CN104725711A - Hybrid polyacrylic fibreglass sleeve - Google Patents

Hybrid polyacrylic fibreglass sleeve Download PDF

Info

Publication number
CN104725711A
CN104725711A CN201510102480.7A CN201510102480A CN104725711A CN 104725711 A CN104725711 A CN 104725711A CN 201510102480 A CN201510102480 A CN 201510102480A CN 104725711 A CN104725711 A CN 104725711A
Authority
CN
China
Prior art keywords
glass fibre
polypropylene
resin
sleeve according
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510102480.7A
Other languages
Chinese (zh)
Inventor
李传明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zibo Enlightening Sound Insulation Materials Co Ltd
Original Assignee
Zibo Enlightening Sound Insulation Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zibo Enlightening Sound Insulation Materials Co Ltd filed Critical Zibo Enlightening Sound Insulation Materials Co Ltd
Priority to CN201510102480.7A priority Critical patent/CN104725711A/en
Publication of CN104725711A publication Critical patent/CN104725711A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

The invention discloses a hybrid polyacrylic fibreglass sleeve. The hybrid polyacrylic fibreglass sleeve is prepared by weaving alkali-free glass fiber into a tube, coating the tube with resin mixed liquor by dip-coating, and heating for dying the tube, wherein the alkali-free glass fiber is prepared by melting quartz sand, alumina, pyrophyllite and limestone into glass and then directly preparing the glass into fiber, and the diameter of the alkali-free glass fiber is 3-20 microns; and the resin mixed liquor is mainly prepared by mixing PE resin with an organic silicone modified polyacrylate hybrid material. The fibreglass sleeve provided by the invention is woven by using good alkali-free glass fiber, so that the fibreglass sleeve has the characteristics of good physical properties, good toughness, excellent flame retardancy, good heat resistance and corrosion resistance, and the like.

Description

A kind of polypropylene acid glass fibre sleeve
Technical field
The invention belongs to glass fiber insulating sleeve production field, be specifically related to a kind of polypropylene acid glass fibre sleeve.
Background technology
Insulating material is one of the base mateiral of electrician, electronic product, it is to electrician's industrial expansion, there is unimportant effect, say in a sense, the development and progression of insulating material industry, be directly connected to country's generating, transmission of electricity and the development with electric industry, and affect the development and progress of national economy.Insulating material is the key condition that electric product has modern technique index, is also that electric product can the important guarantee of long-term safety reliability service.Therefore, require insulating material industry, development new variety, provide premium quality product; Improve constantly quality product, ensure that product is reliable and stable.
At present, in the conventional production practices of glass fiber insulating sleeve, the glass fiber insulating sleeve after to coated with resins is needed to be cured.Insulativity and the thermotolerance that how can increase glass fibre sleeve become the direction needing most research at present.
Summary of the invention
The object of this invention is to provide a kind of polypropylene acid glass fibre sleeve, the formula materials wide material sources that this invention provides, it is convenient to obtain, safety and environmental protection.
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3-20 micron; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50-80 part
Deionized water 1-35 part
Fire retardant 3-6 part
Stablizer 1-2 part
Mould inhibitor 0.1-0.3 part
Water-based insulating packing 0.5-5 part.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30-50%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3-5 hour, adjust ph 8.5-9 at 65-90 DEG C.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20-70%.
Wherein, described fire retardant is one or more in antimonous oxide, zinc borate, brominated flame retardant, aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate.
Wherein, described stablizer be stearic acid, Zinic stearas, calcium stearate, lead stearate one or more.
Wherein, described mould inhibitor is 1,2-isopropyl benzene isothiazolinone-3-ketone or MIT.
Wherein, described water-based insulating packing is one or more in modified manometer silicon dioxide, modified nano-titanium dioxide, modified Nano aluminium nitride.
Compared with prior art, the present invention has following beneficial effect:
(1) the invention provides glass fibre sleeve adopts good alkali free glass fibre to work out, and has good physical behavior.
(2) features such as it is extensive that the resin mixture liquor adopted in the present invention has material source, with low cost, substantially increase economic benefit.
(3) features such as glass fibre sleeve provided by the invention has good toughness, and flame retardant resistance is good, and heat-and corrosion-resistant performance is good.
Embodiment
Embodiment 1
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50 parts
Deionized water 1 part
Antimonous oxide 3 parts
Stearic acid 1 part
1,2-isopropyl benzene isothiazolinone-3-ketone 0.1 part
Modified manometer silicon dioxide 0.5 part.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3-5 hour at 65 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20%.
Embodiment 2
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 20 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 80 parts
Deionized water 35 parts
Zinc borate 6 parts
Zinic stearas 2 parts
MIT 0.3 part
Modified nano-titanium dioxide 5 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 50%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 5 hours at 90 DEG C, adjust ph 9.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 70%.
Embodiment 3
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 10 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 60 parts
Deionized water 18 parts
4 parts, aluminium hydroxide
Calcium stearate 2 parts
MIT 0.2 part
Modified Nano aluminium nitride 3 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 40%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 4 hours at 80 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 45%.
Embodiment 4
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 5 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 60 parts
Deionized water 18 parts
Brominated flame retardant 4 parts
Lead stearate 2 parts
MIT 0.2 part
Modified Nano aluminium nitride 3 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 35%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3 hours at 70 DEG C, adjust ph 9.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 60%.
Embodiment 5
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 15 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 70 parts
Deionized water 10 parts
Ammonium polyphosphate 4 parts
Zinic stearas 1 part
1,2-isopropyl benzene isothiazolinone-3-ketone 0.3 part
Modified nano-titanium dioxide 5 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3 hours at 65 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20%.
The polypropylene acid glass fibre sleeve of above-mentioned each examples produce has good flame retardant properties, and have good toughness, have favorable elasticity simultaneously, heat-and corrosion-resistant performance is splendid; The features such as the raw material adopted has wide material sources, with low cost.
The foregoing is only one embodiment of the invention, do not limit the present invention, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, all drop in protection scope of the present invention.

Claims (9)

1. a polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3-20 micron; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
2. a kind of polypropylene acid glass fibre sleeve according to claims 1, it is characterized in that, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50-80 part
Deionized water 1-35 part
Fire retardant 3-6 part
Stablizer 1-2 part
Mould inhibitor 0.1-0.3 part
Water-based insulating packing 0.5-5 part.
3. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30-50%.
4. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, add in polypropene blended liquid again, isothermal reaction 3-5 hour, adjust ph 8.5-9 at 65-90 DEG C.
5. a kind of polypropylene acid glass fibre sleeve according to claims 4, it is characterized in that, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20-70%.
6. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described fire retardant is one or more in antimonous oxide, zinc borate, brominated flame retardant, aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate.
7. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described stablizer be stearic acid, Zinic stearas, calcium stearate, lead stearate one or more.
8. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described mould inhibitor is 1,2-isopropyl benzene isothiazolinone-3-ketone or MIT.
9. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described water-based insulating packing is one or more in modified manometer silicon dioxide, modified nano-titanium dioxide, modified Nano aluminium nitride.
CN201510102480.7A 2015-03-10 2015-03-10 Hybrid polyacrylic fibreglass sleeve Pending CN104725711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510102480.7A CN104725711A (en) 2015-03-10 2015-03-10 Hybrid polyacrylic fibreglass sleeve

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510102480.7A CN104725711A (en) 2015-03-10 2015-03-10 Hybrid polyacrylic fibreglass sleeve

Publications (1)

Publication Number Publication Date
CN104725711A true CN104725711A (en) 2015-06-24

Family

ID=53450166

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510102480.7A Pending CN104725711A (en) 2015-03-10 2015-03-10 Hybrid polyacrylic fibreglass sleeve

Country Status (1)

Country Link
CN (1) CN104725711A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105330941A (en) * 2015-11-23 2016-02-17 安徽国泰印务有限公司 Preparation technology for mould-proof fresh-keeping film
CN107604469A (en) * 2017-09-05 2018-01-19 界首市宏利塑料有限公司 A kind of nano combined foaming rope and preparation method
CN107879636A (en) * 2017-10-12 2018-04-06 浙江畅通科技有限公司 A kind of preparation method of compound glass microfibre
CN110570984A (en) * 2019-09-27 2019-12-13 长沙华脉新材料有限公司 High-compression-resistance power cable and preparation and application thereof
CN111945437A (en) * 2020-06-29 2020-11-17 安徽浩天新型材料有限公司 High-flame-retardant corrosion-resistant glass fiber sleeve

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434134A (en) * 2008-12-24 2009-05-20 北京化工大学 Broadband multi-layer structured wave absorbing composite material and preparation thereof
CN102979097A (en) * 2011-09-07 2013-03-20 上海启鹏工程材料科技有限公司 Weaving sleeve pipe type fiber reinforce plastic (FRP) rib and preparation method thereof
CN103057174A (en) * 2012-12-29 2013-04-24 山东省呈祥电工电气有限公司 Plastic steel composite cable conduit and manufacturing method thereof
CN103062528A (en) * 2013-01-28 2013-04-24 河北宇通特种胶管有限公司 Coiled plastic composite pipe reinforced with fibre
CN203093151U (en) * 2012-12-29 2013-07-31 山东省呈祥电工电气有限公司 Plastic steel composite cable duct
CN103802335A (en) * 2012-11-14 2014-05-21 辽宁辽杰科技有限公司 Method for preparing fiber-reinforced thermoplastic composite material pipe

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434134A (en) * 2008-12-24 2009-05-20 北京化工大学 Broadband multi-layer structured wave absorbing composite material and preparation thereof
CN102979097A (en) * 2011-09-07 2013-03-20 上海启鹏工程材料科技有限公司 Weaving sleeve pipe type fiber reinforce plastic (FRP) rib and preparation method thereof
CN103802335A (en) * 2012-11-14 2014-05-21 辽宁辽杰科技有限公司 Method for preparing fiber-reinforced thermoplastic composite material pipe
CN103057174A (en) * 2012-12-29 2013-04-24 山东省呈祥电工电气有限公司 Plastic steel composite cable conduit and manufacturing method thereof
CN203093151U (en) * 2012-12-29 2013-07-31 山东省呈祥电工电气有限公司 Plastic steel composite cable duct
CN103062528A (en) * 2013-01-28 2013-04-24 河北宇通特种胶管有限公司 Coiled plastic composite pipe reinforced with fibre

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105330941A (en) * 2015-11-23 2016-02-17 安徽国泰印务有限公司 Preparation technology for mould-proof fresh-keeping film
CN107604469A (en) * 2017-09-05 2018-01-19 界首市宏利塑料有限公司 A kind of nano combined foaming rope and preparation method
CN107879636A (en) * 2017-10-12 2018-04-06 浙江畅通科技有限公司 A kind of preparation method of compound glass microfibre
CN110570984A (en) * 2019-09-27 2019-12-13 长沙华脉新材料有限公司 High-compression-resistance power cable and preparation and application thereof
CN110570984B (en) * 2019-09-27 2020-08-25 宝胜(宁夏)线缆科技有限公司 High-compression-resistance power cable and preparation and application thereof
CN111945437A (en) * 2020-06-29 2020-11-17 安徽浩天新型材料有限公司 High-flame-retardant corrosion-resistant glass fiber sleeve
CN111945437B (en) * 2020-06-29 2023-10-31 安徽浩天新型材料有限公司 High flame-retardant corrosion-resistant glass fiber sleeve

Similar Documents

Publication Publication Date Title
CN104725711A (en) Hybrid polyacrylic fibreglass sleeve
CN103665496B (en) Flame resistance rubber
CN100386298C (en) Novel phenol compound and novel epoxy resin derivable from such phenol compound
CN102875932B (en) A kind of PVC power pipe material and preparation method thereof
CN104231575B (en) Halogen-free and phosphorus-free PBT enhanced composite material and preparation method thereof
CN104293107A (en) Impact-resistant high-adhesive-force inflaming-retarding modified bisphenol A epoxy resin paint
KR101933400B1 (en) a silica inorganic flame retardant coating composition
CN103756136B (en) A kind of halogen-free flame-retardant polypropylene composition and preparation method thereof
CN107805342A (en) A kind of high heat-resistant impact MPP electric power protection pipes and preparation method thereof
CN105331170A (en) Environment-friendly nano-fire-proofing coating and preparation method thereof
CN103881237A (en) Anti-aging polypropylene plastic
CN104725817A (en) Environmentally-friendly flame-retardant reinforced impact-resistant PC composite material
CN106811001A (en) Corrosion-resistant epoxy paint
CN103304907B (en) A kind of chlorinatedpolyethylene CABLE MATERIALS containing modified silicon rubber
CN106928653B (en) Epoxy resin composition for prepreg, preparation method thereof and prepreg
CN105315845A (en) High-strength water-resistant corrosion-resistant epoxy resin powder coating
CN104194574A (en) Coating with high flame retardancy and strong adhesive force
CN104530973A (en) Fireproof paint formula
CN104292421A (en) Epoxy resin composition and reactive type flame retardant thereof
CN107725910B (en) A kind of high-temperature-resistant inorganic fibre pipeline and preparation method thereof based on graphene
CN102391471A (en) Optical epoxy resin and synthesis method thereof
CN104530697A (en) Flame-retardant high-fluidity high-temperature nylon and preparation method thereof
CN105885137A (en) Anti-acid and anti-alkali insulating material and production process thereof
CN103172977B (en) Anti-flaming, high-temperature-resistant, high-property and hybrid glass-fiber prepreg and preparation method thereof
CN110698837A (en) Flame-retardant engineering plastic

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150624