CN106333871A - Hair styling compositions comprising maltodextrin/NVP copolymer - Google Patents
Hair styling compositions comprising maltodextrin/NVP copolymer Download PDFInfo
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- CN106333871A CN106333871A CN201510408886.8A CN201510408886A CN106333871A CN 106333871 A CN106333871 A CN 106333871A CN 201510408886 A CN201510408886 A CN 201510408886A CN 106333871 A CN106333871 A CN 106333871A
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Abstract
The invention discloses a hair styling composition, which comprises the following components: (1) maltodextrin/NVP copolymer; (2) a zwitterionic polymer. The invention also relates to a method for styling hair by applying an effective amount of said hair styling composition and to the use of said hair styling composition for the preparation of a cosmetic product.
Description
Technical field
The present invention relates to a kind of hair setting composition, comprise maltodextrin more particularly, to one kind
/ nvp copolymer and the hair setting composition of amphoteric ion polymer.Described hair setting composition
There is good hair fixing effect, and can have the outward appearance of clarification, can provide for hair good
Moisturizing, soft elastic and reconfigured performance.
Background technology
Hair fixing product (such as hair jelly, eruption water, hair cream, suppurative mastitis or mousse etc.) is intended to help
Help the specific productss form created personal hair style and temporarily keep a period of time in position.Existing skill
In art, typical hair setting composition is all based on (for example comprising gel shape in suitable carrier mass
Become agent aqueous or aqueous alcohol) in hair fixing copolymer.However, these Hairstyling compositions is comprehensive
Close action effect still unsatisfactory, good moisturizing, soft elastic and are more particularly provided at the same time
Secondary mouldability aspect.
It is well known that being used for hair setting composition using conventional polymer, these polymer include sky
So colloid and resin, and the polymer of synthesis source.It is known for use as the city of forming hair or setting agent
Sell polymer include polyvinyl pyrrolidone, polyvinyl pyrrolidone/vinyl acetate copolymer with
And acrylate/hydroxy ester acrylate copolymer (rohm and haas).Other examples are propylene
Acid ester copolymer (balance cr, akzo；Luviflex soft, luvimer 100p and luvimer
Pro55, is sold by basf), amp- acrylate/allyl methacrylate copolymer (fixatetm
G-100, lubrizol advanced materials, inc.) polyacrylate -14 (fixatetmPlus,
Lubrizol advanced materials, inc.) and polyacrylate -2 cross linked polymer (fixatetm
Superhold, lubrizol advanced materials, inc.).For example, U.S. of gehman et al.
State's patent 4,196,190 discloses acrylic compounds hairspray.However, conventional fixative polymers
One of shortcoming is that they generally can not provide significant thickening or contribution aobvious under actual concentration
The rheological equationm of state writing.
In addition, conventional hairspray polymer is often incompatible with rheological modifiers or gel,
Viscosity is led to be damaged, gel products clarity is not good enough, texture attribute is unsatisfactory and shears thinning stream
The loss of degeneration.
The United States Patent (USP) 3,726,288 of nowak et al. is attempted being used for hair using acrylate polymer
Setting agent and the crosslinking of thickening agent, although this product achieves thickening, but hair fixing performance
Under difference (at 72 degrees Fahrenheits (about 22 degrees Celsius)) and 90% relative humidity, after 0.5 hour, bending is protected
Holdup is less than 50%.
Therefore, remain a need for further improved hair setting composition in prior art, it can be hair
Good moisturizing, soft elastic and mouldability again are provided.
Content of the invention
Except as otherwise noted, otherwise all percent used herein all with the gross weight meter of compositionss,
All of ratio is weight ratio.
Used in the present invention, all components should be that skin is acceptable, that is, when contacting with the skin of people
When be not result in unsuitable toxicity, incompatibility, unstability and atopic reaction etc..
Term " hair setting composition " used herein refers to be intended to the combination for personal nursing
Thing, it can provide its required hair fixing to act on to object.
In the present invention, " hair fixing product " or " hairspray " refer to for hair fixing or
The personal care composition of moulding, it can be the such as form such as spray, mousse, pomade and hair jelly.
" personal nursing " is related to be applied topically to the compositionss of people's (not being ingested).Preferably, described
People's care composition is that beauty treatment is acceptable." beauty treatment is acceptable " refers to be generally used for personal nursing group
The long hair of compound, and it is intended to emphasize in the presence of with the amount that generally finds in personal care composition
Virose material is not considered the component of the present invention.
Herein, " polymer " or " copolymer " is term well known to those skilled in the art, can
Enter fw billmeyer jr in " polymer science textbook " (textbook of polymer
Science) defined in (second edition, 1971), it is by the product of less chemical repeat unit
The bigger molecule constituting.
The molecular weight of polymer can be measured by standard method, for example with size exclusion chromatography (SEC)
(sec).Herein, be polymerized alone by certain monomer or be jointly polymerized with other monomers and be obtained
Polymer comprises this monomer as polymerized unit.
It is an object of the present invention to provide one kind has good shape keeping ability, it is possible to provide good moisturizing,
Soft elastic and the hair setting composition of reconfigured performance.
The present inventor in research process it was unexpectedly found that, by maltodextrin/nvp (n- vinyl
Ketopyrrolidine) copolymer with selected from anionic polymer, cationic polymer, amphoteric ion polymer
Or the combination of polymers of its mixture uses, it is possible to achieve above-mentioned purpose.
Therefore, in a first aspect, the invention provides a kind of hair setting composition, it comprises following
Component or composed of the following components:
(1) account for the maltodextrin/nvp (n- vinyl pyrrolidone) of compositionss gross weight 0.1% to 10%
Copolymer；
(2) account for compositionss gross weight 0.1% to 5% anionic polymer, cationic polymer, both sexes from
Sub- polymer or its mixture；With
(3) optional carrier.
Surprisingly, it was found that maltodextrin/nvp copolymer is combined with amphoteric ion polymer
There is the good compatibility, can achieve good sizing and shape-retaining ability energy, particularly can provide good
Moisturizing, soft elastic and reconfigured performance.
In one aspect of the invention, described maltodextrin/nvp copolymer accounts for hair fixing group of the present invention
The 0.1% to 8% of compound gross weight, preferably 0.2% to 8%, 0.2% to 7%, 0.2% to 6%, more
Preferably 0.2% to 5%, even more preferably 0.3% to 5%.
The maltodextrin of the present invention/nvp copolymer can have a following formula:
Between 100,000-150,000 dalton, wherein m is whole between 800 to 1800 to its molecular weight
Number, n is the integer between 500 to 1200.In preferred aspect, the molecular weight of described copolymer
Between 120,000-140,000 dalton.In another preferred aspect, wheat in described polymer
The weight ratio of bud dextrin and nvp component units is about 1: 1.
At a preferred aspect, the molecular weight of the maltodextrin/nvp copolymer of the present invention preferably exists
Between 100,000-150,000 dalton.Inventors have surprisingly discovered that, the wheat in above range
Bud dextrin/nvp copolymer, can bring superior technique effect, particularly good moisturizing,
Soft elastic and reconfigured aspect of performance, and also can have the transparent appearance of clarification.
On the other hand, the hair setting composition of the present invention comprise described maltodextrin/nvp copolymer and
Amphoteric ion polymer, or consisting of.
More specifically on one side, the both sexes that described amphoteric ion polymer is selected from acrylic acid (ester) are polynary
Polymer, vinyl pyrrolidone polymer and its copolymerization derivative.A preferred aspect wherein,
Described multipolymer is ternary and the quadripolymer of acrylic acid (ester), preferably acrylic acid (ester)/Hard Fat
Alcohol acrylate/amine oxides methacrylate copolymer and acrylic acid (ester)/lauryl alcohol propylene
Acid esters/stearyl alcohol acrylate/amine oxides methacrylate copolymer.Preferred at another
Aspect, described amphoteric ion polymer is vinyl pyrrolidone polymer, and its mean molecule quantity exists
Between 8,000-1,300,000.Or preferably, described vinyl pyrrolidone copolymerization derivative is second
The binary of vinyl pyrrolidone and terpolymer, preferably nvp/va copolymer, nvp/ metering system
Sour dimethylamino methacrylate copolymers and caprolactam/nvp/ dimethylaminoethyl second
Ester copolymer.
In one aspect of the method, the hair setting composition of the present invention comprises maltodextrin/nvp (n- second
Vinyl pyrrolidone) copolymer, amphoteric ion polymer, and carrier.At a preferred aspect,
Described carrier is liquid-carrier；It is highly preferred that described carrier is selected from water, c1-c6Alkanol and its mixing
Thing.Described c1-c6Alkanol is in particular selected from ethanol, propanol, isopropanol, butanol or its mixture.Or
Person, described carrier page can be the mixture of water and alcohol.Particularly preferred liquid-carrier is selected from water, second
Alcohol, isopropanol, normal propyl alcohol, glycerol and propylene glycol or a combination thereof.Need description, the present invention
Carrier may include the material playing solvent or diluent functions.
Additionally, as needed, the hair setting composition of the present invention also can comprise selected from following at least
A kind of component or a combination thereof: essence, preservative, solubilizing agent, thickening agent, surfactant, neutralization
Agent, wetting agent, quintessence oil, vitamin, pearling agent and dyestuff.
In another aspect of the present invention, there is provided a kind of method making hair fixing, including to head
Send out the hair setting composition of the invention described above applying effective dose.
In another aspect of the present invention, there is provided the hair setting composition of the present invention is in preparation
Purposes in people's care product.Described product can be for example transparent hair jelly, eruption water, hair cream, send out
The form such as breast or mousse.
Specific embodiment
Embodiment with demonstrating within the scope of the present invention described further below.Provide these specifically real
The mode of applying is intended merely to the purpose illustrating rather than limitation of the present invention, because can be without departing from this
The spirit and scope of invention carry out many change and adjustment to them.Unless otherwise stated, all enumerate
Content, concentration be all w/w percentage ratio.
In one aspect of the invention, there is provided a kind of hair setting composition, it comprises following components
Or composed of the following components:
(1) account for the maltodextrin/nvp (n- vinyl pyrrolidone) of compositionss gross weight 0.1% to 10%
Copolymer；
(2) account for compositionss gross weight 0.1% to 5% amphoteric ion polymer；With
(3) optional carrier.
Maltodextrin in the present invention/nvp copolymer is a kind of by making n- vinyl pyrrolidone
(nvp) hybridized polymer reacting with maltodextrin and generating, its can show the outward appearance of clear,
Suitable rheological characteristic and good stability.This copolymer except contributing to the improvement of shaping performance,
Also there is low production cost and the natural sex originated and safety.However, being used alone this copolymer
Effect as hair setting composition is not still highly satisfactory.
The present inventor is found by research, by the maltodextrin of proper proportion/nvp copolymer with suitably than
The amphoteric ion polymer of example is combined, and can realize good sizing and shape-retaining ability energy well,
Good moisturizing, soft elastic and reconfigured performance particularly can be provided, and product has on the whole
The advantage of the aspects such as outward appearance, cost, safety and the compatibility.
In the present composition, maltodextrin/nvp copolymer accounts for hair setting composition gross weight of the present invention
0.1% to 8%, preferably 0.2% to 8%, 0.2% to 7%, 0.2% to 6%, more preferably 0.2%
To 5%, even more preferably 0.3% to 5%.
Preferably, described maltodextrin/nvp copolymer has a formula:
Between 100,000-150,000 dalton, wherein m is whole between 800 to 1800 to its molecular weight
Number, n is the integer between 500 to 1200.In preferred aspect, the molecular weight of described copolymer
Between 120,000-140,000 dalton.In another preferred aspect, Fructus Hordei Germinatus in described polymer
The weight ratio of dextrin and nvp component units is about 1: 1.
It is particularly preferred that the maltodextrin of the present invention/nvp copolymer particularly above formula copolymer has
Molecular weight between 100,000-150,000 dalton.
Amphoteric ion polymer in the present composition be selected from acrylic acid (ester) both sexes multipolymer,
Vinyl pyrrolidone polymer and its copolymerization derivative.Wherein, described multipolymer is preferably third
The ternary of olefin(e) acid (ester) and quadripolymer, more preferably acrylic acid (ester)/stearyl alcohol acrylate/ethamine oxygen
Compound methacrylate copolymer and acrylic acid (ester)/lauryl alcohol acrylate/stearyl alcohol acrylic acid
Ester/amine oxides methacrylate copolymer.In yet another aspect, described amphoteric ion polymer
For vinyl pyrrolidone polymer, its mean molecule quantity 8,000-1, between 300,000.Or,
Described vinyl pyrrolidone copolymerization derivative is binary and the terpolymer of vinyl pyrrolidone,
Preferably nvp/va copolymer, nvp/ Dimethylaminoethyl Methacrylate copolymer and vinyl are own
Lactams/nvp/ copolymer of dimethylaminoethyl methacrylate.
The compositionss of the present invention preferably also comprise carrier.It is solvent or diluent that described carrier can play
Those materials of function, preferably liquid-carrier；It is highly preferred that described carrier is selected from water, c1-c6
Alkanol and its mixture.Described c1-c6Alkanol in particular selected from ethanol, propanol, isopropanol, butanol or
Its mixture.Or, described carrier can also be the mixture of water and alcohol.Particularly preferred liquid carries
Body is selected from water, ethanol, isopropanol, normal propyl alcohol, glycerol and propylene glycol or a combination thereof.
In addition to the components described above, the hair setting composition of the present invention also can optionally comprise as needed
Selected from following at least one component or a combination thereof: essence, preservative, solubilizing agent, surfactant,
Thickening agent, nertralizer, wetting agent, antistatic additive, oils, vitamin, pearling agent and dyestuff.When
So, it should be appreciated by those skilled in the art that the selection of these optional components and content should not be to the present invention
The effect of compositionss adversely affects, and these components and its amount can be carried out according to being actually needed of product
Suitably select, and be added in the compositionss of the present invention.
With regard to above-mentioned optional components, it is specifically originated and selects component as described below.
Surfactant
Can be selected from anionic surface for the surfactant in the hair setting composition of the present invention
One of activating agent, zwitterionic surfactant and nonionic surfactant or its combination in any.
Described surfactant can bring cleaning action and frothing capacity for compositionss.
Anionic surfactant component not only includes common anion surfactant, is additionally included in
It is the zwitterionic surfactant of the coupling part of anionic property under the ph of compositionss, or they
Combination.The example of the anion surfactant be applied to the compositionss of the present invention includes but does not limit
In sulfate, sulfonate, sarcosinate and sarcosine derivative.Preferably anion surfactant
For poly alkyl alcohol ether sulfate and aliphatic alcohol sulfate.Non-limiting example is ammonium lauryl sulfate, coconut palm
Oil base ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, sodium lauryl sulfate, dodecyl sulfur
Sour sodium, ammonium lauryl sulfate, sodium cocosulfate, lauryl sulfate monoethanolamine, cocoyl sulfur
Sour monoethanolamine, lauryl sulfate diethanolamine, triethanolamine lauryl sulfate, lauryl sulfate three
Ethamine and its mixture, particularly preferably ammonium lauryl sulfate, sodium lauryl sulfate, lauryl gather
Oxygen ethylene ether ammonium sulfate, lauryl polyethenoxy ether sodium sulfate, sodium laureth sulfate,
Laureth potassium sulfate, laureth diethanolamine, lauryl polyoxy
Vinyl Ether sulfate, laureth sulphuric acid triethanolamine, lauryl polyoxyethylene
Ether sulphuric acid triethylamine and its mixture.The example of the anion surfactant of sulfonate includes such as ten
Trialkyl benzene sulfonic acid sodium salt, dodecylbenzene sodium sulfonate, lauryl sulfosuccinates etc..Sarcosine and
The example of sarcosine derivative includes sodium lauryl sarcosinate, cocoyl sarcosine, cocoyl sarcosine
And its mixture.
Amphoteric surfactant be applied to the hair setting composition of the present invention is known in this field
, those can be used for the material in skin nursing, as described in following patent documentation: United States Patent (USP)
5,104,646, United States Patent (USP) 5,106,609.These amphoteric surfactantes include secondary aliphatic amine and uncle
The surfactant of amine derivative, wherein said aliphatic group can be the group of straight or branched,
And one of described aliphatic group can contain about 8-18 carbon atom, and another can comprise one kind
Anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.It is applied to this
The amphoteric surfactant of invention also includes derivative as aliphatic quaternary ammonium, season and season sulfonium compound
The surfactant of thing, one of aliphatic group contains about 8-18 carbon atom, and another can wrap
Containing a kind of anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Excellent
Choosing is betaines zwitterionic compound, including alkyl betaine, sulfobetaines, acylamino-
Alkyl betaine, amidosulfo betaines, hydroxyl sulfo betaine and its mixture, especially coconut palm
Oleoyl amidopropyl betaine, Cocamidopropyl hydroxyl sulfo betaine, coco dimethyl carboxylic first
Base glycine betaine, coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl glycine betaine.
Nonionic surfactant be applied to the hair setting composition of the present invention is known in this field
, for example there is the compound of hydrophobic group and hydrogen atoms, the polyoxyethylene ether of such as alkyl phenol,
Fatty alcohol-polyoxyethylene ether, span class, tween class etc..Particularly preferred nonionic surfactant
It is hydrogenated castor oils, particularly peg-40 castor oil hydrogenated.
Thickening agent
The thickening agent that can be used in the hair setting composition of the present invention is generally used for the present invention with effective dose
Hair setting composition in so that bulk property is suitable to product purpose.The specifically non-limit of thickening agent
Qualitative example includes sodium chloride, sodium sulfate and its mixture.
Wetting agent
The wetting agent being formulated in the hair setting composition of the present invention can be used for promoting water tariff collection to exist
Hair and the surface region of scalp, it includes singly being not limited to polyhydroxy-alcohol, for example butanediol, hexanediol,
Glycerol, propylene glycol, Sorbitol etc.；Lactic acid and lactate include its sodium salt or ammonium salt；Hyaluronic Acid；Hydroxyl
Acetic acid；Sugar and starch；Vaseline；Natural oil；Pantothenylol；And wax etc..
Nertralizer
Can be used for the nertralizer in the hair setting composition of the present invention and be selected from sodium hydroxide, hydroxide
Potassium, ammonium hydroxide, triethanol ammonium, aminomethyl propanol, double isopropanolamine and triisopropanolamine.
Antistatic additive
The optional antistatic additive that can use is for example water-insoluble cationic surfactant,
Its concentration is usually the 0.1% to about 5% of composition weight.Such antistatic additive should fail to understand development
Ring serviceability and the benefit of the present composition.The specific indefiniteness of suitable antistatic additive
Example is three spermaceti methyl ammonium.
Oils
The hair setting composition of the present invention can contain oily substance.Described oily substance can increase
Hair elasticity, contributes to preventing hairs break, jag, and can improve hair color to a certain extent
Pool.Described oily substance includes but is not limited to vegetable oil, animal oil, mineral oil and synthesis oils
(higher fatty acids fat) etc., preferably vegetable oil, mineral oil and artificial oil, particularly preferred vegetable oil.
Vegetable oil includes quintessence oil and expressed oi.Expressed oi is often referred to from plant seed, fruit etc.
Oil, such as Jojoba oil, Semen pruni armeniacae oil, Oleum Vitis viniferae, Rosehips oil, olive oil, cocos nucifera oil,
Oleum Ricini, Oleum Arachidis hypogaeae semen, almond oil etc.；Plants essential oil is typical from the flower of plant, fruit, leaf
Deng the height extract at position, it mostly is volatile oil, for example, change from Flos Pelargonii, lavandula angustifolia, fan
The quintessence oil of the plants such as perfume, Lignum Santali Albi, grapefruit, lavandula angustifolia, Flos Rosae Rugosae, Fructus Citri Sarcodactyliss.
Pearling agent
Can be used for the pearling agent in the hair setting composition of the present invention and include pearly-lustre as known in the art
Agent, such as hard fat compounds of group.Described hard fat compounds of group preferably has about
14 fatty alcohol to 30 carbon atoms, even more preferably about 16 fat to about 22 carbon atoms
Fat alcohol；Described aliphatic compound, in addition to fatty alcohol, may also include fatty acid ester.These aliphatic
The instantiation of compound includes: lauryl alcohol, stearyl alcohol, behenyl alcohol, palmityl alcohol, spermol,
Myristyl alcohol, oleyl alcohol, cetearyl alcohol；Mono laurate glycol ester, Tego-stearate,
Single behenic acid glycol ester, tin dilaurate glycol ester, ethylene glycol distearate, two behenic acid second
Diol ester, mono laurate macrogol ester, monostearate macrogol ester, single behenyl acid polyethylene glycol
Ester, tin dilaurate macrogol ester, double stearic acid macrogol ester, two behenic acid macrogol esters,
Lauric monoethanolamide, stearic acid monoethanolamide, behenic acid but glycollic amide, glycerol stearate
Ester, Glyceryl Behenate and glycerol-1,3-dipalmitate；And their mixture.Its content can be
The 1% to 10% of compositionss gross weight, preferably 2% to 8%, more preferably 3% to 7%.
In another aspect of the present invention, there is provided a kind of method making hair fixing, including to head
Send out the hair setting composition of the present invention applying effective dose.
In another aspect of the present invention, there is provided the hair setting composition of the present invention is in preparation
Purposes in people's care product.The hair setting composition of the present invention can use separately as finished product,
Can also be used for preparing personal care product as intermediate products, described personal care product is included for example
The forms such as transparent hair jelly, eruption water, hair cream, suppurative mastitis or mousse.
Production method
The hair setting composition of the present invention can be by any known or other be effectively adapted to provide for
Preparing, premise is that resulting composition provides as described herein to the technology of hair setting composition
Performance.The method of the compositionss of the preparation present invention is included in preparation, mixing and the soda acid of routine
And technology.Specifically, the showing of hair setting composition of the present invention is given by following examples
Example property preparation method(taking the preparation of Hairstyling composition in embodiment i-xiv as a example).
Preparation:
1. appropriate water, ethanol and amphoteric ion polymer are added in retort, stir；
2. add maltodextrin/nvp copolymer in said mixture, stir 10 minutes；
3. add the other components such as glycerol, d- pantothenylol, essence, preservative, stir.
The composition of the hair setting composition of embodiment of the present invention i-xivi is shown in Table 1.Wherein, embodiment
Ii, iv, vi, viii, x, xii, xiv and xvi are not comprise maltodextrin/nvp copolymer
But comprise the negative control compositionss of anionic polymer；Embodiment iii, vii, xi and xv are bags
Do not comprise containing maltodextrin/nvp copolymer but the negative control compositionss of anionic polymer.
Effect assessment
Evaluation methodology:
Effect for embodiment carries out sensory evaluation, and the method for sensory evaluation is: special through training
Industry tester carries out half a head comparative evaluation to 5 testees.Standards of grading adopt ten point system, and 1
Worst, 10 points best, and the higher the better for fraction.
Evaluation criterion:
Sprayability: whether sensation pump head pressing easy degree is uniform with spraying
8-9 divides: pressing is very easy to, and spraying is very uniform；6-7 divides: pressing is easier, and spraying is less
Uniformly；4-5 divides: pressing is less susceptible to, and spraying is uneven；2-3 divides: pressing is difficult to, and spraying is very uneven
Even；0-1 divides: by motionless.
Tack-free: viscosity while moulding, between sensation hair and handss
8-9 divides: no viscous sense, and 6-7 divides: slightly viscous sense, negligible viscous sense；4-5 divides: compares
Strong viscous sense；2-3 divides: very strong viscous sense；0-1 divides: very strong viscous sense.
Non-greasy: greasy degree while moulding, on sensation hair
8-9 divides: no greasy feeling；6-7 divides: more slightly oil, negligible oil；4-5 divides: oil
Part is heavier；2-3 divides: very greasy；0-1 divides: very greasy.
Moisturizing: feel the wettability of hair
8-9 divides: moisture is very sufficient, very moistening；6-7 divides: moisture is general, relatively more moistening；4-5 divides:
More dry, slightly sensation of dryness；2-3 divides: very dry and astringent；0-1 divides: very dry and astringent.
Gloss: observe the glossy degree of hair.
8-9 divides: hair gloss is bright；6-7 divides: hair gloss is brighter；4-5 divides: hair gloss one
As；2-3 divides: hair gloss is dim；0-1 divides: hair is completely matt.
Dry sizing hardness of sending out: use middle finger, forefinger and thumb to feel the power of hair bending
8-9 divides: very strong hardness；6-7 divides: harder；4-5 divides: hardness is general, has soft feeling；
2-3 divides: relatively soft, do not have hardness；0-1 divides: very soft, there is no hardness.
Curling is not at random: that observes hai roll flies away degree
8-9 divides: hai roll remains intact；6-7 divides: hai roll keeps preferably；4-5 divides: hai roll keeps one
As, locally have and scatter；2-3 divides: hai roll major part is scattered；0-1 divides: hai roll scatters completely.
Soft elastic: pinch hai roll sensation resilience up and down
8-9 divides: elasticity is very good, flexible；6-7 divides: preferably, the general 4-5 of toughness divides elasticity: more stiff
Firmly, nonelastic；2-3 divides: very stiff；0-1 divides: very stiff.
Gloss: observe the glossy degree of hair.
8-9 divides: hair gloss is bright；6-7 divides: hair gloss is brighter；4-5 divides: hair gloss one
As；2-3 divides: hair gloss is dim；0-1 divides: hair is completely matt.
Sizing hardness (after 4 hours): use middle finger, forefinger and thumb to feel the power of hair bending
8-9 divides: very strong hardness；6-7 divides: harder；4-5 divides: hardness is general, has soft feeling；
2-3 divides: relatively soft, do not have hardness；0-1 divides: very soft, there is no hardness.
Crimp (after 4 hours) not at random: observe hai roll and fly away degree
8-9 divides: hai roll remains intact；6-7 divides: hai roll keeps preferably；4-5 divides: hai roll keeps
Typically, locally have and scatter；2-3 divides: hai roll scatters；0-1 divides: hai roll scatters completely.
Reconfigured: reconfigured ability after water spray
8-9 divides: is easy to moulding；6-7 divides: is easier moulding；4-5 divides: is not easy moulding；
2-3 divides: extremely difficult moulding；0-1 divides: can not be reconfigured.
Evaluation result
The evaluation result of embodiment of the present invention i-xvi refers to table 2 below.
As can be seen from the above results, the present invention comprise maltodextrin/nvp copolymer and amphion
The hair setting composition of the combination of polymer and the matched group not comprising maltodextrin/nvp copolymer
Compound is compared, and shows the improvement in moisturizing, soft elastic and the aspect performance such as reconfigured.
Claims (13)
1. a kind of hair setting composition, it comprises following components or composed of the following components:
(1) account for the maltodextrin/nvp (n- vinyl pyrrolidone) of compositionss gross weight 0.1% to 10%
Copolymer；
(2) account for compositionss gross weight 0.1% to 5% amphoteric ion polymer；With
(3) optional carrier.
2. hair setting composition according to claim 1, wherein said maltodextrin/nvp copolymerization
Thing accounts for the 0.1% to 8% of compositionss gross weight, and preferably 0.2% to 8%, more preferably 0.2% to 5%.
3. the hair setting composition according to claim 1 or 2, wherein said maltodextrin/nvp
Copolymer has a formula:
Between 100,000-150,000 dalton, wherein m is whole between 800 to 1800 to its molecular weight
Number, n is the integer between 500 to 1200.
4. hair setting composition as claimed in one of claims 1-3, in wherein said polymer
The weight ratio of maltodextrin and nvp component units is about 1: 1.
5. the hair setting composition according to any one of Claims 1-4, wherein said both sexes from
Sub- polymer be selected from the both sexes multipolymer of acrylic acid (ester), vinyl pyrrolidone polymer and its
Copolymerization derivative.
6. hair setting composition according to claim 5, wherein said multipolymer is acrylic acid
The ternary of (ester) and quadripolymer, preferably acrylic acid (ester)/stearyl alcohol acrylate/amine oxides first
Base acrylate copolymer and acrylic acid (ester)/lauryl alcohol acrylate/stearyl alcohol acrylate/ethamine
Oxide methacrylate copolymer.
7. hair setting composition according to claim 5, wherein said amphoteric ion polymer is second
Vinyl pyrrolidone polymer, its mean molecule quantity 8,000-1, between 300,000.
8. hair setting composition according to claim 5, wherein said vinyl pyrrolidone copolymerization
Derivant is the binary of vinyl pyrrolidone and terpolymer, preferably nvp/va copolymer,
Nvp/ Dimethylaminoethyl Methacrylate copolymer and caprolactam/nvp/ metering system
Sour copolymer of dimethylaminoethyl.
9. the hair setting composition according to any one of aforementioned claim, wherein said carrier is liquid
Body carrier, it is selected from water, c1-c6Alkanol and its mixture.
10. the hair setting composition according to any one of aforementioned claim, wherein said compositionss
Also comprise selected from following at least one component or a combination thereof: essence, preservative, solubilizing agent, thickening
Agent, surfactant, nertralizer, wetting agent, oils, vitamin, pearling agent and dyestuff.
A kind of 11. methods making hair fixing, including to hair apply effective dose as claim 1
To any one of 10 defined hair setting compositions.
The hair setting composition of any one of 12. claim 1 to 10 is in preparation personal care product
In purposes.
The purposes of 13. claim 12, wherein said product be transparent hair jelly, eruption water, hair cream,
Suppurative mastitis or the form of mousse.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2581566A (en) * | 2018-12-18 | 2020-08-26 | Henkel Ag & Co Kgaa | Composition and method for temporarily reshaping keratinous fibres |
Citations (1)
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| CN102549034A (en) * | 2009-07-31 | 2012-07-04 | 阿克佐诺贝尔股份有限公司 | Hybrid copolymer compositions for personal care applications |
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| CN102549034A (en) * | 2009-07-31 | 2012-07-04 | 阿克佐诺贝尔股份有限公司 | Hybrid copolymer compositions for personal care applications |
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| AKZONOBEL: ""BIOSTYLE™ CGP Polymer"，获取网址：http://www.kalekimya.com/admin/tds/1417090543_AkzoNobel_biostyle_cgp.pdf", 《KALE KIMYA网站》 * |
| MITSUBISHI CHEMICAL: ""YUKAFORMER® and DIAFORMER®"，获取网址：http://vajramarketing.com/YFDF_Brochure.pdf", 《VAJRA MARKETING网站》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2581566A (en) * | 2018-12-18 | 2020-08-26 | Henkel Ag & Co Kgaa | Composition and method for temporarily reshaping keratinous fibres |
| GB2581566B (en) * | 2018-12-18 | 2021-04-21 | Henkel Ag & Co Kgaa | Composition and method for temporarily reshaping keratinous fibres |
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