CN104744750A - Novel conductive and flame retardant mining tread mix formula of solid tyre and production process - Google Patents

Novel conductive and flame retardant mining tread mix formula of solid tyre and production process Download PDF

Info

Publication number
CN104744750A
CN104744750A CN201310756809.2A CN201310756809A CN104744750A CN 104744750 A CN104744750 A CN 104744750A CN 201310756809 A CN201310756809 A CN 201310756809A CN 104744750 A CN104744750 A CN 104744750A
Authority
CN
China
Prior art keywords
retardant
rubber
tire
fire
sulfuration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310756809.2A
Other languages
Chinese (zh)
Inventor
彭广森
唐永红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Senguang Rubber Products Co Ltd
Original Assignee
Jiangsu Senguang Rubber Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Senguang Rubber Products Co Ltd filed Critical Jiangsu Senguang Rubber Products Co Ltd
Priority to CN201310756809.2A priority Critical patent/CN104744750A/en
Publication of CN104744750A publication Critical patent/CN104744750A/en
Pending legal-status Critical Current

Links

Classifications

    • Y02T10/862

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to a novel conductive and flame retardant mining tread mix formula of a solid tyre and a production process. 5-8% of 60-150-mesh swarf is doped into the tread mix, so that the conductive performance and the wear resistance of the tyre are improved. A certain proportion of an environmental flame retardant is added into the tread mix formula, and chloroprene rubber which is excellent in flame retardance and natural rubber which is excellent in comprehensive performance are simultaneously used, so that the problem that the existing mining solid tyre is inflammable and poor in conductivity is solved. The tyre can be widely applied to occasions related to high-temperature combustible environments in mining industry, coal mining industry, metal smelting industry and the like.

Description

The fire-retardant new type mining solid tyre tread mix formula of a kind of conduction and production technique
Technical field
The present invention relates to mining solid tyre, particularly the fire-retardant new type mining solid tyre tread mix formula of a kind of conduction and production technique.
Background technology
Since reform and opening-up, national economy increases fast, and " scientific and technical innovation, autonomous innovation " has become the main flow of current domestic industry development, and China's industry is just progressively to the future development of intensive style, energy-saving and emission-reduction, low-carbon (LC).Along with industrial vehicle and the development of other purpose-built vehicle, more and more higher to the requirement of tyre performance.Solid tyre is because having higher portative power, smooth ride, resistance to thorn, being widely used on the slow-moving vehicles such as engineering truck without the need to the frequent feature such as repairing.Be subject to the favor of consumers in general, for infinite commercial opportunities are brought in solid tyre market.The fast development of Domestic Automotive Industry, mining industry, coal mining industry, Metal smelting industry and the needs of the aspect such as fire-fighting, isolation inflammable articles, propose requirements at the higher level to the flame-retardant conductive performance of rubber product, present quick growing trend to its demand.But current most synthetic rubber is all flammable or inflammable glue kind, and wear resistance is bad, brings potential fire hazard thus, brings inconvenience to productive life.Therefore, the flame retardant resistance of these industry special tyre products seems very urgent and important.In order to address this problem, the technician of R&D institution and enterprise is constantly exploring, is studying, wish to develop the fire-retardant novel solid tyre of a kind of conduction, although make some progress, in practice, still there is the technical barrier not yet overcome.
Summary of the invention
The object of the invention is to overcome above deficiency, the fire-retardant new type mining solid tyre tread mix formula of a kind of conduction and production technique are provided, in tread rubber, mix 60 order-150 order swarfs of 5-8%, improve conductivity and the wear resistance of tire; A certain proportion of environment friendly flame retardant is added in tread glue formula, the neoprene of excellent flame retardancy is adopted to resemble the natural rubber of glue and excellent combination property and use, solve the problem of the inflammable and poorly conductive of existing mining solid tyre, this tire can be widely used in the place that mining industry, coal mining industry, Metal smelting industry etc. relate to high temperature combustible environment.
The technical solution adopted for the present invention to solve the technical problems is: the fire-retardant new type mining solid tyre of a kind of conduction, and this tire tread compound adds following material composition: natural rubber 13-18%, chloroprene rubber 35-40%, graphitized carbon black 20-25%, fire retardant 8-12.5%, promoting agent 3.5-4.5%, promotor and anti-aging agent 1.5-2%, swarf 5-8%, other filler about 3%.
Technical process:
1, the preparation of the solid tread mix of fire-retardant new type mining is conducted electricity: after being mixed in Banbury mixer by above-mentioned material except swarf, mix swarf on a mill until;
2, tire building: the green tyres of batching shaping specific standard weight on forming machine respectively by base rubber, core glue, the order of the solid tread rubber of fire-retardant new type mining of conducting electricity;
3, tyre vulcanization: Hydraulic Station work sulfuration unit upper cover is opened, mould is sent into sulfuration unit indoor, upper cover is closed and is started sulfuration, temperature controls at 120-140 DEG C, and pressure is 11-20MPa, is vented 8-9 time, heat-insulation pressure keeping sulfuration 90min to 20h (different from temperature according to tire specification size sulfide stress), sulfuration terminates, and closes air-supplying valve, discharge residue vapor;
4, tire depanning is got: water bag upper cover is opened in Hydraulic Station work, suspension hook takes out mould, open self-locking device and take out tire, deburring, namely obtained the present invention adopts the flame-retardant conductive automobile solid tyre that the solid tyre tread rubber of flame retardant rubber and novel environment-friendly fire retardant obtains.
In addition: what use in the sizing compound formula of core glue, base rubber is industry general purpose material, manufacture craft is mixer mixing.
The principle of this formula is adopted to be:
Chloroprene rubber outward appearance is sheet or the block of oyster white, beige or light brown, has good physical and mechanical properties, oil resistant, heat-resisting, resistance to combustion, resistance to daylight, resistance to ozone, acid and alkali-resistance, chemical-resistant reagent.Have higher tensile strength, elongation and reversible crystallinity, cementability is good.But chloroprene rubber winter hardiness and package stability poor, electrical insulating property is not good, adopt the chloroprene rubber of excellent flame retardancy and the natural rubber of excellent combination property and use, this phenomenon can be improved, improve stability, mix 60 order-150 order swarfs of 5-8%, conductivity and the wear resistance of tire can be increased, reach the effect that conduction is fire-retardant.
Embodiment
Described tire tread compound adds following material composition: natural rubber 13-18%, chloroprene rubber 35-40%, graphitized carbon black 20-25%, fire retardant 8-12.5%, promoting agent 3.5-4.5%, promotor and anti-aging agent 1.5-2%, swarf 5-8%, other filler about 3%.
Technical process:
1, the preparation of the solid tread mix of fire-retardant new type mining is conducted electricity: after being mixed in Banbury mixer by above-mentioned material except swarf, mix swarf on a mill until;
2, tire building: the green tyres of batching shaping specific standard weight on forming machine respectively by base rubber, core glue, the order of the solid tread rubber of fire-retardant new type mining of conducting electricity;
3, tyre vulcanization: Hydraulic Station work sulfuration unit upper cover is opened, mould is sent into sulfuration unit indoor, upper cover is closed and is started sulfuration, temperature controls at 120 DEG C about-130 DEG C, and pressure is 11-20MPa, is vented 8-9 time, heat-insulation pressure keeping sulfuration 90min to 20h (different from temperature according to tire specification size sulfide stress), sulfuration terminates, and closes air-supplying valve, discharge residue vapor;
4, tire depanning is got: water bag upper cover is opened in Hydraulic Station work, suspension hook takes out mould, open self-locking device and take out tire, deburring, namely obtained the present invention adopts the flame-retardant conductive automobile solid tyre that the solid tyre tread rubber of flame retardant rubber and novel environment-friendly fire retardant obtains.
In addition: what use in the sizing compound formula of core glue, base rubber is industry general purpose material, manufacture craft is mixer mixing.
Chloroprene rubber outward appearance is sheet or the block of oyster white, beige or light brown, has good physical and mechanical properties, oil resistant, heat-resisting, resistance to combustion, resistance to daylight, resistance to ozone, acid and alkali-resistance, chemical-resistant reagent.Have higher tensile strength, elongation and reversible crystallinity, cementability is good.But chloroprene rubber winter hardiness and package stability poor, electrical insulating property is not good, adopt the chloroprene rubber of excellent flame retardancy and the natural rubber of excellent combination property and use, this phenomenon can be improved, improve stability, mix 60 order-150 order swarfs of 10-15%, conductivity and the wear resistance of tire can be increased, reach the effect that conduction is fire-retardant.
Case study on implementation 1
By above-mentioned formula rate decile, produce car tires
Tire tread compound adds following material composition: natural rubber 15.50%, chloroprene rubber 36.1%, graphitized carbon black 20.70%, fire retardant 7.75%, zinc oxide magnesium 4.11%, promotor and anti-aging agent 2.94%, swarf 7.22%, other filler 5.68%.
Technical process:
1, the preparation of the solid tread mix of fire-retardant new type mining is conducted electricity: after being mixed in Banbury mixer by above-mentioned material except swarf, mix swarf on a mill until;
2, tire building: the green tyres of batching shaping specific standard weight on forming machine respectively by base rubber, core glue, the order of the solid tread rubber of fire-retardant new type mining of conducting electricity;
3, tyre vulcanization: Hydraulic Station work sulfuration unit upper cover is opened, mould is sent into vulcanizer carefully indoor, upper cover is closed and is started sulfuration, temperature controls at 130-140 DEG C, and pressure is 11-20MPa, is vented 8-9 time, heat-insulation pressure keeping sulfuration 90min to 10h (different from temperature according to tire specification size sulfide stress), sulfuration terminates, and closes air-supplying valve, discharge residue vapor;
4, tire depanning is got: water bag upper cover is opened in Hydraulic Station work, suspension hook takes out mould, open self-locking device and take out tire, deburring, namely obtained the present invention adopts the flame-retardant conductive car solid tyre that the solid tyre tread rubber of flame retardant rubber and novel environment-friendly fire retardant obtains.
In addition: what use in the sizing compound formula of core glue, base rubber is industry general purpose material, manufacture craft is mixer mixing.
Case study on implementation 2
By above-mentioned formula rate decile, tire of producing tractors
Tire tread compound adds following material composition: natural rubber 15.720%, chloroprene rubber 36.1%, graphitized carbon black 20.50%, fire retardant 7.85%, zinc oxide magnesium 4.01%, promotor and anti-aging agent 3.04%, swarf 7.20%, its filler of tool 5.58%.
Technical process:
1, the preparation of the solid tread mix of fire-retardant new type mining is conducted electricity: after being mixed in Banbury mixer by above-mentioned material except swarf, mix swarf on a mill until;
2, tire building: the green tyres of batching shaping specific standard weight on forming machine respectively by base rubber, core glue, the order of the solid tread rubber of fire-retardant new type mining of conducting electricity;
3, tyre vulcanization: Hydraulic Station work sulfuration unit upper cover is opened, mould is sent into sulfuration unit indoor, upper cover is closed and is started sulfuration, temperature controls at 130-140 DEG C, and pressure is 11-20MPa, is vented 8-9 time, heat-insulation pressure keeping sulfuration 5h to 20h (different from temperature according to tire specification size sulfide stress), sulfuration terminates, and closes air-supplying valve, discharge residue vapor;
4, tire depanning is got: water bag upper cover is opened in Hydraulic Station work, suspension hook takes out mould, open self-locking device and take out tire, deburring, the flame-retardant conductive tractor solid tyre that the solid tyre tread rubber that namely obtained the present invention adopts flame retardant rubber and novel environment-friendly to hinder right agent obtains.
In addition: what use in the sizing compound formula of core glue, base rubber is industry general purpose material, manufacture craft is mixer mixing.

Claims (1)

1. conduction fire-retardant new type mining solid tyre tread mix formula and a production technique, described tire tread compound adds following material composition: natural rubber 13-18%, chloroprene rubber 35-40%, graphitized carbon black 20-25%, fire retardant 8-12.5%, promoting agent 3.5-4.5%, promotor and anti-aging agent 1.5-2%, swarf 5-8%, other filler about 3%; Technical process:
(1) preparation of the solid tread mix of fire-retardant new type mining is conducted electricity: after being mixed in Banbury mixer by above-mentioned material except swarf, mix swarf on a mill until;
(2) tire building: the green tyres of batching shaping specific standard weight on forming machine respectively by base rubber, core glue, the order of the solid tread rubber of fire-retardant new type mining of conducting electricity;
(3) tyre vulcanization: Hydraulic Station work sulfuration unit upper cover is opened, mould is sent into sulfuration unit indoor, upper cover is closed and is started sulfuration, temperature controls at 120-140 DEG C, and pressure is 11-20MPa, is vented 8-9 time, heat-insulation pressure keeping sulfuration 90min to 20h (different from temperature according to tire specification size sulfide stress), sulfuration terminates, and closes air-supplying valve, discharge residue vapor;
(4) tire depanning is got: water bag upper cover is opened in Hydraulic Station work, suspension hook takes out mould, open self-locking device and take out tire, deburring, namely obtained the present invention adopts the flame-retardant conductive automobile solid tyre that the solid tyre tread rubber of flame retardant rubber and novel environment-friendly fire retardant obtains.
In addition: what use in the sizing compound formula of core glue, base rubber is industry general purpose material, manufacture craft is mixer mixing.
CN201310756809.2A 2013-12-26 2013-12-26 Novel conductive and flame retardant mining tread mix formula of solid tyre and production process Pending CN104744750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310756809.2A CN104744750A (en) 2013-12-26 2013-12-26 Novel conductive and flame retardant mining tread mix formula of solid tyre and production process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310756809.2A CN104744750A (en) 2013-12-26 2013-12-26 Novel conductive and flame retardant mining tread mix formula of solid tyre and production process

Publications (1)

Publication Number Publication Date
CN104744750A true CN104744750A (en) 2015-07-01

Family

ID=53585057

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310756809.2A Pending CN104744750A (en) 2013-12-26 2013-12-26 Novel conductive and flame retardant mining tread mix formula of solid tyre and production process

Country Status (1)

Country Link
CN (1) CN104744750A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111519A (en) * 2015-08-26 2015-12-02 青岛双星轮胎工业有限公司 Fire fighting truck tire tread rubber composition
CN105906884A (en) * 2016-07-05 2016-08-31 安徽三彩工贸有限责任公司 Heat-resistant solid tire carcass rubber
CN108752657A (en) * 2018-06-08 2018-11-06 明光速耐德实心轮胎有限公司 A kind of preparation method of high-elastic solid tyre tire material
CN110172193A (en) * 2019-06-26 2019-08-27 河南冯氏电子科技有限公司 A kind of tire tread wear-resistant material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5930889A (en) * 1982-08-12 1984-02-18 Furukawa Mining Co Ltd Dry distillation furnace for waste tire and rubber
CN1041566A (en) * 1989-08-23 1990-04-25 陈德新 Pre-vucanized rubber core high elastic solid tyre
CN101462331A (en) * 2008-12-30 2009-06-24 天津滨海新宇科技有限公司 Solid tyre vulcanizing method and vulcanizing machine unit thereof
CN101585939A (en) * 2009-04-21 2009-11-25 际华三五一七橡胶制品有限公司 Coating material of chloronorgutta coated fabric and preparation method thereof
CN101837618A (en) * 2009-11-16 2010-09-22 盐城森光橡胶制品有限公司 Solid tire sulfuration technology for inner forming, outer heating and segment temperature control
CN202863044U (en) * 2012-10-12 2013-04-10 江苏森光橡胶制品有限公司 Novel rubber solid tyre
CN103113746A (en) * 2012-11-15 2013-05-22 青岛融鑫源橡胶机械有限公司 Prescription of electroconductive rubber

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5930889A (en) * 1982-08-12 1984-02-18 Furukawa Mining Co Ltd Dry distillation furnace for waste tire and rubber
CN1041566A (en) * 1989-08-23 1990-04-25 陈德新 Pre-vucanized rubber core high elastic solid tyre
CN101462331A (en) * 2008-12-30 2009-06-24 天津滨海新宇科技有限公司 Solid tyre vulcanizing method and vulcanizing machine unit thereof
CN101585939A (en) * 2009-04-21 2009-11-25 际华三五一七橡胶制品有限公司 Coating material of chloronorgutta coated fabric and preparation method thereof
CN101837618A (en) * 2009-11-16 2010-09-22 盐城森光橡胶制品有限公司 Solid tire sulfuration technology for inner forming, outer heating and segment temperature control
CN202863044U (en) * 2012-10-12 2013-04-10 江苏森光橡胶制品有限公司 Novel rubber solid tyre
CN103113746A (en) * 2012-11-15 2013-05-22 青岛融鑫源橡胶机械有限公司 Prescription of electroconductive rubber

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
WU WEILI: ""Influence of silica loading on performance of chloroprene rubber/natural rubber blends"", 《CHINA SYNTHETIC RUBBER INDUSIRY》 *
张泗文: ""国外氯丁橡胶加工应用研究进展"", 《橡胶工业》 *
徐文总: ""阻燃天然橡胶研究进展"", 《中国橡胶》 *
焦冬梅等: ""实芯轮胎生产方法综述"", 《特种橡胶制品》 *
谢忠麟等: "《橡胶制品实用配方大全》", 30 April 2001 *
邢祥菊等: ""天然橡胶与氯丁橡胶并用性能的研究"", 《橡塑技术与装备》 *
郭振涛等: ""高性能实心轮胎胶料的研制"", 《特种橡胶制品》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111519A (en) * 2015-08-26 2015-12-02 青岛双星轮胎工业有限公司 Fire fighting truck tire tread rubber composition
CN105906884A (en) * 2016-07-05 2016-08-31 安徽三彩工贸有限责任公司 Heat-resistant solid tire carcass rubber
CN108752657A (en) * 2018-06-08 2018-11-06 明光速耐德实心轮胎有限公司 A kind of preparation method of high-elastic solid tyre tire material
CN110172193A (en) * 2019-06-26 2019-08-27 河南冯氏电子科技有限公司 A kind of tire tread wear-resistant material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN101230248B (en) Sealing strip using EPDM rubber as host material and production method thereof
CN102276936B (en) Flame-retardant corrosion-resistant rubber formula of cable sheath for mining
CN104098802B (en) A kind of aluminium hydroxide flame-retardant glue
CN104744750A (en) Novel conductive and flame retardant mining tread mix formula of solid tyre and production process
CN105400086B (en) A kind of flame retardant type EPDM waterproof rolls and its production technology
CN103304861B (en) Covering rubber and usage thereof
CN103421249A (en) Preparation method for novel ethylene propylene rubber sealing material product
CN102977486B (en) Chlorosulfonated polyethylene rubber gasket of a kind of nanoclay modification and preparation method thereof
CN103421250A (en) Preparation method for novel rubber strip for sealing of automobile doors and windows and product
CN103467861A (en) Preparation method of automobile corner window sealing material
CN106519521A (en) Waterproof flame-retardant cable material and preparation method thereof
CN103122138B (en) Power cable TPU/SEBS thermoplastic elastomer Insulating Material and Preparation Method
CN103073802A (en) Chlorosulfonated polyethylene rubber/chlorhydrin rubber sealing pad and preparation method
CN104610668A (en) No-coloring low-peculiar-smell flame-retardant ethylene-propylene rubber material and preparation method thereof
CN103509353A (en) High and low temperature-resistant insulating sheath material for transformer and preparation method thereof
CN103524817A (en) Cold-resistant oil-resistant modified chloroprene rubber cable material
CN102977434B (en) Nanometer potash feldspar powder modified chloroprene rubber sealing gasket and its preparation method
CN103467819A (en) High-temperature-resistant and flame-retardant cable material and preparation method thereof
CN103087431A (en) Chlorosulfonated polyethylene (CSM) rubber/butyl rubber gasket and preparation method thereof
CN105330986A (en) Inflaming retarding ethylene-propylene-diene-monomer rubber foam material and preparing method thereof
CN105061835A (en) Low-toxicity high-efficiency cable material for high power and preparation method thereof
CN105273267A (en) Environment-friendly low-smoke flame-retardant rubber composition as well as preparation method and application of environment-friendly low-smoke flame-retardant rubber composition
CN103030905A (en) High-strength and high-stability modified PVC and preparation method thereof
CN104745121A (en) Flame-retardant wire rope core conveyer belt bonding rubber
CN104341681A (en) Rubber sealing strip and production method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150701

WD01 Invention patent application deemed withdrawn after publication