CN104741327B - A kind of lithium-ion-power cell dynamic conformance method for separating - Google Patents
A kind of lithium-ion-power cell dynamic conformance method for separating Download PDFInfo
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- CN104741327B CN104741327B CN201510168715.2A CN201510168715A CN104741327B CN 104741327 B CN104741327 B CN 104741327B CN 201510168715 A CN201510168715 A CN 201510168715A CN 104741327 B CN104741327 B CN 104741327B
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Abstract
The invention discloses a kind of lithium-ion-power cell dynamic conformance method for separating.Including step(1)Preliminary sorting:Pick out the close cell of capacity;(2)The battery core of the cell after preliminary sorting is carried out into 3 ~ 5 complete filling of normal temperature and puts circulation entirely;(3)Record constant-current charge time and the discharge platform voltage time of each battery core, filter out constant current than more than 90%, electric discharge average voltage time more than 45min battery;(4)Filter out the battery with the qualified core of self discharge;(5)Screening internal resistance is in 1 ~ 3m Ω, and battery of the not charged open-circuit voltage within 200mV;(6)It is the battery of standard screening same type with the instantaneous voltage difference during battery high rate charge-discharge.The magnitude of voltage that dynamic sorting method of the present invention is obtained can sort the close cell of influence for standard scores select cell closer to actual condition, and the stack battery performance for obtaining is significantly better than the battery pack that static sorting is obtained.
Description
Technical field
The present invention relates to a kind of lithium-ion-power cell dynamic conformance method for separating, belong to battery sorting field.
Background technology
Recently as the fast development of electric automobile, the demand to battery is increasing, required for an electric automobile
Number of batteries it is thousands of, the battery consistency of the battery request composition of the battery of such big figure composition is especially high, now
The problem that course continuation mileage is short, battery life is short of widely known electric motor car, reason be certain battery of internal battery pack and other
Battery performance is inconsistent, this battery during battery charging and discharging(Or battery strings where single branch battery)Occur and fill height
The phenomenon lowerd, sample circuit will be considered that the battery pack is charged when causing whole battery pack to reach charging limitation voltage in advance
Terminate to stop being charged for battery pack, so cause the charge less of whole battery pack, cause battery capacity not enough, using process
The performance of middle battery pack to have significantly decline and just occur course continuation mileage shortening, or even triggers safety problem.
Current battery sorting method has platform voltage separating method, static capacity separating method, internal resistance separating method, and in reality
In, it has been found that by the battery that these static methods are sorted out, after being assembled into stack battery, in identical work
Under the conditions of, battery performance in itself can change a lot, and the capacity of battery, internal resistance and charging and discharging curve occur change,
Result causes the overall performance degradation of battery pack, influences the performance of battery pack, and for these situations, the present invention is proposed
A kind of dynamic method of testing sorts cell.
The content of the invention
It is an object of the invention to provide a kind of lithium-ion-power cell dynamic conformance method for separating, mainly solve existing
The battery that sub-elects of battery sorting method be assembled into stack battery after, the low problem of overall performance.Cell it is consistent
Property be the groups of key of battery, directly affects life-span and the performance of stack battery, the present invention proposes battery core after static state sorting,
With a kind of dynamic method for separating, performance is close consistent after battery that is simple to operate, sorting out runs in groups.
To achieve these goals, the technical solution adopted by the present invention is as follows:
A kind of lithium-ion-power cell dynamic conformance method for separating, comprises the following steps:Battery is first carried out static point
Choosing, then enters Mobile state sorting;
The static sorting step:
(1)Preliminary sorting:Pick out the close cell of capacity, capacity difference≤50mAh;
(2)The battery core of the cell after preliminary sorting is carried out into 3 ~ 5 complete filling of normal temperature and puts circulation entirely;
(3)Record constant-current charge time and the discharge platform voltage time of each battery core, filter out constant current ratio 90% with
Battery of upper, the discharge platform voltage time in more than 45min;
(4)45 DEG C of the not charged battery battery core high temperature that will have been screened stands 10 days, after then normal temperature stands 4 ~ 6h, filters out
Battery with the qualified battery core of self discharge, the qualified standard is voltage difference △ V≤50mV before and after standing;
(5)Screening internal resistance is in 1 ~ 3m Ω, and battery of the not charged open-circuit voltage within 200mV;
The dynamic sorting step:
(6)It is the battery of standard screening same type with the instantaneous voltage difference during battery high rate charge-discharge.
Specifically, the step(6)Specific screening technique be:Will be by step(5)Each battery battery core for filtering out afterwards
Charged with 4 ~ 6C under the conditions of 80%SOC, and discharged with 8 ~ 10C under 10% ~ 20%SOC states, collection charging and discharging 10s
Instantaneous Situation voltage, screening is charged within dynamic voltage difference is 7mV, and electric discharge dynamic electric voltage difference is the electricity within 10mV
Pond.
Compared with prior art, the invention has the advantages that:
(1)The present invention is that corresponding dynamic electric voltage instantaneous value, this voltage are recorded after being put using dynamic heavy current pulse and arteries and veins
Instantaneous value combines the situation of change of polarization resistance, ohmic internal resistance, large current density condition and voltage, with this dynamic sorting method
The magnitude of voltage for obtaining can sort the close cell of influence for standard scores select cell closer to actual condition, obtain
Stack battery performance is significantly better than the battery pack that static sorting is obtained.
Brief description of the drawings
Fig. 1 is workflow diagram of the invention.
Fig. 2 is experimental data contrast effect figure of the present invention.
Specific embodiment
The invention will be further described with reference to the accompanying drawings and examples, and embodiments of the present invention are included but is not limited to
The following example.
Embodiment
As shown in figure 1, a kind of lithium-ion-power cell dynamic conformance method for separating, comprises the following steps:
(1)Preliminary sorting:Pick out the close cell of capacity, capacity difference≤50mAh;
(2)The battery core of the cell after preliminary sorting is carried out into 3 ~ 5 complete filling of normal temperature and puts circulation entirely, it is ensured that experiment
Accuracy;
(3)Record constant-current charge time and the discharge platform voltage time of each battery core, filter out constant current ratio 90% with
Battery of upper, the discharge platform voltage time in more than 45min;
(4)45 DEG C of the not charged battery battery core high temperature that will have been sorted stands 10 days, after then normal temperature stands 4 ~ 6h, filters out
Battery with the qualified battery core of self discharge, the qualified standard is voltage difference △ V≤50mV before and after standing;
(5)Screening internal resistance is in 1 ~ 3m Ω, and battery of the not charged open-circuit voltage within 200mV;
(6)It is the battery of standard screening same type with the instantaneous voltage difference during battery high rate charge-discharge, specially:
Each battery battery core that will be filtered out is charged under the conditions of 80%SOC with 4 ~ 6C, and is discharged with 8 ~ 10C under 10% ~ 20%SOC states,
Collection charging and discharging 10s Instantaneous Situation voltages, screening is charged within dynamic voltage difference is 7mV, and electric discharge dynamic electric voltage
Difference is the battery within 10mV.
The present invention is that corresponding dynamic electric voltage instantaneous value, this voltage transient are recorded after being put using dynamic heavy current pulse and arteries and veins
Value combines the situation of change of polarization resistance, ohmic internal resistance, large current density condition and voltage, is obtained with this dynamic sorting method
Magnitude of voltage for standard scores select cell can be closer to actual condition, the close cell of sorting influence is obtained in groups
Battery performance is significantly better than the battery pack that static sorting is obtained.
Such as Fig. 2(a)It is that the battery pack that 10 cells obtained using existing static method for separating are connected into is run
Discharge curve after 50 times, Fig. 2(b)It is to be put point by 80%SOC pulses and 10%SOC arteries and veins using dynamic sorting method of the invention
10 cells of choosing run the discharge curve after 50 times after being connected into battery pack.
From Fig. 2(a)With 2(b)Knowable to Experimental comparison, the battery that the cell obtained using static method for separating is constituted
There is decay in group, battery capacity, and capacity is taken a walk and substantially increase.And the monomer electricity obtained using dynamic sorting method of the present invention
The battery pack of pond composition, battery capacity keeps preferable uniformity.
Experiment shows, using dynamic sorting method, during taken into full account that polarization resistance, ohmic internal resistance and high current are filled
The influence discharged to cell, the close cell of sorting influence, the stack battery performance for obtaining is significantly better than static point
The battery pack that choosing is obtained.
According to above-described embodiment, the present invention just can be well realized.What deserves to be explained is, before said structure design
Put, to solve same technical problem, even if making some in the present invention without substantial change or polishing, used
The essence of technical scheme is still as the present invention, therefore it should also be as within the scope of the present invention.
Claims (3)
1. a kind of lithium-ion-power cell dynamic conformance method for separating, it is characterised in that comprise the following steps:First battery is entered
The static sorting of row, then enters Mobile state sorting;
The static sorting step:
(1) preliminary sorting:Pick out the close cell of capacity;
(2) battery core of the cell after preliminary sorting is carried out into 3~5 complete filling of normal temperature and puts circulation entirely;
(3) constant-current charge time and the discharge platform voltage time of each battery core are recorded, filter out constant current ratio more than 90%, put
Battery of the level platform voltage time in more than 45min;
(4) the not charged battery battery core quiescence in high temperature that will have been screened, the condition of standing is:45 DEG C stand 10 days, and then normal temperature is quiet
After putting 4~6h, filter out the battery with the qualified battery core of self discharge, the qualified standard for voltage difference △ V before and after standing≤
50mV;
(5) screening internal resistance is in 1~3m Ω, and battery of the not charged open-circuit voltage within 200mV;
The dynamic sorting step:
(6) it is the battery of standard screening same type with the instantaneous voltage difference during battery high rate charge-discharge.
2. a kind of lithium-ion-power cell dynamic conformance method for separating according to claim 1, it is characterised in that described
In step (1), the capacity difference≤50mAh of cell.
3. a kind of lithium-ion-power cell dynamic conformance method for separating according to claim 2, it is characterised in that described
The specific screening technique of step (6) is:Each battery battery core that will be filtered out after step (5) under the conditions of 80%SOC with 4~
6C charges, and is discharged with 8~10C under 10%~20%SOC states, gathers charging and discharging 10s Instantaneous Situation voltages, sieve
Choosing is charged within dynamic voltage difference is 7mV, and electric discharge dynamic electric voltage difference is the battery within 10mV.
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