KR101383779B1 - Composition of coacervate conditioner - Google Patents

Abstract

The present invention is a conditioner composition comprising a cationic surfactant and an anionic polymer, characterized in that it comprises a glyceryl quaternary alkyl amido ammonium cationic surfactant of a specific formula. According to the present invention, the amount of coacervate, which is a water-insoluble complex of cationic surfactant and anionic polymer, is increased, resulting in excellent feeling during wet and rinsing, and adsorption of the conditioning component to the adherend of the conditioning component. It provides a conditioner composition for treating hair, skin and fibers, which is excellent and long lasting.

Glyceryl Quaternary Alkylamido Ammonium Cationic Surfactants, Anionic Polymers, Coacervates

Description

Coacervate conditioner composition {Composition of coacervate conditioner}

The present invention relates to a conditioner composition utilizing the coacervate phenomenon of a cationic surfactant and an anionic polymer as a method of obtaining a conditioning effect. More specifically, coacervate formed due to dilution with water during wetting and rinsing acts on the adherend to exhibit excellent wetting and rinsing conditioning effects, and the adsorption amount of various conditioning ingredients is increased by the adsorption characteristics of the active ingredients of these coacervates. The present invention relates to a conditioner composition characterized by having a very good conditioning effect even after drying.

Recently, various physical and chemical factors damage hair and skin, resulting in increased roughness and dryness, loss of gloss and elasticity, and deterioration of softness and softening effect. Problems such as splitting of the ends occur.

In order to solve this problem, continuous research on various conditioner components and formulations for improving the softness of hair and skin and repairing damage during or after cleaning has been continued. In particular, various studies have been increasing to improve the conditioning effect by utilizing the coacervate phenomenon, which is an ion complex of cations and anions.

Japanese Patent Application Laid-open No. Hei 10-87441 uses an anionic polymer for one agent, a cationic substance and a hair treatment agent for two agents, applies one agent to hair, and then applies two agents thereon to apply anion and Reference is made to preparations for conditioning hair by forming a complex of cations, and Japanese Patent Laid-Open No. 2001-48751 also discloses a hair treatment with a first agent containing anionic polysaccharides and amino acids and a second agent containing a cationic active agent and an acidic amino acid. Mention is made of formulations, and the first and second agents are used in the hair in order to refer to agents which exhibit a conditioning effect. However, these technologies have a disadvantage of being complicated and inconvenient because they are composed of two agents. In addition, U.S. Patent Publications 2006/0293197 and 2006/0293213 disclose coacervates, which are water-insoluble complexes formed by dilution with water when used as a single formulation consisting of a cationic surfactant, an anionic polymer and an amphoteric polymer. Although the composition which shows the conditioning effect to hair, skin, fiber, etc. was demonstrated, in this case, the coacervate amount which the coacervate formed in the process of washing off with water is comparatively weak, and it is substantially adsorbed to hair and shows the conditioning effect. There is a disadvantage in that the conditioning effect is weak because it is relatively small.

Therefore, the technical problem to be achieved by the present invention is to provide a conditioner composition that can not only have a good feeling when wet and rinse while overcoming the complex disadvantages of the two-component, but also exhibit an excellent conditioning effect on the hair after drying.

In order to achieve the above technical problem, the present invention provides a conditioner composition comprising a quaternary ammonium cationic surfactant represented by the following formula (1) in the conditioner composition comprising a cationic surfactant and an anionic polymer .

In Formula 1, R is any one selected from the group consisting of a linear alkyl group, branched alkyl group and alkenyl group having 12 to 22 carbon atoms, n is an integer of 0 to 10, X is a halogen group element, sulfate group and acetate Any one selected from the group consisting of groups.

Preferably, the present invention provides a conditioner composition wherein the composition further comprises an amphoteric surfactant, and more preferably, the present invention further comprises the amphoteric surfactant and a cationic polymer. It provides a conditioner composition characterized in that.

The inventors have described a composition comprising a glyceryl quaternary alkyl amido ammonium cationic surfactant represented by Formula 1 above as part or all of the cationic surfactant and an anionic polymer, more preferably cationic surfactant and anionic In addition to the polymer, a composition further comprising a cationic polymer and an amphoteric surfactant forms a complex coacervate which is a strong adhesiveness with the hair and a large amount of water-insoluble ion complex, so that the conditioning effect during wet and rinse is excellent. Adsorption of the conditioning component to the adherend was improved, and it was confirmed that the conditioning effect was very excellent even after drying, thus completing the present invention.

Hereinafter, the coacervate conditioner composition of the present invention will be described in more detail.

The conditioner composition of the present invention is a component catalyzing the formation of coacervate, a water-insoluble complex formed between a cation and an anion by dilution with water when in use, and a cationic interface of a specific formula into which a glyceryl group represented by Formula 1 is introduced. Active agents.

Referring to Formula 1, the cationic surfactant used in the present invention has a structure of a quaternary ammonium compound, in which one substituent of ammonium ion has an alkylamido group, two substituents have a methyl group, and the other one has a hydrophilic group. Is a structure in which at least one glyceryl group is condensed and repeated, and the number of repeating units is 1 to 11.

The quaternary ammonium cationic surfactants can interact with the anionic polymers to form mixed micelles that are soluble in aqueous solutions, commonly referred to as pseudo-nonionic complexes. Such pseudo-nonionic complexes improve the problems such as high viscosity and precipitation that occur when cationic materials such as cationic surfactants and cationic polymers and anionic polymers are used simultaneously. Since the amount of the cationic polymer can be increased, more coacetate can be formed, and the quaternary ammonium cationic surfactant of Formula 1 includes alkylamido groups having relatively hydrophilic properties instead of long-chain fatty acid groups. The two features allow for more cohesive coacetate to be produced.

The quaternary ammonium cationic surfactants of Chemical Formula 1 are compounds classified as quaternary ammonium compounds in Chemical Classes of the International Cosmetic Ingredient Dictionary (INCI) in 2006, preferably alkyltrimethylammonium chloride. It is possible to use with cationic surfactants used in conventional hair compositions, such as dialkyldimethylammonium chloride, benzalkonium chloride, etc., or 2006 International Cosmetic Ingredient Dictionary with some cationic properties at acidic pH. Compounds classified as Amine Oxides in Chemical Classes, preferably natural or synthetic alkylamine oxides, almondamidopropylamine oxide, behenamine oxide, cocamidopropylamine oxide, coca Minoxide, lauramidoxypropylamine oxide, etc. are mixed together Can be used. However, in order to maintain the object of the present invention, the quaternary ammonium cationic surfactant of Formula 1 is preferably contained 0.001% by weight or more relative to the total weight of only the cationic surfactant contained in the composition, If the content of the quaternary ammonium cationic surfactant is less than 0.001% by weight, the above-mentioned effects are insignificant, which leads to a problem in that the amount of coacetate formed and the formation of more cohesive coacetate are difficult. In addition, the total content of the cationic surfactant used with respect to the total weight of the composition, including the quaternary ammonium cationic surfactant of Formula 1 is preferably used 0.1 to 15% by weight. If the content of the total cationic surfactant is less than 0.1% by weight, coacervate formation of the cationic surfactant and the anionic polymer is insignificant, and it is difficult to achieve the desired level of conditioning effect, and if it exceeds 15% by weight, the hair is damp. It may be unsuitable for use as it may give a feeling and may inhibit precipitation and phase stability.

In addition, the conditioner composition of the present invention includes an anionic polymer as a component that reacts with the cationic surfactant to form coacetate. Such anionic polymers include polymethacrylic acid, carboxyvinyl polymer, polyacrylic acid, sulfonate polymer, carboxymethyl cellulose, acrylate copolymer, carboxygua, acrylate silicone copolymer, carbomer, alginic acid, propylene Glycol alginate, carrageenan gum, xanthan gum, cellulose gum, karaya gum, gum acacia, gum arabic, PVM / MA copolymer, polyurethane & acrylate copolymer, VA / crotonate copolymer Can be used, but is not limited thereto.

In the conditioner composition of the present invention, the content of the anionic polymer is preferably 0.01 to 15% by weight based on the total weight of the composition. If the content is less than 0.01% by weight, coacervate formation with cationic substances such as cationic surfactants and cationic polymers is poor, so that adsorption of the conditioning components is reduced, and as a result, the conditioning effect is not sufficiently exhibited. If the weight percentage is exceeded, excessive generation of coacervate may cause the conditioning components to be excessively adsorbed on the hair and scalp to give a bad feeling and worsen the feeling of use.

In addition, the conditioner composition of the present invention comprises an amphoteric surfactant. Such amphoteric surfactants include alkylamide dimethylamine beta acetate, alkylamide dimethylamino acetic acid betaine, 2-alkyl-N-carboxy-N-hydroxyimidazolinium betaine, betaines, amido propyl betaine One or more amino acid-based amphoteric surfactants such as coco amppocarboxy glycinate, sacosinate, and the like may be used, but the present invention is not limited thereto.

In the conditioner composition of the present invention, the content of the amphoteric surfactant is preferably 0.1 to 20% by weight based on the total weight of the composition. If the content is less than 0.1% by weight, the composition itself does not effectively block complex formation between the cationic material and the anionic material, causing insoluble precipitation in the composition, and when exceeding 20% by weight, excessive ions Due to the buffering effect, there is a fear that the desired conditioning effect may not be obtained by preventing the effective coacervate formation.

Preferably, the conditioner composition of the present invention also comprises a cationic polymer. Cationic polymers that may be included in the conditioner composition of the present invention are natural or synthetic cationic polymers, and are classified as quaternary ammonium compounds in the Chemical Classes of the 2006 International Cosmetic Ingredient Dictionary (INCI). It is possible to include all of these compounds, but particularly preferably cationic guar such as guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride, cellulose (polyquaternium-10), polyquaternium, Dimethyldiallylammonium chloride polymer, acrylamide-dimethyldiallylammonium chloride copolymer, polyvinylpyrrolidone (PVP) -dimethylaminoethyl methacrylate copolymer, acrylic acid-dimethyldiallylammonium chloride copolymer, acrylamide-dimethyl Amino ethylmethacrylate methyl chloride copolymer, Trimethylaminoethyl methacrylate polymer, silicone quaternium, etc. can be used 1 or more types, It is not limited to this.

In the conditioner composition of the present invention, the content of the cationic polymer is preferably 0.01 to 5% by weight based on the total weight of the composition. If the content is less than 0.01% by weight, coacervate is poorly produced, and thus the adsorption of the conditioning component is insufficient, so that the conditioning effect is not sufficiently exerted. If the content exceeds 5% by weight, the conditioning component is excessively produced on the hair and the scalp. This is because the adsorption gives a bad feeling, that is, the feeling of use is bad.

The conditioner composition of the present invention optionally comprises oils and / or oils obtained from various silicones, plants or animals for providing conditioning effects to the hair and / or scalp. Fats and oils obtained from these natural oils or vegetable fragrance oils or animals can provide natural mild conditioning and aroma effects to hair and skin, and at the same time reduce irritation by cumulative adsorption.

As the silicone which may be used in the present invention, one or more components commonly referred to as silicones, such as water-insoluble nonvolatile dimethicone, cyclomethicone, aminated silicon, trimethylsilyl amodimethicone, and vinyl silicone, may be used. Hydrocarbon oils and synthetic ester oils, mineral oils, etc. may be used as the oil-based oil component, and examples thereof include hydrocarbon oils, isoparaffins, hydrogenated polydecenes, and the like. ester oils include myristic acid isopropyl, palmitic acid isopropyl, stearic acid, isostearyl, _-15 C ₁₂ alkyl benzoate. In addition, natural oils or vegetable fragrance oils or fats and oils are not particularly limited as long as they can be commonly used in hair and skin compositions, for example, in nature such as vegetable oils, vegetable fragrance oils, vegetable oils, animal oils, animal oils, etc. One or more oils and / or oils derived may be selected and used.

Vegetable oils that may be included in the conditioner compositions of the present invention include, for example, avocado oil, almond oil, sweet almond oil, bitter almond oil, olive oil, sesame (sesame) oil, rice brand oil, safflower oil, soybean oil, Corn oil, Cannula oil, Apricot kernel oil, Peach kernel oil, Palm kernel oil, Palm oil, Castor oil, Sunflower seed oil, Grape seed oil, Cotton seed oil, Coconut oil, Camellia oil, Peach seed oil, Apricot seed oil One or more may be used, but is not limited thereto.

In addition, vegetable fragrance oils that may be included to add flavor to the conditioner composition of the present invention and aid the conditioning effect include, for example, orange oil, lavender oil, jasmine oil, lime oil, bergamot oil, lemon oil, rose Oil, sandalwood oil, geranium oil, cypress oil, frankinsens oil, eucalyptus oil, clary sage oil, eucalyptus oil, rosemary oil, chamomile oil, tea tree oil, lily oil, mint oil, pine oil, mandarin green oil, One or more kinds of neroli oil may be used, but is not limited thereto.

In addition, animal oils or fats and oils that may be included in the conditioner composition of the present invention may be, for example, one or more kinds of tallow, pork, sunny, hardened oil, horse oil, mink oil, egg yolk fat oil, etc., but is not limited thereto. .

The conditioner composition of the present invention may further contain a nonionic surfactant within the scope of not impairing the object of the present invention for the purpose of solubilization, solubility improvement, and the like.

Examples of the nonionic surfactant that can be used in the present invention include, but are not limited to, lauryl acid diethanolamide, palm oil fatty acid diethanolamide, palm oil fatty acid monoethanolamide, and the like.

In addition, the conditioner composition according to the present invention may further contain additives such as preservatives, thickeners, viscosity adjusters, pH adjusters, flavorings, dyes, conditioning agents and the like which can be used as components of conventional hair and / or scalp compositions. And they can be easily purchased and used commercially. Examples of preservatives include methyl parahydroxybenzoate, methyl chloroisothiazolinone, and a mixture of methyl isothiazolinone (trade name: Kathon CG, manufactured by Rohm and Haas Company, USA). Examples of the thickener or viscosity modifier include fatty acid alcohols, fatty acids, hydroxypropylmethylcellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol, and the like. Examples of the pH adjusting agent include citric acid, sodium hydroxide, triethanolamine and the like. Examples of the dye include a water-soluble tar pigment and the like. Examples of the conditioning agent include plant extracts, protein and protein modifications, and higher fatty acids.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail with reference to examples. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the above-described embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

Synthesis of Quaternary Ammonium Cationic Surfactants of the Invention

N, N-dimethyl-N- Glyceryl Stearyl Amidopropyl Ammonium  Synthesis of chloride

As a cationic surfactant in the form of quaternary ammonium, a mono-type N, N-dimethyl-N-glyceryl stearyl amidopropyl ammonium chloride containing one quaternary ammonium group is described as follows. Synthesized.

Isopropyl alcohol, alkylamidopropylamine and the equivalent of 1-chloro-2,3-propanediol were added to the three necked flask, and sodium iodide was added as a catalyst and then refluxed. Amine% was measured to confirm the progress of the reaction. The temperature of the reactor was raised to 120 ° C., and the reaction was carried out for 10 hours. The reaction product was poured into acetone, then cooled and recrystallized. Since the resultant is hygroscopic, the result obtained through recrystallization and filtration was immediately vacuum dried.

N, N-dimethyl-N- Diglyceryl Stearyl Amidopropyl Ammonium  Synthesis of chloride

In order to synthesize a diglyceryl compound substituted with two glyceryl groups, a glyceryl group was further introduced into the monoglyceryl compound. Isopropyl alcohol, a monoglyceryl compound and glycidol were added to a three neck flask, followed by stirring at a temperature of 50 ° C. for 1 hour to complete the reaction. Isopropyl alcohol was removed from the mixture by distillation under reduced pressure. Since the result was hygroscopic, the result was stored as a distilled water 50% solution.

<Production of Example 1-16 and Comparative Example 1-8>

Conditioner compositions were prepared in the compositions and amounts shown in Tables 1 and 2 below. Polyquaternium-10 or guar hydroxypropyltrimonium chloride as a cationic polymer is dispersed and dissolved in distilled water, then warmed to 70 degrees Celsius and N, N-dimethyl-N-glyceryl stearyl amidopropyl ammonium chloride or N Dissolve by adding N-dimethyl-N-diglyceryl stearyl amidopropyl ammonium chloride and cationyl trimethylammonium chloride or disetyl dimethyl ammonium chloride, which are common cationic surfactants, and adding amphoteric surfactants while cooling. After stirring, an anionic polymer such as acrylate silicone copolymer or carbomer previously dispersed in water was added thereto, followed by stirring for 30 minutes or more to prepare a conditioner composition.

Raw material name
(weight%) Example Comparative Example One 2 3 4 5 6 7 8 One 2 3 4 Purified water 75.0 75.5 75.0 75.5 75.0 75.5 75.0 75.5 80.0 80.5 80.0 80.5 Polyquaterny 윰 -10 (1) One - One - One - One - One - One - Guar hydroxypropyltrimonium chloride (2) - 0.5 - 0.5 - 0.5 - 0.5 - 0.5 - 0.5 N, N-dimethyl-N-glyceryl stearyl amidopropyl ammonium chloride 5 5 - - 5 5 - - - - - - N, N-dimethyl-N-diglyceryl stearyl amidopropyl ammonium chloride - - 5 5 - - 5 5 - - - - Cetyltrimethylammonium chloride 3 3 3 3 - - - - 3 3 - - Dicetyl dimethylammonium chloride - - - - 3 3 3 3 - - 3 3 Cocamidopropyl betaine 15 15 15 15 15 15 15 15 15 15 15 15 Acrylate Silicone Copolymer One One One One One One One One One One One One

Raw material name
(weight%) Example Comparative Example 9 10 11 12 13 14 15 16 5 6 7 8 Purified water 75.0 75.5 75.0 75.5 75.0 75.5 75.0 75.5 80.0 80.5 80.0 80.5 Polyquaterny 윰 -10 (1) One - One - One - One - One - One - Guar hydroxypropyltrimonium chloride (2) - 0.5 - 0.5 - 0.5 - 0.5 - 0.5 - 0.5 N, N-dimethyl-N-glyceryl stearyl amidopropyl ammonium chloride 5 5 - - 5 5 - - - - - - N, N-dimethyl-N-diglyceryl stearyl amidopropyl ammonium chloride - - 5 5 - - 5 5 - - - - Cetyltrimethylammonium chloride 3 3 3 3 - - - - 3 3 - - Dicetyl dimethylammonium chloride - - - - 3 3 3 3 - - 3 3 Cocamidopropyl betaine 15 15 15 15 15 15 15 15 15 15 15 15 Carbomer One One One One One One One One One One One One

In Tables 1 and 2, (1) was used a brand name Polymer JR 400 (Amerchol, charge density = 1.25 mEq / g), (2) is a brand name Jaguar C17 (Rhodia, charge density = 0.9 mEq / g) Was used.

&Lt; Evaluation of production of coacervate >

The amount of coacervate, the main mechanism of action of the conditioner composition, was measured. The dilution concentration with water was evaluated when the actual conditioner composition was applied to the hair and skin and massaged. As a result, the concentration of the conditioner was determined to be about 10 to 30% by weight, of which 100 g of the sample was diluted in 400 g of water to measure the amount of coacervate at a dilution concentration of 20%. The coacervate produced by centrifugation (4,000 rpm, 5 The supernatant was discarded, and the precipitated coacetate portion was taken to determine the weight of the coacervate. The results are shown in Table 3 below.

Name of sample Coacervate formation amount (g) Example 1 6.1 Example 2 6.2 Example 3 6.8 Example 4 6.7 Example 5 6.0 Example 6 6.1 Example 7 6.6 Example 8 6.7 Example 9 6.3 Example 10 6.3 Example 11 7.0 Example 12 6.9 Example 13 6.2 Example 14 6.4 Example 15 6.9 Example 16 6.8 Comparative Example 1 3.2 Comparative Example 2 3.2 Comparative Example 3 3.4 Comparative Example 4 3.6 Comparative Example 5 3.2 Comparative Example 6 3.0 Comparative Example 7 3.6 Comparative Example 8 3.5

Conditioner effect evaluation

After shampooing was carried out in a normal use method for 240 women who have experience in sensory evaluation of hair products, Example 1-16 and Comparative Example 1-8 were used as conditioners for each of 10 prescriptions. Hair texture during rinsing and wetting and conditioning after drying were evaluated. The average of these two characteristics was used as the conditioning effect of each prescription. The evaluation method was given 1 point, very bad 2 points, 3 points if the hair texture is normal, 4 points good, 5 points very good, the results are shown in Table 4 below.

Name of sample Rinse / wet touch Conditioning after Drying Conditioning effect Example 1 4.0 3.8 3.9 Example 2 3.9 3.6 3.8 Example 3 3.8 3.6 3.7 Example 4 4.1 3.7 3.9 Example 5 3.9 3.5 3.7 Example 6 4.0 3.6 3.8 Example 7 3.9 3.6 3.8 Example 8 4.1 3.6 3.9 Example 9 3.8 3.6 3.7 Example 10 3.9 3.5 3.7 Example 11 3.8 3.6 3.7 Example 12 3.9 3.7 3.8 Example 13 4.0 3.6 3.8 Example 14 3.9 3.6 3.8 Example 15 3.9 3.7 3.8 Example 16 3.8 3.6 3.7 Comparative Example 1 3.1 3.2 3.2 Comparative Example 2 3.0 3.3 3.2 Comparative Example 3 3.2 3.3 3.3 Comparative Example 4 3.1 3.2 3.2 Comparative Example 5 2.8 3.3 3.1 Comparative Example 6 2.6 3.2 2.9 Comparative Example 7 2.7 3.0 2.9 Comparative Example 8 2.7 3.1 2.9

As can be seen in Tables 3 and 4, the conditioner compositions of the embodiment containing the alkyl amido glyceryl quaternary ammonium cation surfactant of Formula 1 are found to have a higher amount of coacervate production than the comparative examples that do not contain it. In addition, as the amount of coacervate produced was large, the hair feel during hemging and wetting was excellent, and the feeling of conditioning after drying was also excellent.

As described above, the conditioner composition of the present invention contains a quaternary ammonium-type cationic surfactant having a specific chemical structure, thus forming a large amount of coacetate after dilution with water, thereby providing excellent usability when wet and rinsing. Even after drying, it can show excellent conditioning effect on hair.

Claims (12)

A conditioner composition comprising a cationic surfactant and an anionic polymer, To include a quaternary ammonium cationic surfactant represented by the formula (1), The anionic polymer may be polymethacrylic acid, carboxyvinyl polymer, polyacrylic acid, sulfonate polymer, carboxymethyl cellulose, acrylate copolymer, carboxygua, acrylate silicone copolymer, carbomer, alginic acid, propylene glycol Alginate, Carrageenan Gum, Xanthan Gum, Cellulose Gum, Karaya Gum, Gum Acacia, Gum Arabic, PVM / MA Copolymer, Polyurethane & Acrylate Copolymer And a V / crotonate copolymer (VA / Crotonates copolymer), wherein the conditioner composition is at least one selected from the group consisting of: &Lt; Formula 1 >

In Formula 1, R is any one selected from the group consisting of a linear alkyl group, branched alkyl group and alkenyl group having 12 to 22 carbon atoms, n is an integer of 0 to 10, X is a halogen group element, sulfate group and acetate Any one selected from the group consisting of groups. The conditioner composition of claim 1, wherein the content of the quaternary ammonium cationic surfactant represented by Formula 1 is at least 0.001 wt% based on the total weight of the cationic surfactant contained in the conditioner composition. The method of claim 1, wherein the cationic surfactant is alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, benzalkonium chloride, alkylamine oxide, almondamidopropylamine oxide, behenamine oxide, cocamidopropylamine oxide, cocamine Conditioner composition, characterized in that any one or more selected from the group consisting of oxides and lauramidopropylamine oxide. The conditioner composition of claim 1 or 3, wherein the amount of the cationic surfactant is 0.1 to 15% by weight based on the total weight of the composition. delete The conditioner composition of claim 1, wherein the content of the anionic polymer is 0.01 to 15% by weight based on the total weight of the composition. The conditioner composition of claim 1, wherein the composition comprises an amphoteric surfactant. The method of claim 7, wherein the amphoteric surfactants are alkylamide dimethylamine beta acetate, alkylamide dimethylamino beta acetate, 2-alkyl-N-carboxy-N-hydroxyimidazolinium betaine, betaines, Conditioner composition, characterized in that any one or more selected from the group consisting of amido propyl betaine, coco amppocarboxy glycinate and sacosinate.  The conditioner composition of claim 7 or 8, wherein the amount of the amphoteric surfactant is 0.1 to 20% by weight based on the total weight of the composition. 8. The composition of claim 1 or 7, wherein the composition comprises a cationic polymer, The cationic polymer is cationic guar, cellulose (polyquaternium-10), polyquaternium, dimethyldiallylammonium chloride polymer, acrylamide-dimethyldiallylammonium chloride copolymer, polyvinylpyrrolidone (PVP) -dimethyl Any one selected from the group consisting of an aminoethyl methacrylate copolymer, an acrylic acid-dimethyldiallylammonium chloride copolymer, an acrylamide-dimethylamino ethylmethacrylate methyl chloride copolymer, a trimethylaminoethylmethacrylate polymer, and a silicon quaternium The conditioner composition characterized by the above. delete The conditioner composition of claim 10, wherein the content of the cationic polymer is 0.01 to 5 wt% based on the total weight of the composition.