CN104784728B - A kind of deodorant handled suitable for organic solid castoff and its application - Google Patents

A kind of deodorant handled suitable for organic solid castoff and its application Download PDF

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CN104784728B
CN104784728B CN201510165053.3A CN201510165053A CN104784728B CN 104784728 B CN104784728 B CN 104784728B CN 201510165053 A CN201510165053 A CN 201510165053A CN 104784728 B CN104784728 B CN 104784728B
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deodorant
solid
acid solution
weight
organic solid
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CN104784728A (en
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李春萍
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Beijing Jinyu Limited-Liability Co
Beijing Building Materials Academy of Sciences Research
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Beijing Jinyu Limited-Liability Co
Beijing Building Materials Academy of Sciences Research
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Abstract

The present invention is a kind of deodorant handled suitable for organic solid castoff and its application, and the deodorant includes solid, liquid two parts, and solid portion is:Bentonite, diatomite, magnesia, ferrite based substances, porous straw class, each component ratio are 0.5 ~ 2.5:0.5~2.5:0.5~2.5:3~5:5~10;Liquid portion is:The mixture of 5% phosphoric acid solution, 10% furfuryl aldehyde solution and 15% butyric acid solution, each component ratio is 2 ~ 4:1~2:3~5.Deodorant solid portion is mixed in organic solid castoff, its volume is 5% ~ 10%, the liquid portion of deodorant is sprayed after stirring, its volume is 1 ~ 5%, compost or biological dewatered processing are carried out after stirring, odor concentration reduction by more than 90% in biological treatment process, while air PM2.5 class material total emission volumns can be reduced, can be increased the content of organic matter and calorific value of organic solid castoff.

Description

A kind of deodorant handled suitable for organic solid castoff and its application
Technical field
Field is recycled the present invention relates to solid waste, in particular for being related to house refuse, sludge, kitchen garbage etc. The stench control technology of organic solid waste compost and the treatment technology such as biological dewatered.
Background technology
With the continuous expansion of city size, growing and living standards of the people the continuous improvement of urban population, The yield of domestic waste is gradually increasing.Early in 1996, the Chinese municipal refuse amount of clearing just reached 100,000,000 Ton, and it is annual with 8% ~ 10% speed growth.The volume of cargo in storage over the years of rubbish reaches more than 60 hundred million tons, and there is more than 200 city in the whole nation It is absorbed among the encirclement of rubbish, rubbish stores up the land area occupied up to more than 500,000,000 square metre.
With developing rapidly for economy and going deep into for Development of China's Urbanization, the municipal sewage treatment amount of China is also increasing year by year It is long.Municipal sewage sludge results from the stage of the biochemical treatment of city domestic sewage, mostlys come from sewage treatment plants First and secondary sedimentation tank, the volume that produces is maximum when being city domestic sewage processing, be easiest to produce the pair of secondary pollution Product.The yield of sludge is big, and 1000 tons of city domestic sewages of processing about produce the sludge that 1 ton of moisture content is 80%.Sewage disposal In whole construction costs of factory, the part for Treatment of Sludge can reach 70%.Sludge without appropriate processing disposal enters After environment, secondary pollution is brought directly to water body and air, the effective processing capacity of sewage disposal system is not only reduced, and Activity to ecological environment and the mankind constitutes serious threat.
China's kitchen garbage yield is big, wide, and mainly hotel, restaurant, enterprises and institutions dining room etc. are in business process The mixtures such as leftovers, the leftover bits and pieces of middle generation.At home, the organic waste of the eating and drinking establishment such as some dining rooms, hotel, restaurant Yield is surprising.Beijing produces kitchen garbage about more than 1600 ton daily, is responsible for what is completed according to University Of Chongqing《Chongqing City City kitchen garbage yield investigation and analysis of physical and chemical property report》, the daily yield of Chongqing kitchen garbage in 2007 About 1000 tons;By 2003, the kitchen garbage that Shanghai City is produced daily was also up to 1100 tons or so.
Organic solid castoff necessarily leads to odor pollution in biological treatment process.Odor pollution is one kind of atmosphere pollution Form, but due to its particularity, many countries treat as single-row public hazards, belong to the typical public hazards in seven kinds of the world today (big One of gas pollution, water pollution, soil pollution, noise pollution, vibration, land subsidence, stench).Foul gas is directly acted on The smell of people is simultaneously damaged by breathing to human body, the increasingly raising with people to environmental quality requirement, and people are to various The discontented mood that stench is caused and the ratio complained also more and more higher, especially in some developed countries, the complaint to stench More than 90% always complained beyond environmental pollution.In the area such as Japan and Hong Kong, odor pollution has turned into the main ring that the public complains Border problem.In recent years, China cities and towns odor pollution event frequently occurs, and stench is complained shared by whole environment tip-offs about environmental issues Ratio occupies second, and odor pollution is increasingly becoming a serious society and environmental problem.Odor pollution preventing and treating has caused China Government and the great attention of environmental management department at different levels,《Chinese national economy and the planning outline of social development 12》Clearly carry Going out " will strengthen odorant pollutant improvement ".
The content of the invention
It is suitable for the present invention is to solve providing one kind at the organic solid wastes such as house refuse, sludge, kitchen garbage biology The formula of stench deodorant in situ during reason, can be solved in puzzlement organic solid waste biological treatment process using the deodorant Deodor problem, reduces air PM2.5 class material total emission volumns, increases the content of organic matter and calorific value of organic solid waste, improves Follow-up fertilizer efficiency and burning utilization rate.
Catch, adsorb and degrade for the odor pollution source of generation original position of organic solid castoff biological treatment, can take Must be than the more preferable effect of loss odor pollution gas outside simple subsequent treatment.In-situ control thought is in garbage compost nitrogen loss control It is applied in system research, improves quality of compost products;And the concentration of ammonia in odor pollution is considerably reduced, reduce Disposal of pollutants.But ozone Control in situ focuses primarily upon the control of nitrogen in composting process, for olfact, other Contribution of the control of element such as sulphur to foul smell is bigger, and the Cl elements contained in the deodorant of addition are unfavorable for follow-up burn and soil Ground etc. is utilized.Therefore, the deodorant that maladorous material in-situ control is directed in organic solid castoff biological treatment process is developed, For controlling the malodorous discharge of solidification disposal of waste facility significant.
The purpose of the present invention is realized by following scheme:
A kind of deodorant handled suitable for organic solid castoff, the deodorant includes solid portion and liquid portion Point, the solid portion includes:Bentonite, diatomite, magnesia, ferrite based substances, porous straw, the weight of each solid constituent Measuring number is:
Bentonite 0.5 ~ 2.5
Diatomite 0.5 ~ 2.5
Magnesia 0.5 ~ 2.5
Ferrite based substances 3 ~ 5
Porous straw 5 ~ 10;
The liquid portion includes:5% phosphoric acid solution, 10% furfuryl aldehyde solution and 15% butyric acid solution, the weight of each liquid component Number is:5% phosphoric acid solution 2 ~ 4
10% furfuryl aldehyde solution 1 ~ 2
15% butyric acid solution 3 ~ 5.
Further, the ferrite based substances are the mixed of any one or more in iron powder, iron oxide, iron ore, Waste iron slag Compound.
Further, the porous straw is any one in sunflower pole, cornstalk, kaoliang stalk, waste of flax or many The mixture planted.
Further, the parts by weight of each solid constituent are:
Bentonite 1
Diatomite 1
Magnesia 1
Ferrite based substances 3
Porous straw 10;
The parts by weight of each liquid component are:
5% phosphoric acid solution 3
10% furfuryl aldehyde solution 2
15% butyric acid solution 5.
Further, the parts by weight of each solid constituent are:
Bentonite 2
Diatomite 2
Magnesia 2
Ferrite based substances 5
Porous straw 10;
The parts by weight of each liquid component are:
5% phosphoric acid solution 4
10% furfuryl aldehyde solution 2
15% butyric acid solution 5.
It is a kind of for organic solid castoff handle deodorant application, deodorant using the step of be:
1)The deodorant solid portion is mixed in organic solid castoff, its volume accounts for organic solid castoff gross weight The 5% ~ 10% of amount;
2)The organic solid castoff that with the addition of deodorant solid portion is stirred into mixing uniformly to be mixed within 5 ~ 15 minutes Compound;
3)Spray the liquid portion of the deodorant into above-mentioned uniform mixture, its volume for mixture weight 1 ~ 5%, continue to stir more than 10 minutes, complete the addition of deodorant;
4)The organic solid castoff for completing deodorant addition is subjected to compost or biological dewatered processing.
Beneficial effects of the present invention are:
1)Composite deodurizing:Two kinds of materials of solid-state and liquid have been used as compound deodorizer;Solid and liquid synergy, By the compound action such as adsorbing, being complexed, activate, buffer, build, the conversion and fixation of odorant have been further speeded up;
2)Solid matter is added first, solid matter is played absorption organic solid waste in collecting, transporting due to temporary The percolate deposited process and produced, and solid matter has also built the skeleton of growth, air entrance for microorganism;Annex solution again Body material, excites the activity of the inorganic components such as bentonite, diatomite, magnesia, has buffered the pH value of material, is also microorganism Growth provides substantial amounts of trace element;
3)Deodorization in situ:The Sources controlling foul gas volatilization produced in stench, has saved follow-up Odor control link;
4)Fertilizer efficiency and calorific value can also be improved simultaneously in deodorization, beneficial to follow-up land use or burning disposal.
5)Reduce air PM2.5 total emission volumns:Using this deodorization medicament, organic solid waste is in compost or biological dewatered process In, PM2.5 total emission volumns reduce more than 70%.
Embodiment
Embodiment 1
A kind of deodorant handled suitable for organic solid castoff, the deodorant includes solid portion and liquid portion Point, the solid portion includes:Bentonite(Powder), diatomite(Powder), magnesia(Powder), ferrite based substances, porous plant Stalk(5~10cm), the parts by weight of each solid constituent are:
Bentonite 0.5 ~ 2.5
Diatomite 0.5 ~ 2.5
Magnesia 0.5 ~ 2.5
Waste iron slag 3 ~ 5
Porous straw 5 ~ 10;
The liquid portion includes:5% phosphoric acid solution, 10% furfuryl aldehyde solution and 15% butyric acid solution, are the aqueous solution above, The parts by weight of each liquid component are:
5% phosphoric acid solution 2 ~ 4
10% furfuryl aldehyde solution 1 ~ 2
15% butyric acid solution 3 ~ 5.
The ferrite based substances can be the mixture of any one or more in iron powder, iron oxide, iron ore, Waste iron slag. The porous straw can be the mixture of any one or more in sunflower pole, cornstalk, kaoliang stalk, waste of flax.Cause For the short texture of sunflower pole, soft texture, so sunflower pole is first choice.
The preparation of solid portion:Bentonite, diatomite, magnesia are blended in after 60 degree or so drying, particle diameter is crushed to 0.5mm~1mm(Dispersion effect and adsorption effect are preferable), then ferrite based substances are crushed to 0.5 ~ 1mm, then by porous plant straw Stalk is crushed to 5 ~ 10mm(Such a stalk length can reach optimum efficiency, and stalk is too short to require high to crushing operation, and stalk is oversize not Beneficial to being uniformly dispersed, deodorizing effect does not reach most preferably), then three kinds of crushed materials are mixed evenly.
Deodorant using the step of be:
1)The deodorant solid portion is mixed in organic solid castoff, its volume accounts for organic solid castoff gross weight The 5% ~ 10% of amount;
2)The organic solid castoff that with the addition of deodorant solid portion is stirred into mixing uniformly to be mixed within 5 ~ 15 minutes Great efforts are stirred in compound, feeding mixer, effect can be significantly improved;
3)Spray the liquid portion of the deodorant into above-mentioned uniform mixture, its volume for mixture weight 1 ~ 5%, continue to stir more than 10 minutes, complete the addition of deodorant;
4)The organic solid castoff for completing deodorant addition is subjected to compost or biological dewatered processing, can be by biology Odor concentration reduction by more than 90% during reason.
Bentonite, diatomite and the effect to porous straw class are to adsorb the percolate produced in biological treatment process And the foul smell of volatilization;The effect of magnesia and phosphoric acid is to generate struvite crystallization thing, the effect of ferrite based substances with the ammonia in material It is to be combined with the sulphur in material, forms iron sulfide, suppresses the volatilization of sulphur class compound;The effect of furfural and butyric acid is regulation material PH buffering ranges and excite the activity of bentonite, diatomite, magnesia.During three class material compound uses, not only adsorbable, network Odor causing substance is closed, and excites the activity of the inorganic components such as bentonite, diatomite, magnesia, is also provided for microorganism growth Substantial amounts of trace element, has built the skeleton of microorganism growth, has further speeded up the conversion and fixation of odorant.
Embodiment 2
Further optimize on the basis of embodiment 1.
It is 60% domestic waste by moisture content(Equivalent to the solid waste), through rotary screen(The profit of Tianjin hundred, 10t/h), vibrating screen classifier(The flat industrial mining machinery plant in the western gulf of osmanthus directorial area, model:1200*2400;)And magnetic separator(Dongyang Tian Li magnetoelectricities Co., Ltd, model:CTB-712)Remove after inorganic debris(Obtain organic solid), by bentonite:Diatomite:Water chestnut Magnesia:Iron powder:Sunflower pole(About 5cm)According to 1:1:1:3:After 10 part by weight is configured, the ratio using weight proportion as 5% Example is added in domestic waste, is well mixed in batch mixer, mixes 10 minutes.Then, by 5% phosphoric acid:10% furfural: 15% butyric acid solution is according to 3:2:5 proportions are sprayed into batch mixer with 1% ratio, remixed 10 minutes into mixed solution. The house refuse that the deodorant of liquid and solid will be with the addition of again be put into homemade composting device carrying out compost treatment, The 3rd day, the 5th day, the 10th day, the 15th day and the 21st day of compost determines odor concentration respectively(Using triangle odor bag method Determine, emission standard for odor pollutants, GB 14554-93), the odor concentration reduction by more than 90% of discharge.
Embodiment 3
Optimized on the basis of embodiment 1.
By moisture content be 80% domestic sludge in add certain auxiliary material(Such as rice husk, mushroom residue, garden waste)Afterwards, By bentonite:Diatomite:Magnesia:Waste iron slag:Broomcorn straw is according to 2:2:2:5:After 10 part by weight is configured, with weight Proportion is added in sludge for 5% ratio, is well mixed in batch mixer, mixes 15 minutes.Then, by 5% phosphoric acid:10% chaff Aldehyde:15% butyric acid is according to 4:2:5 proportions are sprayed into batch mixer with 5% ratio, remixed 10 minutes into mixed solution. The sludge that the deodorant of liquid and solid will be with the addition of again carries out being put into the biological dewatered processing of biological dewatered workshop progress, in biology The 3rd day, the 5th day, the 10th day, the 15th day and the 21st day of desiccation determines odor concentration respectively(Using triangle odor bag method Determine, emission standard for odor pollutants, GB 14554-93), the odor concentration reduction by more than 90% in environment, by biological dewatered Sludge calorific value add 5.8%.

Claims (3)

1. a kind of deodorant handled suitable for organic solid castoff, it is characterised in that the deodorant includes solid portion And liquid portion, the solid portion includes:Bentonite, diatomite, magnesia, ferrite based substances, porous straw, each solid The parts by weight of composition are:
Bentonite 0.5 ~ 2.5
Diatomite 0.5 ~ 2.5
Magnesia 0.5 ~ 2.5
Ferrite based substances 3 ~ 5
Porous straw 5 ~ 10;
The liquid portion includes:5% phosphoric acid solution, 10% furfuryl aldehyde solution and 15% butyric acid solution, the parts by weight of each liquid component For:5% phosphoric acid solution 2 ~ 4
10% furfuryl aldehyde solution 1 ~ 2
15% butyric acid solution 3 ~ 5;
The ferrite based substances are the mixture of any one or more in iron powder, iron oxide, iron ore, Waste iron slag;
The porous straw is the mixture of any one or more in sunflower pole, cornstalk, kaoliang stalk, waste of flax;
Deodorant using the step of be:
1)The deodorant solid portion is mixed in organic solid castoff, its volume occupies machine solid waste stream by weight 5%~10%;
2)The organic solid castoff that with the addition of deodorant solid portion is stirred into mixing and obtains uniform mixture within 5 ~ 15 minutes;
3)The liquid portion of the deodorant is sprayed into above-mentioned uniform mixture, its volume is the 1 ~ 5% of mixture weight, Continue to stir more than 10 minutes, complete the addition of deodorant;
4)The organic solid castoff for completing deodorant addition is subjected to compost or biological dewatered processing.
2. deodorant according to claim 1, it is characterised in that:The parts by weight of each solid constituent are:
Bentonite 1
Diatomite 1
Magnesia 1
Ferrite based substances 3
Porous straw 10;
The parts by weight of each liquid component are:
5% phosphoric acid solution 3
10% furfuryl aldehyde solution 2
15% butyric acid solution 5.
3. deodorant according to claim 1, it is characterised in that:The parts by weight of each solid constituent are:
Bentonite 2
Diatomite 2
Magnesia 2
Ferrite based substances 5
Porous straw 10;
The parts by weight of each liquid component are:
5% phosphoric acid solution 4
10% furfuryl aldehyde solution 2
15% butyric acid solution 5.
CN201510165053.3A 2015-04-09 2015-04-09 A kind of deodorant handled suitable for organic solid castoff and its application Active CN104784728B (en)

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Publication number Priority date Publication date Assignee Title
CN105384516B (en) * 2015-11-12 2019-02-12 北京建筑材料科学研究总院有限公司 A kind of co-induction agent and its application method for kitchen waste compost deodorization
CN109529526A (en) * 2018-12-28 2019-03-29 南京金湖环保科技有限公司 A kind of microorganism composite type deodorization agent and preparation method thereof
CN113908680A (en) * 2021-09-01 2022-01-11 郑州轻工业大学 Deodorant for organic solid waste aerobic fermentation treatment and preparation method thereof

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN1434002A (en) * 2003-03-05 2003-08-06 湖南大学 Deodorant, modified deodorant and deodorizing method for refuse compost
CN1569241A (en) * 2003-07-10 2005-01-26 吕蔺强 Air sterilizing and freshing agent
CN103110971A (en) * 2011-10-20 2013-05-22 国际香料和香精公司 Low valatile reactive malodor counteractives and methods of use thereof
CN103878172A (en) * 2014-04-14 2014-06-25 北京建筑材料科学研究总院有限公司 Method for jointly treating polycyclic aromatic hydrocarbon polluted soil and urban organic waste
CN104189934A (en) * 2014-09-15 2014-12-10 安徽工业大学 Chemical type deodorant for waste transfer station and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1434002A (en) * 2003-03-05 2003-08-06 湖南大学 Deodorant, modified deodorant and deodorizing method for refuse compost
CN1569241A (en) * 2003-07-10 2005-01-26 吕蔺强 Air sterilizing and freshing agent
CN103110971A (en) * 2011-10-20 2013-05-22 国际香料和香精公司 Low valatile reactive malodor counteractives and methods of use thereof
CN103878172A (en) * 2014-04-14 2014-06-25 北京建筑材料科学研究总院有限公司 Method for jointly treating polycyclic aromatic hydrocarbon polluted soil and urban organic waste
CN104189934A (en) * 2014-09-15 2014-12-10 安徽工业大学 Chemical type deodorant for waste transfer station and preparation method thereof

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