CN107604469A - A kind of nano combined foaming rope and preparation method - Google Patents
A kind of nano combined foaming rope and preparation method Download PDFInfo
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- CN107604469A CN107604469A CN201710791801.8A CN201710791801A CN107604469A CN 107604469 A CN107604469 A CN 107604469A CN 201710791801 A CN201710791801 A CN 201710791801A CN 107604469 A CN107604469 A CN 107604469A
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- rope
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- free glass
- polypropylene
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Abstract
The present invention discloses a kind of nano combined foaming rope and preparation method, each raw material weight percentage：Nano modification polypropylene 65% 80%, natural fiber 5% 11%, methyl-propyl naphthyl phosphate 2.5% 6%, trimethyl ethanedioic acid acetate 4% 10%, compound stabilizer 2% 6%, magnesium oxalate 0.2% 0.7%, defoamer 1% 3%, antioxidant 0.8% 1.6%.Alkali-free glass powder is surface-treated by using surfactant, obtain being modified alkali-free glass Ultramicro-powder nano modification is carried out to polypropylene and fill to obtain nano modification polypropylene, it is high to not only increase rigidity, good toughness, dimensional stability, relatively low coefficient of thermal expansion, the polyacrylic melt strength of nano modification improves 57 times, with good low-temperature flexibility, 30 DEG C of low-temperature impact is resistant to；Preparation method is simple, improves operating efficiency, and the common fillers of 5 times of Nano filling and the filling of filling reach suitable rigidity, greatly reduce cost；Obtained nano combined foaming rope intensity is high, toughness is good, service life length.
Description
Technical field
The present invention relates to field of rope, and in particular to a kind of nano combined foaming rope and preparation method.
Background technology
A kind of thermoplastic of prepared by foaming rope is one kind of plastic ties, and main component is polypropylene, and it is by propylene polymerization
Property resin, compared with other thermoplastic resins, polypropylene has low-density, high-melting-point, source is wide, price is low and mechanical performance
Superior, the features such as chemical stability is good, it is indispensable to have become packaging, light industry, building, electronics, electrical equipment and automobile and other industries
Base stock.But plain polypropylene strand is linear structure, molecular weight distribution relative narrower, this results in polypropylene
The shortcomings such as rigidity is low, poor heat resistance, shrinkage factor is big, melt strength is low, are processed in thermoforming, after temperature is higher than fusing point, melt
Intensity and viscosity all drastically decline, and product wall thickness is uneven when causing thermoforming, curved edge occur, receive when extrusion, coating, calendering
The problems such as abscess collapses when contracting, extrusion foaming, so as to limit polypropylene in thermoforming processing, foaming, Extrusion Coating, blowing etc.
The application of aspect.
In order to overcome these problems, inorganic filler is generally added wherein, but conventional fillers are modified it is generally necessary to larger
Addition, the moulding processability of product is often influenceed, can also decline toughness of material, and significantly increase polyacrylic close
Degree, so as to increase the weight of product parts, and material recovery is difficult, is unfavorable for energy-conserving and environment-protective requirement.
The content of the invention
It is an object of the invention to provide a kind of nano combined foaming rope and preparation method, using Nano filling to poly- third
Alkene carries out nano modification and fills to obtain nano modification polypropylene, and obtained nano combined foaming rope intensity is high, toughness is good, uses the longevity
Life length.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of nano combined foaming rope, each raw material weight percentage are：Nano modification polypropylene 65%-80%, natural fibre
Tie up 5%-11%, methyl-propyl naphthyl phosphate 2.5%-6%, trimethyl ethanedioic acid acetate 4%-10%, compound stabilizer
2%-6%, magnesium oxalate 0.2%-0.7%, defoamer 1%-3%, antioxidant 0.8%-1.6%.
Further, described nano modification polypropylene is after carrying out nano modification filling to polypropylene by Nano filling
Composite, including polypropylene, Nano filling and solubilizer, polypropylene, Nano filling, the mass ratio of solubilizer are 7-8.5:
0.6-1.6:0.05-1.5。
Further, described Nano filling is modified alkali-free glass Ultramicro-powder, and modified alkali-free glass Ultramicro-powder includes alkali-free
Glass dust and surfactant, alkali-free glass powder, the mass ratio of surfactant are 1:0.5-0.8, described surfactant
For dodecyl sodium sulfate.
Further, described solubilizer is dibenzoic acid graft polyisobutene, the poly- epoxypentene of oxalic acid grafting, 3- along isobutyl
One kind in alkenyl benzoyl isocyanate.
Further, described natural fiber is wool fiber, fruit fiber, cotton, one kind in gypsum walling material or several
Kind combination.
Further, described compound stabilizer is stearic acid file, the compound of phosphorous vinegar, and stearic acid is filed, phosphorous vinegar
Mass ratio be 1:3-4.6.
Further, described defoamer be polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether,
One kind in polypropylene glycerol aether.
Further, described antioxidant is one kind in 2- amino -4- methylquinolines, 4- ethoxyquinolines.
A kind of preparation method of nano combined foaming rope, specifically includes following steps：
(1) the polyacrylic preparation of nano modification
Alkali-free glass powder is added in ball mill and ground, the first sieve is crossed, alkali-free glass Ultramicro-powder is obtained, by alkali-free glass
Ultramicro-powder mixes with purified water, adds surfactant while stirring, constant temperature stirring, centrifuges, dry, ground second
Sieve, that is, obtain being modified alkali-free glass Ultramicro-powder；
The polypropylene, Nano filling and solubilizer of mass parts are added into screw extruder extrusion molding to be granulated, that is, obtained
Nano modification polypropylene；
(2) preparation of nano combined foaming rope
Raw material each by weight is added to plastic optical fibre of the multiple screw extruder after melting extrusion, metering, spinneret process
It is put into tank and cools down, obtains plastic monofilament fiber；Plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, afterwards
Plastic strip of shaping to obtain is introduced into forming press-roller；Plastic strip synthesizes rope, i.e., in rope machine afterwards into stock is twisted in stock machine
Must be foamed rope；
Further, the sieve mesh of the first sieve described in step (1) is 60 mesh, and the sieve mesh of the second sieve is 100 mesh；Described purifying
The quality of water is 10-15 times of alkali-free glass Ultramicro-powder；Described constant temperature whipping temp is 50-75 DEG C, mixing time 2-3h；
Described extrusion temperature is 240-260 DEG C.
Beneficial effects of the present invention：
Compared with prior art, the present invention is surface-treated by using surfactant to alkali-free glass powder, is obtained
Modified alkali-free glass Ultramicro-powder carries out nano modification to polypropylene and fills to obtain nano modification polypropylene, not only increase rigidity,
Good toughness, dimensional stability are high, and relatively low coefficient of thermal expansion, the polyacrylic melt strength of nano modification improves 5-7 times, have good
Good low-temperature flexibility, it is resistant to -30 DEG C of low-temperature impact；Preparation method is simple, improves operating efficiency, the Nano filling of filling with
The common fillers of 5 times of filling reach suitable rigidity, greatly reduce cost；Obtained nano combined foaming rope intensity is high, tough
Property good, service life length.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
All other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment 1
(1) the polyacrylic preparation of nano modification
1kg alkali-free glass powder is added in ball mill and ground, it is that 60 purposes first are sieved to cross sieve mesh, obtains alkali-free glass and surpasses
Micro mist, alkali-free glass Ultramicro-powder is mixed with 15kg purified waters, add 0.8kg dodecyl sodium sulfates while stirring, constant temperature stirs
2h is mixed, is centrifuged, is dried, ground 100 mesh second sieves, that is, obtains being modified alkali-free glass Ultramicro-powder, particle diameter 25nm；
70kg polypropylene, 16kg are modified alkali-free glass Ultramicro-powder and 14kg dibenzoic acid graft polyisobutenes are added to spiral shell
Bar extruder for shaping is granulated, and extrusion temperature is 240 DEG C, that is, obtains nano modification polypropylene；
(2) preparation of nano combined foaming rope
By nano modification polypropylene 65kg, wool fiber 11kg, methyl-propyl naphthyl phosphate 6kg, trimethyl ethanedioic acid
Acetate 10kg, stearic acid file 1.5kg, phosphorous vinegar 4.5kg, magnesium oxalate 0.2kg, polyoxyethylene polyoxypropylene pentaerythrite ether
It is fine that 1kg, 2- amino -4- methylquinolines 0.8kg are added to plastics of the multiple screw extruder after melting extrusion, metering, spinneret process
Dimension, which is put into tank, to be cooled down, and obtains plastic monofilament fiber；Plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, it
The plastic strip of shaping to obtain is introduced into forming press-roller afterwards；Plastic strip synthesizes rope in rope machine afterwards into stock is twisted in stock machine,
Produce foaming rope.
Embodiment 2
(1) the polyacrylic preparation of nano modification
1kg alkali-free glass powder is added in ball mill and ground, it is that 60 purposes first are sieved to cross sieve mesh, obtains alkali-free glass and surpasses
Micro mist, alkali-free glass Ultramicro-powder is mixed with 10kg purified waters, add 0.5kg dodecyl sodium sulfates while stirring, constant temperature stirs
2h is mixed, is centrifuged, is dried, ground 100 mesh second sieves, that is, obtains being modified alkali-free glass Ultramicro-powder, particle diameter 55nm；
85kg polypropylene, 10kg are modified alkali-free glass Ultramicro-powder and 5kg oxalic acid is grafted poly- epoxypentene and is added to screw rod
Extruder for shaping is granulated, and extrusion temperature is 260 DEG C, that is, obtains nano modification polypropylene；
(2) preparation of nano combined foaming rope
By nano modification polypropylene 80kg, fruit fiber 4kg, cotton 1kg, methyl-propyl naphthyl phosphate 2.5kg, front three
Base ethanedioic acid acetate 5.2kg, stearic acid file 0.4kg, phosphorous vinegar 1.6kg, magnesium oxalate 0.7kg, polyoxyethylene polyoxy propyl alcohol
Amidogen ether 3kg, 4- ethoxyquinoline 1.6kg is added to plastic optical fibre of the multiple screw extruder after melting extrusion, metering, spinneret process
It is put into tank and cools down, obtains plastic monofilament fiber；Plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, afterwards
Plastic strip of shaping to obtain is introduced into forming press-roller；Plastic strip synthesizes rope, i.e., in rope machine afterwards into stock is twisted in stock machine
Must be foamed rope.
Embodiment 3
(1) the polyacrylic preparation of nano modification
1kg alkali-free glass powder is added in ball mill and ground, it is that 60 purposes first are sieved to cross sieve mesh, obtains alkali-free glass and surpasses
Micro mist, alkali-free glass Ultramicro-powder is mixed with 12kg purified waters, add 0.6kg dodecyl sodium sulfates while stirring, constant temperature stirs
2.5h is mixed, is centrifuged, is dried, ground 100 mesh second sieves, that is, obtains being modified alkali-free glass Ultramicro-powder, particle diameter 69nm；
82kg polypropylene, 8kg are modified alkali-free glass Ultramicro-powder and 10kg3- adds along isobutenyl benzoyl isocyanate
Enter to screw extruder extrusion molding and be granulated, extrusion temperature is 255 DEG C, that is, obtains nano modification polypropylene；
(2) preparation of nano combined foaming rope
By nano modification polypropylene 78kg, cotton 2.5kg, gypsum walling material 7kg, methyl-propyl naphthyl phosphate 3.8kg,
Trimethyl ethanedioic acid acetate 4kg, stearic acid file 0.5kg, phosphorous vinegar 2.3kg, magnesium oxalate 0.3kg, polypropylene glycerol aether
1.5kg, 4- ethoxyquinoline 1.1kg are added to plastic optical fibre of the multiple screw extruder after melting extrusion, metering, spinneret process and put
Enter in tank and cool down, obtain plastic monofilament fiber；Plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, Zhi Houyin
Enter plastic strip of being shaped in forming press-roller to obtain；Plastic strip synthesizes rope in rope machine, produced afterwards into stock is twisted in stock machine
Foaming rope.
Embodiment 4
(1) the polyacrylic preparation of nano modification
1kg alkali-free glass powder is added in ball mill and ground, it is that 60 purposes first are sieved to cross sieve mesh, obtains alkali-free glass and surpasses
Micro mist, alkali-free glass Ultramicro-powder is mixed with 13kg purified waters, add 0.7kg dodecyl sodium sulfates while stirring, constant temperature stirs
3h is mixed, is centrifuged, is dried, ground 100 mesh second sieves, that is, obtains being modified alkali-free glass Ultramicro-powder, particle diameter 32nm；
79kg polypropylene, 12kg are modified alkali-free glass Ultramicro-powder and 9kg dibenzoic acid graft polyisobutenes are added to spiral shell
Bar extruder for shaping is granulated, and extrusion temperature is 252 DEG C, that is, obtains nano modification polypropylene；
(2) preparation of nano combined foaming rope
By nano modification polypropylene 75kg, wool fiber 1.6kg, fruit fiber 1.5kg, cotton 2.5kg, methyl-propyl naphthalene
Base phosphate 5.2kg, trimethyl ethanedioic acid acetate 7.5kg, stearic acid file 0.7kg, phosphorous vinegar 2.4kg, magnesium oxalate
0.4kg, polyoxyethylene polyoxypropylene pentaerythrite ether 2.3kg, 2- amino -4- methylquinolines 0.9kg are added to multiple screw extruder
Plastic optical fibre after melting extrusion, metering, spinneret process, which is put into tank, to be cooled down, and obtains plastic monofilament fiber；After cooling down
Plastic monofilament fiber be put into drafting machine carry out drawing-off, be introduced into forming press-roller plastic strip of shaping to obtain afterwards；Plastic strip exists
Stock is twisted into stock machine, synthesizes rope in rope machine afterwards, produces foaming rope.
Above content is only to design example and explanation of the invention, affiliated those skilled in the art
Various modifications or supplement are made to described specific embodiment or is substituted using similar mode, without departing from invention
Design or surmount scope defined in the claims, protection scope of the present invention all should be belonged to.
Claims (10)
- A kind of 1. nano combined foaming rope, it is characterised in that：Each raw material weight percentage is：Nano modification polypropylene 65%- 80%th, natural fiber 5%-11%, methyl-propyl naphthyl phosphate 2.5%-6%, trimethyl ethanedioic acid acetate 4%-10%, Compound stabilizer 2%-6%, magnesium oxalate 0.2%-0.7%, defoamer 1%-3%, antioxidant 0.8%-1.6%.
- 2. the nano combined foaming rope of one kind according to claim 1, it is characterised in that：Described nano modification polypropylene is Composite after nano modification filling, including polypropylene, Nano filling and solubilizer are carried out to polypropylene by Nano filling, Polypropylene, Nano filling, the mass ratio of solubilizer are 7-8.5:0.6-1.6:0.05-1.5.
- 3. the nano combined foaming rope of one kind according to claim 2, it is characterised in that：Described Nano filling is modified nothing Alkali glass Ultramicro-powder, modified alkali-free glass Ultramicro-powder include alkali-free glass powder and surfactant, alkali-free glass powder, surface-active The mass ratio of agent is 1:0.5-0.8, described surfactant are dodecyl sodium sulfate.
- 4. the nano combined foaming rope of one kind according to claim 2, it is characterised in that：Described solubilizer is dibenzoic acid Graft polyisobutene, oxalic acid are grafted poly- epoxypentene, 3- along one kind in isobutenyl benzoyl isocyanate.
- 5. the nano combined foaming rope of one kind according to claim 1, it is characterised in that：Described natural fiber is that wool is fine One or more combination in dimension, fruit fiber, cotton, gypsum walling material.
- 6. the nano combined foaming rope of one kind according to claim 1, it is characterised in that：Described compound stabilizer is tristearin Acid file, the compound of phosphorous vinegar, stearic acid file, the mass ratio of phosphorous vinegar are 1:3-4.6.
- 7. the nano combined foaming rope of one kind according to claim 1, it is characterised in that：Described defoamer is polyoxyethylene One kind in polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
- 8. the nano combined foaming rope of one kind according to claim 1, it is characterised in that：Described antioxidant be 2- amino- One kind in 4- methylquinolines, 4- ethoxyquinolines.
- 9. a kind of preparation method of nano combined foaming rope, specifically includes following steps：(1) the polyacrylic preparation of nano modificationAlkali-free glass powder is added in ball mill and ground, the first sieve is crossed, alkali-free glass Ultramicro-powder is obtained, by alkali-free glass ultra micro Powder mixes with purified water, adds surfactant while stirring, constant temperature stirring, centrifuges, dry, ground second sieve, i.e., Obtain being modified alkali-free glass Ultramicro-powder；The polypropylene, Nano filling and solubilizer of mass parts are added into screw extruder extrusion molding to be granulated, that is, obtain nanometer Modified polypropene；(2) preparation of nano combined foaming ropeRaw material each by weight is added into plastic optical fibre of the multiple screw extruder after melting extrusion, metering, spinneret process to be put into Cooled down in tank, obtain plastic monofilament fiber；Plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, is introduced afterwards Shaped in forming press-roller to obtain plastic strip；Plastic strip synthesizes rope in rope machine, produces hair afterwards into stock is twisted in stock machine Bubble rope.
- A kind of 10. preparation method of nano combined foaming rope according to claim 9, it is characterised in that：Step (1) is described The sieve mesh of the first sieve be 60 mesh, the second sieve mesh sieved is 100 mesh；The quality of described purified water is alkali-free glass Ultramicro-powder 10-15 times；Described constant temperature whipping temp is 50-75 DEG C, mixing time 2-3h；Described extrusion temperature is 240-260 DEG C.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363253A (en) * | 2020-04-24 | 2020-07-03 | 界首市宏利塑料有限公司 | Corrosion-resistant plastic rope |
| CN111501384A (en) * | 2020-04-24 | 2020-08-07 | 界首市宏利塑料有限公司 | High-strength wear-resistant PP plastic rope |
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| KR20070025040A (en) * | 2005-08-31 | 2007-03-08 | 길은주 | Packing sheet for bottle lid of unrefined rice wine and method of manufacturing the same |
| CN102532685A (en) * | 2010-12-23 | 2012-07-04 | 上海普利特复合材料股份有限公司 | Nano talcpowder modified polypropylene composite material and preparation method thereof |
| CN104725711A (en) * | 2015-03-10 | 2015-06-24 | 淄博迪声绝缘材料有限公司 | Hybrid polyacrylic fibreglass sleeve |
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- 2017-09-05 CN CN201710791801.8A patent/CN107604469A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070025040A (en) * | 2005-08-31 | 2007-03-08 | 길은주 | Packing sheet for bottle lid of unrefined rice wine and method of manufacturing the same |
| CN102532685A (en) * | 2010-12-23 | 2012-07-04 | 上海普利特复合材料股份有限公司 | Nano talcpowder modified polypropylene composite material and preparation method thereof |
| CN104725711A (en) * | 2015-03-10 | 2015-06-24 | 淄博迪声绝缘材料有限公司 | Hybrid polyacrylic fibreglass sleeve |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363253A (en) * | 2020-04-24 | 2020-07-03 | 界首市宏利塑料有限公司 | Corrosion-resistant plastic rope |
| CN111501384A (en) * | 2020-04-24 | 2020-08-07 | 界首市宏利塑料有限公司 | High-strength wear-resistant PP plastic rope |
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Application publication date: 20180119 |