CN104804553A - Water-based solid window drawing bar prepared by combination of acrylic copolymer emulsion and sodium stearate and preparation method of water-based solid window drawing bar - Google Patents
Water-based solid window drawing bar prepared by combination of acrylic copolymer emulsion and sodium stearate and preparation method of water-based solid window drawing bar Download PDFInfo
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- CN104804553A CN104804553A CN201510198242.0A CN201510198242A CN104804553A CN 104804553 A CN104804553 A CN 104804553A CN 201510198242 A CN201510198242 A CN 201510198242A CN 104804553 A CN104804553 A CN 104804553A
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- copolymer emulsion
- sodium stearate
- water
- acrylate copolymer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a water-based solid window drawing bar prepared by combination of acrylic copolymer emulsion and sodium stearate and a preparation method of the water-based solid window drawing bar. The water-based solid window drawing bar comprises the following raw materials in percentage by mass: 30-50 percent of acrylic copolymer emulsion, 6-15 percent of the sodium stearate, 0.5-1 percent of a surface active agent, 5-10 percent of a moisturizing agent, 5-15 percent of pigment, 0.5-1 percent of a sterilizing agent and 28-52 percent of deionized water. The window drawing bar prepared by a water-based solid material formed by the combination of the acrylic copolymer emulsion and the sodium stearate has good adhesive force to glass, plastic and other smooth surfaces, meanwhile, is stable in state at the temperate of 60 DEG C and easy to clean with water and has the advantages of being simple, convenient and practical.
Description
Invention field
The present invention relates to a kind of window and draw rod, specifically relate to the water solid-shaped window that a kind of acrylate copolymer emulsion prepared in conjunction with sodium stearate and draw rod and preparation method.
Background technology
Graphic products common in the market has artistic oil painting stick and wax crayon, and this series products starting material used are oiliness, do not have bonding strength, be not suitable for drawing a picture in the smooth glass such as window to smooth glass, can not meet the demand of convenient decoration in people's life.
Acrylate copolymer emulsion has the polarity close with smooth glass surface, easily formed at glass surface and stick, simultaneously, can quality film at low temperatures in conjunction with certain sodium stearate, this look film has good sticking power to glass surface, and simultaneously the character of acrylate copolymer emulsion determines that this look film has and has good wetting ability simultaneously.
Summary of the invention
In conjunction with the advantageous property of acrylate copolymer emulsion, the invention provides the water solid-shaped window that a kind of acrylate copolymer emulsion prepared in conjunction with sodium stearate and draw rod and preparation method.
For achieving the above object, the technical solution used in the present invention is:
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, and said composition comprises the raw material by following masses per-cent: acrylate copolymer emulsion 30-50%, sodium stearate 6-15%, tensio-active agent 0.5-1%, wetting Agent for Printing Inks 5-10%, pigment 5-15%, sterilant 0.5-1%, deionized water 28-52%;
Described acrylate copolymer emulsion comprises the raw material by following masses per-cent: methacrylic acid 15-20%, butyl acrylate 10-15%, methyl methacrylate 5-15%, and described methacrylic acid, butyl acrylate, methyl methacrylate form through being uniformly mixed at 90-100 DEG C.
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, it is characterized in that: described tensio-active agent be selected from organically-modified silicone, dimethyl silicone oil any one.
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, it is characterized in that: described wetting Agent for Printing Inks is any one in ethylene glycol, propylene glycol, glycerol.
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, it is characterized in that: described pigment is any one or a few combination in red pigment, yellow ultramarine, blue pigments.
Acrylate copolymer emulsion draws a preparation method for rod in conjunction with water solid-shaped window prepared by sodium stearate, comprises the following steps:
(1) deionized water is placed in retort, with 75-80r/min agitating deionized water under 60-70 DEG C of condition, in whipping process, add homo-polypropylene yogurt liquid continuously at a slow speed and keep this temperature and stirring velocity until polyacrylate emulsion has dissolved, forming uniform and stable suspension liquid; In suspension liquid, add sodium stearate, raising Heating temperature is 70-80 DEG C, and raising stirring velocity is 80-90r/min, and heated and stirred, until sodium stearate dissolves completely, obtains substrate;
(2) in substrate, tensio-active agent, wetting Agent for Printing Inks, pigment, sterilant is added fast, even mixture is stirred to 80-90r/min under 80-90 DEG C of heating condition, 60 DEG C are cooled to rapidly after mixture being poured into mould, mixture is shaped to water solid-shaped, mixture is continued to be cooled to room temperature, obtains window and draw rod.
Beneficial effect of the present invention:
The present invention forms water solid-shaped material in conjunction with acrylate copolymer emulsion and sodium stearate and prepares window picture rod, has good sticking power, meanwhile, easily with water cleaning at resistance to 60 DEG C of temperature, have succinctly convenient and practical benefit to smooth glass surface.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is further described.
Embodiment 1:
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, and said composition comprises the raw material by following masses per-cent: acrylate copolymer emulsion 50%, sodium stearate 6.75%, organically-modified silicone 0.5%, glycerol 9%, red pigment 5%, sterilant 0.75%, deionized water 28%.
Described acrylate copolymer emulsion comprises by the raw material methacrylic acid 20% of following masses per-cent, butyl acrylate 15%, methyl methacrylate 10%, and described methacrylic acid, butyl acrylate, methyl methacrylate form through being uniformly mixed at 90 DEG C.
Acrylate copolymer emulsion draws a preparation method for rod in conjunction with water solid-shaped window prepared by sodium stearate, comprises the following steps:
(1) deionized water is placed in retort, with 75r/min agitating deionized water under 60 DEG C of conditions, in whipping process, add homo-polypropylene yogurt liquid continuously at a slow speed and keep this temperature and stirring velocity until polyacrylate emulsion dissolves the uniform and stable suspension liquid of complete formation; In suspension liquid, add sodium stearate to improve Heating temperature be 80-90 DEG C and stirring velocity be 80r/min until sodium stearate dissolves completely, obtain substrate;
(2) in substrate, organically-modified silicone, glycerol, red pigment, sterilant is added fast, be stirred to evenly with 80r/min under 80 DEG C of heating conditions and obtain mixture, when being cooled to rapidly 60 DEG C after pouring mould into, mixture is shaped to water solid-shaped, mixture is cooled, to room temperature, obtain window and draw rod.
Embodiment 2:
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, and said composition comprises the raw material by following masses per-cent: acrylate copolymer emulsion 39%, sodium stearate 7.5%, organically-modified silicone 1%, propylene glycol 7%, yellow ultramarine 5%, sterilant 0.5%, deionized water 40%.
Described acrylate copolymer emulsion comprises the raw material by following masses per-cent: methacrylic acid 20%, butyl acrylate 12%, methyl methacrylate 7%, and described methacrylic acid, butyl acrylate, methyl methacrylate form through being uniformly mixed at 95 DEG C.
Acrylate copolymer emulsion draws a preparation method for rod in conjunction with water solid-shaped window prepared by sodium stearate, comprises the following steps:
(1) deionized water is placed in retort, with 78r/min agitating deionized water under 68 DEG C of conditions, in whipping process, add homo-polypropylene yogurt liquid continuously at a slow speed and keep this temperature and stirring velocity until polyacrylate emulsion dissolves the uniformly stable suspension liquid of gestalt; In suspension liquid, add sodium stearate to improve Heating temperature be 80-90 DEG C and stirring velocity be 85r/min until sodium stearate dissolves completely, obtain substrate;
(2) in substrate, organically-modified silicone, propylene glycol, yellow ultramarine, sterilant is added fast, the mixture is evenly stirred to 85r/min under 85 DEG C of heating conditions, when being cooled to rapidly 60 DEG C after pouring mould into, mixture is shaped to water solid-shaped, mixture is cooled to room temperature, obtains window and draw rod.
Embodiment 3:
The water solid-shaped window that a kind of acrylate copolymer emulsion is prepared in conjunction with sodium stearate draws rod, and said composition comprises the raw material by following masses per-cent: acrylate copolymer emulsion 30%, sodium stearate 9.75%, dimethyl silicone oil 0.5%, ethylene glycol 5%, blue pigments 2%, yellow ultramarine 4%, sterilant 0.75%, deionized water 48%;
Described acrylate copolymer emulsion comprises the raw material by following masses per-cent: methacrylic acid 15%, butyl acrylate 10%, methyl methacrylate 5%, and described methacrylic acid, butyl acrylate, methyl methacrylate form through being uniformly mixed at 100 DEG C.
Acrylate copolymer emulsion draws a preparation method for rod in conjunction with water solid-shaped window prepared by sodium stearate, comprises the following steps:
(1) deionized water is placed in retort, with 80r/min agitating deionized water under 70 DEG C of conditions, in whipping process, add homo-polypropylene yogurt liquid continuously at a slow speed and keep this temperature and stirring velocity until polyacrylate emulsion dissolves the uniform and stable suspension liquid of complete formation; In suspension liquid, add sodium stearate to improve Heating temperature be 80-90 DEG C and stirring velocity be 90r/min until sodium stearate dissolves completely, obtain substrate;
(2) in substrate, dimethyl silicone oil, ethylene glycol, blue pigments, yellow ultramarine, sterilant is added fast, be stirred to evenly with 90r/min under 85 DEG C of heating conditions and obtain mixture, when being cooled to rapidly 60 DEG C after pouring mould into, mixture is shaped to water solid-shaped, mixture is cooled to room temperature, obtains window and draw rod.
Claims (5)
1. an acrylate copolymer emulsion is drawn excellent in conjunction with water solid-shaped window prepared by sodium stearate, it is characterized in that, said composition comprises the raw material by following masses per-cent: acrylate copolymer emulsion 30-50%, sodium stearate 6-15%, tensio-active agent 0.5-1%, wetting Agent for Printing Inks 5-10%, pigment 5-15%, sterilant 0.5-1%, deionized water 28-52%;
Described acrylate copolymer emulsion comprises the raw material by following masses per-cent: methacrylic acid 15-20%, butyl acrylate 10-15%, methyl methacrylate 5-15%, and described methacrylic acid, butyl acrylate, methyl methacrylate form through being uniformly mixed at 90-100 DEG C.
2. the water solid-shaped window that a kind of acrylate copolymer emulsion according to claim 1 is prepared in conjunction with sodium stearate draws rod, it is characterized in that: described tensio-active agent be selected from organically-modified silicone, dimethyl silicone oil any one.
3. the water solid-shaped window that a kind of acrylate copolymer emulsion according to claim 1 is prepared in conjunction with sodium stearate draws rod, it is characterized in that: described wetting Agent for Printing Inks is any one in ethylene glycol, propylene glycol, glycerol.
4. the water solid-shaped window that a kind of acrylate copolymer emulsion according to claim 1 is prepared in conjunction with sodium stearate draws rod, it is characterized in that: described pigment is any one or a few combination in red pigment, yellow ultramarine, blue pigments.
5. acrylate copolymer emulsion as claimed in claim 1 draws a preparation method for rod in conjunction with water solid-shaped window prepared by sodium stearate, it is characterized in that, comprises the following steps:
(1) by deionized water in being placed in retort, with 75-80r/min agitating deionized water under 60-70 DEG C of condition, in whipping process, add acrylate copolymer emulsion continuously at a slow speed and keep this temperature and stirring velocity until acrylate copolymer emulsion has dissolved, forming uniform and stable suspension liquid; In suspension liquid, add sodium stearate, raising Heating temperature is 80-90 DEG C, and raising stirring velocity is 80-90r/min, and heated and stirred, until sodium stearate dissolves completely, obtains substrate;
(2) in substrate, tensio-active agent, wetting Agent for Printing Inks, pigment, sterilant is added fast, even mixture is stirred to 80-90r/min under 80-90 DEG C of heating condition, 60 DEG C are cooled to rapidly after mixture being poured into mould, mixture is shaped to water solid-shaped, mixture is continued to be cooled to room temperature, obtains window and draw rod.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510198242.0A CN104804553A (en) | 2015-04-23 | 2015-04-23 | Water-based solid window drawing bar prepared by combination of acrylic copolymer emulsion and sodium stearate and preparation method of water-based solid window drawing bar |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510198242.0A CN104804553A (en) | 2015-04-23 | 2015-04-23 | Water-based solid window drawing bar prepared by combination of acrylic copolymer emulsion and sodium stearate and preparation method of water-based solid window drawing bar |
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| CN104804553A true CN104804553A (en) | 2015-07-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510198242.0A Pending CN104804553A (en) | 2015-04-23 | 2015-04-23 | Water-based solid window drawing bar prepared by combination of acrylic copolymer emulsion and sodium stearate and preparation method of water-based solid window drawing bar |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115991949A (en) * | 2022-12-14 | 2023-04-21 | 河源市云彩实业有限公司 | Transparent window color pigment and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1690141A (en) * | 2004-04-26 | 2005-11-02 | 株式会社百乐 | Aqueous ink for ball-point pen using oil-in-water type resin emulsion and ball-point pen using the aqueous ink |
| US20050252409A1 (en) * | 2004-01-29 | 2005-11-17 | Keiko Nakamura | Solid drawing material and method for producing the same |
| CN101033354A (en) * | 2007-04-10 | 2007-09-12 | 上海乐美文具有限公司 | Water-based multipurpose painting pen |
| CN103254670A (en) * | 2013-04-03 | 2013-08-21 | 沭阳凤凰美术颜料有限公司 | Glass painting pigment |
-
2015
- 2015-04-23 CN CN201510198242.0A patent/CN104804553A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050252409A1 (en) * | 2004-01-29 | 2005-11-17 | Keiko Nakamura | Solid drawing material and method for producing the same |
| CN1690141A (en) * | 2004-04-26 | 2005-11-02 | 株式会社百乐 | Aqueous ink for ball-point pen using oil-in-water type resin emulsion and ball-point pen using the aqueous ink |
| CN101033354A (en) * | 2007-04-10 | 2007-09-12 | 上海乐美文具有限公司 | Water-based multipurpose painting pen |
| CN103254670A (en) * | 2013-04-03 | 2013-08-21 | 沭阳凤凰美术颜料有限公司 | Glass painting pigment |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115991949A (en) * | 2022-12-14 | 2023-04-21 | 河源市云彩实业有限公司 | Transparent window color pigment and preparation method thereof |
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Application publication date: 20150729 |