CN104788939A - TUP taper knob and manufacturing method thereof - Google Patents
TUP taper knob and manufacturing method thereof Download PDFInfo
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- CN104788939A CN104788939A CN201510172875.4A CN201510172875A CN104788939A CN 104788939 A CN104788939 A CN 104788939A CN 201510172875 A CN201510172875 A CN 201510172875A CN 104788939 A CN104788939 A CN 104788939A
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- Prior art keywords
- tup
- taper knob
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- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000002245 particle Substances 0.000 claims abstract description 47
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 33
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 22
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 22
- 229920001971 elastomer Polymers 0.000 claims abstract description 17
- 239000000806 elastomer Substances 0.000 claims abstract description 13
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000004014 plasticizer Substances 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 27
- 229920002635 polyurethane Polymers 0.000 claims description 27
- 239000004814 polyurethane Substances 0.000 claims description 27
- 238000002360 preparation method Methods 0.000 claims description 27
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 27
- 239000004215 Carbon black (E152) Substances 0.000 claims description 16
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims description 16
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 15
- 238000007493 shaping process Methods 0.000 claims description 12
- 229920001169 thermoplastic Polymers 0.000 claims description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims description 12
- 150000001336 alkenes Chemical class 0.000 claims description 10
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 10
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- QKUNKVYPGIOQNP-UHFFFAOYSA-N 4,8,11,14,17,21-hexachlorotetracosane Chemical compound CCCC(Cl)CCCC(Cl)CCC(Cl)CCC(Cl)CCC(Cl)CCCC(Cl)CCC QKUNKVYPGIOQNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- -1 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 238000003856 thermoforming Methods 0.000 abstract 1
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a TUP taper knob and a manufacturing method thereof. The TUP taper knob is manufactured by thermoforming anti-aging thermoplastic polyurethane elastomer particles, and has the characteristics of being uvioresistant, anti-aging, skid-resistant, soft in texture, good in hand feeling and long in service life. Particularly, an antioxygen 1010, an antioxygen 168, polytetrafluoroethylene, chlorcosane and semi-reinforced carbon black, which are added into the anti-aging thermoplastic polyurethane elastomer particles, greatly improve the heat resistance, flame retardancy, friction resistance, ageing resistance and oxidation resistance performance of the cable material, and prolong the service life; by adding an external plasticizer, the plasticity of the anti-aging thermoplastic polyurethane elastomer particles is improved; by adding polyolefin elastomers, the manufactured TUP taper knob is better in elasticity, soft in texture and good in hand feeling.
Description
Technical field
The present invention relates to a kind of TUP taper knob and preparation method thereof.
Background technology
The rubber cable material many employings terpolymer EP rubber circulated on the market, terpolymer EP rubber, because of performances such as its outstanding ageing-resistant, water-fast, heat-resistant deformings, is widely used with on low, midium voltage cable peculiar to vessel, mobile.But along with the development of society and the progress of science and technology, the insulating property of existing rubber cable material also change gradually not fully up to expectations.
Summary of the invention
For the problems referred to above, the present invention proposes a kind of TUP taper knob and preparation method thereof.
For solving above technical problem, technical scheme provided by the invention is:
A kind of TUP taper knob and preparation method thereof, it is characterized in that, comprise the taper knob be made up of Polyurethane Thermoplastic Elastomer, described anti-aging Polyurethane Thermoplastic Elastomer particle is prepared from by the feed composition of following weight part:
TPU particle 65-78 part
Polyolefin elastomer 17-28 part
Antioxidant 1010 2-3 part
Irgasfos 168 1-2 part
Clorafin 5-15 part
Semi-reinforcing hydrocarbon black 7-15 part
Auxiliary agent 6-12 part
Tetrafluoroethylene 10-15 part.
Above-mentioned a kind of TUP taper knob and preparation method thereof, wherein, described auxiliary agent is softening agent, and described softening agent is external plasticizer.
Wherein, preferably, the moiety of described anti-aging Polyurethane Thermoplastic Elastomer particle is counted as follows by weight:
TPU particle 70 parts
Polyolefin elastomer 20 parts
Antioxidant 1010 3 parts
Irgasfos 168 1 part
Clorafin 8 parts
Semi-reinforcing hydrocarbon black 9 parts
Auxiliary agent 9 parts
Tetrafluoroethylene 12 parts.
Above-mentioned a kind of TUP taper knob and preparation method thereof, wherein, described auxiliary agent is softening agent, and described softening agent is external plasticizer.
A preparation method for TUP taper knob, is characterized in that, described preparation method is:
One, anti-aging Polyurethane Thermoplastic Elastomer particle preparation:
(1) each raw material is taken by the weight part of constitutive material: TPU particle: 65-78 part; Polyolefin elastomer: 17-28 part; Antioxidant 1010: 2-3 part; Irgasfos 168: 1-2 part; Clorafin: 5-15 part; Semi-reinforcing hydrocarbon black: 7-15 part; Auxiliary agent: 6-12 part; Tetrafluoroethylene: 10-15 part, and it is dry that TPU particle and olefin elastomer are passed through drying machine, drying temperature is 86 DEG C, and time of drying is 1.7 hours;
(2) antioxidant 1010, irgasfos 168, clorafin, semi-reinforcing hydrocarbon black and the tetrafluoroethylene in above-mentioned steps (1) is put into mixing machine to mix, etc. auxiliary agent A;
(3) auxiliary agent A that auxiliary agent, dried TPU particle and olefin elastomer and step (2) obtain is added mill and Banbury mixer or twin screw extruder are mixing, granulation, control temperature, between 140-155 DEG C, obtains anti-aging Polyurethane Thermoplastic Elastomer particle.
Two, thermoplastic shaping:
The anti-aging Polyurethane Thermoplastic Elastomer particle of step one gained is inserted in thermoplastic shaping machine, molded through mold hot, obtain TUP taper knob.
Beneficial effect of the present invention is:
A kind of TUP taper knob provided by the invention and preparation method thereof, this TUP taper knob anti-aging Polyurethane Thermoplastic Elastomer particle thermoplastic shaping is made, there is uvioresistant, anti-aging, quality is soft, good hand touch, the feature of anti-skidding long service life, be embodied in the antioxidant 1010 added in anti-aging Polyurethane Thermoplastic Elastomer particle, irgasfos 168, tetrafluoroethylene, clorafin, semi-reinforcing hydrocarbon black, greatly improve the heat-resisting of CABLE MATERIALS, fire-retardant, friction resistant, anti-aging and oxidation resistant performance, increase the service life, and add external plasticizer, add anti-aging Polyurethane Thermoplastic Elastomer particle plasticity-, by adding polyolefin elastomer, the TUP taper knob made is made to have more elasticity, quality is soft, good hand touch.
Embodiment
Example one
A preparation method for TUP taper knob, is characterized in that, described preparation method is:
One, anti-aging Polyurethane Thermoplastic Elastomer particle preparation:
(1) each raw material is taken by the weight part of constitutive material: TPU particle: 70 parts; Polyolefin elastomer: 20 parts; Antioxidant 1010: 3 parts; Irgasfos 168: 1 part; Clorafin: 8 parts; Semi-reinforcing hydrocarbon black: 9 parts; Auxiliary agent: 9 parts; Tetrafluoroethylene: 12 parts, and it is dry that TPU particle and olefin elastomer are passed through drying machine, drying temperature is 86 DEG C, and time of drying is 1.7 hours;
(2) antioxidant 1010, irgasfos 168, clorafin, semi-reinforcing hydrocarbon black and the tetrafluoroethylene in above-mentioned steps (1) is put into mixing machine to mix, etc. auxiliary agent A;
(3) auxiliary agent A that auxiliary agent, dried TPU particle and olefin elastomer and step (2) obtain is added mill and Banbury mixer or twin screw extruder are mixing, granulation, control temperature, between 150 DEG C, obtains anti-aging Polyurethane Thermoplastic Elastomer particle.
Two, thermoplastic shaping:
The anti-aging Polyurethane Thermoplastic Elastomer particle of step one gained is inserted in thermoplastic shaping machine, molded through mold hot, obtain TUP taper knob.
Example two
A preparation method for TUP taper knob, is characterized in that, described preparation method is:
One, anti-aging Polyurethane Thermoplastic Elastomer particle preparation:
(1) each raw material is taken by the weight part of constitutive material: TPU particle: 78 parts; Polyolefin elastomer: 17 parts; Antioxidant 1010: 2 parts; Irgasfos 168: 2 parts; Clorafin: 10 parts; Semi-reinforcing hydrocarbon black: 10 parts; Auxiliary agent: 6 parts; Tetrafluoroethylene: 11 parts, and it is dry that TPU particle and olefin elastomer are passed through drying machine, drying temperature is 86 DEG C, and time of drying is 1.7 hours;
(2) antioxidant 1010, irgasfos 168, clorafin, semi-reinforcing hydrocarbon black and the tetrafluoroethylene in above-mentioned steps (1) is put into mixing machine to mix, etc. auxiliary agent A;
(3) auxiliary agent A that auxiliary agent, dried TPU particle and olefin elastomer and step (2) obtain is added mill and Banbury mixer or twin screw extruder are mixing, granulation, control temperature, between 151 DEG C, obtains anti-aging Polyurethane Thermoplastic Elastomer particle.
Two, thermoplastic shaping:
The anti-aging Polyurethane Thermoplastic Elastomer particle of step one gained is inserted in thermoplastic shaping machine, molded through mold hot, obtain TUP taper knob.
Example three
A preparation method for TUP taper knob, is characterized in that, described preparation method is:
One, anti-aging Polyurethane Thermoplastic Elastomer particle preparation:
(1) each raw material is taken by the weight part of constitutive material: TPU particle: 68 parts; Polyolefin elastomer: 25 parts; Antioxidant 1010: 1 part; Irgasfos 168: 2 parts; Clorafin: 13 parts; Semi-reinforcing hydrocarbon black: 9 parts; Auxiliary agent: 12 parts; Tetrafluoroethylene: 15 parts, and it is dry that TPU particle and olefin elastomer are passed through drying machine, drying temperature is 86 DEG C, and time of drying is 1.7 hours;
(2) antioxidant 1010, irgasfos 168, clorafin, semi-reinforcing hydrocarbon black and the tetrafluoroethylene in above-mentioned steps (1) is put into mixing machine to mix, etc. auxiliary agent A;
(3) auxiliary agent A that auxiliary agent, dried TPU particle and olefin elastomer and step (2) obtain is added mill and Banbury mixer or twin screw extruder are mixing, granulation, control temperature, between 155 DEG C, obtains anti-aging Polyurethane Thermoplastic Elastomer particle.
Two, thermoplastic shaping:
The anti-aging Polyurethane Thermoplastic Elastomer particle of step one gained is inserted in thermoplastic shaping machine, molded through mold hot, obtain TUP taper knob.
A kind of TUP taper knob provided by the invention and preparation method thereof, this TUP taper knob anti-aging Polyurethane Thermoplastic Elastomer particle thermoplastic shaping is made, there is uvioresistant, anti-aging, quality is soft, good hand touch, the feature of anti-skidding long service life, be embodied in the antioxidant 1010 added in anti-aging Polyurethane Thermoplastic Elastomer particle, irgasfos 168, tetrafluoroethylene, clorafin, semi-reinforcing hydrocarbon black, greatly improve the heat-resisting of CABLE MATERIALS, fire-retardant, friction resistant, anti-aging and oxidation resistant performance, increase the service life, and add external plasticizer, add anti-aging Polyurethane Thermoplastic Elastomer particle plasticity-, by adding polyolefin elastomer, the TUP taper knob made is made to have more elasticity, quality is soft, good hand touch.
The above; be only the present invention's preferably embodiment, but protection scope of the present invention is not limited thereto, is anyly familiar with those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.
Claims (5)
1. TUP taper knob and preparation method thereof, is characterized in that, comprises the taper knob be made up of Polyurethane Thermoplastic Elastomer, and described anti-aging Polyurethane Thermoplastic Elastomer particle is prepared from by the feed composition of following weight part:
TPU particle 65-78 part
Polyolefin elastomer 17-28 part
Antioxidant 1010 2-3 part
Irgasfos 168 1-2 part
Clorafin 5-15 part
Semi-reinforcing hydrocarbon black 7-15 part
Auxiliary agent 6-12 part
Tetrafluoroethylene 10-15 part.
2. a kind of TUP taper knob as claimed in claim 1 and preparation method thereof, is characterized in that, preferably, the moiety of described anti-aging Polyurethane Thermoplastic Elastomer particle is counted as follows by weight:
TPU particle 70 parts
Polyolefin elastomer 20 parts
Antioxidant 1010 3 parts
Irgasfos 168 1 part
Clorafin 8 parts
Semi-reinforcing hydrocarbon black 9 parts
Auxiliary agent 9 parts
Tetrafluoroethylene 12 parts.
3. a kind of TUP taper knob as claimed in claim 1 and preparation method thereof, it is characterized in that, described preparation method is:
One, anti-aging Polyurethane Thermoplastic Elastomer particle preparation:
(1) each raw material is taken by the weight part of constitutive material: TPU particle: 65-78 part; Polyolefin elastomer: 17-28 part; Antioxidant 1010: 2-3 part; Irgasfos 168: 1-2 part; Clorafin: 5-15 part; Semi-reinforcing hydrocarbon black: 7-15 part; Auxiliary agent: 6-12 part; Tetrafluoroethylene: 10-15 part, and it is dry that TPU particle and olefin elastomer are passed through drying machine, drying temperature is 86 DEG C, and time of drying is 1.7 hours;
(2) antioxidant 1010, irgasfos 168, clorafin, semi-reinforcing hydrocarbon black and the tetrafluoroethylene in above-mentioned steps (1) is put into mixing machine to mix, etc. auxiliary agent A;
(3) auxiliary agent A that auxiliary agent, dried TPU particle and olefin elastomer and step (2) obtain is added mill and Banbury mixer or twin screw extruder are mixing, granulation, control temperature, between 140-155 DEG C, obtains anti-aging Polyurethane Thermoplastic Elastomer particle;
Two, thermoplastic shaping:
The anti-aging Polyurethane Thermoplastic Elastomer particle of step one gained is inserted in thermoplastic shaping machine, molded through mold hot, obtain TUP taper knob.
4. a kind of TUP taper knob as claimed in claim 1 and preparation method thereof, is characterized in that, described auxiliary agent is softening agent.
5. a kind of TUP taper knob as claimed in claim 4 and preparation method thereof, is characterized in that, described softening agent is external plasticizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510172875.4A CN104788939A (en) | 2015-04-14 | 2015-04-14 | TUP taper knob and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510172875.4A CN104788939A (en) | 2015-04-14 | 2015-04-14 | TUP taper knob and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104788939A true CN104788939A (en) | 2015-07-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510172875.4A Pending CN104788939A (en) | 2015-04-14 | 2015-04-14 | TUP taper knob and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104788939A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914281A (en) * | 2010-08-03 | 2010-12-15 | 营口巨成教学科技开发有限公司 | Thermoplastic elastomer composition |
| CN103436005A (en) * | 2013-08-13 | 2013-12-11 | 东莞市安拓普塑胶聚合物科技有限公司 | High-temperature-resistant halogen-free flame retardant thermoplastic polyurethane elastomer for cable and preparation method thereof |
| CN103756286A (en) * | 2014-01-16 | 2014-04-30 | 珠海汉胜科技股份有限公司 | Thermoplastic polyurethane cable sheath material and preparation method |
-
2015
- 2015-04-14 CN CN201510172875.4A patent/CN104788939A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914281A (en) * | 2010-08-03 | 2010-12-15 | 营口巨成教学科技开发有限公司 | Thermoplastic elastomer composition |
| CN103436005A (en) * | 2013-08-13 | 2013-12-11 | 东莞市安拓普塑胶聚合物科技有限公司 | High-temperature-resistant halogen-free flame retardant thermoplastic polyurethane elastomer for cable and preparation method thereof |
| CN103756286A (en) * | 2014-01-16 | 2014-04-30 | 珠海汉胜科技股份有限公司 | Thermoplastic polyurethane cable sheath material and preparation method |
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Application publication date: 20150722 |