CN104830136A - Environmental-friendly and antibacterial coating - Google Patents
Environmental-friendly and antibacterial coating Download PDFInfo
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- CN104830136A CN104830136A CN201510277595.XA CN201510277595A CN104830136A CN 104830136 A CN104830136 A CN 104830136A CN 201510277595 A CN201510277595 A CN 201510277595A CN 104830136 A CN104830136 A CN 104830136A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention disclose an environmental-friendly and antibacterial coating which comprises, by weight, 20-40 parts of water, 10-20 parts of deodorizing emulsion, 0.2-0.6 part of dispersant, 0.2-0.4 part of wetting agent, 0.1-0.3 part of defoaming agent, 10-25 parts of alumina powder, 5-15 parts of silicon powder, 5-15 parts of talcum powder, 10-20 parts of ground calcium carbonate powder, 0.1-0.5 part of sodium pyrophosphate, 0.1-0.2 part of nano silica, 0.4-0.6 part of preservative, and 0.4-0.8 part of antibacterial agent. The environmental-friendly and antibacterial coating is reasonable in formula, low in cost, good in component compatibility, environmental friendly, mould preventing, antibacterial, and excellent in application value; the mould preventing effect is durable due to the fact that the natural antibacterial agent and the inorganic antibacterial agent are mixed in use; the coating is short in film forming drying time, good in hardness, and good in extension property and heat resistance.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of environment friendly bacteriostatic coating.
Background technology
Coating is widely applied to life and the every field in producing, the film that coating is formed can play decoration to object, protection and mark effect, along with the raising that people require, existing coating has been changed into the coating of environmental protection more by the coating that traditional hazardness is larger, the environmental protection coating material used in the market, when mostly there is film forming, time of drying is long, be coated with film elasticity easily aging, flintiness is bad, and water soluble paint subjects to biological damage, generation due to bacterium depends on the environment of water, therefore, existing water soluble paint is easy to occur going mouldy mostly, its anticorrosion and uniform ideal of wear resisting property, effectively can not protect relevant device.
Summary of the invention
For the defect existed in prior art, the object of this invention is to provide a kind of environment friendly bacteriostatic coating.
Described a kind of environment friendly bacteriostatic coating, is characterized in that this environment friendly bacteriostatic coating is made up of the component of following weight part: water 20-40 part, clean taste emulsion 10-20 part, dispersion agent 0.2-0.6 part, wetting agent 0.2-0.4 part, defoamer 0.1-0.3 part, aluminum oxide powder 10-25 part, silica flour 5-15 part, talcum powder 5-15 part, heavy calcium carbonate 10-20 part, trisodium phosphate 0.1-0.5 part, nano silicon 0.1-0.2 part, sanitas 0.4-0.6 part, antiseptic-germicide 0.4-0.8 part.
Described a kind of environment friendly bacteriostatic coating, is characterized in that this environment friendly bacteriostatic coating is made up of the component of following weight part: water 25-35 part, clean taste emulsion 12-18 part, dispersion agent 0.3-0.5 part, wetting agent 0.2-0.3 part, defoamer 0.2-0.3 part, aluminum oxide powder 15-20 part, silica flour 6-12 part, talcum powder 6-12 part, heavy calcium carbonate 12-18 part, trisodium phosphate 0.2-0.4 part, nano silicon 0.1-0.2 part, sanitas 0.3-0.5 part, antiseptic-germicide 0.5-0.7 part.
Described a kind of environment friendly bacteriostatic coating, is characterized in that described environment friendly bacteriostatic coating is made up of the component of following weight part: 30 parts, water, clean taste emulsion 15 parts, dispersion agent 0.4 part, wetting agent 0.3 part, defoamer 0.2 part, aluminum oxide powder 17 parts, silica flour 10 parts, talcum powder 8 parts, heavy calcium carbonate 15 parts, trisodium phosphate 0.3 part, nano silicon 0.1 part, sanitas 0.4 part, antiseptic-germicide 0.6 part.
Described a kind of environment friendly bacteriostatic coating, is characterized in that described antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 4:1.
Described a kind of environment friendly bacteriostatic coating, is characterized in that described natural antibacterial agent is Folium Bambosae extract, Folium Ginkgo extract, Aloe extract mix with the weight of 3:2:3.
Described a kind of environment friendly bacteriostatic coating, it is characterized in that described inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, phosphate type antiseptic-germicide, described bentonite bactericidal agent: montmorillonite germicide: the weight ratio of phosphate type antiseptic-germicide is 2:1:1.
Described a kind of environment friendly bacteriostatic coating, is characterized in that described defoamer is the mixture of organo-siloxane defoamer and polyether antifoam agent, and both weight ratios are organo-siloxane defoamer: polyether antifoam agent=1:0.5.
Described a kind of environment friendly bacteriostatic coating, is characterized in that described sanitas is the mixture that isothiazolinone derivatives and benzo miaow frustrate ester class, and both weight ratios are isothiazolinone derivatives: benzo miaow frustrates ester class=1:1.
Wetting agent of the present invention adopts the wetting agent D-504 of low bubble performance, transparent yellow liquid, uses in formula with other components matching, has certain froth breaking and presses down bubble effect, can improve the flow leveling of product simultaneously; For the mixture of organo-siloxane defoamer and polyether antifoam agent, both weight ratios are organo-siloxane defoamer: polyether antifoam agent=1:0.5, defoaming capacity is strong, being easy to prepares burden with other mixes, side reaction can not caused, with wetting agent with the use of reaching better wetting effect in film process.Nano silicon can have extremely strong absorption ultraviolet, reflective infrared line features, can improve the ageing resistance of coating; Trisodium phosphate is as making water-softening chemicals, what produce water-borne coatings is common water, and often hardness is higher, adds trisodium phosphate and can reduce water hardness and make dispersion agent and emulsifying agent: trisodium phosphate has deflocculation, play emulsifying effect with coating, improve the stability of coating.Aluminum oxide powder plays strengthening action, and improve hardness and the wear resistance of coating, hardness whatever you like increases and improves; Do not affect coating adhesion and the transparency.
The use of antiseptic-germicide of the present invention, can the generation of effective mould fungus inhibition, and fungistatic effect is lasting, and this antiseptic-germicide environmental protection, can not to environment.
Compared with prior art, the present invention has following beneficial effect:
1, coating disclosed by the invention composition rationally, and cost is low, and between each component, consistency is good, environmental protection, mildew-resistant, antibacterial, has excellent using value;
2, natural antibacterial agent of the present invention and inorganic antiseptic is used in combination, namely avoids and uses merely the problem of the poor stability existing for natural antibacterial agent or be used alone the pollution that organic antibacterial agent brings and the high cost problem being used alone inorganic antiseptic; Combinationally use its anti-mold effect more lasting;
3, water-borne coatings film forming of the present invention is short for time of drying, and flintiness is good, also has good extension property and resistance toheat simultaneously.
Embodiment
The present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
A kind of environment friendly bacteriostatic coating, is made up of the component of following weight part: 30 parts, water, clean taste emulsion 15 parts, dispersion agent 0.4 part, wetting agent 0.3 part, defoamer 0.2 part, aluminum oxide powder 17 parts, silica flour 10 parts, talcum powder 8 parts, heavy calcium carbonate 15 parts, trisodium phosphate 0.3 part, nano silicon 0.1 part, sanitas 0.4 part, antiseptic-germicide 0.6 part.
Wherein, antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 4:1, and natural antibacterial agent is Folium Bambosae extract, Folium Ginkgo extract, Aloe extract mix with the weight of 3:2:3; Inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, phosphate type antiseptic-germicide, bentonite bactericidal agent: montmorillonite germicide: the weight ratio of phosphate type antiseptic-germicide is 2:1:1.The each composition of natural antibacterial agent and each composition of inorganic antiseptic all can be bought by market and obtain.Defoamer is the mixture of organo-siloxane defoamer and polyether antifoam agent, and both weight ratios are organo-siloxane defoamer: polyether antifoam agent=1:0.5.Sanitas is the mixture that isothiazolinone derivatives and benzo miaow frustrate ester class, and both weight ratios are isothiazolinone derivatives: benzo miaow frustrates ester class=1:1.
Embodiment 2
A kind of environment friendly bacteriostatic coating, is made up of the component of following weight part: 20 parts, water, clean taste emulsion 20 parts, dispersion agent 0.2 part, wetting agent 0.4 part, defoamer 0.1 part, aluminum oxide powder 25 parts, silica flour 5 parts, talcum powder 15 parts, heavy calcium carbonate 10 parts, trisodium phosphate 0.5 part, nano silicon 0.1 part, sanitas 0.6 part, antiseptic-germicide 0.4 part.
Wherein, antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 4:1, and natural antibacterial agent is Folium Bambosae extract, Folium Ginkgo extract, Aloe extract mix with the weight of 3:2:3; Inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, phosphate type antiseptic-germicide, bentonite bactericidal agent: montmorillonite germicide: the weight ratio of phosphate type antiseptic-germicide is 2:1:1.The each composition of natural antibacterial agent and each composition of inorganic antiseptic all can be bought by market and obtain.Defoamer is the mixture of organo-siloxane defoamer and polyether antifoam agent, and both weight ratios are organo-siloxane defoamer: polyether antifoam agent=1:0.5.Sanitas is the mixture that isothiazolinone derivatives and benzo miaow frustrate ester class, and both weight ratios are isothiazolinone derivatives: benzo miaow frustrates ester class=1:1.
Embodiment 3
A kind of environment friendly bacteriostatic coating, is made up of the component of following weight part: 35 parts, water, clean taste emulsion 12 parts, dispersion agent 0.5 part, wetting agent 0.2 part, defoamer 0.3 part, aluminum oxide powder 15 parts, silica flour 12 parts, talcum powder 6 parts, heavy calcium carbonate 18 parts, trisodium phosphate 0.2 part, nano silicon 0.2 part, sanitas 0.3 part, antiseptic-germicide 0.7 part.
Wherein, antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 4:1, and natural antibacterial agent is Folium Bambosae extract, Folium Ginkgo extract, Aloe extract mix with the weight of 3:2:3; Inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, phosphate type antiseptic-germicide, bentonite bactericidal agent: montmorillonite germicide: the weight ratio of phosphate type antiseptic-germicide is 2:1:1.The each composition of natural antibacterial agent and each composition of inorganic antiseptic all can be bought by market and obtain.Defoamer is the mixture of organo-siloxane defoamer and polyether antifoam agent, and both weight ratios are organo-siloxane defoamer: polyether antifoam agent=1:0.5.Sanitas is the mixture that isothiazolinone derivatives and benzo miaow frustrate ester class, and both weight ratios are isothiazolinone derivatives: benzo miaow frustrates ester class=1:1.
Performance test
Test the VOC content of above-mentioned coating according to GB18582-2008, test the sticking power of above-mentioned coating, time of drying and impact resistance according to GB1720, GB1728, GB1732, the results are shown in Table 1.
Table 1 performance test
Sterilant is tested: Chaetomium globosum bacterium, Aspergillus flavus are spread evenly across and scribble on the slide glass of above-mentioned coating, after 0,5,15,30,60,120 hour, be gently stained with bacterium liquid by swab stick is placed in physiological saline, vibration, get 0.5ml in culture dish, add substratum, cultivate 48 hours in incubator, take out number colony number, according to formulae discovery sterilizing rate: sterilizing rate=(after initial colony number-sterilization colony number)/initial colony number × 100%, the results are shown in Table 2.
Table 2 sterilization is tested
As can be seen from table 1 and table 2, coating antibiosis fungicidal properties of the present invention is good, environmental protection, solidification are quick, has excellent flame retardant properties, is applicable to applying.
To adopting the water-based anticorrosive paint of embodiment 1 formula preparation to carry out antiseptic property detection, detected result is in table 3.
Table 3: antiseptic property detected result of the present invention
As shown in Table 3: adopt the present invention fill a prescription preparation environment friendly bacteriostatic coating there is higher resisting salt fog corrosion ability, favorable anti-corrosion effect.
Claims (8)
1. an environment friendly bacteriostatic coating, is characterized in that this environment friendly bacteriostatic coating is made up of the component of following weight part: water 20-40 part, clean taste emulsion 10-20 part, dispersion agent 0.2-0.6 part, wetting agent 0.2-0.4 part, defoamer 0.1-0.3 part, aluminum oxide powder 10-25 part, silica flour 5-15 part, talcum powder 5-15 part, heavy calcium carbonate 10-20 part, trisodium phosphate 0.1-0.5 part, nano silicon 0.1-0.2 part, sanitas 0.4-0.6 part, antiseptic-germicide 0.4-0.8 part.
2. a kind of environment friendly bacteriostatic coating according to claim 1, is characterized in that this environment friendly bacteriostatic coating is made up of the component of following weight part: water 25-35 part, clean taste emulsion 12-18 part, dispersion agent 0.3-0.5 part, wetting agent 0.2-0.3 part, defoamer 0.2-0.3 part, aluminum oxide powder 15-20 part, silica flour 6-12 part, talcum powder 6-12 part, heavy calcium carbonate 12-18 part, trisodium phosphate 0.2-0.4 part, nano silicon 0.1-0.2 part, sanitas 0.3-0.5 part, antiseptic-germicide 0.5-0.7 part.
3. a kind of environment friendly bacteriostatic coating according to claim 1 and 2, is characterized in that described environment friendly bacteriostatic coating is made up of the component of following weight part: 30 parts, water, clean taste emulsion 15 parts, dispersion agent 0.4 part, wetting agent 0.3 part, defoamer 0.2 part, aluminum oxide powder 17 parts, silica flour 10 parts, talcum powder 8 parts, heavy calcium carbonate 15 parts, trisodium phosphate 0.3 part, nano silicon 0.1 part, sanitas 0.4 part, antiseptic-germicide 0.6 part.
4. a kind of environment friendly bacteriostatic coating according to claim 1 or 2 or 3, is characterized in that described antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 4:1.
5. a kind of environment friendly bacteriostatic coating according to claim 4, is characterized in that described natural antibacterial agent is Folium Bambosae extract, Folium Ginkgo extract, Aloe extract mix with the weight of 3:2:3.
6. a kind of environment friendly bacteriostatic coating according to claim 4, it is characterized in that described inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, phosphate type antiseptic-germicide, described bentonite bactericidal agent: montmorillonite germicide: the weight ratio of phosphate type antiseptic-germicide is 2:1:1.
7. a kind of environment friendly bacteriostatic coating according to claim 1 or 2 or 3, is characterized in that described defoamer is the mixture of organo-siloxane defoamer and polyether antifoam agent, and both weight ratios are organo-siloxane defoamer: polyether antifoam agent=1:0.5.
8. a kind of environment friendly bacteriostatic coating according to claim 1 or 2 or 3, is characterized in that described sanitas is the mixture that isothiazolinone derivatives and benzo miaow frustrate ester class, and both weight ratios are isothiazolinone derivatives: benzo miaow frustrates ester class=1:1.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20200110054A (en) * | 2019-03-15 | 2020-09-23 | 고의석 | Package for food using ginkgo biloba extracts and manufacturing method thereof |
CN113999590A (en) * | 2021-11-09 | 2022-02-01 | 江门市皇宙实业有限公司 | Powder coating with antibacterial function and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20200110054A (en) * | 2019-03-15 | 2020-09-23 | 고의석 | Package for food using ginkgo biloba extracts and manufacturing method thereof |
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CN113999590A (en) * | 2021-11-09 | 2022-02-01 | 江门市皇宙实业有限公司 | Powder coating with antibacterial function and preparation method thereof |
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Application publication date: 20150812 |