described active toughening auxiliary agent, receive The consumption of meter Zeng Qiang accelerator and water-retaining agent and the mass ratio of water are 0.5~1.5:0.5~1.5:0.5~1.5:30.
2. method according to claim 1 is it is characterised in that control presetting period > in die casting forming process 35min, final setting time < 8h.
3. method according to claim 1 is it is characterised in that foamed time is 2~3min.
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