CN104804713A - Anhydrous coolant of automobile engine - Google Patents

Anhydrous coolant of automobile engine Download PDF

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Publication number
CN104804713A
CN104804713A CN201510222331.4A CN201510222331A CN104804713A CN 104804713 A CN104804713 A CN 104804713A CN 201510222331 A CN201510222331 A CN 201510222331A CN 104804713 A CN104804713 A CN 104804713A
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China
Prior art keywords
parts
poly
motor car
car engine
engine water
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Application number
CN201510222331.4A
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Chinese (zh)
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CN104804713B (en
Inventor
袁娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Junsheng Qunying Automobile System Co Ltd
Original Assignee
宁波保税区韬鸿化工科技有限公司
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Priority to CN201510222331.4A priority Critical patent/CN104804713B/en
Publication of CN104804713A publication Critical patent/CN104804713A/en
Application granted granted Critical
Publication of CN104804713B publication Critical patent/CN104804713B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20Antifreeze additives therefor, e.g. for radiator liquids

Abstract

The invention discloses an anhydrous coolant of an automobile engine, which comprises the following raw materials in parts by mass: 100 parts of 1,2-propylene glycol, 0.1-0.5 parts of benzotriazole, 0.5-1.5 parts of polyamino acid, 0.1-0.5 parts of sodium nitrate, 0.5-1.5 parts of sodium molybdate and 0.1-0.3 parts of dimethicone. The anhydrous coolant of the automobile engine is high in stability, overcomes the technical defect of easy boiling of the traditional hydrous coolant, and facilitates operation of the engine at a full load and a high load.

Description

Motor car engine water-free cooling
Technical field
The present invention relates to a kind of cooling fluid, particularly relate to a kind of motor car engine water-free cooling.
Background technology
The full name of deicing fluid should be anti-freeze cooling liquid, means the cooling fluid of antifreeze function.Deicing fluid can prevent the unfrozen cooling fluid when Cold Winter stops and spalling scatterer and freezing engine cylinder block or lid.But we will correct a misunderstanding, deicing fluid is not only winter, and it should use in the whole year.In automobile maintenance project normally, often travel 1 year, need engine fluid be changed.
Cooling fluid is mainly used in car engine cooling system, has cooling, antifreeze, antiscale, anticorrosion, the anti-effect such as to boil.Cooling fluid is primarily of compositions such as frostproofer, water, inhibiter, defoamer, staining agents.The gordian technique of cooling fluid is the reasonable interworking of the additive such as various inhibiter and defoamer.The over-all properties of existing cooling fluid product is still not ideal enough.
Containing water coolant, all there is the technological deficiency of easily " boiling " in tradition.
Summary of the invention
One of technical problem to be solved by this invention is to provide a kind of motor car engine water-free cooling.
The present invention, is achieved by the following technical solution:
A kind of motor car engine water-free cooling, be made up of by mass parts following raw material: 1,2-propylene glycol (No. CAS: 57-55-6) 100 parts, benzotriazole (No. CAS: 95-14-7) 0.1-0.5 part, polyamino acid 0.5-1.5 part, SODIUMNITRATE (No. CAS: 7631-99-4) 0.1-0.5 part, Sodium orthomolybdate (No. CAS: 10102-40-6) 0.5-1.5 part, dimethyl silicone oil (No. CAS: 9006-65-9) 0.1-0.3 part.
Described polyamino acid is one in poly-aspartic-acid (No. CAS: 181828-06-8), poly-L-Leu (No. CAS: 25322-63-8) and polyglycine (No. CAS: 25718-94-9) or its mixture.
Preferably, described polyamino acid is the mixture of poly-aspartic-acid and poly-L-Leu, and wherein the mass ratio of poly-aspartic-acid and poly-L-Leu is 4:1-1:4.
Mixed by above-mentioned raw materials, stir, all material mixings can obtain motor car engine water-free cooling of the present invention.Enter interpolation one step ground, motor car engine water-free cooling pH to 8-9 of the present invention can be regulated with sodium hydroxide or potassium hydroxide again.
Motor car engine water-free cooling of the present invention, stability is high, not blocking pipe, and antifreeze, antirust, ant-scaling is high, effectively can prevent the corrosion to ferrous metal, tin, Copper and its alloy, Al and Alalloy, and overcome the technological deficiency of easy " boiling " that tradition exists containing water coolant, be conducive to engine to run under fully loaded, high loading, can guarantee vehicle on plateau, desert, the safety traffic of the severe environment such as cold, be particularly suitable for military vehicle, high-end vehicles and high-power heavy loading lorry and passenger vehicle.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1-4
Under room temperature, take each raw material, mixed by each raw material, stir by the corresponding embodiment 1-4 of table 1, hydro-oxidation sodium regulates pH to 8.5, can obtain motor car engine water-free cooling of the present invention.
Table 1: motor car engine water-free cooling formula table unit: kilogram
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
1,2-PD 100 100 100 100
Benzotriazole 0.3 0.3 0.3 0.3
Poly-aspartic-acid 0.5 - 1 -
Poly-L-Leu 0.5 1 - -
SODIUMNITRATE 0.3 0.3 0.3 0.3
Sodium orthomolybdate 1 1 1 1
Dimethyl silicone oil 0.2 0.2 0.2 0.2
Test case 1
Cast aluminium alloy heat transfer corrosion test, experimental data is as table 2.
Table 2: cast aluminium alloy heat transfer corrosion test table
Cast aluminium alloy heat transfer corrosion, mg/cm 2
Embodiment 1 0.18
Embodiment 2 0.43
Embodiment 3 0.46
Embodiment 4 0.92
Test case 2
Glassware corrosion is tested, and experimental data is as table 3.
Table 3: glassware corrosion test card
Glassware corrosion test (672 hours, 20%v/v, copper sheet), mg/ sheet
Embodiment 1 0.6
Embodiment 2 1.7
Embodiment 3 1.6
Embodiment 4 4.4
Motor car engine water-free cooling of the present invention, stability is high, not blocking pipe, and antifreeze, antirust, ant-scaling is high.After automobile uses cooling fluid of the present invention, throttle lightens; Power strengthens; Speed-raising is accelerated smooth; Engine noise diminishes; Parking fetches boiling water case lid without pressure.

Claims (4)

1. a motor car engine water-free cooling, is characterized in that, comprises following raw material: 1,2-PD, benzotriazole, SODIUMNITRATE, Sodium orthomolybdate and dimethyl silicone oil.
2. a motor car engine water-free cooling, is characterized in that, is made up of: 1 following raw material by mass parts, 2-propylene glycol 100 parts, benzotriazole 0.1-0.5 part, polyamino acid 0.5-1.5 part, SODIUMNITRATE 0.1-0.5 part, Sodium orthomolybdate 0.5-1.5 part, dimethyl silicone oil 0.1-0.3 part.
3. motor car engine water-free cooling as claimed in claim 2, is characterized in that, described polyamino acid is one in poly-aspartic-acid, poly-L-Leu and polyglycine or its mixture.
4. motor car engine water-free cooling as claimed in claim 3, it is characterized in that, described polyamino acid is the mixture of poly-aspartic-acid and poly-L-Leu, and wherein the mass ratio of poly-aspartic-acid and poly-L-Leu is 4:1-1:4.
CN201510222331.4A 2015-05-04 2015-05-04 Automobile engine water-free cooling Expired - Fee Related CN104804713B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510222331.4A CN104804713B (en) 2015-05-04 2015-05-04 Automobile engine water-free cooling

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510222331.4A CN104804713B (en) 2015-05-04 2015-05-04 Automobile engine water-free cooling

Publications (2)

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CN104804713A true CN104804713A (en) 2015-07-29
CN104804713B CN104804713B (en) 2018-04-27

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107794006A (en) * 2017-09-04 2018-03-13 南通捷皋家具有限公司 A kind of construction machinery equipment nanometer water-free cooling
CN107828389A (en) * 2017-09-04 2018-03-23 南通捷皋家具有限公司 A kind of antifreeze coolant for outdoor building equipment
CN110776878A (en) * 2019-11-28 2020-02-11 济南鼎隆化工科技有限公司 Environment-friendly high-boiling-point energy exchange medium and preparation method thereof
CN112812756A (en) * 2020-12-31 2021-05-18 兰洋(宁波)科技有限公司 Low-oiliness cooling liquid

Citations (7)

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Publication number Priority date Publication date Assignee Title
US6676847B2 (en) * 2000-02-25 2004-01-13 Ashland Inc. Monocarboxylic acid based antifreeze composition for diesel engines
CN1618921A (en) * 2004-10-14 2005-05-25 杨毅男 Multifunction strong effect automobile cooling liquid
CA2333046C (en) * 1998-05-22 2007-02-06 Ashland Inc. Diesel engine antifreeze composition
CN102250591A (en) * 2010-09-29 2011-11-23 张显军 Water-free coolant for engine
CN102260486A (en) * 2011-06-23 2011-11-30 江苏张家港迪克汽车化学品有限公司 1,2-propylene glycol antifreezing liquid coolant
CN102399538A (en) * 2010-09-14 2012-04-04 瑞乾坤(北京)贸易有限公司 Non-aqueous coolant for engine
CN102732232A (en) * 2012-07-19 2012-10-17 张家港迪克汽车化学品有限公司 1,2-propanediol antifreezing cooling liquid

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2333046C (en) * 1998-05-22 2007-02-06 Ashland Inc. Diesel engine antifreeze composition
US6676847B2 (en) * 2000-02-25 2004-01-13 Ashland Inc. Monocarboxylic acid based antifreeze composition for diesel engines
CN1618921A (en) * 2004-10-14 2005-05-25 杨毅男 Multifunction strong effect automobile cooling liquid
CN102399538A (en) * 2010-09-14 2012-04-04 瑞乾坤(北京)贸易有限公司 Non-aqueous coolant for engine
CN102250591A (en) * 2010-09-29 2011-11-23 张显军 Water-free coolant for engine
CN102260486A (en) * 2011-06-23 2011-11-30 江苏张家港迪克汽车化学品有限公司 1,2-propylene glycol antifreezing liquid coolant
CN102732232A (en) * 2012-07-19 2012-10-17 张家港迪克汽车化学品有限公司 1,2-propanediol antifreezing cooling liquid

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
万书晓: "《机动车发动机冷却液》", 30 September 2014 *
戴汝泉: "《汽车运行材料》", 31 January 2012 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107794006A (en) * 2017-09-04 2018-03-13 南通捷皋家具有限公司 A kind of construction machinery equipment nanometer water-free cooling
CN107828389A (en) * 2017-09-04 2018-03-23 南通捷皋家具有限公司 A kind of antifreeze coolant for outdoor building equipment
CN110776878A (en) * 2019-11-28 2020-02-11 济南鼎隆化工科技有限公司 Environment-friendly high-boiling-point energy exchange medium and preparation method thereof
CN110776878B (en) * 2019-11-28 2021-02-12 济南鼎隆化工科技有限公司 Environment-friendly high-boiling-point energy exchange medium and preparation method thereof
CN112812756A (en) * 2020-12-31 2021-05-18 兰洋(宁波)科技有限公司 Low-oiliness cooling liquid
CN112812756B (en) * 2020-12-31 2022-05-06 兰洋(宁波)科技有限公司 Low-oiliness cooling liquid

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Effective date of registration: 20190624

Address after: 315000 No. 1266 Juxian Road, Ningbo High-tech Zone, Zhejiang Province

Patentee after: Ningbo Junsheng Qunying Automobile System Co., Ltd.

Address before: 315100 room 1, 1 18 Xingye two, Ningbo bonded area, Zhejiang, China

Patentee before: NINGBO FREE TRADE ZONE TAOHONG CHEMICAL TECHNOLOGY CO., LTD.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180427

Termination date: 20210504