A kind of cable
Technical field
The present invention relates to electric power project engineering field, be specifically related to a kind of cable.
Background technology
Cable is normally by the cable of several or at least two every group stranded similar ropes that form of several groups of wires,Mutually insulated between every group of wire, and being often twisted into round Yi Gen center, whole outside is surrounded by high-insulationCover layer.
Cable has power cable, control cables, compensating cable, shielded cable, high-temperature cable, calculating electromechanicsCable, signal cable, coaxial cable, fire-resisting cable, cable for ship, mine cable, aluminium alloy cable etc.They are all made up of sub-thread or stranded conductor and insulating barrier, are used for connecting circuit, electrical equipment etc.
Therefore cable is being played the part of very important role in industry-by-industry, and in order to prevent accident, it is anti-Fire performance must be protected, and prior art is difficult to meet this requirement.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of cable, to solve deficiency of the prior art.
For solving the problems of the technologies described above, embodiments of the invention provide a kind of cable, it is characterized in that, compriseThe core, filler and the cover layer that coaxially arrange successively from the inside to the outside;
The component of described covering layer material and parts by weight are: polyolefin elastomer 60-70 part, hydroxideMagnesium dust 20-30 part, aluminium-hydroxide powder 30-40 part, magnesium oxide powder 1-2 part, aerosil1-2 part, coupling agent 0.2-1 part, plasticiser 5-7 part, crosslinking agent 1-3 part; Wherein, described polyolefin bulletGonosome is POE8450; Described coupling dosage is ethyl alkene silane coupling agent; Described plasticiser is or partiallyBenzenetricarboxylic acid three monooctyl esters; Described crosslinking agent is cumyl peroxide.
Described tectal preparation method comprises and comprising the following steps:
(1) polyolefin elastomer, the magnesium hydroxide powder of formula rate, aluminium-hydroxide powder, oxygen will be pressedChange magnesium dust, aerosil and put into banbury, at 100 DEG C mixing 20 minutes;
(2) add again the surplus stock by formula rate, at 85 DEG C mixing 10 minutes, then in 75 DEG CLower mixing 10 minutes;
(3) double screw extruder extruding pelletization, obtains covering layer material
The polyolefin elastomer 8450 that main sizing material adopts E.I.Du Pont Company to produce, POE has thermoplastic elasticThe general physical property of body, as mouldability, waste material recycling and cured properties etc., and relative density is little, because ofAnd volume is cheap, heat resistance, cold resistance excellence, scope of application broadness, weatherability, resistance to ag(e)ing are goodGood. The performances such as oil resistivity, compression resistant permanent deformation and abrasion performance are general. Be applicable to electric wire is industrialHeat resistance and environment resistantly require high insulating barrier. POE physical property is close to general plastic material, but the whileHave again vulcanizing of rubber concurrently, can conformability, its use, has not only ensured the properties of insulation, andBe beneficial to post-cure processing, reduced formula rubber shape possibility.
Magnesium hydroxide powder 20-30 part, aluminium-hydroxide powder 30-40 part is used in conjunction with by a certain percentage, isGood fire proofing.
Described cover layer internal layer is coated with scolds water flame retardant coating, described in scold water resistance combustion coating material component andParts by weight are: polyethers 40-60 part, epoxy resin 5-8 part, polytetrafluoroethylene (PTFE) 5-15 part, magnesium hydroxidePowder 3-5 part, aluminium-hydroxide powder 2-3 part, phthalic acid ester 1-2 part, polyurethane 10-15 part,Dimethicone 1-5 part, aerosil 5-10 part, ethanol 30-50 part.
The described preparation method who scolds water resistance combustion coating material, concrete steps comprise:
[1] first by press formula rate polyethers, epoxy resin, polytetrafluoroethylene (PTFE), magnesium hydroxide powder,Aluminium-hydroxide powder, phthalic acid ester mix, and are then uniformly mixed reaction 3h at 80-160 DEG C;
[2] again by by the polyurethane of formula rate, dimethicone, aerosil, ethanol according to joiningSide's ratio adds hot reflux 16h after mixing;
[3] by the mixing of materials of step [1] and step [2] gained, then ultrasonic dispersion 100min, is scoldedWater resistance combustion coating material.
It is 92.2-95 ° that the feeler analyzer of this coating detects water contact angle, under-15 low temperature environment without crispSplit, without peeling off, at 0.8MPa, under the 20min degree of depth without infiltration, function admirable.
The beneficial effect of technique scheme of the present invention is as follows:
In such scheme, cable of the present invention can reach flame retardant grade UL94-V0 level, and fire-proof and water-proof performance is allGood, can be widely used in every field, there are good market prospects.
Brief description of the drawings
Fig. 1 is the structural representation of the cable of the embodiment of the present invention.
Detailed description of the invention
For making the technical problem to be solved in the present invention, technical scheme and advantage clearer, below in conjunction with attachedFigure and specific embodiment are described in detail.
As shown in Figure 1, a kind of cable that the embodiment of the present invention provides, comprises from the inside to the outside and coaxially establishing successivelyCore 1, filler 2 and the cover layer 3 put, described cover layer 3 internal layers are coated with scolds water flame retardant coating4。
Embodiment mono-
The component of described covering layer material and parts by weight are: 845060 parts of polyolefin elastomers,20 parts of magnesium hydroxide powders, 30 parts of aluminium-hydroxide powders, 1 part of magnesium oxide powder, aerosil 1Part, 0.2 part of ethyl alkene silane coupling agent, 5 parts of trioctyl trimellitate (TOTM) plasticisers, cumyl peroxide1 part of crosslinking agent;
Described component and parts by weight of scolding water resistance combustion coating material are: 40 parts of polyethers, epoxy resin 5Part, 5 parts of polytetrafluoroethylene (PTFE), 3 parts of magnesium hydroxide powders, 2 parts of aluminium-hydroxide powders, phthalic acid ester1 part, 10 parts of polyurethane, 1 part of dimethicone, 5 parts of aerosils, 30 parts of ethanol.
Embodiment bis-
The component of described covering layer material and parts by weight are: 845070 parts of polyolefin elastomers,30 parts of magnesium hydroxide powders, 40 parts of aluminium-hydroxide powders, 2 parts of magnesium oxide powders, aerosil 2Part, 1 part of ethyl alkene silane coupling agent, 7 parts of trioctyl trimellitate (TOTM) plasticisers, cumyl peroxide are handed over3 parts of connection agent;
Described component and parts by weight of scolding water resistance combustion coating material are: 60 parts of polyethers, epoxy resin 8Part, 15 parts of polytetrafluoroethylene (PTFE), 5 parts of magnesium hydroxide powders, 3 parts of aluminium-hydroxide powders, phthalic acid2 parts of esters, 15 parts of polyurethane, 5 parts of dimethicones, 10 parts of aerosils, 50 parts of ethanol.
Embodiment tri-
The component of described covering layer material and parts by weight are: 845065 parts of polyolefin elastomers,25 parts of magnesium hydroxide powders, 35 parts of aluminium-hydroxide powders, 1.5 parts of magnesium oxide powders, aerosil1.5 parts, 0.5 part of ethyl alkene silane coupling agent, 6 parts of trioctyl trimellitate (TOTM) plasticisers, peroxidating two are different2 parts of propyl benzene crosslinking agents;
Described component and parts by weight of scolding water resistance combustion coating material are: 50 parts of polyethers, epoxy resin 7Part, 10 parts of polytetrafluoroethylene (PTFE), 4 parts of magnesium hydroxide powders, 2.5 parts of aluminium-hydroxide powders, O-phthalic1.5 parts of acid esters, 12 parts of polyurethane, 3 parts of dimethicones, 8 parts of aerosils, 40 parts of ethanol.
The above is the preferred embodiment of the present invention, it should be pointed out that the common skill for the artArt personnel, not departing under the prerequisite of principle of the present invention, can also make some improvements and modifications,These improvements and modifications also should be considered as protection scope of the present invention.