CN104784064A - Hair styling composition containing quaternized hydroxyethyl cellulose - Google Patents
Hair styling composition containing quaternized hydroxyethyl cellulose Download PDFInfo
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- CN104784064A CN104784064A CN201410020077.5A CN201410020077A CN104784064A CN 104784064 A CN104784064 A CN 104784064A CN 201410020077 A CN201410020077 A CN 201410020077A CN 104784064 A CN104784064 A CN 104784064A
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Abstract
The invention discloses a hair styling composition, which comprises the following components: quaternized hydroxyethyl cellulose, a rheology modifier selected from copolymers of acrylic acid (esters) and methacrylate derivatives, and a setting agent selected from copolymers of acrylic acid (esters) and hydroxyacrylic acid (esters). The invention also relates to a method for styling hair by applying an effective amount of said hair styling composition and to the use of said hair styling composition for the preparation of a cosmetic product.
Description
Technical field
The present invention relates to a kind of hair setting composition, more specifically, relate to and a kind ofly comprise quaternized hydroxyethylcellulos and as the rheology modifier of anion component and the hair setting composition of setting agent.Described hair setting composition has good hair fixing effect, provides good sense of touch to hair, has good antistatic effect, especially can improve the guarantor type ability of hair in high humility situation.
Background technology
Hair fixing product (such as spray, mousse, pomade, hair jelly etc.) is intended to help to create individual hair style and the specific products form in position temporarily keeping a period of time.The described retention time is when should be enough in theory last till use next time shampoo washing hair.In prior art, typical hair setting composition is all based on the hair fixing copolymer in suitable carrier mass (such as comprising the moisture of gel former or aqueous alcohol).But, the most polymer with excellent hair fixing ability is responsive to high humility, make when the hair crossed by polymer treatment is exposed in dampness, polymer can lose its part or all of hair fixing effect, thus good hair fixing cannot be realized, be more difficult to required hair fixing to remain to the desired sufficiently long time.Therefore, the moisture resistance improving hair fixing product is high expectations, particularly when not losing the beneficial effect needed for other (such as easy cleaning, cardability, feel etc.).
Well known employing conventional polymer is used for hair setting composition, and these polymer comprise lac and resin, and synthesizes neutrality and the anionic polymer, particularly anionic polymer in source.The known commercial anionic type polymer being used as forming hair or setting agent comprises polyvinyl pyrrolidone, polyvinyl pyrrolidone/vinyl acetate copolymer and acrylate/hydroxy ester acrylate copolymer (Rohm and Haas).Other example of anionic polymer is acrylate copolymer (Balance CR, Akzo; Luviflex Soft, Luvimer100P and Luvimer Pro55, is sold by BASF), AMP-acrylate/allyl methacrylate copolymer (Fixate
tMg-100, Lubrizol Advanced Materials, Inc.) polyacrylate-14 (Fixate
tMplus, Lubrizol Advanced Materials, Inc.) and polyacrylate-2 cross linked polymer (Fixate
tMsuperhold, Lubrizol Advanced Materials, Inc.).Such as, the United States Patent (USP) 4,196,190 of the people such as Gehman discloses acrylic compounds hairspray.But, one of shortcoming of conventional fixative polymers is, they usually can not provide significant thickening or contribute the significant rheological equationm of state under the working concentration of reality, for this reason, one or more viscosity raising thickening agents or gel is usually needed to add to provide more convenient or gratifying product.
Nonetheless, conventional anion type hairspray polymer often with rheological modifiers or gel incompatible, cause viscosity damage, gel products clarity is not good enough, the unsatisfactory loss with the thinning rheological characteristic of shearing of texture attribute.
The United States Patent (USP) 3 of the people such as Nowak, 726,288 attempt adopting acrylate polymers to be used for the crosslinked of hairspray and thickening agent, but, although this product achieves thickening, hair fixing poor performance (at 72 degrees Fahrenheits (about 22 degrees Celsius)) and 90% relative humidity under after 0.5 hour bending conservation rate lower than 50%.
Therefore, the hair setting composition still required further improvement in prior art, it can improve the guarantor type ability of hair in high humidity situation, and/or provides good sense of touch and/or antistatic effect.
Summary of the invention
Except as otherwise noted, otherwise all percent used herein is all with the total weight of compositions, and all ratios are weight ratio.
The all components used in the present invention should be that skin is acceptable, namely can not cause unsuitable toxicity, incompatibility, unstability and atopic reaction etc. when contacting with the skin of people.
Term used herein " hair setting composition " refers to the compositions be intended to for personal nursing, and it can provide the effect of the hair fixing needed for it to object.
In the present invention, " hair fixing product " or " hairspray " refers to the personal care composition for hair fixing or moulding, and it can be the forms such as such as spray, mousse, pomade and hair jelly." personal nursing " relates to the compositions being applied topically to people's (not ingested).Preferably, described personal care composition is that beauty treatment is acceptable." improve looks acceptable " and refer to the long hair being generally used for personal care composition, and be intended to emphasize that virose material is not considered component of the present invention when existing with the usual amount found in personal care composition.
In this article, " polymer " or " copolymer " is term well known to those skilled in the art, FW Billmeyer JR can be entered in " polymer science textbook " (Textbook of PolymerScience) (second edition, 1971) defining in, is the comparatively macromole be made up of the product of less chemical repeat unit.
The molecular weight of polymer can be measured by standard method, such as, adopt size exclusion chromatography (SEC) (SEC).In this article, be polymerized separately by certain monomer or be jointly polymerized with other monomers and obtained polymer comprises this monomer as polymerized unit.
An object of the present invention is to provide a kind of hair setting composition still at high humidity with good shape keeping ability.
The present inventor finds unexpectedly in research process, using the quaternized hydroxyethylcellulos as cation quaternary ammonium salt and acrylic acid (ester) class as rheology modifier with the copolymer of methacrylic acid (ester) analog derivative and combinationally use together with the copolymer of hydroxy acrylic acid (ester) class as acrylic acid (ester) class of setting agent, above-mentioned purpose can be realized.
Therefore, in first aspect, the invention provides a kind of hair setting composition, it comprises following component:
(1) quaternized hydroxyethylcellulos of compositions gross weight 0.1% to 8% is accounted for;
(2) account for the rheology modifier of compositions gross weight 0.2% to 8%, it is selected from the copolymer of acrylic acid (ester) class and methacrylic acid (ester) class; With
(3) account for the setting agent of compositions gross weight 0.5% to 20%, it is selected from the copolymer of acrylic acid (ester) class and hydroxy acrylic acid (ester) class.
The present inventor is surprised to find, and the anionic polymer system of quaternized hydroxyethylcellulos and above-mentioned rheology modifier and setting agent does not occur incompatible.This is for realizing good sizing and shape-retaining ability energy, and the curly headed conservation rate particularly improved in high humility situation is significant.
Preferably, quaternized hydroxyethylcellulos of the present invention is following copolymer a) and b):
C) hydroxyethyl-cellulose
Wherein R=H or
n represents the degree of polymerization of hydroxyethyl-cellulose monomer, and n is the integer of 1000 ~ 4000, and x is the integer of 500 ~ 1500;
D) quaternized ammonium groups
Wherein R
1be selected from halogen ion, acetate, phosphate radical, nitrate anion and Methylsulfate, y represents the degree of polymerization of quaternized ammonium groups monomer, and y is the integer of 2000 ~ 4000.
In preferred at one, between nitrogen content (percentage composition of the nitrogen) 0.1%-6% of quaternized hydroxyethylcellulos of the present invention, preferably between 0.2%-5%, between 0.3%-4%, between 0.4%-3%, most preferably between 0.7%-2%.In another is preferred, the charge density of quaternized hydroxyethylcellulos of the present invention between 0.5-1.5meq/g, between preferred 0.6-1.3meq/g, more preferably between 0.8-1.2meq/g.The present inventor finds unexpectedly, the nitrogen content of the quaternized hydroxyethylcellulos in above-mentioned scope and the combination of charge density, better technique effect can be brought, particularly with above-mentioned anion systems, there is the good compatibility, auxiliary sizing can also be provided, and cause compositions to have good antistatic effect and high humility curl retention.
One concrete preferred in, quaternized hydroxyethylcellulos of the present invention is selected from the copolymer of hydroxyethyl-cellulose and dimethyl diallyl ammonium chloride.
In preferred version of the present invention, described rheology modifier is polymerized by acrylic acid (ester) class and methyl acrylic ester derivant, and its structural formula is as follows:
R
2represent hydrogen atom or the unsaturated or saturated alkyl containing 1-30 carbon atom;
R
3represent hydrogen atom or methyl;
R
4unsaturated or the saturated alkyl of representative containing 1-30 carbon atom;
A represents the degree of polymerization of acrylic acid (ester) class monomer, and scope is between 2-30;
B represents the degree of polymerization of methacrylate monomer, and scope is between 2-30;
C represents the degree of polymerization of ethyoxyl in methacrylate, and scope is between 0-30.
In other preferred embodiments of the present invention, described setting agent is selected from acrylic acid (ester) class/hydroxyl esters acrylic acid (ester) analog copolymer (Acrylates/Hydroxyesters Acrylates Copolymer).
In addition, as required, hair setting composition of the present invention also can comprise be selected from following at least one component or its combination: essence, antiseptic, solubilizing agent, thickening agent, surfactant, nertralizer, wetting agent, quintessence oil, vitamin, pearling agent, dyestuff, solvent and diluent.Especially, described solvent or diluent are selected from water and alcohols or its and combine, and the example of described alcohols comprises ethanol, isopropyl alcohol, normal propyl alcohol, glycerol and propylene glycol.
In another aspect of the present invention, provide a kind of method making hair fixing, comprise the hair setting composition of the invention described above using effective dose to hair.
In another aspect of the present invention, the purposes of hair setting composition of the present invention in preparation personal care product is provided.
Accompanying drawing explanation
Fig. 1 is the effectiveness comparison of the curling conservation rate of (RH=90%) under the different hair setting compositions of display embodiment of the present invention I-IV improve high humility situation.Wherein, example I is not containing the reference product of quaternized hydroxyethylcellulos; Example II-IV is hair setting composition prepared in accordance with the present invention.Result shows, the present composition comprising quaternized hydroxyethylcellulos, compared with not comprising the reference composition of quaternized hydroxyethylcellulos, shows the curl retention of improvement.
Fig. 2 is that the different hair setting compositions of display embodiment of the present invention I-IV of the present invention are for sizing intensity and elastic effectiveness comparison.Wherein, example I is not containing the reference product of quaternized hydroxyethylcellulos; Example II-IV is hair setting composition prepared in accordance with the present invention.Result shows, the present composition comprising quaternized hydroxyethylcellulos, compared with not comprising the reference composition of quaternized hydroxyethylcellulos, shows the sizing intensity of increase and the elasticity of improvement.
Detailed description of the invention
Below further describe and demonstrate embodiment within the scope of the present invention.Provide these detailed description of the invention just in order to the object that illustrates instead of limitation of the present invention, because the spirit and scope of the present invention can not be departed from carry out many changes and adjustment to them.Except as otherwise noted, all content, concentration enumerated is all w/w percentage ratio.
In one aspect of the invention, provide a kind of hair setting composition, its comprise following component or:
(1) quaternized hydroxyethylcellulos of compositions gross weight 0.1% to 8% is accounted for;
(2) account for the rheology modifier of compositions gross weight 0.2% to 8%, it is selected from the copolymer of acrylic acid (ester) class and methacrylic acid (ester) class; With
(3) account for the setting agent of compositions gross weight 0.5% to 20%, it is selected from the copolymer of acrylic acid (ester) class and hydroxy acrylic acid (ester) class.
Quaternized hydroxyethylcellulos in the present invention is the compound of the quaternized rear formation of hydroxyethyl-cellulose, and it shows the characteristic of cation opsonizing agent.Hydroxyethyl-cellulose is the one of cellulose ether, it can be considered the macromolecular compound with ether structure be made up of cellulose, primary alconol wherein in cellulosic molecule on each glucose ring and/or the hydroxyl of secondary alcohol are replaced by alkyl and generate cellulose ether derivative, are the products that the hydrogen of gunslinging in cellulosic molecule is replaced by alkyl.It replaces degree (substitution value, DS) provides hydroxyalkyl amount with mole form of replacement MS.For the purpose of the present invention, be 0.1-2.5 based on DS, preferred 0.2-2.0, more preferably the quaternized hydroxyethylcellulos of the ether substitution value of 0.3-1.5 shows better performance, particularly shows with the raising of hair affinity, after repeatedly having one's hair wash, does not show the wet cardability of accumulating and significantly improving.
Particularly preferably, quaternized hydroxyethylcellulos of the present invention is following copolymer a) and b):
E) hydroxyethyl-cellulose
Wherein R=H or
n represents the degree of polymerization of hydroxyethyl-cellulose monomer, and wherein n is the integer of 1000 ~ 4000, and x is the integer of 500 ~ 1500;
F) quaternized ammonium groups
Wherein R
1be selected from halogen ion, acetate, phosphate radical, nitrate anion and Methylsulfate, y represents the degree of polymerization of quaternized ammonium groups monomer, and y is the integer of 2000 ~ 4000.
In an especially preferred embodiment, described quaternized hydroxyethylcellulos is the copolymer (INCI name is called polyquaternary ammonium salt-4) of hydroxyethyl-cellulose and dimethyl diallyl ammonium chloride.
The preparation method of quaternized hydroxyethylcellulos is well known in the prior art, such as can by US3,472, and the universal method described in 840 prepares.The order of the different step of the method is also nonessential, but preferably quaternary ammonium compound such as cationic epoxides (as glycidyltrimetiiylammonium ammonium chloride) or corresponding halohydrin (such as 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride) is joined in previously prepared good hydroxyethyl ether cellulose.
Or, described quaternized hydroxyethylcellulos also can directly business be buied, such as sell (hydroxyethyl-cellulose/dimethyl diallyl ammonium chloride copolymer as trade name Celquat H-100, AkzoNobel), and sell (hydroxyethyl-cellulose/dimethyl diallyl ammonium chloride copolymer, be bestowed by heaven in Guangzhou) as trade name POLYQUTA 100H.
In hair setting composition of the present invention, the nitrogen content (percentage composition of nitrogen) of described quaternized hydroxyethylcellulos is between 0.1%-6%, preferably between 0.2%-5%, between 0.3%-4%, between 0.4%-3%, most preferably between 0.7%-2%.In another is preferred, the charge density of quaternized hydroxyethylcellulos of the present invention between 0.5-1.5meq/g, between preferred 0.6-1.3meq/g, more preferably between 0.8-1.2meq/g.The present inventor finds unexpectedly, the nitrogen content of the quaternized hydroxyethylcellulos in above-mentioned scope and the combination (combination of the nitrogen content of such as 0.2%-5% and the charge density of 0.5-1.5meq/g of charge density, the combination of the nitrogen content of 0.2%-5% or 0.4%-3% and the charge density of 0.6-1.3meq/g or 0.8-1.2meq/g, Deng), better technique effect can be brought, particularly with above-mentioned anion systems, there is the good compatibility, auxiliary sizing can also be provided, and cause compositions to have good antistatic effect and high humility curl retention.
In some embodiments of the present invention, the molecular weight of described quaternized hydroxyethylcellulos is between 800000-1600000.
Rheology modifier in the present invention and setting agent are the copolymer of the copolymer of acrylic acid (ester) class and methacrylic acid (ester) analog derivative, acrylic acid (ester) class and hydroxy acrylic acid (ester) class respectively.Wherein, acrylic acid (ester) class can respectively as the monomer be polymerized with hydroxy acrylic acid (ester) class with methacrylic acid (ester) class and acrylic acid (ester) class.
Preferably, described rheology modifier accounts for 0.5% to 4% of compositions gross weight.
In certain preferred embodiments of the present invention, described rheology modifier is polymerized by acrylic acid (ester) class and methyl acrylic ester derivant, and its structural formula is as follows:
R
2represent hydrogen atom or the unsaturated or saturated alkyl containing 1-30 carbon atom;
R
3represent hydrogen atom or methyl;
R
4unsaturated or the saturated alkyl of representative containing 1-30 carbon atom;
A represents the degree of polymerization of acrylic acid (ester) class monomer, and scope is between 2-30;
B represents the degree of polymerization of methacrylate monomer, and scope is between 2-30;
C represents the degree of polymerization of ethyoxyl in methacrylate, and scope is between 0-30.
In some preferred embodiments, described rheology modifier is selected from acrylic acid (ester) analog copolymer (Acrylates Copolymer), acrylic acid (ester) class cross linked polymer (AcrylatesCrosspolymer), acrylic acid (ester) class/C
10-30alkylol acrylamide acid esters cross linked polymer (Acrylates/C
10-30alkyl Acrylate Crosspolymer), acrylic acid (ester) class/C
12-22alkanol methacrylate copolymer (Acrylates/C
12-22alkyl Methacrylate Copolymer), acrylic acid (ester) class/C
10-30alkanol methacrylate copolymer (Acrylates/C
10-30alkylMethacrylate Copolymer), acrylic acid (ester) class/stearyl alcohol methacrylate copolymer (Acrylates/Stearyl Methacrylate Copolymer), acrylic acid (ester) class/laureth-25 methacrylate copolymer (Acrylates/Laureth-25Methacrylate Copolymer), acrylic acid (ester) class/Palmitoleyl alcohol polyethers-25 acrylate copolymer (Acrylates/Palmeth-25Acrylate Copolymer), acrylic acid (ester) class/ceteth-20 methacrylate copolymer (Acrylates/Ceteth-20 Methacrylate Copolymer), acrylic acid (ester) class/stereth-20 methacrylate copolymer (Acrylates/Steareth-20 MethacrylateCopolymer), acrylic acid (ester) class/stereth-20 Methacrylate Crosspolymer (Acrylates/Steareth-20 Methacrylate Crosspolymer), acrylic acid (ester) class/stereth-50 acrylate copolymer (Acrylates/Steareth-50 Acrylate Copolymer), at least one in acrylic acid (ester) class/behenyl alcohol polyethers-25 methacrylate copolymer (Acrylates/Beheneth-25Methacrylate Copolymer), and their mixture.
Preferably, described setting agent accounts for 0.5% to 8% of compositions gross weight.
Particularly preferably, described setting agent is acrylic acid (ester) class/hydroxyl esters acrylic acid (ester) analog copolymer (Acrylates/Hydroxyesters Acrylates Copolymer).Its commercially available prod has commodity that such as Rohm & Haas provides to be called the setting agent of Acudyne 180, Acudyne DHR and Acudyne1000.
In addition to the components described above, hair setting composition of the present invention also can optionally comprise as required be selected from following at least one component or its combination: essence, antiseptic, solubilizing agent, surfactant, thickening agent, nertralizer, wetting agent, antistatic additive, oils, vitamin, pearling agent, dyestuff, liquid-carrier and diluent.Certainly, those skilled in the art should understand that, the selection of these optional components and content should not cause adverse effect to the effect of the present composition, and these components and amount thereof suitably can be selected according to the actual needs of product, and add in compositions of the present invention.
About above-mentioned optional components, it is specifically originated and selects component as described below.
surfactant
Can be selected from one in anion surfactant, zwitterionic surfactant and non-ionic surface active agent or its combination in any for the surfactant in hair setting composition of the present invention.
Described surfactant can be compositions and brings cleaning action and frothing capacity.
Anionic surfactant component not only comprises common anion surfactant, is the zwitterionic surfactant of the coupling part of anionic property under being also included in the pH of compositions, or their combination.The example being applicable to the anion surfactant in compositions of the present invention includes but not limited to sulfate, sulfonate, sarcosinate and sarcosine derivative.Preferred anion surfactant is poly alkyl alcohol ether sulfate and aliphatic alcohol sulfate.Non-limiting example is ammonium lauryl sulfate, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, sodium lauryl sulfate, sodium lauryl sulphate, ammonium lauryl sulfate, sodium cocosulfate, lauryl sulfate monoethanolamine, cocoyl diethanolamine, lauryl sulfate diethanolamine, triethanolamine lauryl sulfate, lauryl sulfate triethylamine and composition thereof, particularly preferably be ammonium lauryl sulfate, sodium lauryl sulfate, lauryl polyethenoxy ether sodium sulfate, lauryl polyethenoxy ether sodium sulfate, sodium laureth sulfate, laureth potassium sulfate, laureth diethanolamine, laureth sulfate, laureth sulphuric acid triethanolamine, laureth sulphuric acid triethylamine and composition thereof.The example of the anion surfactant of sulfonate comprises such as tridecyl benzene sulfonate, dodecylbenzene sodium sulfonate, lauryl sulfosuccinates etc.The example of sarcosine and sarcosine derivative comprises sodium lauryl sarcosinate, cocoyl sarcosine, cocoyl sarcosine and composition thereof.
The amphoteric surfactant be applicable in hair setting composition of the present invention is well known in the art, and those can be used for the material in skin nursing, as described in following patent documentation: United States Patent (USP) 5,104,646, United States Patent (USP) 5,106,609.These amphoteric surfactantes comprise the surfactant of secondary aliphatic amine and tertiary amines derived thing, wherein said aliphatic group can be the group of straight or branched, and one in described aliphatic group can containing 8-18 carbon atom of having an appointment, another can comprise a kind of anionic hydrophilic group as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Be applicable to amphoteric surfactant of the present invention also comprise as aliphatic quaternary ammonium, quaternary phosphine and season sulfonium compound the surfactant of derivant, one of them aliphatic group containing 8-18 carbon atom of having an appointment, another can comprise a kind of anionic hydrophilic group as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Preferably betaines zwitterionic compound, comprise alkyl betaine, sulfobetaines, amidoalkyl betaine, amidosulfo betaines, hydroxyl sulfo betaine and composition thereof, especially cocoamidopropyl, Cocamidopropyl hydroxyl sulfo betaine, coco dimethyl carboxymethyl betanin, coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betanin.
The non-ionic surface active agent be applicable in hair setting composition of the present invention is well known in the art, such as there is the compound of hydrophobic group and hydrogen atoms, the polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, span class, tween class etc. of such as alkyl phenol.Particularly preferred non-ionic surface active agent is hydrogenated castor oils, particularly Cremophor RH40.
thickening agent
Thickening agent in hair setting composition used in the present invention is used for, in hair setting composition of the present invention, making bulk property be suitable for product purpose with effective dose usually.The concrete non-limiting example of thickening agent comprises sodium chloride, sodium sulfate and composition thereof.
wetting agent
The wetting agent that can be formulated in hair setting composition of the present invention can be used for the surf zone promoting water tariff collection at hair and scalp, and it comprises and is singly not limited to polyhydroxy-alcohol, such as butanediol, hexanediol, glycerol, propylene glycol, sorbitol etc.; Lactic acid and lactate comprise its sodium salt or ammonium salt; Hyaluronic Acid; Glycolic; Sugar and starch; Vaseline; Natural oil; Pantothenylol; And wax etc.
nertralizer
Nertralizer selected from sodium hydroxide in hair setting composition used in the present invention, potassium hydroxide, ammonium hydroxide, triethanol ammonium, aminomethyl propanol, two isopropanolamine and triisopropanolamine.
antistatic additive
Operable optional antistatic additive is such as water-insoluble cationic surfactant, and its concentration is generally 0.1% of composition weight to about 5%.Such antistatic additive should not obvious serviceability and the benefit affecting the present composition.The concrete non-limiting example of suitable antistatic additive is three cetyl ammonio methacrylates.
oils
Hair setting composition of the present invention can contain oily substance.Described oily substance can increase hair elasticity, contributes to preventing hairs break, jag, and can improve hair color and luster to a certain extent.Described oily substance includes but not limited to vegetable oil, animal oil, mineral oil and synthesis oils (higher fatty acids fat) etc., preferably vegetable oil, mineral oil and artificial oil, particularly preferably vegetable oil.Vegetable oil comprises quintessence oil and expressed oi.Expressed oi is often referred to the oil from plant seed, fruit etc., such as Jojoba oil, Semen pruni armeniacae oil, Oleum Vitis viniferae, Rosehips oil, olive oil, cocos nucifera oil, Oleum Ricini, Oleum Arachidis hypogaeae semen, Semen Armeniacae Amarum wet goods; Plants essential oil is normally from the height extract at the position such as flower, fruit, leaf of plant, and it mostly is volatile oil, such as from Flos Pelargonii, lavandula angustifolia, Herba Rosmarini Officinalis, the quintessence oil of the plant such as Lignum Santali Albi, grapefruit, lavandula angustifolia, Flos Rosae Rugosae, Fructus Citri Sarcodactylis.
pearling agent
Pearling agent in hair setting composition used in the present invention comprises pearling agent as known in the art, such as hard fat compounds of group.Described hard fat compounds of group preferably has about 14 fatty alcohol to 30 carbon atoms, is more preferably about 16 fatty alcohol to about 22 carbon atoms; Described aliphatic compound, except fatty alcohol, also can comprise fatty acid ester.The instantiation of these aliphatic compounds comprises: lauryl alcohol, stearyl alcohol, behenyl alcohol, palmityl alcohol, spermol, myristyl alcohol, oleyl alcohol, cetearyl alcohol, mono laurate glycol ester, Tego-stearate, single behenic acid glycol ester, tin dilaurate glycol ester, ethylene glycol distearate, two behenic acid glycol esters, mono laurate macrogol ester, monostearate macrogol ester, single behenic acid macrogol ester, tin dilaurate macrogol ester, two stearic acid macrogol ester, two behenic acid macrogol esters, lauric monoethanolamide, stearic acid monoethanolamide, behenic acid but glycollic amide, tristerin, Glyceryl Behenate and glycerol-1,3-dipalmitate, and their mixture.Its content can be 1% to 10% of compositions gross weight, preferably 2% to 8%, more preferably 3% to 7%.
liquid-carrier and diluent
Hair setting composition of the present invention can be used alone, and also can use together with suitable liquid-carrier or diluent.Such as, can using water as independent carrier or solvent; Also alcohols (particularly ethanol, propanol, isopropyl alcohol, butanols) can be adopted separately as carrier or solvent, or adopt the mixture of water and alcohol.Particularly preferred liquid-carrier or diluent are selected from water, ethanol, isopropyl alcohol, normal propyl alcohol, glycerol and propylene glycol or its combination.Certainly, other organic solvents be applicable to also can be used as described carrier and diluent.
In another aspect of the present invention, provide a kind of method making hair fixing, comprise the hair setting composition of the present invention using effective dose to hair.
In another aspect of the present invention, the purposes of hair setting composition of the present invention in preparation personal care product is provided.Hair setting composition of the present invention can use as finished product separately, also can as intermediate products for the preparation of personal care product, and described personal care product comprises such as spray, mousse, pomade, hair jelly, shaping glue, hair sprays etc.
production method
Hair setting composition of the present invention can by any known or other be effectively suitable for providing the technology of hair setting composition to prepare, prerequisite is that resulting composition provides performance as described in the present invention.The method preparing compositions of the present invention comprises conventional preparation, mixing and acid-base neutralization technology.Particularly, the illustrative preparation method of hair setting composition of the present invention is given by following examples.
embodiment
1. appropriate water and quaternized hydroxyethylcellulos are joined in retort, stir, be then heated to about 70 DEG C, treat that quaternized hydroxyethylcellulos is uniformly dispersed, be cooled to less than 45 DEG C;
2. appropriate water is mixed with nertralizer, under agitation setting agent is added wherein, undetermined type agent all neutralize transparent after, then add the mixed solution of suitable quantity of water and rheology modifier, fully stir 30 minutes;
3. finally add the good essence of solubilising and antiseptic, stir.
The composition of the hair setting composition of embodiment of the present invention I-IV is in table 1.Wherein, example I is not containing the reference product of quaternized hydroxyethylcellulos; Example II-IV is according to hair setting composition of the present invention.
The composition of the hair setting composition of table 1 example I-IV
1. purchased from the Celquat H-100 of AkzoNobel
2. purchased from the Aculyn 88 of Rohm & Haas
3. purchased from the Acudyne 1000 of Rohm & Haas
4. purchased from the AMP-ULTRA PC 2000 of DOW
Effect assessment-curl retention
Evaluation methodology:
1. with clean pure water moistening topknot (2 grams, 15 centimeter length, one end super glue is fixed), and combing topknot gently, remove unnecessary moisture content;
2. accurately take 0.5 gram of embodiment sample respectively, and uniform application is on wet topknot;
3. topknot is wound on hai roll, and buckles well the rubber band on hai roll, then make its in the baking oven of 45 DEG C dry 16 hours;
4. topknot taken out from baking oven and treat that it is returned to room temperature, untiing rubber band, the topknot spooled being taken off from a rod be suspended on the panel of scale carefully, and read now topknot length L
0;
5. panel is moved into (relative humidity is 90%, and temperature is 25 DEG C) in constant-temperature constant-humidity air-conditioner case;
6. the length L of topknot was read at ensuing 15th, 30,60,90,120,180,240,300,360,420 and 480 minute
t;
7. be calculated as follows out the curl retention of each sample under different time points:
In above formula,
L is the length (15 centimetres) that topknot stretches completely,
L
0for the length of bundle of perming when not applying hair spray,
L
tbe the length of t minute curly hair bundle.
Evaluation result
As seen from Figure 1, the present composition comprising quaternized hydroxyethylcellulos, compared with not comprising the reference composition of quaternized hydroxyethylcellulos, shows the curl retention of improvement.
Effect assessment-sizing intensity and elasticity
1. accurately take 0.8 gram of embodiment sample respectively, and uniform application is to (2.5 grams, 15 centimeter length, one end super glue is fixed) on topknot;
2. topknot is wound on diameter 2.5cm cylinder and is fixed into Ω shape, then make its in the constant temperature constant humidity baking oven of 25 DEG C dry 16 hours;
3. topknot is taken out from baking oven, carefully topknot is taken off from holder, and be arranged on Texture instrument (TA.XT.plus) testing mould;
4. Ω topknot is compressed 25% of its diameter downwards, obtain power F maximum in compression process, circulation compression 10 times;
5. be calculated as follows sizing intensity and the elasticity of each sample:
Sizing intensity=F1; Elasticity=F10/F1,
In above formula,
F1 is power suffered maximum in first time compression cycle,
F10 is power suffered maximum in the tenth second compression circulation,
Evaluation result
As seen from Figure 2, the present composition comprising quaternized hydroxyethylcellulos, compared with not comprising the reference composition of quaternized hydroxyethylcellulos, shows the sizing intensity of increase and the elasticity of improvement.
Claims (16)
1. a hair setting composition, it comprises following component:
(1) quaternized hydroxyethylcellulos of compositions gross weight 0.1% to 8% is accounted for;
(2) account for the rheology modifier of compositions gross weight 0.2% to 8%, it is selected from the copolymer of acrylic acid (ester) class and methacrylic acid (ester) class; With
(3) account for the setting agent of compositions gross weight 0.5% to 20%, it is selected from the copolymer of acrylic acid (ester) class and hydroxy acrylic acid (ester) class.
2. hair setting composition according to claim 1, wherein said quaternized hydroxyethylcellulos accounts for 0.1% to 4% of compositions gross weight, and preferably 0.2% to 3%, more preferably 0.3% to 2%.
3., according to the hair setting composition of claim 1 or 2, wherein said quaternized hydroxyethylcellulos is following copolymer a) and b):
A) hydroxyethyl-cellulose
Wherein R=H or
n represents the degree of polymerization of hydroxyethyl-cellulose monomer, and wherein n is the integer of 1000 ~ 4000, and x is the integer of 500 ~ 1500;
B) quaternized ammonium groups
Wherein R
1be selected from halogen ion, acetate, phosphate radical, nitrate anion and Methylsulfate, y represents the degree of polymerization of quaternized ammonium groups monomer, and y is the integer of 2000 ~ 4000.
4. the hair setting composition any one of aforementioned claim, in wherein said quaternized hydroxyethylcellulos, the percentage composition of nitrogen is between 0.1%-6%, preferably between 0.2%-5%, more preferably between 0.7%-2%.
5. the hair setting composition any one of aforementioned claim, the molecular weight of wherein said quaternized hydroxyethylcellulos is between 800000-1600000.
6. the hair setting composition any one of aforementioned claim, the charge density of wherein said quaternized hydroxyethylcellulos is between 0.5-1.5meq/g.
7. the hair setting composition any one of aforementioned claim, wherein said quaternized hydroxyethylcellulos is the copolymer of hydroxyethyl-cellulose and dimethyl diallyl ammonium chloride.
8. the hair setting composition any one of aforementioned claim, wherein said rheology modifier accounts for 0.5% to 4% of compositions gross weight.
9. the hair setting composition any one of aforementioned claim, wherein said rheology modifier is polymerized by acrylic acid (ester) class and methyl acrylic ester, and its structural formula is as follows:
R
2represent hydrogen atom or the unsaturated or saturated alkyl containing 1-30 carbon atom;
R
3represent hydrogen atom or methyl;
R
4unsaturated or the saturated alkyl of representative containing 1-30 carbon atom;
A represents the degree of polymerization of acrylic acid (ester) class monomer, and scope is between 2-30;
B represents the degree of polymerization of methacrylate monomer, and scope is between 2-30;
C represents the degree of polymerization of ethyoxyl in methacrylate, and scope is between 0-30.
10. hair setting composition according to claim 9, wherein said rheology modifier is selected from acrylic acid (ester) analog copolymer, acrylic acid (ester) class cross linked polymer, acrylic acid (ester) class/C
10-30alkylol acrylamide acid esters cross linked polymer, acrylic acid (ester) class/C
12-22alkanol methacrylate copolymer, acrylic acid (ester) class/C
10-30alkanol methacrylate copolymer, acrylic acid (ester) class/stearyl alcohol methacrylate copolymer, acrylic acid (ester) class/laureth-25 methacrylate copolymer, acrylic acid (ester) class/Palmitoleyl alcohol polyethers-25 acrylate copolymer, acrylic acid (ester) class/ceteth-20 methacrylate copolymer, acrylic acid (ester) class/stereth-20 methacrylate copolymer, acrylic acid (ester) class/stereth-20 Methacrylate Crosspolymer, acrylic acid (ester) class/stereth-50 acrylate copolymer, acrylic acid (ester) class/behenyl alcohol polyethers-25 methacrylate copolymer and their mixture.
11. hair setting compositions any one of aforementioned claim, wherein said setting agent accounts for 0.5% to 8% of compositions gross weight.
12. hair setting compositions any one of aforementioned claim, wherein said setting agent is selected from acrylic acid (ester) class/hydroxyl esters acrylic acid (ester) analog copolymer.
13. hair setting compositions any one of aforementioned claim, wherein said compositions also comprises and is selected from following at least one component or its combination: essence, antiseptic, solubilizing agent, thickening agent, surfactant, nertralizer, wetting agent, oils, vitamin, pearling agent, dyestuff, liquid-carrier and diluent.
14. hair setting compositions according to claim 13, wherein said liquid-carrier or diluent are selected from water, ethanol, isopropyl alcohol, normal propyl alcohol, glycerol and propylene glycol or its combination.
15. 1 kinds of methods making hair fixing, comprise to hair use effective dose any one of claim 1 to 14 the hair setting composition that defines.
The purposes of hair setting composition any one of 16. claim 1 to 14 in preparation personal care product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410020077.5A CN104784064A (en) | 2014-01-16 | 2014-01-16 | Hair styling composition containing quaternized hydroxyethyl cellulose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410020077.5A CN104784064A (en) | 2014-01-16 | 2014-01-16 | Hair styling composition containing quaternized hydroxyethyl cellulose |
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| Publication Number | Publication Date |
|---|---|
| CN104784064A true CN104784064A (en) | 2015-07-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410020077.5A Pending CN104784064A (en) | 2014-01-16 | 2014-01-16 | Hair styling composition containing quaternized hydroxyethyl cellulose |
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| Country | Link |
|---|---|
| CN (1) | CN104784064A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2018018488A1 (en) * | 2016-07-28 | 2018-02-01 | Beiersdorf Daily Chemical (Wuhan) Co., Ltd. | A hair styling composition containing rose hip oil and use thereof |
| US20180092826A1 (en) * | 2016-09-30 | 2018-04-05 | L'oreal | Compositions and methods for treating hair |
| CN111317682A (en) * | 2020-04-15 | 2020-06-23 | 惠州兆婷化妆品有限公司 | Hair styling powder and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018018488A1 (en) * | 2016-07-28 | 2018-02-01 | Beiersdorf Daily Chemical (Wuhan) Co., Ltd. | A hair styling composition containing rose hip oil and use thereof |
| CN109640943A (en) * | 2016-07-28 | 2019-04-16 | 拜尔斯道夫日化（武汉）有限公司 | Hair styling composition containing rose hip oil and its use |
| US20180092826A1 (en) * | 2016-09-30 | 2018-04-05 | L'oreal | Compositions and methods for treating hair |
| CN111317682A (en) * | 2020-04-15 | 2020-06-23 | 惠州兆婷化妆品有限公司 | Hair styling powder and preparation method thereof |
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