CN104830578B - High-efficiency toilet cleaning agent and preparation method thereof - Google Patents
High-efficiency toilet cleaning agent and preparation method thereof Download PDFInfo
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- CN104830578B CN104830578B CN201510216596.3A CN201510216596A CN104830578B CN 104830578 B CN104830578 B CN 104830578B CN 201510216596 A CN201510216596 A CN 201510216596A CN 104830578 B CN104830578 B CN 104830578B
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Abstract
The invention specifically relates to a high-efficiency toilet cleaning agent and a preparation method thereof, belonging to the field of cleaning agents. The toilet cleaning agent provided by the invention is composed of iso-alcohol polyoxyethylene ether, (Z)-2,2'-(octadec-9-enylimino)bisethanol, oxalic acid, (hydroxyethylidene)diphosphonic acid, citric acid, sodium chloride, hydrogen peroxide and essence. The preparation method for the toilet cleaning agent comprises the following steps: adding water to dissolve oxalic acid and (Z)-2,2'-(octadec-9-enylimino)bisethanol; then adding iso-alcohol polyoxyethylene ether and carrying out uniform mixing; and adding citric acid, sodium chloride, (hydroxyethylidene)diphosphonic acid, hydrogen peroxide and essence and carrying out uniform mixing under stirring until a transparent liquid is obtained. The toilet cleaning agent provided by the invention has the advantages of exclusion of any inorganic acid, low corrosivity, mildness, environment friendliness, good wall adhesion performance, good cleaning effect and sterilization and disinfection effects; and after usage of the toilet cleaning agent, the porcelain surface of a water closet pan reflects weak blue light, which endows people with comfortability, so requirements of modern people are better met and popularization and utilization of the toilet cleaning agent are facilitated.
Description
Technical field
The invention belongs to cleaning agent field is and in particular to a kind of efficient detergent for toilet and preparation method thereof.
Background technology
With the raising of social development and people's living standard, people to quality of life it is also proposed that higher requirement, especially
It is higher to living environment requirement.Detergent for toilet be in daily life cleaning the requisite magic weapon of lavatory, at present, market clean
Lavatory agent is broadly divided into three major types：Acidic products, neutral products, basic products, wherein optimal with the cleaning performance of acidic products.
Except cleaning and the taste removal of glaze porcelain sanitary equipment can be used for, remove organic beyond the region of objective existence of body discharges, the ferrum of tap water can also be removed
Rust, incrustation scale, have biocidal efficacies and kill the effect such as antibacterial hidden.
But the acidic materials of acid detergent for toilet are mainly mineral acid at present, such as adopt hydrochloric acid, phosphoric acid in inorganic acid salt more
Deng cost is relatively low and also cleaning effect preferably raw material, but these mineral acids have severe corrosive, if Long Term Contact or suction
Enter, strong influence can be caused to the healthy of human body.Therefore, research and develop a kind of cleaning effect good, pollution is little, to people
The detergent for toilet that body does not have harm is a difficult problem for urgent need to resolve.
Content of the invention
Detergent for toilet corrosivity in order to solve prior art are larger, and the strong defect of zest, it is an object of the invention to carry
For a kind of efficient detergent for toilet and preparation method thereof, to solve disadvantages described above.
A kind of efficient detergent for toilet that the present invention provides, described detergent for toilet includes following component and its mass percent：
Isomeric alcohol polyethenoxy ether 1.0-6.0%, oleyl amine polyoxyethylene（2）Ether 0.5-3.0%, oxalic acid 1.0-5.0%, hydroxyl
Ethylene phosphoric acid 0.1-5.0%, citric acid 0.5-4%, sodium chloride 0.1-2.0%, hydrogen peroxidase 10 .1-2.0%, essence 0.05-
2.5%, water 70.5-96.65%.
Preferably, the efficient detergent for toilet of the present invention includes following component and its mass percent：
Isomeric alcohol polyethenoxy ether 1.0-4.0%, oleyl amine polyoxyethylene（2）Ether 0.5-2.0%, oxalic acid 1-4%；Hydroxyl Asia second
Base diphosphonic acid 1.0-4.0%, citric acid 0.5-2.0%, sodium chloride 0.1-1.0%, hydrogen peroxidase 10 .1-1.0%, essence 0.1-1.0%,
Water 80-95%.
Further, the optimal formula of the efficient detergent for toilet of the present invention is as follows：
Isomeric alcohol polyethenoxy ether 2%, oleyl amine polyoxyethylene（2）Ether 1.0%, oxalic acid 3.0%；Hydroxy ethylidene-diphosphate
2.0%, citric acid 1.0%, sodium chloride 0.5%, hydrogen peroxidase 10 .5%, essence 0.5%, water 89.5%.
Isomeric alcohol polyethenoxy ether in the efficient detergent for toilet of the present invention is heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol
One of polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether, preferably isomerous tridecanol polyoxyethylene ether.
Preferably, in the efficient detergent for toilet of the present invention, the concentration of hydrogen peroxide is 27% or 35%, and preferred concentration is 27%.
In addition, the present invention also provides a kind of preparation method preparing efficient detergent for toilet, comprise the following steps：
A) by oxalic acid and oleyl amine polyoxyethylene（2）Ether adds water to be stirred into transparency liquid, obtains oxalic acid and oleyl amine polyoxy
Ethylene（2）The mixed liquor of ether；
B) by step A) mixed liquor that obtains adds isomeric alcohol polyethenoxy ether while stirring, and it is stirred into transparent liquid
Body, obtains isomeric alcohol polyethenoxy ether mixed liquor；
C) by step B) add citric acid, sodium chloride, hydroxy ethylidene-diphosphate, mistake while stirring after the mixed liquor that obtains
Hydrogen oxide and essence, and it is stirred into transparency liquid, obtain final product.
In detergent for toilet of the present invention, isomeric alcohol polyethenoxy ether is that surfactant is a kind of, has emulsifying capacity by force, live in surface
Property high, hard water resistance advantage, in wider pH value range, chemical stability and Environmental compatibility are good, are widely used in domestic and work
Industry washs field.Isomeric alcohol polyethenoxy ether has more preferable infiltration, decontamination and barbotage, tool than fatty alcohol-polyoxyethylene ether
There is more preferably cleaning effect.
Oleyl amine polyoxyethylene in detergent for toilet of the present invention（2）Ether, entitled (Z) -2,2'- (octadec-9- of English
Enylimino) bisethanol, No. CAS is 13127-82-7, and molecular formula is C22H45NO2, molecular weight is 355.5982.Oleyl amine
Polyoxyethylene（2）The Main Function of ether is to bubble, and adjusts the viscosity of detergent for toilet, makes detergent for toilet have preferable wall built-up；Oxalic acid
The spot that oxidant cannot remove can be removed, and hydrogen peroxide is then to remove the dirt that oxalic acid and reducing agent cannot remove
Stain, so, oxalic acid and hydrogen peroxide are used in combination, and can more effectively remove all spots, reach the effect of all-round decontamination.Hydroxyl
Base ethylene phosphoric acid has the effect of stable peroxide hydrogen, strengthens the cleaning effect of detergent for toilet of the present invention.
Compared with prior art, the efficient detergent for toilet of the present invention has the advantage that：
（1）The efficient detergent for toilet of the present invention does not contain mineral acid, and corrosivity are low, gentle environmental protection, and it is good to have a wall built-up, cleaning effect
Fruit is strong, and the advantage having disinfection effect concurrently, is the detergent for toilet of environment-friendly high-efficiency；
（2）The efficient detergent for toilet of the present invention had both contained reducing agent and had contained oxidant simultaneously, can remove various spots comprehensively, and
Water closet pan porcelain facing after making to wash reflects faint blue light, increases the whiteness washing rear porcelain facing.
Specific embodiment：
Below by way of the description of specific embodiment, the invention will be further described, but this is not the limit to the present invention
System, according to the basic thought of the present invention, various modifications may be made or improves for those skilled in the art, but without departing from this
The basic thought of invention, all within the scope of the present invention.
Embodiment 1, the efficient detergent for toilet of the present invention
Detergent for toilet includes following component and its mass percent：Isomeric alcohol polyethenoxy ether 1.0%, oleyl amine polyoxyethylene（2）
Ether 3.0%, oxalic acid 1.0%, hydroxy ethylidene-diphosphate 0.1%, citric acid 0.5%, sodium chloride 2.0%, 35% hydrogen peroxide 2.0% is fragrant
Essence 2.5%, water 87.9%.
Preparation method：
A) weigh 879g water and add oxalic acid 10g and oleyl amine polyoxyethylene while stirring（2）Ether 30g, and be stirred into
Prescribed liquid, obtains oxalic acid and oleyl amine polyoxyethylene（2）The mixed liquor of ether；
B) by step A）The mixed liquor obtaining adds heterogeneous ten alcohol polyoxyethylene ether 10g while stirring, and is stirred into
Transparency liquid, obtains heterogeneous ten alcohol polyoxyethylene ether mixed liquor；
C）By step B）Citric acid 5g, sodium chloride 20g, hydroxyl Asia second is sequentially added while stirring after the mixed liquor obtaining
Base diphosphonic acid 1g, 35% hydrogen peroxide 20g and essence 25g, and it is stirred into transparency liquid, obtain final product.
Embodiment 2, the efficient detergent for toilet of the present invention
Detergent for toilet includes following component and its mass percent：Isomeric alcohol polyethenoxy ether 2.0%, oleyl amine polyoxyethylene（2）
Ether 1.0%, oxalic acid 1.0%, hydroxy ethylidene-diphosphate 2.0%, citric acid 1.0%, sodium chloride 0.5%, 27% hydrogen peroxidase 10 .5% is fragrant
Essence 0.5%, water 91.5%.
Preparation method such as embodiment 1.
Embodiment 3, the efficient detergent for toilet of the present invention
Detergent for toilet includes following component and its mass percent：Isomeric alcohol polyethenoxy ether 3.0%, oleyl amine polyoxyethylene（2）
Ether 5.0%, oxalic acid 5.0%, hydroxy ethylidene-diphosphate 2.0%, citric acid 0.5%, sodium chloride 2.0%, 35% hydrogen peroxidase 10 .1% is fragrant
Essence 0.05%, water 83.85%.
Preparation method such as embodiment 1.
Comparative example one, a kind of detergent for toilet
The composition of detergent for toilet：
The mass percent of oxalic acid is 0, and the mass percent of 27% hydrogen peroxide is 1.5%, remaining composition and preparation technology
As embodiment 2.
Comparative example two, a kind of detergent for toilet
The composition of detergent for toilet：
The mass percent of 27% hydrogen peroxide is 0, and the mass percent of oxalic acid is 1.5%, remaining composition and preparation technology
As embodiment 2.
Comparative example three, a kind of detergent for toilet
The composition of detergent for toilet：
Oxalic acid mass percent is 0, and citric acid mass percent is 0, adds the hydrochloric acid that mass percent is 1.5%, remaining
Composition and preparation technology such as embodiment 2.
Test example 1, the test of detergent for toilet corrosion resistance measurement
1st, method of testing：According to GB/T 21241-2007《Sanitary ware abluent》The test embodiment of the present invention 1, enforcement
The corrosivity to ceramic tile and cast iron of the detergent for toilet of the detergent for toilet of example 2 and embodiment 3 preparation and comparative example three preparation.According to GB/T
21241-2007《Sanitary ware abluent》Regulation, urinal and toilet tailored version detergent for toilet, Z qualified to ceramic tile corrosivity30
1 grade of iron corrosion rank, rank is higher, and corrosivity are stronger.
2nd, testing result shows：It is qualified that 4 sections of detergent for toilet are all judged to the corrosivity of ceramic tile, but corrosivity
Have differences, result is as shown in table 1：
Table 1 detergent for toilet corrosion resistance measurement test data
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example three |
| Ceramic tile | Qualified | Qualified | Qualified | Qualified |
| Z30Iron corrosion rank | 0 grade of corrosion | 0 grade of corrosion | 0 grade of corrosion | 1 grade of corrosion |
From table 1, the detergent for toilet of embodiment of the present invention 1-3 preparation is all qualified to the corrosivity of ceramic tile, to Z30Cast iron
Corrosion level is 0 grade, and a pair of Z of comparative example30Iron corrosion rank is 1 grade, to Z30There are larger corrosivity in cast iron,
Prove with hydrochloric detergent for toilet, the detergent for toilet of present invention preparation has the advantages that corrosivity are low, be conducive to the popularization of this detergent for toilet
And application.
Test example 2, detergent for toilet cleaning effect determination test
1st, test material：The embodiment of the present invention 1, embodiment 2, embodiment 3, comparative example one, comparative example two and comparative example three
The detergent for toilet of preparation.
2nd, subjects：The porcelain facing being processed using artificial urine, makes porcelain facing cover the spot of last layer yellow.
3rd, test method：Prepared by embodiment 1, embodiment 2, embodiment 3, comparative example one, comparative example two and comparative example three
Detergent for toilet be sprayed onto 6 pieces respectively simultaneously and indicate sample 1, sample 2, sample 3, the porcelain facing of sample 4, sample 5 and sample 6 respectively,
Rinsed with clear water simultaneously, observe the cleaning situation of 6 pieces of porcelain facings；Simultaneously white using the porcelain facing after portable whiteness instrument test processes
Degree.
4th, result of the test：
4.1st, spray the porcelain facing of detergent for toilet, with the naked eye can see some solids foul with liquid flow, and
The color of porcelain facing bleaches, and after being rinsed with clear water, porcelain facing is rinsed well substantially；
4.2nd, as shown in table 2, wherein matched group is the porcelain facing processing without detergent for toilet to porcelain facing brightness results, sample 1 be through
The porcelain facing that the detergent for toilet of embodiment 1 preparation is processed, sample 2 is the porcelain facing that the detergent for toilet through embodiment 2 preparation is processed, and sample 3 is
The porcelain facing that detergent for toilet through embodiment 3 preparation is processed, sample 4 is the porcelain facing of the detergent for toilet process of example one preparation by contrast, sample 5
It is the porcelain facing that the detergent for toilet of example two preparation by contrast is processed, sample 6 is the porcelain facing of the detergent for toilet process of example three preparation by contrast.
Table 2 present invention efficient detergent for toilet cleaning effect test data
| Index | Matched group | Sample 1 | Sample 2 | Sample 3 | Sample 4 | Sample 5 | Sample 6 |
| Whiteness | 85 | 80.5 | 83.4 | 81.2 | 72.4 | 73.2 | 76.2 |
From above-mentioned table 2,
1）By sample 1-3 compared with sample 6, the whiteness of the cleaning porcelain facing of the detergent for toilet of present invention preparation is cleaner than hydrochloric
Agent effect in lavatory is good, and the detergent for toilet corrosivity of the present invention are low, gentle environmental protection, has that wall built-up is good, and cleaning effect is good, has concurrently and kills
The advantage of bacterium Disinfection Effect, the water closet pan porcelain facing after simultaneously making to wash reflects faint blue light, gives people a kind of comfort, more can meet existing
Requirement for people；
2）By sample 1-3 it was demonstrated that oxalic acid and hydrogen peroxide are used in combination compared with sample 4-5, can more effectively remove
All spots, reach the effect of all-round decontamination, are used alone oxalic acid or hydrogen peroxide, and its cleaning effect can be greatly reduced.
Claims (4)
1. a kind of efficient detergent for toilet is it is characterised in that be made up of following component and its mass percent：Isomeric alcohol polyethenoxy ether
2.0%, oleyl amine polyoxyethylene (2) ether 1.0%, oxalic acid 3.0%, hydroxy ethylidene-diphosphate 2.0%, citric acid 1.0%, chlorination
Sodium 0.5%, hydrogen peroxidase 10 .5%, essence 0.5%, water 89.5%；Described isomeric alcohol polyethenoxy ether is isomery ten alcohol polyoxy second
One of alkene ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether；The quality hundred of described hydrogen peroxide
Specific concentration is divided to be 27% or 35%.
2. as claimed in claim 1 efficiently detergent for toilet it is characterised in that described isomeric alcohol polyethenoxy ether is isomerous tridecanol
Polyoxyethylene ether.
3. as claimed in claim 1 efficiently detergent for toilet it is characterised in that the mass percent concentration of described hydrogen peroxide is
27%.
4. a kind of preparation method of efficient as claimed in claim 1 detergent for toilet is it is characterised in that comprise the following steps：
A) oxalic acid and oleyl amine polyoxyethylene (2) ether are added to the water, are stirred into transparency liquid, obtain and gather containing oxalic acid and oleyl amine
The mixed liquor of oxygen ethylene (2) ether；
B) by step A) mixed liquor that obtains adds isomeric alcohol polyethenoxy ether while stirring, and it is stirred into transparency liquid
Mixed liquor；
C) by step B) mixed liquor that obtains adds citric acid, sodium chloride, hydroxy ethylidene-diphosphate, hydrogen peroxide while stirring
And essence, and it is stirred into transparency liquid, obtain final product.
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| CN106281784A (en) * | 2016-08-25 | 2017-01-04 | 仇颖超 | A kind of preparation method of efficient detergent for toilet |
| CN106350242A (en) * | 2016-08-30 | 2017-01-25 | 武汉金泉环保有限公司 | Mobile toilet detergent |
| CN107674770A (en) * | 2017-10-26 | 2018-02-09 | 桂林大创科技有限公司 | A kind of efficiently detergent for toilet and preparation method thereof |
| CN108659971A (en) * | 2018-06-15 | 2018-10-16 | 河北晨晨环境科技股份有限公司 | Detergent for toilet and preparation method thereof |
| CN110257183A (en) * | 2019-06-27 | 2019-09-20 | 广州珺凯清洁剂有限公司 | A kind of cleaning toilet aromatic |
| CN113583762A (en) * | 2021-09-10 | 2021-11-02 | 湖南金裕环保科技有限公司 | High-alkali-resistant low-foam surfactant and preparation method thereof |
| CN114698634B (en) * | 2022-03-09 | 2023-04-07 | 四川科宏达集团有限责任公司 | Application of isomeric tridecanol polyoxyethylene ether in iodine disinfectant and application method thereof |
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| CN101463293A (en) * | 2007-12-21 | 2009-06-24 | 上海和黄白猫有限公司 | Perfuming viscous type acidic closestool cleanser |
| CN104059783B (en) * | 2014-06-10 | 2017-10-03 | 深圳市新纶科技股份有限公司 | A kind of preparation method of detergent use surfactant |
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