CN104804379A - Insulating material for cable - Google Patents
Insulating material for cable Download PDFInfo
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- CN104804379A CN104804379A CN201510211466.0A CN201510211466A CN104804379A CN 104804379 A CN104804379 A CN 104804379A CN 201510211466 A CN201510211466 A CN 201510211466A CN 104804379 A CN104804379 A CN 104804379A
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Abstract
The invention discloses a cable which consists of a cable conductor and an insulating material wrapping the cable conductor, wherein the insulating material is prepared from the following components: 90-100 parts of bisphenol F-type epoxy resin, 50-60 parts of phenolic resin powder, 25-30 parts of silicon carbide, 18-20 parts of white carbon black, 12-15 parts of N-ethyl-N-phenyl aminodithioformic acid zinc, 8-10 parts of calcium carbonate, 8-10 parts of cryolite, 6-8 parts of N-phenyl-2-naphthylamine, 5-7 parts of stearic acid, 4-6 parts of magnesium hydrate, 4-6 parts of zinc borate, 2-3 parts of triallyl isocyanuric acid ester, 2 parts of dimethyl ethoxyethanol and 2 parts of oligopeptide. The insulating material disclosed by the invention is good in mechanical property and insulating flame-retardancy property, and is simple in preparation method.
Description
Technical field
The invention belongs to field of compound material, be specifically related to a kind of insulating material for cable.
Background technology
Cable (electric cable; Power cable) be normally made up of the conductor outsourcing insulation of one or more mutually insulated and protective layer, electric power or information are transferred to the wire at another place from one, are widely used in power system.The model of cable mainly contains: power cable with cross-linked polyethylene insulation, rubber sleeve flexible cable, colliery resistance cable, shipboard cable, aluminum stranded conductor and Aluminium Cable Steel Reinforced, polyvinyl chloride insulation control cables, polyvinyl chloride insulated line, electric cable of submersible pump, elevator cable, railway signal cable, computer cable special etc.
Along with the development of power industry, the improved products such as fire-retardant radioprotective power cable have been widely applied in daily life.But flame retardant cable commercially available is at present mainly the fire-retardant PV C cable of PV C sheath and insulation, or add the fire retardant polyolefin cable of harmful fire retardant.Along with the progress of society and going deep into of safety and environmental protection consciousness, the secondary pollution produced when national governments burn to Halogen flame-retardant system gives unprecedented concern, research finds that these smog are enough to make people because being choked to death, and visual plant (computer etc.) is paralysed because of corrosion.When halogen-free anti-flaming polyolefin cable not only can overcome halogen, the burning of antimony system flame retardant cable smog large, give off poisonous gas and the defect such as corrosive gases, also can overcome common halogen, antimony system CABLE MATERIALS is easily aging, the problems such as low temperature brittleness difference, are subject to the extensive attention of countries in the world scientific research personnel.Above mentioned problem, also there is tensile strength and the defect such as hardness is inadequate in cable of the prior art, causes usually occurring fracture or damaged; Meanwhile, outdoor use cable also usually can, due to reasons such as radiation, make the various aspects of performance of cable significantly reduce, and there is larger potential safety hazard.
Summary of the invention
The cable insulation flame retardant properties that the object of the invention is to solve prior art existence is poor, and the not high defect of tensile strength and hardness, provides a kind of novel cable and application thereof.Present invention also offers a kind of insulating material for cable.
To achieve these goals, the present invention has come by following technical solution:
A kind of cable, be made up of cable conductor and the insulating material be wrapped on cable conductor, it is characterized in that, described insulating material is prepared from by the raw material of following weight part: bisphenol f type epoxy resin (liquid bisphenol F type epoxy resin) 100-90, phenol-formaldehyde resin powder 60-50 part, silicon carbide 30-25 part, white carbon black 20-18 part, N-ethyl, N-phenyl zinc dithiocarbamate 15-12 part, calcium carbonate 10-8 part, sodium aluminum fluoride 10-8 part, N-phenyl-2-naphthylamine 8-6 part, stearic acid 7-5 part, magnesium hydroxide 6-4 part, zinc borate 6-4 part, cyanacrylate 3-2 part, dimethylaminoethoxyethanol 2 parts, small peptide 2 parts.
Preferably, the particle diameter of phenol-formaldehyde resin powder and white carbon black all controls at below 10um; The particle diameter of silicon carbide, calcium carbonate and sodium aluminum fluoride all controls at below 1um; Small peptide is the small peptide of below 10 amino acid, such as Gly-Thr-Gly-Gly or Pro-Gly-Val-Thr-Val.
The present invention without any restriction, can be the material for conducting electricity conventional in prior art to cable conductor, such as silver-plated copper, copper cover aluminum and copper sheathed steel etc.
The invention also discloses above-mentioned insulating material preparation method as follows:
Get each raw material according to part by weight, pour in homogenizer, under room temperature, be first uniformly mixed 30-40min with the speed of 800 revs/min, then at 65-85 DEG C, stir 10-15min with the speed of 5000 revs/min; The batch mixing stirred is discharged in twin screw extruder, is expressed in injection moulding machine after the complete melting of batch mixing, injection moulding and get final product at 200 DEG C.
The invention also discloses a kind of cable insulating material, be prepared from by the raw material of following weight part: bisphenol f type epoxy resin (liquid bisphenol F type epoxy resin) 100-90, phenol-formaldehyde resin powder 60-50 part, silicon carbide 30-25 part, white carbon black 20-18 part, N-ethyl, N-phenyl zinc dithiocarbamate 15-12 part, calcium carbonate 10-8 part, sodium aluminum fluoride 10-8 part, N-phenyl-2-naphthylamine 8-6 part, stearic acid 7-5 part, magnesium hydroxide 6-4 part, zinc borate 6-4 part, cyanacrylate 3-2 part, dimethylaminoethoxyethanol 2 parts, small peptide 2 parts.
The present invention achieves technique effect useful as follows:
Cable material fire retardant insulating radiation resistance prepared by the present invention is better, possesses application prospect widely;
The mechanical propertys such as cable material tensile strength prepared by the present invention and hardness improve greatly, and fracture and the possibility damaged reduce, and improve safety coefficient;
The present invention is by a large amount of tests, and the raw material of selection is cheap and compatibility reasonable, and preparation method is simple;
The present invention have employed small peptide innovatively, adopts the physicals of its uniqueness, improves the complex ability of each raw material, improves the insulating property of matrix material and tensile strength and hardness.
Embodiment
By adopting the mode of specific embodiment, the invention will be further described below, but it can not be interpreted as it is restriction to core of innovation spirit of the present invention.
Embodiment 1
A kind of cable, be made up of cable conductor and the insulating material be wrapped on cable conductor, this insulating material is prepared from by the raw material of following weight part: liquid bisphenol F type epoxy resin 100, phenol-formaldehyde resin powder 60 parts, 30 parts, silicon carbide, white carbon black 20 parts, N-ethyl, N-phenyl zinc dithiocarbamate 15 parts, 10 parts, calcium carbonate, sodium aluminum fluoride 10 parts, N-phenyl-2-naphthylamine 8 parts, stearic acid 7 parts, magnesium hydroxide 6 parts, zinc borate 6 parts, cyanacrylate 3, dimethylaminoethoxyethanol 2 parts, small peptide 2 parts.The particle diameter of phenol-formaldehyde resin powder and white carbon black all controls at below 10um; The particle diameter of silicon carbide, calcium carbonate and sodium aluminum fluoride all controls at below 1um; Small peptide is Gly-Thr-Gly-Gly.
Above-mentioned insulating material preparation method is as follows: get each raw material according to part by weight, pours in homogenizer, is first uniformly mixed 30min with the speed of 800 revs/min under room temperature, then at 65 DEG C, stirs 10min with the speed of 5000 revs/min; The batch mixing stirred is discharged in twin screw extruder, is expressed in injection moulding machine after the complete melting of batch mixing, injection moulding and get final product at 200 DEG C.
Embodiment 2
A kind of cable insulation material, is prepared from by the raw material of following weight part: bisphenol f type epoxy resin (liquid bisphenol F type epoxy resin) 90, phenol-formaldehyde resin powder 50 parts, 25 parts, silicon carbide, white carbon black 18 parts, N-ethyl, N-phenyl zinc dithiocarbamate 12 parts, 8 parts, calcium carbonate, sodium aluminum fluoride 8 parts, N-phenyl-2-naphthylamine 6 parts, stearic acid 5 parts, magnesium hydroxide 4 parts, zinc borate 4 parts, cyanacrylate 2 parts, dimethylaminoethoxyethanol 2 parts, small peptide 2 parts.The particle diameter of phenol-formaldehyde resin powder and white carbon black all controls at below 10um; The particle diameter of silicon carbide, calcium carbonate and sodium aluminum fluoride all controls at below 1um; Small peptide is Pro-Gly-Val-Thr-Val.
Above-mentioned insulating material preparation method is as follows: get each raw material according to part by weight, pours in homogenizer, is first uniformly mixed 40min with the speed of 800 revs/min under room temperature, then at 85 DEG C, stirs 15min with the speed of 5000 revs/min; The batch mixing stirred is discharged in twin screw extruder, is expressed in injection moulding machine after the complete melting of batch mixing, injection moulding and get final product at 200 DEG C.
Embodiment 3
The various performance parameter tests of insulating material prepared by the present invention
1. flame retardant properties test:
Table 1
Conclusion: the better mechanical property of cable insulation material prepared by the present invention, can be applicable to various cable material.
2. (radiation quantity is 1000kGy) after gammairradiation, the change of mechanical property:
Conclusion: after gammairradiation, tensile strength, elongation at break and hardness obviously do not decline, and radiation resistance is better.
3. fire-retardant and insulating property:
Table 3
Conclusion: good insulation preformance, oxygen index is higher, belongs to nonflammable material, and flame retardant effect is better.
Above in conjunction with specific embodiments to invention has been exemplary description; obvious realization of the present invention is not subject to the restrictions described above; as long as have employed the various improvement that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all in protection scope of the present invention without to improve.
Claims (1)
1., for an insulating material for cable, it is characterized in that,
Described insulating material is prepared from by the raw material of following weight part: bisphenol f type epoxy resin 100-90, phenol-formaldehyde resin powder 60-50 part, silicon carbide 30-25 part, white carbon black 20-18 part, N-ethyl, N-phenyl zinc dithiocarbamate 15-12 part, calcium carbonate 10-8 part, sodium aluminum fluoride 10-8 part, N-phenyl-2-naphthylamine 8-6 part, stearic acid 7-5 part, magnesium hydroxide 6-4 part, zinc borate 6-4 part, cyanacrylate 3-2 part, dimethylaminoethoxyethanol 2 parts, small peptide 2 parts;
The particle diameter of described phenol-formaldehyde resin powder and described white carbon black all controls at below 10um; The particle diameter of described silicon carbide, described calcium carbonate and described sodium aluminum fluoride all controls at below 1um; Described small peptide is Gly-Thr-Gly-Gly or Pro-Gly-Val-Thr-Val;
Described insulating material preparation method is as follows: take each raw material according to weight part, pours in homogenizer, is first uniformly mixed 30-40min with the speed of 800 revs/min under room temperature, then at 65-85 DEG C, stirs 10-15min with the speed of 5000 revs/min; The batch mixing stirred is discharged in twin screw extruder, is expressed in injection moulding machine after the complete melting of batch mixing, injection moulding and get final product at 200 DEG C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310221262.6A CN103289323B (en) | 2013-05-31 | 2013-05-31 | Cable and application thereof to electric power system |
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CN201310221262.6A Division CN103289323B (en) | 2013-05-31 | 2013-05-31 | Cable and application thereof to electric power system |
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CN104804379A true CN104804379A (en) | 2015-07-29 |
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CN201310221262.6A Expired - Fee Related CN103289323B (en) | 2013-05-31 | 2013-05-31 | Cable and application thereof to electric power system |
CN201510211466.0A Pending CN104804379A (en) | 2013-05-31 | 2013-05-31 | Insulating material for cable |
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CN201310221262.6A Expired - Fee Related CN103289323B (en) | 2013-05-31 | 2013-05-31 | Cable and application thereof to electric power system |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105118636A (en) * | 2015-09-17 | 2015-12-02 | 国网山东省电力公司临沂供电公司 | Distribution transformer bushing |
CN105419243A (en) * | 2016-01-12 | 2016-03-23 | 芜湖航天特种电缆厂股份有限公司 | Insulating material for cable and preparation method of insulating material |
CN105551692A (en) * | 2016-01-12 | 2016-05-04 | 芜湖航天特种电缆厂股份有限公司 | Insulated cable and preparation method thereof |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105038111B (en) * | 2015-07-23 | 2017-11-17 | 安徽瑞侃电缆科技有限公司 | A kind of heat-resisting resist bending wear-resistant cable |
CN108948659A (en) * | 2018-06-06 | 2018-12-07 | 镇江市鑫泰绝缘材料有限公司 | A kind of superelevation proof voltage epoxy resins insulation plate and its processing technology |
CN110615969B (en) * | 2019-08-14 | 2021-11-23 | 江西瀚泰新材料科技有限公司 | Anti-aging and flame-retardant epoxy resin cable insulating material and preparation thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1814682A (en) * | 2005-02-04 | 2006-08-09 | 上海康达化工有限公司 | Anti-corrosion coating layer for water pump, water pump containing same and construction method therefor |
CN102725802A (en) * | 2010-02-03 | 2012-10-10 | Abb研究有限公司 | Electric insulation system |
-
2013
- 2013-05-31 CN CN201310221262.6A patent/CN103289323B/en not_active Expired - Fee Related
- 2013-05-31 CN CN201510211466.0A patent/CN104804379A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1814682A (en) * | 2005-02-04 | 2006-08-09 | 上海康达化工有限公司 | Anti-corrosion coating layer for water pump, water pump containing same and construction method therefor |
CN102725802A (en) * | 2010-02-03 | 2012-10-10 | Abb研究有限公司 | Electric insulation system |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105118636A (en) * | 2015-09-17 | 2015-12-02 | 国网山东省电力公司临沂供电公司 | Distribution transformer bushing |
CN105419243A (en) * | 2016-01-12 | 2016-03-23 | 芜湖航天特种电缆厂股份有限公司 | Insulating material for cable and preparation method of insulating material |
CN105551692A (en) * | 2016-01-12 | 2016-05-04 | 芜湖航天特种电缆厂股份有限公司 | Insulated cable and preparation method thereof |
Also Published As
Publication number | Publication date |
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CN103289323A (en) | 2013-09-11 |
CN103289323B (en) | 2015-05-13 |
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