CN104829913A - 一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料及其制作方法 - Google Patents
一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料及其制作方法 Download PDFInfo
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Abstract
本发明公开了一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料,其特征在于,由下列重量份的原料制成:高密度聚乙烯65-75、三元乙丙橡胶20-25、尼龙6 16-22、PET纤维6-10、聚乙烯蜡2-4、硫代二丙酸二月桂酯3-5、硫磺0.2-0.3、硅烷偶联剂G-570 15-20、环氧大豆油6-9、醋丙乳液40-45、棕刚玉烟尘17-20、硼酸锌0.3-0.6、苯并三氮唑0.4-0.7、水适量;本发明配方合理,添加PET纤维提高了电缆料的耐磨性能,添加硅烷偶联剂G-570与聚乙烯复合物交联后形成的网状结构能有效阻止油类物质向共混材料分子内的渗透扩散,从而表现出良好的阻隔性能,同时还添加其他有效助剂制得的电缆料具有抗开裂、耐候、低烟、耐臭氧等优点,适用于矿井或安全性很高的特殊工作环境的场合。
Description
技术领域
本发明涉及电缆料技术领域,具体涉及一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料及其制作方法。
背景技术
随着现代科学技术的发展,人们对电线电缆的质量要求越来越高,硅烷交联聚乙烯的出现,弥补了普通聚乙烯电线电缆的不足。硅烷交联聚乙烯电缆料能提高线路的传输容量、过载能力,且该材料在制造交联电线电缆时,与过氧化物交联和辐照交联相比,具有所需制造设备简单,操作方便,综合成本低等优点,作为低压电力电缆的绝缘材料目前在我国电线电缆行业中已成为低压交联电缆用绝缘的主导材料。
高密度聚乙烯价格低廉、质轻、性能优良,但高密度聚乙烯的线型分子结构决定了其在较高温度下存在性能缺陷,如分子间结合力下降、易发生形变、表现为蠕变增大、刚性和力学性能下降;高密度聚乙烯为非极性聚合物,虽对水等极性溶剂具有良好阻隔性,但对二甲苯等有机溶剂具有较高的透过性,气体阻隔性也不好。尼龙为极性聚合物,对非极性溶剂、气体的阻隔性好,但对极性溶剂的阻隔性较差,而且尼龙易吸水,从而降低材料的力学性能。将硅烷交联改性的高密度聚乙烯与尼龙进行共混,虽然可以提高电缆料的阻隔性,但功能较为单一,在耐磨性、抗弯曲能力、耐老化程度、易腐蚀状况、强度和耐日照性等方面还存在缺陷。
发明内容
本发明的目的就是提供一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料及其制作方法,以克服现有技术的不足。
本发明的目的是这样实现的:
一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料,其特征在于,由下列重量份的原料制成:高密度聚乙烯65-75、三元乙丙橡胶20-25、尼龙6 16-22、PET纤维6-10、聚乙烯蜡2-4、硫代二丙酸二月桂酯3-5、硫磺0.2-0.3、硅烷偶联剂G-570 15-20、环氧大豆油6-9、醋丙乳液40-45、棕刚玉烟尘17-20、硼酸锌0.3-0.6、苯并三氮唑0.4-0.7、水适量。
所述的一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料的制备方法,其特征在于包括以下步骤:
(1)将棕刚玉烟尘于610-730℃煅烧2-3小时,冷却加入硼酸锌、苯并三氮唑研磨30-40分钟,制得改性棕刚玉烟尘;
(2)将尼龙6在真空干燥箱中80℃干燥24h后与改性棕刚玉烟尘、硫代二丙酸二月桂酯、硫磺一起投入高混机搅拌均匀,加入到挤出机中混炼造粒;
(3)将PET纤维投入醋丙乳液中浸泡5-8小时,烘干粉碎过100-200目筛,加入硅烷偶联剂G-570、环氧大豆油分散研磨30-50分钟,得到硅烷复合剂;
(4)将高密度聚乙烯、三元乙丙橡胶投入高混机,加入硅烷复合剂,搅拌均匀, 加入步骤(2)物料及其他剩余成分混合搅拌均匀,放入单螺杆挤出机挤出成片,将试片放入80℃水浴中交联6-8小时,出料。
本发明有以下有益效果:本发明配方合理,添加PET纤维提高了电缆料的耐磨性能,添加硅烷偶联剂G-570与聚乙烯复合物交联后形成的网状结构能有效阻止油类物质向共混材料分子内的渗透扩散,从而表现出良好的阻隔性能,同时还添加其他有效助剂制得的电缆料具有抗开裂、耐候、低烟、耐臭氧等优点,适用于矿井或安全性很高的特殊工作环境的场合。
具体实施方式
所述的一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料,其特征在于,由下列重量份的原料制成:高密度聚乙烯69、三元乙丙橡胶21、尼龙6 18、PET纤维8、聚乙烯蜡2、硫代二丙酸二月桂酯3、硫磺0.2、硅烷偶联剂G-570 18、环氧大豆油6、醋丙乳液43、棕刚玉烟尘18、硼酸锌0.5、苯并三氮唑0.6、水适量。
制作方法包括以下步骤:
(1)将棕刚玉烟尘于610-730℃煅烧2-3小时,冷却加入硼酸锌、苯并三氮唑研磨30-40分钟,制得改性棕刚玉烟尘;
(2)将尼龙6在真空干燥箱中80℃干燥24h后与改性棕刚玉烟尘、硫代二丙酸二月桂酯、硫磺一起投入高混机搅拌均匀,加入到挤出机中混炼造粒;
(3)将PET纤维投入醋丙乳液中浸泡5-8小时,烘干粉碎过100-200目筛,加入硅烷偶联剂G-570、环氧大豆油分散研磨30-50分钟,得到硅烷复合剂;
(4)将高密度聚乙烯、三元乙丙橡胶投入高混机,加入硅烷复合剂,搅拌均匀, 加入步骤(2)物料及其他剩余成分混合搅拌均匀,放入单螺杆挤出机挤出成片,将试片放入80℃水浴中交联6-8小时,出料。
使用本发明生产的硅烷交联聚乙烯电缆料的技术参数指标如下:
(1)按HG2-146-65的标准测定交联6h的吸油率:10.37%;
(2)按GB/T 1040-1992测定交联6h的拉伸强度:21.37MPa;
(3)氧指数:31.33%。
Claims (2)
1.一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料,其特征在于,由下列重量份的原料制成:高密度聚乙烯65-75、三元乙丙橡胶20-25、尼龙6 16-22、PET纤维6-10、聚乙烯蜡2-4、硫代二丙酸二月桂酯3-5、硫磺0.2-0.3、硅烷偶联剂G-570 15-20、环氧大豆油6-9、醋丙乳液40-45、棕刚玉烟尘17-20、硼酸锌0.3-0.6、苯并三氮唑0.4-0.7、水适量。
2.根据权利要求1所述的一种低烟耐候电线电缆用硅烷交联聚乙烯电缆料的制作方法,其特征在于包括以下步骤:
(1)将棕刚玉烟尘于610-730℃煅烧2-3小时,冷却加入硼酸锌、苯并三氮唑研磨30-40分钟,制得改性棕刚玉烟尘;
(2)将尼龙6在真空干燥箱中80℃干燥24h后与改性棕刚玉烟尘、硫代二丙酸二月桂酯、硫磺一起投入高混机搅拌均匀,加入到挤出机中混炼造粒;
(3)将PET纤维投入醋丙乳液中浸泡5-8小时,烘干粉碎过100-200目筛,加入硅烷偶联剂G-570、环氧大豆油分散研磨30-50分钟,得到硅烷复合剂;
(4)将高密度聚乙烯、三元乙丙橡胶投入高混机,加入硅烷复合剂,搅拌均匀, 加入步骤(2)物料及其他剩余成分混合搅拌均匀,放入单螺杆挤出机挤出成片,将试片放入80℃水浴中交联6-8小时,出料。
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CN105801975A (zh) * | 2016-04-21 | 2016-07-27 | 安徽万泰电缆有限公司 | 一种阻燃抗开裂电缆材料 |
CN105860184A (zh) * | 2016-05-20 | 2016-08-17 | 安徽新科电缆集团股份有限公司 | 一种电线外护套配方 |
CN108440814A (zh) * | 2018-01-30 | 2018-08-24 | 昆明天磊线缆材料有限公司 | 一种125℃低烟无卤交联型聚烯烃线缆料制作方法 |
CN109754923A (zh) * | 2019-02-28 | 2019-05-14 | 苏州金弘峰电子有限公司 | 一种绝缘线及其制备方法 |
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CN105801975A (zh) * | 2016-04-21 | 2016-07-27 | 安徽万泰电缆有限公司 | 一种阻燃抗开裂电缆材料 |
CN105860184A (zh) * | 2016-05-20 | 2016-08-17 | 安徽新科电缆集团股份有限公司 | 一种电线外护套配方 |
CN108440814A (zh) * | 2018-01-30 | 2018-08-24 | 昆明天磊线缆材料有限公司 | 一种125℃低烟无卤交联型聚烯烃线缆料制作方法 |
CN109754923A (zh) * | 2019-02-28 | 2019-05-14 | 苏州金弘峰电子有限公司 | 一种绝缘线及其制备方法 |
CN109754923B (zh) * | 2019-02-28 | 2020-08-04 | 苏州金弘峰电子有限公司 | 一种绝缘线及其制备方法 |
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