CN104801003A - Pesticide residue decomposer and preparation method thereof - Google Patents

Pesticide residue decomposer and preparation method thereof Download PDF

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Publication number
CN104801003A
CN104801003A CN201510245984.4A CN201510245984A CN104801003A CN 104801003 A CN104801003 A CN 104801003A CN 201510245984 A CN201510245984 A CN 201510245984A CN 104801003 A CN104801003 A CN 104801003A
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parts
residual
distintegrant
agriculture
natural pond
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CN104801003B (en
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吴唐青
林斌
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/02Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by biological methods, i.e. processes using enzymes or microorganisms
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/14Soil-conditioning materials or soil-stabilising materials containing organic compounds only
    • C09K17/18Prepolymers; Macromolecular compounds
    • C09K17/32Prepolymers; Macromolecular compounds of natural origin, e.g. cellulosic materials
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/04Pesticides, e.g. insecticides, herbicides, fungicides or nematocides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Soil Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Microbiology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Fertilizers (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

The invention discloses a pesticide residue decomposer. The pesticide residue decomposer comprises the following components in parts by weight: 0.1-10 parts of grub residue homogenate, 100 parts of biogas slurry, 0.1-10 parts of biogas residue, 0.1-10 parts of deep seawater, 0.1-10 parts of activated carbon, 1-18 parts of chlorella and 500 parts of distilled water. A preparation process of the pesticide residue decomposer is simple and rich in multiple beneficial microorganisms, active enzyme and natural nutrient substances, the residue of harmful substances such as pesticides on the surfaces of fruits and vegetables and in soil can be effectively degraded, the soil is improved, the crop growth is promoted, the crop yield is improved, and the quality of a product is improved.

Description

Residual distintegrant of a kind of agriculture and preparation method thereof
Technical field
The invention belongs to organic fertilizer field, be specifically related to residual distintegrant of a kind of agriculture and preparation method thereof.
Background technology
In recent years, along with China's economy and social fast development, China's soil pollution is on the rise.According to statistics, the whole nation has 1,300 ten thousand hm at least 2~ 1,600 ten thousand hm 2arable land is subject to pollution by pesticides.Every year, the various agricultural economy losses caused because of soil pollution add up to about 20,000,000,000 yuan.At present, China's Pesticide use amount reaches 1,300,000 tons, be 2.5 times of world average level, and practical efficiency is less than 30%, and remaining 70% all causes pollution to soil, water body environment.Residues of pesticides cause the beneficial bacterium in soil to reduce in a large number, lack beneficial bacterium, the organic fertilizer used effectively cannot be decomposed, is absorbed, originally fertile soil becomes barren, and soil self purification activity weakens, and soil quality and fertility decline, affect the yield and quality of crops, be detrimental to health, destroy agricultural sustainable development, even occur environment revenge risk.
Current, chemistry, physics and biological method is mainly adopted to control for soil remediation, but, chemical leaching rehabilitating soil is according to similar dissolve mutually theory, by chemical/biological solvent, by Leaching rule, then the solution containing pollutant is extracted from soil, carry out being separated and sewage disposal, exist operation loaded down with trivial details, power consumption cause secondary pollution problems greatly, easily; And many physical methods cannot be applied owing to being subject to the restriction such as appointed condition, operating technology.Biological prosthetic be transformed by the physiological and biochemical activity of microorganism, the process of degradation of contaminant, microorganism is widely distributed at occurring in nature, of a great variety, and metabolic pathway is various, can the effective soil pollutant such as decomposing pesticide and fertilizer residue, can various bioactivators be produced simultaneously, promote profitable strain propagation, suppress pernicious bacteria, improve soil aggregate, recover soil vitality, promote plant growth, improve agricultural output and quality.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, provide a kind of agriculture residual distintegrant, the residual distintegrant of this agriculture is rich in multiple beneficial microorganism, organized enzyme, natural nutrient substance, and the harmful substance such as fruit and vegetable surfaces, Pesticide Residue in Soil of can effectively degrading remains.
For achieving the above object, the present invention adopts following technical scheme:
The residual distintegrant of a kind of agriculture, comprises the component of following weight portion: the residual body homogenate of grub 0.1 ~ 10 part, natural pond liquid 100 parts, natural pond slag 0.1 ~ 10 part, deep sea water 0.1 ~ 10 part, active carbon 0.1 ~ 10 part, chlorella 1 ~ 18 part and distilled water 500 parts.
More excellent, the residual distintegrant of described agriculture, comprises the component of following weight portion: the residual body homogenate of grub 5 ~ 8 parts, natural pond liquid 100 parts, natural pond slag 6 ~ 9 parts, deep sea water 4 ~ 7 parts, active carbon 8 ~ 10 parts, chlorella 15 ~ 16 parts and distilled water 500 parts.
More excellent, the residual distintegrant of described agriculture, comprises the component of following weight portion: the residual body homogenate of grub 7 parts, natural pond liquid 100 parts, natural pond slag 6 parts, deep sea water 7 parts, active carbon 10 parts, chlorella 15 parts and distilled water 500 parts.
Described deep sea water refers to the seawater of the deep-sea part exceeding less than 200 meters, sea.
The preparation method of the residual distintegrant of described agriculture, specifically comprises the following steps:
(1) join in the liquid of natural pond by chlorella, deep sea water, in glass closed container, anaerobic fermentation 30 days at temperature 30 DEG C, filters, obtains filtrate (1);
(2) grub is shredded, after residual body homogenate, be dissolved in distilled water, make it to form nutrient solution; Natural pond slag adds in nutrient solution, and at temperature 25 DEG C, aerobic fementation cultivates 10 days, filters, obtains filtrate (2);
(3) by filtrate (1) and filtrate (2) mixing, add active carbon, aerobic fementation 2 days at temperature 25 DEG C, gained zymotic fluid is the residual distintegrant of agriculture.
beneficial effect of the present invention is:
The residual distintegrant of agriculture of the present invention is rich in multiple beneficial microorganism, organized enzyme, natural nutrient substance, and the harmful substance such as fruit and vegetable surfaces, Pesticide Residue in Soil of can effectively degrading remains, and improvement soil, promotes plant growth, improves crop yield, improves product quality.
Detailed description of the invention
The present invention's the following example further illustrates the present invention, but protection scope of the present invention is not limited to the following example.
embodiment 1
The residual distintegrant of agriculture, comprises the component of following weight portion: the residual body homogenate of grub 7 parts, natural pond liquid 100 parts, natural pond slag 6 parts, deep sea water 7 parts, active carbon 10 parts, chlorella 15 parts and distilled water 500 parts.
Preparation method, specifically comprises the following steps:
(1) join in the liquid of natural pond by chlorella, deep sea water, in glass closed container, anaerobic fermentation 30 days at temperature 30 DEG C, filters, obtains filtrate (1);
(2) grub is shredded, after residual body homogenate, be dissolved in distilled water, make it to form nutrient solution; Natural pond slag adds in nutrient solution, and at temperature 25 DEG C, aerobic fementation cultivates 10 days, filters, obtains filtrate (2);
(3) by filtrate (1) and filtrate (2) mixing, add active carbon, aerobic fementation 2 days at temperature 25 DEG C, gained zymotic fluid is the residual distintegrant of agriculture.
Carry out nitrogen, phosphorus, heavy metal etc. to the residual distintegrant of agriculture obtained by embodiment 1 to detect, testing result is:
(1) mensuration of N, P
Assay method the 3rd part according to GB/T 17767.3-2010 organic-inorganic complex fertilizer: total potassium content; The assay method part 2 of GB/T 17767.2-2010 organic-inorganic complex fertilizer: total phosphorus content; NY 525-2012 organic fertilizer, testing result is as shown in table 1.
N, P assay result of the residual distintegrant of table 1 agriculture
(2) detection of heavy metal component
According to GB 18877-2009 organic-inorganic complex fertilizer, NY 525-2012 organic fertilizer, * DZ/T 0064-93, detects that in the residual distintegrant of agriculture that the present invention obtains, heavy metal component is as shown in table 2.
The measurement result of the heavy metal component of the residual distintegrant of table 2 agriculture
Test item Testing result
Plumbous (Pb), mg/L <0.01
Cadmium (Cd), mg/L <0.001
Chromium (Cr), mg/L <0.01
Arsenic (As), mg/L <0.01
Mercury (Hg), mg/L <0.0001
(3) toxicological evaluation result
Detect according to GB 15193.3-2003 " toxicological evaluation of food safety procedure acute toxicity test ", test result is sample the acute toxicity tests of the present invention is LD50 > 19.8g/kg body weight, belongs to nontoxic according to acute toxicity dose fractionation.
(4) microbe composition testing result
Containing beneficial microbe bacterial flora in the residual distintegrant of agriculture: by kingdom bar lattice Leah bacterium (more than 90%), archeobacteria; By door classification WPS-2 content 87%, wart germ containing 6%, TM containing 1.2%, mycetozoan containing 1.1%, Tm6 is containing 1% etc.
embodiment 2
The residual body homogenate of grub 0.1 part, natural pond liquid 100 parts, natural pond slag 10 parts, deep sea water 10 parts, active carbon 5 parts, chlorella 18 parts and distilled water 500 parts.
Preparation method, specifically comprises the following steps:
(1) join in the liquid of natural pond by chlorella, deep sea water, in glass closed container, anaerobic fermentation 30 days at temperature 30 DEG C, filters, obtains filtrate (1);
(2) grub is shredded, after residual body homogenate, be dissolved in distilled water, make it to form nutrient solution; Natural pond slag adds in nutrient solution, and at temperature 25 DEG C, aerobic fementation cultivates 10 days, filters, obtains filtrate (2);
(3) by filtrate (1) and filtrate (2) mixing, add active carbon, aerobic fementation 2 days at temperature 25 DEG C, gained zymotic fluid is the residual distintegrant of agriculture.
embodiment 3
The residual distintegrant of a kind of agriculture, comprises the component of following weight portion: the residual body homogenate of grub 10 parts, natural pond liquid 100 parts, natural pond slag 0.1 part, deep sea water 0.1 part, active carbon 10 parts, chlorella 1 part and distilled water 500 parts.
Preparation method, specifically comprises the following steps:
(1) join in the liquid of natural pond by chlorella, deep sea water, in glass closed container, anaerobic fermentation 30 days at temperature 30 DEG C, filters, obtains filtrate (1);
(2) grub is shredded, after residual body homogenate, be dissolved in distilled water, make it to form nutrient solution; Natural pond slag adds in nutrient solution, and at temperature 25 DEG C, aerobic fementation cultivates 10 days, filters, obtains filtrate (2);
(3) by filtrate (1) and filtrate (2) mixing, add active carbon, aerobic fementation 2 days at temperature 25 DEG C, gained zymotic fluid is the residual distintegrant of agriculture.
application Example 1
The residual distintegrant of agriculture that above-described embodiment is obtained carries out agricultural chemicals decomposition run:
(1) test material
For examination agricultural chemicals: 30% orthene missible oil, business men is Hubei Shalongda Co., Ltd.;
For examination vegetables: Brassica rapa L, purchased from food market, Lao Guang village, Cangshan District, Fuzhou City;
The residual distintegrant of agriculture that embodiment 1 is obtained.
(2) test method
Vegetables Brassica rapa L is immersed 30min in 30% orthene, 300 times of dilutions, dry and immerse 10min, 30min and 50min in the residual distintegrant of agriculture of the present invention and clear water respectively afterwards, dry the rear orthene residual quantity measured respectively in vegetables Brassica rapa L.The method that in vegetable sample, orthene assay specifies by NY/T 761-2008 is carried out.Vegetable sample numbering is as shown in table 3.
Table 3 vegetable sample is numbered
Sample number into spectrum Remarks
CK—10 The sample of clear water process 10min
ZWB—10 The sample of agriculture residual distintegrant process 10min
CK—30 The sample of clear water process 30min
ZWB—30 The sample of agriculture residual distintegrant process 30min
CK—50 The sample of clear water process 50min
ZWB—50 The sample of agriculture residual distintegrant process 50min
(3) result of the test
In each vegetable sample, the measurement result of orthene residual quantity is as shown in table 4:
Orthene residual quantity in table 4 vegetable sample
Sample number into spectrum Orthene content (mg/kg)
CK—10 15
ZWB—10 12
CK—30 13
ZWB—30 9.1
CK—50 10
ZWB—50 8.8
As shown in table 4, after the residual distintegrant of agriculture of the present invention respectively immersion treatment 10min, 30min and 50min, vegetable surface orthene residual quantity is respectively 12mg/kg, 9.1mg/kg and 8.8mg/kg; And after clear water respectively immersion treatment 10min, 30min and 50min, vegetable surface orthene residual quantity is respectively 15mg/kg, 13mg/kg and 10mg/kg.Visible, the residual quantity of the orthene on the vegetables that the residual distintegrant of agriculture soaks, lower than the residual quantity of the vegetables soaked through clear water, shows that the agricultural chemicals orthene of vegetable surface obtains good decomposition after the residual distintegrant process of agriculture.
application Example 2
The residual distintegrant of agriculture that above-described embodiment is obtained carries out plant growth test:
Play May Mining in April, 2014 to pluck, tobacco leaf technical advice station, Jianyang City is tried out the residual distintegrant of agriculture of the present invention, and through finding the contrast of index of correlation, the residual distintegrant of agriculture effectively can improve cigarette strain quality, lifting quality of tobacco.
1. primary growth stage analysis
As shown in Table 5, due to the use of the residual distintegrant of agriculture, effectively can improve soil texture, promote the early growth and quick tiller of cigarette strain, impel group's phase of community in advance; Show as the process of plant treasured squaring period and comparatively contrast early 3 days, growing stage shortens after showing as and using the residual distintegrant of agriculture to some extent, impels the growth level reasonable distribution of cigarette strain.
Table 5 primary growth stage performance (unit day/moon)
Process Transplant Group Budding Pinch Beginning adopts Adopt eventually Breeding time
The residual distintegrant of agriculture 5/3 8/4 3/5 5/5 27/5 26/6 114
Routine control 5/3 10/4 6/5 8/5 29/5 28/6 116
2. Other Main Agronomic Characters contrast
The residual distintegrant process of agriculture and Routine control Related Agronomic Characters index are in table 6.Owing to being two samples, therefore take two class mean Student in DPS software, t checks, and whether remarkable whether is greater than 0.05 judgement difference according to P value.As seen from table, plant height aspect shows as contrast higher than process; Pitch aspect, the residual distintegrant process of agriculture is greater than contrast, as can be seen here, by using of the residual distintegrant of agriculture, promotes that cigarette strain is to the absorption of nutrient, impels blade in picturesque disorder, increases effective photosynthesis area; Stem girth aspect shows as the residual distintegrant process of agriculture lower than contrast; Blade area shows as the residual distintegrant process of agriculture and is greater than contrast, and t assay is remarkable, therefore the residual distintegrant process of known agriculture effectively can increase blade area, impels blade texture to grow.
The comparative analysis of table 6 Other Main Agronomic Characters
Process Plant height (cm) Pitch (cm) Stem girth (cm) The number of blade Waist leaf long (cm) Waist leaf wide (cm) Waist leaf area (cm 2)
The residual distintegrant of agriculture 101.24 5.338 9.57 17 88.74 34.88 1975.64
Routine control 104.76 4.261 11.43 18 77.16 34.74 1704.15
3. Evaluation on Appearance Quality
As shown in Table 7, former cigarette presentation quality relevant evaluation index is contrasted, as maturity, blade construction, color, identity, oil content, colourity etc., visible agriculture residual distintegrant process tobacco leaf maturity is better, and blade construction loosens, and tobacco leaf color is orange, to strong in colourity, identity is medium, and oil content is better.The residual distintegrant process of agriculture can improve soil texture, promotes that blade construction loosens, meets the desired nutritional that grows of tobacco leaf, improve quality of tobacco.
The former cigarette Evaluation on Appearance Quality of table 7
4. Analysis on Economic Traits
As shown in Table 8, per mu yield, average price, per mu yield value, first-class cigarette ratio aspect, the residual distintegrant process of agriculture, higher than contrast, as seen by using the residual distintegrant of agriculture, improving soil texture and impelling nutrient consistent supply in fertilizer, meeting needed for cigarette strain growth.Promote cigarette strain leaf development, improve quality of tobacco.
Table 8 economic characters contrast
The residual distintegrant of agriculture is a kind of material being of value to plant growth, described on end, by using of the residual distintegrant of agriculture, effectively can improve quality of tobacco.
The foregoing is only preferred embodiment of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to covering scope of the present invention.

Claims (4)

1. the residual distintegrant of agriculture, it is characterized in that: the component comprising following weight portion: the residual body homogenate of grub 0.1 ~ 10 part, natural pond liquid 100 parts, natural pond slag 0.1 ~ 10 part, deep sea water 0.1 ~ 10 part, active carbon 0.1 ~ 10 part, chlorella 1 ~ 18 part and distilled water 500 parts.
2. the residual distintegrant of agriculture according to claim 1, it is characterized in that: the component comprising following weight portion: the residual body homogenate of grub 5 ~ 8 parts, natural pond liquid 100 parts, natural pond slag 6 ~ 9 parts, deep sea water 4 ~ 7 parts, active carbon 8 ~ 10 parts, chlorella 15 ~ 16 parts and distilled water 500 parts.
3. the residual distintegrant of agriculture according to claim 1, is characterized in that: the component comprising following weight portion: the residual body homogenate of grub 7 parts, natural pond liquid 100 parts, natural pond slag 6 parts, 7 parts, deep-sea water, active carbon 10 parts, chlorella 15 parts and distilled water 500 parts.
4. prepare a method for the residual distintegrant of agriculture as claimed in claim 1, it is characterized in that: comprise the following steps:
(1) join in the liquid of natural pond by chlorella, deep sea water, in glass closed container, anaerobic fermentation 30 days at temperature 30 DEG C, filters, obtains filtrate (1);
(2) grub is shredded, after residual body homogenate, be dissolved in distilled water, make it to form nutrient solution; Natural pond slag adds in nutrient solution, and at temperature 25 DEG C, aerobic fementation cultivates 10 days, filters, obtains filtrate (2);
(3) by filtrate (1) and filtrate (2) mixing, add active carbon, aerobic fementation 2 days at temperature 25 DEG C, gained zymotic fluid is the residual distintegrant of agriculture.
CN201510245984.4A 2015-05-15 2015-05-15 A kind of residual distintegrant of agriculture and preparation method thereof Active CN104801003B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106416495A (en) * 2016-09-04 2017-02-22 云南省能源研究院有限公司 Method for effectively removing soil pesticide residues in microenvironment under plateau photovoltaic panel
CN108178706A (en) * 2017-12-21 2018-06-19 王红军 A kind of efficient global function soil-repairing agent and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN106416495A (en) * 2016-09-04 2017-02-22 云南省能源研究院有限公司 Method for effectively removing soil pesticide residues in microenvironment under plateau photovoltaic panel
CN108178706A (en) * 2017-12-21 2018-06-19 王红军 A kind of efficient global function soil-repairing agent and preparation method thereof

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