CN110240839A - A kind of graphene fireproof coating - Google Patents
A kind of graphene fireproof coating Download PDFInfo
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- CN110240839A CN110240839A CN201910687731.0A CN201910687731A CN110240839A CN 110240839 A CN110240839 A CN 110240839A CN 201910687731 A CN201910687731 A CN 201910687731A CN 110240839 A CN110240839 A CN 110240839A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of graphene fireproof coating, ingredient is divided by number: 35-40 parts of clean water, 5-8 parts of graphene, 0.1-0.2 parts of dispersing agent, 23-25 parts of ammonium polyphosphate, 11-13 parts of pentaerythrite, 11-13 parts of melamine, 3-5 parts of titanium dioxide, 13-15 parts of acrylate and vinyl acetate emulsion, 1-2 parts of hydroxyethyl cellulose, 0.1-0.2 parts of defoaming agent, 2-5 parts of talcum powder, 3-7 parts of powdered whiting and 1.2-2 parts of polypropylene fibre.The beneficial effects of the present invention are: 1, using the high rigidity of graphene, increase the surface hardness of paint film, improve the stain resistance of paint film；2, using the high compactness of graphene and superconductivity, enhance the mechanical strength of paint film, improve the anti-corrosive properties of truss-steel beam；3, using the heat resistance of graphene, disperse the surface temperature of paint film, postpone the oxidation of surface of the paint film, enhance the weatherability of paint film.
Description
Technical field
The present invention relates to a kind of technical field of graphene, more particularly, to a kind of graphene fireproof coating.
Background technique
Fireproof coating is exactly by that on the surface of those combustible materials, can improve the refractory ability of material, subtract paint brush
Slow propagation of flame spread speed, or can prevent to burn within a certain period of time, this kind of coating are known as fireproof coating, or are called fire-retardant
Coating.
Fireproof coating is to reduce by the combustibility of painting material surface for flammable substrates surface, block the fast of fire
Speed sprawling, to improve by a kind of sapecial coating of painting material fire endurance.It is applied to flammable substrates surface, to change material
Expect that surface burning characteristics, retardance fire are spread rapidly；Or it is applied on building element, the spy of the fire endurance to improve component
Kind coating, claims fireproof coating.
But universal fire proofing material has following a few class problems: 1, surface of the paint film hardness is low, easily stains；2, paint film is mechanical
Intensity is low, corrodes truss-steel beam；3, the surface oxidation rate of paint film is too fast, therefore makes improvement according to the above several points.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of new graphene fireproof coating, from
And it solves the above problems.
To achieve the above object, the invention provides the following technical scheme: a kind of graphene fireproof coating, ingredient is by number point
Are as follows: 35-40 parts of clean water, 5-8 parts of graphene, 0.1-0.2 parts of dispersing agent, 23-25 parts of ammonium polyphosphate, 11-13 parts of pentaerythrite,
11-13 parts of melamine, 3-5 parts of titanium dioxide, 13-15 parts of acrylate and vinyl acetate emulsion, 1-2 parts of hydroxyethyl cellulose, defoaming agent 0.1-0.2
Part, 2-5 parts of talcum powder, 3-7 parts of powdered whiting and 1.2-2 parts of polypropylene fibre.
Further, ingredient the preparation method comprises the following steps: grind powder-grinding-liquid-storage processed.
More specifically, it is described grind powder-grinding technique: by clean water, graphene, dispersing agent, ammonium polyphosphate, pentaerythrite,
Melamine, titanium dioxide, acrylate and vinyl acetate emulsion, hydroxyethyl cellulose, defoaming agent, talcum powder, powdered whiting and polypropylene fibre
It successively puts into reaction kettle in order and carries out dispersion stirring.
Preferably, the time of the reaction kettle stirring is 30 minutes, and whipping temp is 0-40 DEG C.
More specifically, the technique of the liquid processed: by clean water, graphene, dispersing agent, ammonium polyphosphate, pentaerythrite, trimerization
Cyanamide, titanium dioxide, acrylate and vinyl acetate emulsion, hydroxyethyl cellulose, defoaming agent, talcum powder, powdered whiting and polypropylene fibre are milled
Wherein all multicomponents are liquid to powder after powder processed, can be realized in whipping process in and.
More specifically, the technique of the storage: the coating after liquid processed is sealed tank body storage, the container of storage is modeling
Material container, when storage, which need to seal, to be vacuumized, and storage temperature is 10-25 DEG C.
Further, the reaction kettle includes upper case, the next case, slideway, slide plate, sliding block, sliding bar, output electricity
Machine, rotating bar, follower lever, driving gear, driven gear, down-pressed pole, support frame, sewing button, limited post, hinge, supporting leg with
And stirring blade, active link, the supporting leg setting are carried out by the hinge between the upper case and the next case
In the lower end surface of the next case, slideway setting opposite sides surface in the upper case, opposite the two of the slide plate
Side is respectively provided with the sliding block, and the sliding block is inlaid in the slideway, and the sliding bar is inserted into the upper case, the sliding
The lower end of bar is fixedly connected with the output motor, and the output end of the output motor connects the rotating bar, the follower lever
It is arranged on the slide plate, in the rotating bar, the driven gear is arranged in the follower lever driving geared sleeve
It above and with the driving gear is meshed, the sliding bar is connect with the down-pressed pole pin shaft, and support frame as described above is arranged described
The upper surface of upper case, pin shaft connects between support frame as described above and the down-pressed pole, and the limited post setting is in the next case
Side surface, the sewing button is arranged in the side surface of the upper case and is meshed with the limited post.
Compared with prior art, the beneficial effects of the present invention are: 1, using the high rigidity of graphene, increase the surface of paint film
Hardness improves the stain resistance of paint film；2, using the high compactness of graphene and superconductivity, enhance the mechanical strength of paint film,
Improve the anti-corrosive properties of truss-steel beam；3, using the heat resistance of graphene, disperse the surface temperature of paint film, postpone the oxygen of surface of the paint film
Change, enhances the weatherability of paint film.
Detailed description of the invention
Attached drawing is used to provide further understanding of the present invention, and constitutes part of specification, with reality of the invention
It applies example to be used to explain the present invention together, not be construed as limiting the invention.In the accompanying drawings:
Fig. 1 is a kind of structural schematic diagram of new graphene fireproof coating；
It is as shown in the figure: 1, upper case；2, the next case；3, slideway；4, slide plate；5, sliding block；6, sliding bar；7, output motor；8, turn
Lever；9, follower lever；10, gear is driven；11, driven gear；12, down-pressed pole；13, support frame；14, sewing button；15, it limits
Column；16, hinge；17, supporting leg；18, stirring blade.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments, is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Please refer to shown in Fig. 1, the present invention provides a kind of technical solution: a kind of graphene fireproof coating, ingredient press number
It is divided into: 35-40 parts of clean water, 5-8 parts of graphene, 0.1-0.2 parts of dispersing agent, 23-25 parts of ammonium polyphosphate, pentaerythrite 11-13
Part, 11-13 parts of melamine, 3-5 parts of titanium dioxide, 13-15 parts of acrylate and vinyl acetate emulsion, 1-2 parts of hydroxyethyl cellulose, defoaming agent 0.1-
0.2 part, 2-5 parts of talcum powder, 3-7 parts of powdered whiting and 1.2-2 parts of polypropylene fibre.
In the present embodiment, ingredient the preparation method comprises the following steps: grind powder-grinding-liquid-storage processed.
Specific production process: the technique for grinding powder-grinding: by clean water, graphene, dispersing agent, ammonium polyphosphate, season penta
Tetrol, melamine, titanium dioxide, acrylate and vinyl acetate emulsion, hydroxyethyl cellulose, defoaming agent, talcum powder, powdered whiting and polypropylene
Fiber successively puts into reaction kettle in order and carries out dispersion stirring, and the time of the reaction kettle stirring is 30 minutes, whipping temp
It is 0-40 DEG C, the technique of the liquid processed: by clean water, graphene, dispersing agent, ammonium polyphosphate, pentaerythrite, melamine, titanium
After white powder, acrylate and vinyl acetate emulsion, hydroxyethyl cellulose, defoaming agent, talcum powder, powdered whiting and polypropylene fibre grind powder-grinding
Wherein all multicomponents are liquid to powder, can be realized in whipping process in and, the technique of the storage: by the painting after liquid processed
Material is sealed tank body storage, and the container of storage is plastic containers, and when storage, which need to seal, to be vacuumized, and storage temperature is 10-25 DEG C.
In the technical scheme, the reaction kettle includes upper case 1, the next case 2, slideway 3, slide plate 4, sliding block 5, sliding bar
6, output motor 7, rotating bar 8, follower lever 9, driving gear 10, driven gear 11, down-pressed pole 12, support frame 13, sewing button 14,
Limited post 15, hinge 16, supporting leg 17 and stirring blade 18 pass through the conjunction between the upper case 1 and the next case 2
Page 16 carries out active link, and the lower end surface of the next case 2 is arranged in the supporting leg 17, and the slideway 3 is arranged on described
Opposite sides surface in the case 1 of position, the opposite sides of the slide plate 4 are respectively provided with the sliding block 5, and the sliding block 5 is inlaid in the cunning
In road 3, the sliding bar 6 is inserted into the upper case 1, and the lower end of the sliding bar 6 is fixedly connected with the output motor 7,
The output end of the output motor 7 connects the rotating bar 8, and the follower lever 9 is arranged on the slide plate 4, the sliding tooth
Wheel 10 is sleeved in the rotating bar 8, the driven gear 11 be arranged on the follower lever 9 and with 10 phase of driving gear
Engagement, the sliding bar 6 are connect with 12 pin shaft of down-pressed pole, and the upper surface of the upper case 1 is arranged in support frame as described above 13,
Pin shaft connects between support frame as described above 13 and the down-pressed pole 12, and the side surface of the next case 2 is arranged in the limited post 15,
The sewing button 14 is arranged in the side surface of the upper case 1 and is meshed with the limited post 15.
Firstly, down-pressed pole 12 is pressed downwards, lever principle is played by support frame 13 at this time, so that sliding bar 6 is upward
It is mobile, slide plate 4 is moved up, sewing button 14 is made to be detached from limited post 15 at this time, upper case 1 is overturn by hinge 16,
After raw material being put into the next case 2 at this time, upper case 1 and the next closure of case 2 are realized into sealing, and upward by down-pressed pole 12
After lifting, so that sliding bar 6 moves down, after slide plate 4 is slided by slideway 3 at this time, stirring blade 18 is moved down,
After opening output motor 7, several stirring blade 18 is driven to be stirred respectively with driven gear 11 by driving gear 10.
Finally, also it should be noted that the example above and explanation are also not limited to above-described embodiment, skill of the present invention without description
Art feature can realize that details are not described herein by or using the prior art；Above embodiments are merely to illustrate skill of the invention
Art scheme is not limitation of the present invention, is described the invention in detail referring to preferred embodiment, this field
It is to be appreciated by one skilled in the art that the change that those skilled in the art are made within the essential scope of the present invention
Change, remodeling, add or replace without departure from spirit of the invention, also should belong to claims of the invention, again
Illustrate, above-described embodiment has been merely given as random having lifted a currently used embodiment.
Claims (7)
1. a kind of graphene fireproof coating, which is characterized in that ingredient is divided by number: 35-40 parts of clean water, 5-8 parts of graphene,
0.1-0.2 parts of dispersing agent, 23-25 parts of ammonium polyphosphate, 11-13 parts of pentaerythrite, 11-13 parts of melamine, 3-5 parts of titanium dioxide,
13-15 parts of acrylate and vinyl acetate emulsion, 1-2 parts of hydroxyethyl cellulose, 0.1-0.2 parts of defoaming agent, 2-5 parts of talcum powder, 3-7 parts of powdered whiting
And 1.2-2 parts of polypropylene fibre.
2. a kind of graphene fireproof coating according to claim 1, which is characterized in that ingredient the preparation method comprises the following steps: milling
Powder-liquid-storage processed processed.
3. a kind of graphene fireproof coating according to claim 2, which is characterized in that the technique for grinding powder-grinding: will
Clean water, graphene, dispersing agent, ammonium polyphosphate, pentaerythrite, melamine, titanium dioxide, acrylate and vinyl acetate emulsion, hydroxyethyl cellulose,
Defoaming agent, talcum powder, powdered whiting and polypropylene fibre successively put into reaction kettle in order and carry out dispersion stirring.
4. a kind of graphene fireproof coating according to claim 3, which is characterized in that the time of reaction kettle stirring is
30 minutes, whipping temp was 0-40 DEG C.
5. a kind of graphene fireproof coating according to claim 2, which is characterized in that the technique of the liquid processed: will be clean
Water, graphene, dispersing agent, ammonium polyphosphate, pentaerythrite, melamine, titanium dioxide, acrylate and vinyl acetate emulsion, hydroxyethyl cellulose, defoaming
Wherein all multicomponents are liquid to powder after agent, talcum powder, powdered whiting and polypropylene fibre stone roller powder-grinding, are being stirred
Neutralization can be realized in the process.
6. a kind of graphene fireproof coating according to claim 2, which is characterized in that the technique of the storage: by liquid processed
Coating afterwards is sealed tank body storage, and the container of storage is plastic containers, and when storage, which need to seal, to be vacuumized, and storage temperature is
10-25℃。
7. a kind of graphene fireproof coating according to claim 3, which is characterized in that the reaction kettle includes upper case
(1), the next case (2), slideway (3), slide plate (4), sliding block (5), sliding bar (6), output motor (7), rotating bar (8), follower lever
(9), gear (10) are driven, driven gear (11), down-pressed pole (12), support frame (13), sewing button (14), limited post (15), are closed
Page (16), supporting leg (17) and stirring blade (18) pass through the conjunction between the upper case (1) and the next case (2)
Page (16) carries out active link, and supporting leg (17) setting is in the lower end surface of the next case (2), slideway (3) setting
On the upper interior opposite sides surface of case (1), the opposite sides of the slide plate (4) is respectively provided with the sliding block (5), the sliding block
(5) be inlaid in the slideway (3), the sliding bar (6) is inserted into the upper case (1), the lower end of the sliding bar (6) with
The output motor (7) is fixedly connected, and the output end of the output motor (7) connects the rotating bar (8), the follower lever
(9) it is arranged on the slide plate (4), the driving gear (10) is sleeved on the rotating bar (8), the driven gear (11)
It is arranged on the follower lever (9) and is meshed with the driving gear (10), the sliding bar (6) and the down-pressed pole (12)
Pin shaft connection, support frame as described above (13) setting is in the upper surface of the upper case (1), support frame as described above (13) and the down-pressed pole
(12) pin shaft connects between, and limited post (15) setting is in the side surface of the next case (2), sewing button (14) setting
The upper case (1) side surface and be meshed with the limited post (15).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910687731.0A CN110240839A (en) | 2019-07-29 | 2019-07-29 | A kind of graphene fireproof coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910687731.0A CN110240839A (en) | 2019-07-29 | 2019-07-29 | A kind of graphene fireproof coating |
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| CN110240839A true CN110240839A (en) | 2019-09-17 |
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| CN201910687731.0A Pending CN110240839A (en) | 2019-07-29 | 2019-07-29 | A kind of graphene fireproof coating |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702869A (en) * | 2012-05-10 | 2012-10-03 | 江苏兰陵高分子材料有限公司 | Fireproof coating primer of single-mass-system indoor thin steel structure |
| CN104693928A (en) * | 2015-02-28 | 2015-06-10 | 济宁利特纳米技术有限责任公司 | Graphene fireproof paint as well as preparation method and application method thereof |
| CN104789062A (en) * | 2015-04-14 | 2015-07-22 | 北京慕成防火绝热特种材料有限公司 | Fireproof paint, preparation method and application thereof |
| CN107384062A (en) * | 2017-08-10 | 2017-11-24 | 合肥果成科技有限公司 | A kind of aqueous fire-proof coating factory formula |
-
2019
- 2019-07-29 CN CN201910687731.0A patent/CN110240839A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702869A (en) * | 2012-05-10 | 2012-10-03 | 江苏兰陵高分子材料有限公司 | Fireproof coating primer of single-mass-system indoor thin steel structure |
| CN104693928A (en) * | 2015-02-28 | 2015-06-10 | 济宁利特纳米技术有限责任公司 | Graphene fireproof paint as well as preparation method and application method thereof |
| CN104789062A (en) * | 2015-04-14 | 2015-07-22 | 北京慕成防火绝热特种材料有限公司 | Fireproof paint, preparation method and application thereof |
| CN107384062A (en) * | 2017-08-10 | 2017-11-24 | 合肥果成科技有限公司 | A kind of aqueous fire-proof coating factory formula |
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Application publication date: 20190917 |