CN104743880B - A kind of high-temperature enamel - Google Patents
A kind of high-temperature enamel Download PDFInfo
- Publication number
- CN104743880B CN104743880B CN201510100247.5A CN201510100247A CN104743880B CN 104743880 B CN104743880 B CN 104743880B CN 201510100247 A CN201510100247 A CN 201510100247A CN 104743880 B CN104743880 B CN 104743880B
- Authority
- CN
- China
- Prior art keywords
- hot
- temperature
- steel
- enamel
- drafts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
A kind of high-temperature enamel, it is made of base-material and reinforcing particle, base-material is made of high-melting-point substances, such as silica, zirconium dioxide, alundum (Al2O3), calcium oxide etc., which is used in enamel steel surface, excellent bonding performance, high temperature corrosion is good, and no overburden generation, can be widely used for various harsh hot environments, such as the field such as aircraft heat exchanger, turbogenerator.
Description
Technical field
This application involves the enamel that a kind of glassed steel and its surface use.
Background technology
The quick-fried phenomenon of squama is to cause the major reason of glassed steel high rejection rate, and fish scaling resistance is to weigh glassed steel enamel property
Important indicator.Cause enamelware produce squama it is quick-fried factor it is very much, but the quality of enamelled pressed steel in itself can produce it is very big
Influence.In order to improve the fish scaling resistance of steel plate, the quality for improving steel plate interior tissue and raising steel plate is very important.Will
Prevent that squama is quick-fried, enough field trashes, hole or precipitate must be contained in steel.Field trash is conducive to improve fish scaling resistance,
Reason is around field trash that there are tiny holes these tiny holes play a part of catching hydrogen, become hydrogen trap.But
Field trash can damage the field trash of the forming property and mechanical property of steel plate, different types of field trash and different Size Distributions
Influence be also not quite similar, therefore, to be allowed a choice for the characteristic of field trash.
In view of the above-mentioned problems, applicant carries out a series of researchs so as to develop a variety of new steel grades, however, steel grade can not
Directly apply in actual product, but needs further impose enamel on its surface and could use in practice.Different
In enamel product, have nothing in common with each other to the performance emphasis of glassed steel, as glassed steel includes high temperature resistant enamel, insulating enamel, resistance to
Grind the kinds such as enamel.The application makes plate possess resistance to elevated temperatures, so as to solve by spraying high temperature resistant enamel in plate surface
The problem of prior art glassed steel resistance to elevated temperatures is insufficient, obtained product can be widely used for combustion turbine system, aircraft heat is handed over
The high-temperature fields such as changing device, airplane heat exchanger, turbine assembly.
The content of the invention
The application provides the good hot rolled plate of a kind of intensity height, enamel coating strong adhesive force, fish scaling resistance and preparation side
Method, plate surface enamel and preparation method.
This application provides a kind of counterenamel steel hot-rolled sheet material, it is characterised in that the plate chemical composition is to press
Percentage by weight, C：0.02-0.05%, N：0.012-0.015%, S：0.01-0.05%, P：≤ 0.05%, Si：≤ 0.04%, W≤
0.025%, Mn：0.05-1.5%, Al：0.01-0.05%, Ti：0.01-0.025%, surplus are Fe and inevitable impurity.
Pass through the accurate control to W content in plate, and making between its content and remaining element in process of production
Relation can obtain the optimal performance of plate, and wherein relational expression can be shown with following formula：W=(C+0.98N+0.5S)/2-Ti.And due to
The measurement of each element content is inevitably present error in actual production process, therefore the error range of above formula is controlled ± 1%
Within be allowed, those skilled in the art can be appreciated that reasonability existing for error.And for the theoretical angle of above-mentioned arithmetic expression
For degree, it can speculate that the ratio between element W and each element can reach its gap as the site of trapping hydrogen, so that
Make it have height and catch the state of Hydrogen Energy power, so as to be easy to react and absorbed with hydrogen.Scheme listed by above formula is this Shen
Please hot rolled steel plate most preferred technique scheme.
By conventional test method, the mechanical property that can obtain above-mentioned plate has following features：Yield limit is
100-480MPa, tensile strength 200-500MPa, elongation percentage 20-45%, cupping depth are more than or equal to 5mm.
Present invention also provides one kind to be used for counterenamel steel hot-rolled sheet material and its preparation process, comprises the following steps：
1）Hot rolling：Hot rolling blank on request；2）Quick cooling, is batched after rolling, and plate is made.
Further, hot rolling start rolling temperature is 1100-1350 DEG C, and finishing temperature is 800-950 DEG C, and accumulative drafts is
50%-90%。
In actual production, conventional continuous rolling process can be used, however, caused cracking is asked during in order to reduce hot rolling
Topic, when hot rolling is rolled using zonal cooling, can be greatly decreased the harm cracked during hot rolling, and the tissue of final resulting plate
Performance is also preferable.In actual production, the rolling temperature difference control of adjacent rolling mill practice in the operation of rolling can will be further segmented
System is within 50-200 DEG C of scope.
In addition, for the counterenamel steel involved by the application, applicant finds out the segmentation particularly suitable for the steel grade
Rolling technological parameter, it is specific as follows：First stage hot-rolled temperature is 1300 ± 50 DEG C, drafts 25-35%；Second stage heat
It is 1200 ± 50 DEG C to roll temperature, drafts 15-25%；Phase III hot-rolled temperature is 1100 ± 30 DEG C, drafts 10-
20%, fourth stage hot-rolled temperature is 1000 ± 10 DEG C, drafts 5-15%；5th stage hot-rolled temperature is 900 ± 10 DEG C, pressure
Lower amount is 1-8%, adds up drafts control within 50-90% interval ranges.In addition, the plate drafts in above-mentioned each stage is equal
It is to be calculated based on original blank sheet metal thickness.
Most preferably being segmented rolling technological parameter is：First stage hot-rolled temperature is 1330 DEG C, drafts 30%；Second
Stage hot-rolled temperature is 1200 DEG C, drafts 15%；Phase III hot-rolled temperature is 1110 DEG C, drafts 12%, fourth order
Section hot-rolled temperature is 990 DEG C, drafts 5%；5th stage hot-rolled temperature is 900 DEG C, drafts 3%, and accumulative drafts is
65%.The plate drafts in above-mentioned each stage is calculated based on original blank sheet metal thickness.
In addition, for the method for roller repairing quick cooling, such as section cooling can be used, cooling velocity for 25-40 DEG C/
S, coiling temperature are 600-650 DEG C, and final sheet metal thickness is 15-25mm.
The application also provides a kind of enamel for above-mentioned enamel steel surface, it is made of base-material and reinforcing particle.Wherein
Base-material is adopted replaces the low melting point material in routine techniques to improve the high-temperature stability of finished product glaze layer for high-melting-point substances.
Further, the base-material includes silica, zirconium dioxide, alundum (Al2O3), calcium oxide, nickel oxide and dioxy
Change titanium.
Further, the reinforcing particle includes corundum.
It is preferred that base-material is by silica 50-70wt%, zirconium dioxide 10-20wt%, alundum (Al2O3) 5-10wt%, calcium oxide
5-10wt%, nickel oxide 1-5wt%, titanium dioxide 1-5wt% compositions, and the sum of above-mentioned each composition mass fraction is 100wt%, institute
It is corundum to state reinforcing particle, and reinforcing particle dosage is the 10-20wt% of base-material parts by weight.
It is preferred that base-material composition is by silica 60-70wt%, zirconium dioxide 15-20wt%, alundum (Al2O3) 5-7wt%, oxidation
Calcium 8-10wt%, nickel oxide 1-2wt%, the sum of titanium dioxide 1-2wt% compositions, above-mentioned each composition mass fraction are 100wt%.
It is preferred that reinforcing particle is corundum, and the 15-20wt% that reinforcing particle dosage is base-material parts by weight.
It is preferred that corundum is nano particle, particle size range is no more than 1 μm, preferably between 50-200nm.
The application also provides a kind of preparation method of enamel, and detailed process is as follows：1) proportioning on request carries out dispensing, so
After carry out melt.Smelting technology is constant-speed heating, and programming rate is 10-50 DEG C/minute, when being warming up to 1500-1700 DEG C, preferably
1550 DEG C, when then insulation 1-2 is small, cold water is quenched to obtain glaze base；2) obtained glaze base ball milling is obtained into micro mist, then
Mixed with corundum powder, using ethanol as dispersant, stir to obtain suspension；3) gained suspension is sprayed using mesohigh spraying coating process
In plate surface, obtain embryo material, after drying through 900-1050 DEG C sintering 10-40 it is small when, natural cooling obtains finished product.
Matrix is tested without bright through 900 DEG C of thermal etchings in the steel plate that surface of steel plate described above sprays by the above method
Aobvious corrosion product generation, produces, the associativity of enamel and plate is good, is tested by high-temperature fusion salt hot corrosion without overburden
Sample increases weight in 0.20-0.25mg/cm without weightlessness, sample2Between.
Compared with prior art, the invention has the advantages that：（1）The steel plate of preparation can effectively prevent squama is quick-fried to lack
Fall into, counterenamel process light plate bilateral enamel adherence is high, is applicable in high-temperature tubring, has no that the quick-fried phenomenon of squama occurs；（2）Ti dosages
Decline, effectively prevent excess accumulation of the second phases of Ti/C/N on surface is formed in traditional counterenamel steel stain, de- porcelain to lack
Fall into, while advantageously reduce melting cost；（3）Compression strength significantly improves, to counterenamel steel in high weighing structure part
Using being obviously improved；（4）Zonal cooling rolling effectively avoids steel plate deformed Random Effect factor during traditional continuous rolling
Caused by surface defects, effectively lifted steel plate quality；（5）The steel plate of spraying enamel has a good surface characteristic, compact structure,
Without obvious microdefect；(6) base-material used in enamel is all made of high-melting-point substances, so as to improve the high temperature of enamel layer
Stability, so that glaze layer can play plate under High Temperature Hot-corrosion Behaviorof environment good protective effect；(7) glaze layer prepares work
Skill is simple, and service life length, has a good application prospect.
The glassed steel that what this method obtained be covered with glaze layer can be used for various harsh hot environments, such as combustion turbine system,
Engine system, aircraft heat exchanger device, space flight, the field such as aviation heat exchanger, turbine assembly.
Embodiment
（1）Embodiment 1-6：Component list as shown in table 1 carries out blank proportioning, however carry out hot rolling, cooling treatment so as to
Obtain plate.
Wherein hot rolling concretely comprises the following steps：First stage hot-rolled temperature is 1300 ± 50 DEG C, drafts 25-35%；Second
Stage hot-rolled temperature is 1200 ± 50 DEG C, drafts 15-25%；Phase III hot-rolled temperature is 1100 ± 30 DEG C, and drafts is
10-20%, fourth stage hot-rolled temperature are 1000 ± 10 DEG C, drafts 5-15%；5th stage hot-rolled temperature is 900 ± 10
DEG C, drafts 1-8%, adds up drafts control within 50-90% interval ranges.Quick cooling, cooling velocity 25- after rolling
40 DEG C/s, coiling temperature is 600-650 DEG C, and final sheet metal thickness is 15-25mm.
It is emphasized that embodiment 1, embodiment 2, embodiment 4 are optimal embodiment, to C content in 0.02-
The content value 0.02% of 4 kinds of C of the enumeration in the range of 0.05%, 0.03%, 0.05% are refined, and the content of W is carried out
Accurate control, is subject to W=(C+0.98N+0.5S)/2-Ti, and precision controlling is ± 1%.In embodiment 5-6, in the base of embodiment 1
On plinth, the content of element is adjusted, to investigate the influence of its performance to steel.
Counterenamel steel hot-rolled sheet material component list in 1 embodiment 1-6 of table（Unit：wt%）.
| Embodiment | C | N | S | P | Si | W | Mn | Al | Ti |
| 1 | 0.05 | 0.015 | 0.05 | 0.05 | 0.04 | 0.02 | 1.5 | 0.05 | 0.025 |
| 2 | 0.02 | 0.015 | 0.04 | 0.02 | 0.04 | 0.0074 | 1.5 | 0.04 | 0.02 |
| 3 | 0.04 | 0.012 | 0.05 | 0.02 | 0.03 | 0.013 | 1.0 | 0.04 | 0.025 |
| 4 | 0.03 | 0.015 | 0.05 | 0.02 | 0.02 | 0.025 | 0.05 | 0.01 | 0.01 |
| 5 | 0.05 | 0.015 | 0.05 | 0.05 | 0.01 | 0.015 | 1.5 | 0.05 | 0.025 |
| 6 | 0.05 | 0.015 | 0.05 | 0.05 | 0.04 | 0.024 | 1.5 | 0.05 | 0.025 |
（2）Comparative example 7-9：As a comparison, comparative example 7-9 is enumerated, is smelted by the component of following steel.
Counterenamel steel hot-rolled sheet material component list in 2 comparative example 7-9 of table（Unit：wt%）.
| Comparative example | C | N | S | P | Si | W | Mn | Al | Ti |
| 7 | 0.05 | 0.015 | 0.05 | 0.05 | 0.04 | — | 1.5 | 0.05 | 0.05 |
| 8 | 0.02 | 0.015 | 0.04 | 0.02 | 0.04 | — | 1.5 | 0.04 | 0.04 |
| 9 | 0.04 | 0.012 | 0.05 | 0.02 | 0.03 | — | 1 | 0.04 | 0.05 |
Said ratio is smelted to the degassed processing of the molten steel completed to be molded, forms the blank that thickness is about 100mm, heat
Roll, be specially：Using technique for continuous rolling of the prior art, hot rolling start rolling temperature is 1100-1300 DEG C, and finishing temperature is
800-950 DEG C, it is 85% to add up reduction ratio.
（3）Plate property measures：To the plate grab sample prepared by embodiment 1-6 and comparative example 7-9（100mm×
100mm）, reference numeral is sample 1-9 groups, and every group of 50, sample, yield limit, tensile strength, elongation percentage, cup are carried out by standard
The detection of prominent depth and enamel qualification rate, wherein enamel qualification rate are with two-sided glazing, 200 DEG C of placement 5h of enamel finished parts, detection
Whether sample both side surface has the quick-fried generation of squama.
3 sample 1-9 Specifeca tion speeifications of table and enamel qualification rate.
| Sample | Yield limit/MPa | Tensile strength/MPa | Elongation percentage/% | Cupping depth/mm | Enamel qualification rate/% |
| 1 | 475 | 450 | 25 | 7 | ≥98 |
| 2 | 330 | 300 | 43 | 10 | ≥97 |
| 3 | 400 | 365 | 32 | 8 | ≥96 |
| 4 | 360 | 340 | 38 | 8.5 | ≥97 |
| 5 | 465 | 434 | 24 | 6.6 | ≥95 |
| 6 | 460 | 416 | 25 | 6.9 | ≥95 |
| 7 | 325 | 230 | 21 | 5≤ | ~90 |
| 8 | 190 | 206 | 26 | 8 | ~90 |
| 9 | 245 | 217 | 19 | 5≤ | ~80 |
（4）Enamel is imposed to the surface of steel plate of embodiment 1-6, operating procedure is as follows.
1. dispensing is carried out on request, wherein silica 60-70wt%, zirconium dioxide 15-20wt%, alundum (Al2O3) 5-
7wt%, calcium oxide 8-10wt%, nickel oxide 1-2wt%, titanium dioxide 1-2wt%, and the sum of above-mentioned each composition mass fraction is
100wt%.Smelting technology is constant-speed heating, and programming rate is 10-50 DEG C, heating expire to 1500-1700 DEG C of insulation 1-2 it is small when
Cold water is quenched to obtain glaze base.
2. obtained glaze base ball milling is obtained micro mist, then the corundum powder with particle size range 50-200nm mixes,
Using ethanol as dispersant, suspension is stirred to obtain.
3. gained suspension is sprayed on plate surface using mesohigh spraying coating process, embryo material is obtained, then through 900-1050
DEG C sintering 10-40 it is small when, natural cooling obtains finished product.
900 DEG C of high-temperature fusion salt corrosion tests are carried out to gained glazing glassed steel（75wt%Na2SO4+25% NaCl）, heat corruption
Lose time when being respectively 30 small, 50 it is small when and 100 it is small when, weightless test is then carried out to laboratory sample, all samples surface applies
Layer is without obscission, and the surrosion of three groups of experimental results is respectively 0.25mg/cm-2, 0.22 mg/cm-2, 0.23 mg/
cm-2.And those skilled in the art know that general alloy or common enamel layer can produce weightlessness, and surface after high temperature corrosion
Macroscopic top layer obscission occurs, therefore contrast experiment, people in the art are not carried out to above-mentioned comparative example 7-9
Member above-mentioned experimental result can be speculated according to normal experiment theory and expectation obtains.
Claims (8)
1. a kind of high-temperature enamel, is made of base-material and reinforcing particle,
The base-material is by silica 50-70wt%, zirconium dioxide 10-20wt%, alundum (Al2O3) 5-10wt%, calcium oxide 5-
10wt%, nickel oxide 1-5wt%, titanium dioxide 1-5wt% compositions, and the sum of above-mentioned each composition mass fraction is 100wt%,
The reinforcing particle is corundum, and reinforcing particle dosage is the 15-20wt% of base-material parts by weight.
2. high-temperature enamel according to claim 1, the corundum is nano particle.
3. a kind of preparation method of high-temperature enamel, it includes the following steps：
1) according to the component dispensing of claim 1-2 any one high-temperature enamels, melt is then carried out；Smelting technology is at the uniform velocity to add
Heat, programming rate is 10-50 DEG C/minute, and when being warming up to 1500-1700 DEG C, when then insulation 1-2 is small, cold water is quenched to obtain enamel base
Material；
2) obtained glaze base ball milling is obtained into micro mist, is then mixed with corundum powder, using ethanol as dispersant, stirring to hang
Supernatant liquid；
3) gained suspension is sprayed on plate surface using mesohigh spraying coating process, embryo material is obtained, through 900-1050 DEG C after drying
When sintering 10-40 is small, natural cooling obtains finished product.
4. a kind of glassed steel, surface includes the high-temperature enamel according to claim 1-2 any one, and the glassed steel is double
Face Steel for enamel hot rolled plate；
The counterenamel is with steel hot-rolled sheet material chemical composition, by weight percentage, C：0.02-0.05%, N：0.012-
0.015%, S：0.01-0.05%, P：≤ 0.05%, Si：≤ 0.04%, W≤0.025%, Mn：0.05-1.5%, Al：0.01-
0.05%, Ti：0.01-0.025%, surplus are Fe and inevitable impurity；
Counterenamel is accurately controlled with W content in steel hot-rolled sheet material in process of production, and makes its content and remaining element
Between meet relational expression：W=(C+0.98N+0.5S)/2-Ti；
Since the measurement of each element content in actual production process is inevitably present error, the error range of above-mentioned relation formula
Control is within ± 1%.
5. glassed steel according to claim 4, the glassed steel is counterenamel steel hot-rolled sheet material；
The counterenamel has following features with the mechanical property of steel hot-rolled sheet material：Yield limit is 100-480MPa, tension
Intensity is 200-500MPa, elongation percentage 20-45%, and cupping depth is more than or equal to 5mm.
6. the preparation method of the glassed steel described in a kind of claim 4-5 any one, it is characterised in that make in enamel steel surface
High-temperature enamel is prepared with the method described in claim 3；
The glassed steel is counterenamel steel hot-rolled sheet material；
Preparation method comprises the following steps：1）Hot rolling：Hot rolling blank on request；2）Quick cooling, is batched after rolling, and plate is made.
7. the preparation method of glassed steel according to claim 6, it is characterised in that：Hot rolling start rolling temperature is 1100-1350
DEG C, finishing temperature is 800-950 DEG C, and it is 50%-90% to add up drafts.
8. the preparation method of glassed steel according to claim 7, it is characterised in that with rolling mill practice is segmented, specifically such as
Under：
First stage hot-rolled temperature is 1300 ± 50 DEG C, drafts 25-35%；
Second stage hot-rolled temperature is 1200 ± 50 DEG C, drafts 15-25%；
Phase III hot-rolled temperature is 1100 ± 30 DEG C, drafts 10-20%,
Fourth stage hot-rolled temperature is 1000 ± 10 DEG C, drafts 5-15%；
5th stage hot-rolled temperature is 900 ± 10 DEG C, drafts 1-8%,
Accumulative drafts control is within 50-90% interval ranges；The plate drafts in above-mentioned each stage is with original blank
Calculated based on sheet metal thickness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510100247.5A CN104743880B (en) | 2015-03-08 | 2015-03-08 | A kind of high-temperature enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510100247.5A CN104743880B (en) | 2015-03-08 | 2015-03-08 | A kind of high-temperature enamel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104743880A CN104743880A (en) | 2015-07-01 |
| CN104743880B true CN104743880B (en) | 2018-04-27 |
Family
ID=53584250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510100247.5A Active CN104743880B (en) | 2015-03-08 | 2015-03-08 | A kind of high-temperature enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104743880B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113754282A (en) * | 2021-10-13 | 2021-12-07 | 福建省德化威航艺品有限公司 | Metal enamel glaze with milky glaze and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5326728A (en) * | 1993-02-12 | 1994-07-05 | Corning Incorporated | Lead-free enamel compositions for the decoration of low-expansion glass-ceramics |
| CN101734858A (en) * | 2008-11-07 | 2010-06-16 | 肖特股份有限公司 | Lead and cadmium-free glass composite for coating porcelain glaze and enamel on and decorating glass or glass ceramics |
-
2015
- 2015-03-08 CN CN201510100247.5A patent/CN104743880B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5326728A (en) * | 1993-02-12 | 1994-07-05 | Corning Incorporated | Lead-free enamel compositions for the decoration of low-expansion glass-ceramics |
| CN101734858A (en) * | 2008-11-07 | 2010-06-16 | 肖特股份有限公司 | Lead and cadmium-free glass composite for coating porcelain glaze and enamel on and decorating glass or glass ceramics |
Non-Patent Citations (1)
| Title |
|---|
| 镍基高温合金上双层搪瓷-陶瓷复合涂层1000℃氧化机理;沈明礼等;《腐蚀科学与防护技术》;20120115;第24卷(第1期);第10-14页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104743880A (en) | 2015-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103394685B (en) | Alloy powder for manufacturing high-entropy alloy coatings, and manufacturing method and application for alloy powder | |
| CN107217173A (en) | Titanium alloy and its preparation technology with high-strength high-plastic and good fracture toughness | |
| CN105483448A (en) | Manufacturing method of nuclear nickel-base high-temperature alloy GH 4145 wire | |
| CN104446325A (en) | High temperature, contamination and slagging resistant ceramic paint as well as preparation method and application of high temperature, contamination and slagging resistant ceramic paint | |
| CN102773253B (en) | Steel-aluminum bronze bimetal material compounding method | |
| CN105369136B (en) | A kind of hot-dip aluminizing zincium steel plate and its manufacture method | |
| CN104831268B (en) | A kind of composite alloy coat preparation method on tantalum-tungsten alloy | |
| CN107931354B (en) | A kind of short flow process of high-ductility low yield strength titanium plate | |
| CN109811165A (en) | A method of regulation Ti/ beta-titanium alloy laminar composite interfacial structure | |
| EP3202507A1 (en) | METHOD FOR PRODUCING Ni-BASED SUPER HEAT-RESISTANT ALLOY | |
| CN105518174A (en) | Cold-rolled steel sheet for enameling, method for producing same, and enamel product | |
| CN104043821B (en) | Resistant corrosion-resistant spray-coating powder and preparation method thereof | |
| CN106893965A (en) | The double ceramic layer structure refractory coatings of YAG/8YSZ and plasma preparation method | |
| CN104195548A (en) | Zinc-corrosion-resistant coating cobalt-based alloy powder for laser cladding | |
| Xiao et al. | Oxidation protection of commercial-purity titanium by Na2O–CaO–SiO2 and Na2O–CaO–Al2O3–SiO2 glass–ceramic coatings | |
| CN104046979B (en) | The spraying method of resistive connection tumor composite coating | |
| Zhao et al. | Determining the microstructure and properties of magnesium aluminum composite panels by hot rolling and annealing | |
| Shan et al. | A protective ceramic coating to improve oxidation and thermal shock resistance on CrMn alloy at elevated temperatures | |
| Fan et al. | Study on the oxidation resistance and tribological behavior of glass lubricants used in hot extrusion of commercial purity titanium | |
| CN104743880B (en) | A kind of high-temperature enamel | |
| CN106222486B (en) | A kind of high intensity zirconium titanium ferro-aluminum vanadium alloy and preparation method thereof | |
| CN104928674B (en) | Bury and cover the coating production that Combined Processing improves thermal barrier coating and basal body binding force | |
| CN104044304B (en) | Anti-dross compound coating | |
| Yang et al. | Investigation on reducing residual stress and optimizing performance of 2219 aluminum alloy friction stir welded joint by cold spraying | |
| CN104788021B (en) | A kind of vitreous enamel and obtained product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |