CN104789062A - Fireproof paint, preparation method and application thereof - Google Patents
Fireproof paint, preparation method and application thereof Download PDFInfo
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- CN104789062A CN104789062A CN201510174941.1A CN201510174941A CN104789062A CN 104789062 A CN104789062 A CN 104789062A CN 201510174941 A CN201510174941 A CN 201510174941A CN 104789062 A CN104789062 A CN 104789062A
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- kaolin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a fireproof paint, a preparation method and application thereof, and belongs to the field of fireproof material. The raw material components of the fireproof paint comprise sterile water, ammonium polyphosphate, melamine, dipentaerythritol, acetic styrene-acrylic emulsion, titanium dioxide, kaolin, wollastonite powder, vermiculite and graphite. According to the fireproof paint provided by the invention, the expanded multiplication rate of the fireproof paint can reach 15-30 times; a formed carbon layer is adamantine and compact and meanwhile will not fall down from a steel girder; and the fireproof time is increased. The fireproof paint solves the problem that the expanded multiplication rate of expansive type fireproof paints is low, and perfectly integrates chemical reaction expansion with physical expansion.
Description
Technical field
The invention belongs to fire-retardant material field, relate to a kind of frie retardant coating, its preparation method and application thereof.
Background technology
Conventional frie retardant coating effectively can be coated in organic synthesis material, metallic substance and concrete structure material surface, not only material is played to the effect of decoration, can extend the time of deformation failure when fire occurs simultaneously, effectively reduce the loss of fire.Therefore the market demand of frie retardant coating is increasing.
Existing frie retardant coating fireproofing mechanism is divided into expanded polystyrene veneer and non-expansibility, and little with its coat-thickness at actual market performance expanded polystyrene veneer, consumption is few, and the advantage such as to construct simple occupies most of market, especially maximum with slim frie retardant coating consumption.The slim frie retardant coating of commercial type meets the rear expansion multiplying power of fire in 5-15 doubly left and right, and so its expansion multiplying power and fire resistance period can not meet actual demand far away.
Summary of the invention
According to demand and the deficiency in above-mentioned field, the invention provides a kind of frie retardant coating, its preparation method and application thereof, the expansion multiplying power of frie retardant coating of the present invention can reach 15-30 doubly, and the carbon-coating hard and compact formed can not come off with girder steel simultaneously, and fire resistance period increases.The invention solves the difficult problem that expanding fire-proof paint expansion multiplying power is low, chemical reaction is expanded and physical expansion perfect adaptation.
Technical scheme of the present invention is as follows:
A kind of frie retardant coating, it is characterized in that, described frie retardant coating starting components comprises: sterilized water, ammonium polyphosphate, trimeric cyanamide, dipentaerythritol, acrylate and vinyl acetate emulsion, titanium dioxide, kaolin, wollastonite powder, vermiculite, graphite.
Described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 10-30 part, ammonium polyphosphate: 10-30 part, trimeric cyanamide: 5-15 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-8 part, kaolin: 2-5 part, vermiculite: 1-5, graphite: 2-5, wollastonite powder: 2-10 part.
Described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 15-25 part, ammonium polyphosphate: 15-30 part, trimeric cyanamide: 6-13 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-6 part, kaolin: 2-5 part, vermiculite: 1-4 part, graphite: 2-4 part, wollastonite powder: 2-6 part.
Described frie retardant coating starting components and proportioning thereof are: sterilized water: 20 parts, acrylate and vinyl acetate emulsion: 20 parts, ammonium polyphosphate: 23 parts, trimeric cyanamide: 12 parts, dipentaerythritol: 11 parts, titanium dioxide: 6 parts, kaolin: 2 parts, vermiculite: 1.5, graphite: 2.5, wollastonite: 2 parts.
The preparation method of above-mentioned frie retardant coating, is characterized in that, in order by the sterilized water of proportional quantity, ammonium polyphosphate, trimeric cyanamide, dipentaerythritol, titanium dioxide, kaolin, vermiculite, graphite, wollastonite powder adds in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion, rotating speed 600 revs/min, stirs, obtains frie retardant coating.
Described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 10-30 part, ammonium polyphosphate: 10-30 part, trimeric cyanamide: 5-15 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-8 part, kaolin: 2-5 part, vermiculite: 1-5, graphite: 2-5, wollastonite powder: 2-10 part.
Described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 15-25 part, ammonium polyphosphate: 15-30 part, trimeric cyanamide: 6-13 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-6 part, kaolin: 2-5 part, vermiculite: 1-4 part, graphite: 2-4 part, wollastonite powder: 2-6 part.
Described frie retardant coating starting components and proportioning thereof are: sterilized water: 20 parts, acrylate and vinyl acetate emulsion: 20 parts, ammonium polyphosphate: 23 parts, trimeric cyanamide: 12 parts, dipentaerythritol: 11 parts, titanium dioxide: 6 parts, kaolin: 2 parts, vermiculite: 1.5, graphite: 2.5, wollastonite: 2 parts.
The application of above-mentioned frie retardant coating.
In the present invention, described starting material combine with its specific proportioning, complement each other between it, and synergy finally reaches the technique effect that the present invention claims, realizes goal of the invention of the present invention.The present invention is except the N-P chemical reaction foaming and intumescing principle of inheriting tradition, in coating, add physical expansion raw material finally makes the expansion multiplying power of frie retardant coating of the present invention can reach 15-30 doubly, and the carbon-coating hard and compact formed can not come off with girder steel simultaneously, fire resistance period increases.The invention solves the difficult problem that expanding fire-proof paint expansion multiplying power is low, chemical reaction is expanded and physical expansion perfect adaptation.The whole preparation process of frie retardant coating of the present invention is without the need to grinding, and technique is simple, saves money, saves time, laborsaving.
The beneficial effect of frie retardant coating of the present invention:
Frie retardant coating of the present invention can promote the expansion multiplying power about a times of slim frie retardant coating, also improves the workability of coating simultaneously, reduces difficulty of construction.
Embodiment
Following embodiment is provided to be to understand the present invention further better; be not limited to described preferred forms; content of the present invention and protection domain are not construed as limiting; anyone is under enlightenment of the present invention or any and the present invention the present invention being carried out combining with the feature of other prior aries and draw is identical or akin product, all drops within protection scope of the present invention.
If do not specialize, the conventional means that technique means used in embodiment is well known to those skilled in the art.Material used in the present invention, if no special instructions, is commercial sources and obtains, or prepare with normal experiment method; Test method used in embodiment, if no special instructions, is normal experiment method well known to those skilled in the art.
Acrylate and vinyl acetate emulsion is also known as vinyl acetate emulsion.It is the aqueous high molecular resin that is major function monomer copolymerization with vinyl acetate between to for plastic and butyl acrylate.
reagent material used in the present invention (is the starting material that the embodiment of the present invention uses below, but is of the present inventionly not limited to this, also can select any be purchased or homemade following starting material):
Acrylate and vinyl acetate emulsion: be purchased from Beijing Orient ROHM AND HAAS company limited, happy all things 661, solid content >=55%, viscosity (centipoise)≤500, minimum film-forming temperature (5 DEG C).
Ammonium polyphosphate: be purchased from Shandong Shi An Chemical Co., Ltd., crystallization II-type ammonium polyphosphate with high degree of polymerization
Trimeric cyanamide: be purchased from Zhong Yuan DaHua Group Ltd. of Henan Province
Dipentaerythritol: be purchased from Jiangsu Ruiyang Chemical Industry Co., Ltd, purity >=90%;
Titanium dioxide: be purchased from du pont company, model is titanium dioxide R-706;
Kaolin: be purchased from Beijing and benefit the nation the ultra-fine split company limited of great achievement, 1250 orders;
Vermiculite: Lingshou County Qian Xin vermiculite factory, 20-30 order
Graphite: Baoding Chinese mugwort can gloomy carbon product company limited, 100 orders
Wollastonite powder: be purchased and Ye Shi Gang You mining industry company limited, dioxide-containing silica: 50 (%), grade: first grade, Mohs' hardness: 4.5-5.0, density: 28-29 (g/cm3), fusing point: 1540 (DEG C)
embodiment 1.
In order by sterilized water: 20 parts, ammonium polyphosphate: 23 parts, trimeric cyanamide: 12 parts, dipentaerythritol: 11 parts, titanium dioxide: 6 parts, kaolin: 2 parts, vermiculite: 1.5 parts, graphite: 2.5 parts, wollastonite powder: 2 parts add in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion 20 parts, rotating speed 600 revs/min, stir and reach degree of uniformity in 15 minutes, obtain frie retardant coating 1, then by canned for frie retardant coating 1.
embodiment 2.
In order by sterilized water: 30 parts, ammonium polyphosphate: 10 parts, trimeric cyanamide: 6 parts, tetramethylolmethane: 15 parts, titanium dioxide: 8 parts, kaolin: 3 parts, vermiculite: 1 part, graphite: 2 parts, wollastonite powder: 3 parts add in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion 20 parts, rotating speed 600 revs/min, stir and reach degree of uniformity in 15 minutes, obtain frie retardant coating 2, then by canned for frie retardant coating 2.
embodiment 3.
In order by sterilized water: 15 parts, ammonium polyphosphate: 30 parts, trimeric cyanamide: 13 parts, tetramethylolmethane: 5 parts, titanium dioxide: 6 parts, kaolin: 2 parts, vermiculite: 5 parts, graphite: 2.5 parts, wollastonite powder: 2 parts add in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion 15 parts, rotating speed 600 revs/min, stir and reach degree of uniformity in 15 minutes, obtain frie retardant coating 3, then by canned for frie retardant coating 3.
embodiment 4.
In order by sterilized water: 18 parts, ammonium polyphosphate: 30 parts, trimeric cyanamide: 5 parts, tetramethylolmethane: 7 parts, titanium dioxide: 8 parts, kaolin: 5 parts, vermiculite: 3 parts, graphite: 4 parts, wollastonite powder: 10 parts add in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion 21 parts, rotating speed 600 revs/min, stir and reach degree of uniformity in 15 minutes, obtain frie retardant coating 4, then by canned for frie retardant coating 4.
embodiment 5.
In order by sterilized water: 20 parts, ammonium polyphosphate: 15 parts, trimeric cyanamide: 15 parts, tetramethylolmethane: 11 parts, titanium dioxide: 2 parts, kaolin: 4 parts, vermiculite: 4 parts, graphite: 5 parts, wollastonite powder: 6 parts add in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion 25 parts, rotating speed 600 revs/min, stir and reach degree of uniformity in 15 minutes, obtain frie retardant coating 5, then by canned for frie retardant coating 5.
embodiment 6.
The effect data of the frie retardant coating of embodiment 1-5
In this area, the frie retardant coating side of viscosity data >=0.15MPa is qualified, and the viscosity number of frie retardant coating of the present invention minimum be 0.85MPa, its viscosity index is obviously far superior to national standard level, in use it is bonding with girder steel firmly for frie retardant coating of the present invention in addition, does not occur dropping situations.
From above data, the expansion multiplying power of frie retardant coating of the present invention can reach 15-30 doubly, and the carbon-coating hard and compact formed can not come off with girder steel simultaneously, and fire resistance period increases.
More than describe preferably specific embodiment of the present invention in detail.Should be appreciated that those of ordinary skill in the art just design according to the present invention can make many modifications and variations without the need to paying performing creative labour.Therefore, every those skilled in the art, all should within the determined protection domain of claims of the present invention according to design of the present invention available technical scheme of experiment by logic analysis, reasoning or limited number of time on the basis of prior art.
Claims (9)
1. a frie retardant coating, is characterized in that, described frie retardant coating starting components comprises: sterilized water, ammonium polyphosphate, trimeric cyanamide, dipentaerythritol, acrylate and vinyl acetate emulsion, titanium dioxide, kaolin, wollastonite powder, vermiculite, graphite.
2. frie retardant coating according to claim 1, it is characterized in that, described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 10-30 part, ammonium polyphosphate: 10-30 part, trimeric cyanamide: 5-15 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-8 part, kaolin: 2-5 part, vermiculite: 1-5, graphite: 2-5, wollastonite powder: 2-10 part.
3. frie retardant coating according to claim 2, it is characterized in that, described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 15-25 part, ammonium polyphosphate: 15-30 part, trimeric cyanamide: 6-13 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-6 part, kaolin: 2-5 part, vermiculite: 1-4 part, graphite: 2-4 part, wollastonite powder: 2-6 part.
4. frie retardant coating according to claim 3, it is characterized in that, described frie retardant coating starting components and proportioning thereof are: sterilized water: 20 parts, acrylate and vinyl acetate emulsion: 20 parts, ammonium polyphosphate: 23 parts, trimeric cyanamide: 12 parts, dipentaerythritol: 11 parts, titanium dioxide: 6 parts, kaolin: 2 parts, vermiculite: 1.5, graphite: 2.5, wollastonite: 2 parts.
5. the preparation method of the arbitrary described frie retardant coating of claim 1-4, is characterized in that, in order by the sterilized water of proportional quantity, ammonium polyphosphate, trimeric cyanamide, dipentaerythritol, titanium dioxide, kaolin, vermiculite, graphite, wollastonite powder adds in a mixing bowl, after a mixing bowl rotating speed 800 revs/min stirs half an hour, add acrylate and vinyl acetate emulsion, rotating speed 600 revs/min, stirs, obtains frie retardant coating.
6. preparation method according to claim 5, it is characterized in that, described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 10-30 part, ammonium polyphosphate: 10-30 part, trimeric cyanamide: 5-15 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-8 part, kaolin: 2-5 part, vermiculite: 1-5, graphite: 2-5, wollastonite powder: 2-10 part.
7. preparation method according to claim 6, it is characterized in that, described frie retardant coating starting components and proportioning thereof are: sterilized water: 15-30 part, acrylate and vinyl acetate emulsion: 15-25 part, ammonium polyphosphate: 15-30 part, trimeric cyanamide: 6-13 part, dipentaerythritol: 5-15 part, titanium dioxide: 2-6 part, kaolin: 2-5 part, vermiculite: 1-4 part, graphite: 2-4 part, wollastonite powder: 2-6 part.
8. preparation method according to claim 7, it is characterized in that, described frie retardant coating starting components and proportioning thereof are: sterilized water: 20 parts, acrylate and vinyl acetate emulsion: 20 parts, ammonium polyphosphate: 23 parts, trimeric cyanamide: 12 parts, dipentaerythritol: 11 parts, titanium dioxide: 6 parts, kaolin: 2 parts, vermiculite: 1.5, graphite: 2.5, wollastonite: 2 parts.
9. the application of the arbitrary described frie retardant coating of claim 1-4.
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CN201510174941.1A CN104789062A (en) | 2015-04-14 | 2015-04-14 | Fireproof paint, preparation method and application thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110240839A (en) * | 2019-07-29 | 2019-09-17 | 龚卫伟 | A kind of graphene fireproof coating |
CN112934054A (en) * | 2021-02-04 | 2021-06-11 | 北京慕成防火绝热特种材料有限公司 | Production device of intrinsic hydrophobic non-expansion type steel structure fireproof coating |
CN114874662A (en) * | 2022-04-28 | 2022-08-09 | 无锡市斯塔木包装有限公司 | Fireproof coating for surface of packaging wooden box and preparation method thereof |
CN115058157A (en) * | 2022-07-08 | 2022-09-16 | 广东粤港澳大湾区国家纳米科技创新研究院 | Temperature-humidity-alternating-temperature-resistant water-based fireproof coating and preparation method thereof |
CN115260862A (en) * | 2022-08-02 | 2022-11-01 | 青岛爱尔家佳新材料股份有限公司 | Polymer composite material and preparation method thereof |
-
2015
- 2015-04-14 CN CN201510174941.1A patent/CN104789062A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110240839A (en) * | 2019-07-29 | 2019-09-17 | 龚卫伟 | A kind of graphene fireproof coating |
CN112934054A (en) * | 2021-02-04 | 2021-06-11 | 北京慕成防火绝热特种材料有限公司 | Production device of intrinsic hydrophobic non-expansion type steel structure fireproof coating |
CN114874662A (en) * | 2022-04-28 | 2022-08-09 | 无锡市斯塔木包装有限公司 | Fireproof coating for surface of packaging wooden box and preparation method thereof |
CN115058157A (en) * | 2022-07-08 | 2022-09-16 | 广东粤港澳大湾区国家纳米科技创新研究院 | Temperature-humidity-alternating-temperature-resistant water-based fireproof coating and preparation method thereof |
CN115260862A (en) * | 2022-08-02 | 2022-11-01 | 青岛爱尔家佳新材料股份有限公司 | Polymer composite material and preparation method thereof |
CN115260862B (en) * | 2022-08-02 | 2023-08-22 | 青岛爱尔家佳新材料股份有限公司 | Polymer composite material and preparation method thereof |
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