CN104725711A - Hybrid polyacrylic fibreglass sleeve - Google Patents
Hybrid polyacrylic fibreglass sleeve Download PDFInfo
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- CN104725711A CN104725711A CN201510102480.7A CN201510102480A CN104725711A CN 104725711 A CN104725711 A CN 104725711A CN 201510102480 A CN201510102480 A CN 201510102480A CN 104725711 A CN104725711 A CN 104725711A
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- glass fibre
- polypropylene
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- sleeve according
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
The invention discloses a hybrid polyacrylic fibreglass sleeve. The hybrid polyacrylic fibreglass sleeve is prepared by weaving alkali-free glass fiber into a tube, coating the tube with resin mixed liquor by dip-coating, and heating for dying the tube, wherein the alkali-free glass fiber is prepared by melting quartz sand, alumina, pyrophyllite and limestone into glass and then directly preparing the glass into fiber, and the diameter of the alkali-free glass fiber is 3-20 microns; and the resin mixed liquor is mainly prepared by mixing PE resin with an organic silicone modified polyacrylate hybrid material. The fibreglass sleeve provided by the invention is woven by using good alkali-free glass fiber, so that the fibreglass sleeve has the characteristics of good physical properties, good toughness, excellent flame retardancy, good heat resistance and corrosion resistance, and the like.
Description
Technical field
The invention belongs to glass fiber insulating sleeve production field, be specifically related to a kind of polypropylene acid glass fibre sleeve.
Background technology
Insulating material is one of the base mateiral of electrician, electronic product, it is to electrician's industrial expansion, there is unimportant effect, say in a sense, the development and progression of insulating material industry, be directly connected to country's generating, transmission of electricity and the development with electric industry, and affect the development and progress of national economy.Insulating material is the key condition that electric product has modern technique index, is also that electric product can the important guarantee of long-term safety reliability service.Therefore, require insulating material industry, development new variety, provide premium quality product; Improve constantly quality product, ensure that product is reliable and stable.
At present, in the conventional production practices of glass fiber insulating sleeve, the glass fiber insulating sleeve after to coated with resins is needed to be cured.Insulativity and the thermotolerance that how can increase glass fibre sleeve become the direction needing most research at present.
Summary of the invention
The object of this invention is to provide a kind of polypropylene acid glass fibre sleeve, the formula materials wide material sources that this invention provides, it is convenient to obtain, safety and environmental protection.
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3-20 micron; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50-80 part
Deionized water 1-35 part
Fire retardant 3-6 part
Stablizer 1-2 part
Mould inhibitor 0.1-0.3 part
Water-based insulating packing 0.5-5 part.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30-50%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3-5 hour, adjust ph 8.5-9 at 65-90 DEG C.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20-70%.
Wherein, described fire retardant is one or more in antimonous oxide, zinc borate, brominated flame retardant, aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate.
Wherein, described stablizer be stearic acid, Zinic stearas, calcium stearate, lead stearate one or more.
Wherein, described mould inhibitor is 1,2-isopropyl benzene isothiazolinone-3-ketone or MIT.
Wherein, described water-based insulating packing is one or more in modified manometer silicon dioxide, modified nano-titanium dioxide, modified Nano aluminium nitride.
Compared with prior art, the present invention has following beneficial effect:
(1) the invention provides glass fibre sleeve adopts good alkali free glass fibre to work out, and has good physical behavior.
(2) features such as it is extensive that the resin mixture liquor adopted in the present invention has material source, with low cost, substantially increase economic benefit.
(3) features such as glass fibre sleeve provided by the invention has good toughness, and flame retardant resistance is good, and heat-and corrosion-resistant performance is good.
Embodiment
Embodiment 1
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50 parts
Deionized water 1 part
Antimonous oxide 3 parts
Stearic acid 1 part
1,2-isopropyl benzene isothiazolinone-3-ketone 0.1 part
Modified manometer silicon dioxide 0.5 part.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3-5 hour at 65 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20%.
Embodiment 2
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 20 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 80 parts
Deionized water 35 parts
Zinc borate 6 parts
Zinic stearas 2 parts
MIT 0.3 part
Modified nano-titanium dioxide 5 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 50%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 5 hours at 90 DEG C, adjust ph 9.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 70%.
Embodiment 3
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 10 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 60 parts
Deionized water 18 parts
4 parts, aluminium hydroxide
Calcium stearate 2 parts
MIT 0.2 part
Modified Nano aluminium nitride 3 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 40%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 4 hours at 80 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 45%.
Embodiment 4
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 5 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 60 parts
Deionized water 18 parts
Brominated flame retardant 4 parts
Lead stearate 2 parts
MIT 0.2 part
Modified Nano aluminium nitride 3 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 35%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3 hours at 70 DEG C, adjust ph 9.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 60%.
Embodiment 5
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 15 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 70 parts
Deionized water 10 parts
Ammonium polyphosphate 4 parts
Zinic stearas 1 part
1,2-isopropyl benzene isothiazolinone-3-ketone 0.3 part
Modified nano-titanium dioxide 5 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3 hours at 65 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20%.
The polypropylene acid glass fibre sleeve of above-mentioned each examples produce has good flame retardant properties, and have good toughness, have favorable elasticity simultaneously, heat-and corrosion-resistant performance is splendid; The features such as the raw material adopted has wide material sources, with low cost.
The foregoing is only one embodiment of the invention, do not limit the present invention, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, all drop in protection scope of the present invention.
Claims (9)
1. a polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3-20 micron; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
2. a kind of polypropylene acid glass fibre sleeve according to claims 1, it is characterized in that, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50-80 part
Deionized water 1-35 part
Fire retardant 3-6 part
Stablizer 1-2 part
Mould inhibitor 0.1-0.3 part
Water-based insulating packing 0.5-5 part.
3. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30-50%.
4. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, add in polypropene blended liquid again, isothermal reaction 3-5 hour, adjust ph 8.5-9 at 65-90 DEG C.
5. a kind of polypropylene acid glass fibre sleeve according to claims 4, it is characterized in that, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20-70%.
6. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described fire retardant is one or more in antimonous oxide, zinc borate, brominated flame retardant, aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate.
7. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described stablizer be stearic acid, Zinic stearas, calcium stearate, lead stearate one or more.
8. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described mould inhibitor is 1,2-isopropyl benzene isothiazolinone-3-ketone or MIT.
9. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described water-based insulating packing is one or more in modified manometer silicon dioxide, modified nano-titanium dioxide, modified Nano aluminium nitride.
Priority Applications (1)
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CN201510102480.7A CN104725711A (en) | 2015-03-10 | 2015-03-10 | Hybrid polyacrylic fibreglass sleeve |
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CN201510102480.7A CN104725711A (en) | 2015-03-10 | 2015-03-10 | Hybrid polyacrylic fibreglass sleeve |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105330941A (en) * | 2015-11-23 | 2016-02-17 | 安徽国泰印务有限公司 | Preparation technology for mould-proof fresh-keeping film |
CN107604469A (en) * | 2017-09-05 | 2018-01-19 | 界首市宏利塑料有限公司 | A kind of nano combined foaming rope and preparation method |
CN107879636A (en) * | 2017-10-12 | 2018-04-06 | 浙江畅通科技有限公司 | A kind of preparation method of compound glass microfibre |
CN110570984A (en) * | 2019-09-27 | 2019-12-13 | 长沙华脉新材料有限公司 | High-compression-resistance power cable and preparation and application thereof |
CN111945437A (en) * | 2020-06-29 | 2020-11-17 | 安徽浩天新型材料有限公司 | High-flame-retardant corrosion-resistant glass fiber sleeve |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101434134A (en) * | 2008-12-24 | 2009-05-20 | 北京化工大学 | Broadband multi-layer structured wave absorbing composite material and preparation thereof |
CN102979097A (en) * | 2011-09-07 | 2013-03-20 | 上海启鹏工程材料科技有限公司 | Weaving sleeve pipe type fiber reinforce plastic (FRP) rib and preparation method thereof |
CN103057174A (en) * | 2012-12-29 | 2013-04-24 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable conduit and manufacturing method thereof |
CN103062528A (en) * | 2013-01-28 | 2013-04-24 | 河北宇通特种胶管有限公司 | Coiled plastic composite pipe reinforced with fibre |
CN203093151U (en) * | 2012-12-29 | 2013-07-31 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable duct |
CN103802335A (en) * | 2012-11-14 | 2014-05-21 | 辽宁辽杰科技有限公司 | Method for preparing fiber-reinforced thermoplastic composite material pipe |
-
2015
- 2015-03-10 CN CN201510102480.7A patent/CN104725711A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101434134A (en) * | 2008-12-24 | 2009-05-20 | 北京化工大学 | Broadband multi-layer structured wave absorbing composite material and preparation thereof |
CN102979097A (en) * | 2011-09-07 | 2013-03-20 | 上海启鹏工程材料科技有限公司 | Weaving sleeve pipe type fiber reinforce plastic (FRP) rib and preparation method thereof |
CN103802335A (en) * | 2012-11-14 | 2014-05-21 | 辽宁辽杰科技有限公司 | Method for preparing fiber-reinforced thermoplastic composite material pipe |
CN103057174A (en) * | 2012-12-29 | 2013-04-24 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable conduit and manufacturing method thereof |
CN203093151U (en) * | 2012-12-29 | 2013-07-31 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable duct |
CN103062528A (en) * | 2013-01-28 | 2013-04-24 | 河北宇通特种胶管有限公司 | Coiled plastic composite pipe reinforced with fibre |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105330941A (en) * | 2015-11-23 | 2016-02-17 | 安徽国泰印务有限公司 | Preparation technology for mould-proof fresh-keeping film |
CN107604469A (en) * | 2017-09-05 | 2018-01-19 | 界首市宏利塑料有限公司 | A kind of nano combined foaming rope and preparation method |
CN107879636A (en) * | 2017-10-12 | 2018-04-06 | 浙江畅通科技有限公司 | A kind of preparation method of compound glass microfibre |
CN110570984A (en) * | 2019-09-27 | 2019-12-13 | 长沙华脉新材料有限公司 | High-compression-resistance power cable and preparation and application thereof |
CN110570984B (en) * | 2019-09-27 | 2020-08-25 | 宝胜(宁夏)线缆科技有限公司 | High-compression-resistance power cable and preparation and application thereof |
CN111945437A (en) * | 2020-06-29 | 2020-11-17 | 安徽浩天新型材料有限公司 | High-flame-retardant corrosion-resistant glass fiber sleeve |
CN111945437B (en) * | 2020-06-29 | 2023-10-31 | 安徽浩天新型材料有限公司 | High flame-retardant corrosion-resistant glass fiber sleeve |
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Application publication date: 20150624 |