CN104725696A - Flexible polyolefin thermoplastic elastic material - Google Patents

Flexible polyolefin thermoplastic elastic material Download PDF

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Publication number
CN104725696A
CN104725696A CN201410608481.4A CN201410608481A CN104725696A CN 104725696 A CN104725696 A CN 104725696A CN 201410608481 A CN201410608481 A CN 201410608481A CN 104725696 A CN104725696 A CN 104725696A
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Prior art keywords
maleic anhydride
copolymer
ethylene
anhydride grafted
blend
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CN201410608481.4A
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Inventor
陈常明
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SHENZHEN OLLOY NEW MATERIAL TECHNOLOGY Co
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SHENZHEN OLLOY NEW MATERIAL TECHNOLOGY Co
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Priority to CN201410608481.4A priority Critical patent/CN104725696A/en
Publication of CN104725696A publication Critical patent/CN104725696A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a design thought and a preparation method for a flexible polyolefin elastomer. The polyolefin elastomer prepared with the method has good flexibility and comprehensively excellent mechanical property.

Description

A kind of flexible polyolefin thermoplastic elastomer (s)
Technical field
The present invention relates to thermoplastic elastomer technical field, particularly relate to a kind of mentality of designing and preparation method of flexible polyolefin elastomer material.
Background technology
Thermoplastic elastomer is that a class is of wide application, and with the macromolecular material of rubber and thermoplastics characteristic, is widely used in the fields such as rubber overshoes, toy, sports equipment, power tool, automobile component, electric wire, sebific duct and household electrical appliance.The present invention obtains a kind of polyolefin elastomer by a kind of combination of innovation, and the existing flexibility well of this elastomerics, has again good elasticity and comprehensively superior mechanical property.
Summary of the invention
The object of the invention is to design and produce a kind of flexible polyolefin elastomer material, the polyolefin elastomer material prepared by the method, existing flexibility well, has again good elasticity and comprehensively superior mechanical property.
In order to achieve the above object, the technical scheme of employing of the present invention is:
A kind of flexible polyolefin elastomer material, it is characterized in that, according to the mass fraction, its feed composition comprises:
Polyvinyl resin: 10-60 part
Polyolefin copolymer: 5-80 part
Mealy elastomer: 1-30 part
Extending oil: 5-50 part
Compatilizer: 5-40 part
Weighting material: 0-180 part
Processing aid: 0.2-10 part
Oxidation inhibitor: 0.1-2 part
Lubricant: 0.1-2 part
Described polyvinyl resin is one or more blend following: Low Density Polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene(HDPE) (HDPE), metallocene PE (MPE);
Described polyolefin copolymer is one or more blend following: ethylene-propylene rubber(EPR) (EPR), terpolymer EP rubber (EPDM), ethylene-octene copolymer (POE), ethene-vinyl acetate copolymer (EVA), ethylene-ethyl acrylate copolymer (EEA), ethylene-acrylic acid copolymer (EAA), ethylene-methyl acrylate copolymer (EMA);
Described mealy elastomer is: styrene-butadiene-styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymers (SEBS), styrene isoprene styrene block copolymer (SIS) (SIS), hydrogenated styrene isoprene-styrene block copolymer (SEPS);
Described extending oil is naphthenic oil, paraffin oil, white oil, silicone oil;
Described compatilizer is: maleic anhydride grafted polyethylene, maleic anhydride graft ethylene-propylene rubber(EPR) (EPR), maleic anhydride graft terpolymer EP rubber (EPDM), maleic anhydride grafted ethene-octene copolymer (POE), maleic anhydride grafted ethene-vinyl acetate copolymer (EVA), maleic anhydride grafted ethene-ethyl acrylate copolymer (EEA), maleic anhydride grafted ethene-acrylic copolymer (EAA), maleic anhydride grafted ethene-methyl acrylate copolymer (EMA), maleic anhydride grafted polyethylene/terpolymer EP rubber (EPDM) blend, maleic anhydride grafted polyethylene/ethylene-propylene rubber(EPR) (EPR) blend, maleic anhydride grafted polyethylene/ethylene-octene copolymer (POE) blend, maleic anhydride grafted polyethylene/ethene-vinyl acetate copolymer (EVA) blend, maleic anhydride grafted polyethylene/ethylene-ethyl acrylate copolymer (EEA) blend, maleic anhydride grafted polyethylene/ethylene-acrylic acid copolymer (EAA) blend, maleic anhydride grafted polyethylene/ethylene-methyl acrylate copolymer (EMA) blend,
Described weighting material is one or more mixture following: magnesium hydroxide, aluminium hydroxide, zinc borate, calcium carbonate, magnesiumcarbonate, barium sulfate, talcum powder, mica powder, silicon-dioxide, potter's clay, wollastonite, glass microballon and various organic and inorganic fire retardant;
Described processing aid is silicone powder, silicone master batch or processing aids acrylic resin;
Described oxidation inhibitor is Hinered phenols, hindered amines, phosphite ester kind antioxidant;
Described lubricant is polyethylene wax, Poly Propylene Wax, stearate soap class or stearate class.
A kind of preparation method of flexible polyolefin elastomer material, it is characterized in that: take each component according to composition of raw materials, first mealy elastomer is mixed with extending oil, 5-20 minute is mixed in homogenizer, make elastomerics oil suction abundant, and then polyvinyl resin, polyolefin copolymer, compatilizer, weighting material, processing aid, oxidation inhibitor are added wherein mixing 5-20 minute, fully mix, the raw material mixed is added in plasticating equipment and melt extrudes, pelletizing, obtains a kind of flexible polyolefin elastomer material.
Embodiment
Below by embodiment, the present invention is further illustrated, but the scope of protection of present invention is not limited to the scope that embodiment represents.
Embodiment 1:
1000gSEBS (Yueyang petrochemical industry YH-503) is mixed 10 minutes with 3000g naphthenic oil in homogenizer, and then add 4000gLDPE, 1000EPR, 1000g maleic anhydride graft PE, 12000g magnesium hydroxide, 100g silicone powder, 30g antioxidant 1010,30g irgasfos 168,50g lubricant PE wax successively, start stirrer Homogeneous phase mixing 8 minutes.The raw materials melt mixed extruded, pelletizing, obtain having flexible polyolefin elastomer material, this material softer hardness is shore hardness 85A, and tensile strength is 7.5MPa, and elongation at break is 220%, and tear strength is: 28KN/m.
Embodiment 2:
1000gSBS (Yueyang petrochemical industry YH-792) is mixed 10 minutes with 2500g paraffin oil in homogenizer, and then add 2000gLLDPE, 2000gPOE, 2500g maleic anhydride graft POE, 500g magnesium hydroxide, 500g aluminium hydroxide, 100g silicone powder, 30g antioxidant 1010,30g irgasfos 168,50g lubricant PE wax successively, start stirrer Homogeneous phase mixing 8 minutes.The raw materials melt mixed extruded, pelletizing, obtain having flexible polyolefin elastomer material, this material softer hardness is shore hardness 80A, and tensile strength is 8.5MPa, and elongation at break is 320%, and tear strength is: 26KN/m.
Embodiment 3:
1000gSEPS (G1730) is mixed 10 minutes with 4000g white oil in homogenizer, and then add 1000gLLDPE, 1000gMPE, 2000EVA, 1000g maleic anhydride graft PE/EVA, 300g calcium carbonate, 100g silicone powder, 30g antioxidant 1010,30g irgasfos 168,50g lubricant stearic acid calcium successively, start stirrer Homogeneous phase mixing 8 minutes.The raw materials melt mixed extruded, pelletizing, obtain having flexible polyolefin elastomer material, this material softer hardness is shore hardness 70A, and tensile strength is 5.5MPa, and elongation at break is 450%, and tear strength is: 36KN/m.
Embodiment 4:
500gSIS (Yueyang petrochemical industry 1105) is mixed 10 minutes with 2000g white oil in homogenizer, and then add 500gHDPE, 3000gMPE, 2000gEMA, 2000g maleic anhydride graft PE/EEA, 500g talcum powder, 100g silicone powder, 30g antioxidant 1010,30g irgasfos 168,50g lubricant stearic acid zinc successively, start stirrer Homogeneous phase mixing 8 minutes.The raw materials melt mixed extruded, pelletizing, obtain having flexible polyolefin elastomer material, this material softer hardness is shore hardness 90A, and tensile strength is 13.5MPa, and elongation at break is 480%, and tear strength is: 31KN/m.
Embodiment 5:
1000gSEPS (G1726) is mixed 10 minutes with 2500g paraffin oil in homogenizer, and then add 2000gMPE, 2500gPOE, 2000g maleic anhydride graft POE, 80g red phosphor masterbatch, 1000g aluminium hydroxide, 100g silicone powder, 30g antioxidant 1010,30g irgasfos 168,50g lubricant PE wax successively, start stirrer Homogeneous phase mixing 8 minutes.The raw materials melt mixed extruded, pelletizing, obtain flame retardant flexible polyolefin elastomer material, this material softer hardness is shore hardness 85A, and tensile strength is 11.5MPa, and elongation at break is 260%, and tear strength is: 30KN/m.
Above to provided by the present invention a kind of there is flexible polyolefin elastomer material mentality of designing and preparation method be described in detail; and an application implementation example is set forth principle of the present invention and embodiment; embodiment just understands feature of the present invention and core concept thereof for helping; its object is to the personage of skilled can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (7)

1. a flexible polyolefin elastomer material, is characterized in that, according to the mass fraction, its feed composition comprises:
Polyvinyl resin: 10-60 part
Polyolefin copolymer: 5-80 part
Mealy elastomer: 1-30 part
Extending oil: 5-50 part
Compatilizer: 5-40 part
Weighting material: 0-180 part
Processing aid: 0.2-10 part
Oxidation inhibitor: 0.1-2 part
Lubricant: 0.1-2 part.
2. a kind of flexible polyolefin elastomer material according to claim 1, it is characterized in that, described polyvinyl resin is one or more blend following: Low Density Polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene(HDPE) (HDPE), metallocene PE (MPE).
3. a kind of flexible polyolefin elastomer material according to claim 1, it is characterized in that, described polyolefin copolymer is one or more blend following: ethylene-propylene rubber(EPR) (EPR), terpolymer EP rubber (EPDM), ethylene-octene copolymer (POE), ethene-vinyl acetate copolymer (EVA), ethylene-ethyl acrylate copolymer (EEA), ethylene-acrylic acid copolymer (EAA), ethylene-methyl acrylate copolymer (EMA).
4. a kind of flexible polyolefin elastomer material according to claim 1, it is characterized in that, described mealy elastomer is: styrene-butadiene-styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymers (SEBS), styrene isoprene styrene block copolymer (SIS) (SIS), hydrogenated styrene isoprene-styrene block copolymer (SEPS).
5. a kind of flexible polyolefin elastomer material according to claim 1, it is characterized in that, described extending oil is: naphthenic oil, paraffin oil, white oil, silicone oil.
6. a kind of flexible polyolefin elastomer material according to claim 1, it is characterized in that, described compatilizer is: maleic anhydride grafted polyethylene, maleic anhydride graft ethylene-propylene rubber(EPR) (EPR), maleic anhydride graft terpolymer EP rubber (EPDM), maleic anhydride grafted ethene-octene copolymer (POE), maleic anhydride grafted ethene-vinyl acetate copolymer (EVA), maleic anhydride grafted ethene-ethyl acrylate copolymer (EEA), maleic anhydride grafted ethene-acrylic copolymer (EAA), maleic anhydride grafted ethene-methyl acrylate copolymer (EMA), maleic anhydride grafted polyethylene/terpolymer EP rubber (EPDM) blend, maleic anhydride grafted polyethylene/ethylene-propylene rubber(EPR) (EPR) blend, maleic anhydride grafted polyethylene/ethylene-octene copolymer (POE) blend, maleic anhydride grafted polyethylene/ethene-vinyl acetate copolymer (EVA) blend, maleic anhydride grafted polyethylene/ethylene-ethyl acrylate copolymer (EEA) blend, maleic anhydride grafted polyethylene/ethylene-acrylic acid copolymer (EAA) blend, maleic anhydride grafted polyethylene/ethylene-methyl acrylate copolymer (EMA) blend.
7. a kind of flexible polyolefin elastomer material according to claim 1, it is characterized in that, described weighting material is one or more mixture following: magnesium hydroxide, aluminium hydroxide, zinc borate, calcium carbonate, magnesiumcarbonate, barium sulfate, talcum powder, mica powder, silicon-dioxide, potter's clay, wollastonite, glass microballon and various organic and inorganic fire retardant.
CN201410608481.4A 2014-11-04 2014-11-04 Flexible polyolefin thermoplastic elastic material Pending CN104725696A (en)

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Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104910573A (en) * 2015-06-26 2015-09-16 台橡（上海）实业有限公司 Thermoplastic elastomer medical film material
CN105037965A (en) * 2015-09-02 2015-11-11 大连科盟新材料有限公司 Halogen-free flame-retardant polyolefin thermoplastic elastomer
CN105273413A (en) * 2015-11-09 2016-01-27 安徽韧达高分子材料有限公司 Low-hardness high-strength TPE material and preparation method thereof
CN105295241A (en) * 2015-11-13 2016-02-03 宁波一舟塑胶有限公司 Ceramic polyvinyl chloride wire and cable material and preparation method thereof
CN105713291A (en) * 2016-04-29 2016-06-29 上海工程技术大学 Insulating material for preparing aerial insulated cable and preparation method thereof
CN105778390A (en) * 2016-01-20 2016-07-20 苏州市景荣科技有限公司 Preparation method of high-hardness, heat-resistant and wear-resistant SBS shoe sloe material
CN105778210A (en) * 2016-03-14 2016-07-20 苏州莱特复合材料有限公司 Preparation method of high-fire-retardant automobile bumper composite material
CN106589518A (en) * 2016-10-31 2017-04-26 平湖伟峰科技有限责任公司 Calcium carbonate toughened HDPE composite material and preparation process for blow molding product of calcium carbonate toughened HDPE composite material
CN106971768A (en) * 2017-05-13 2017-07-21 中天科技装备电缆有限公司 A kind of new-energy automobile inside high-tension cable and preparation method thereof
CN106977957A (en) * 2017-04-01 2017-07-25 广州市凯德热塑性弹性体有限公司 It is a kind of specially to add TPE material of glass and preparation method thereof in encapsulated nylon
CN107151369A (en) * 2017-07-03 2017-09-12 界首市燎原塑胶有限公司 A kind of environment-friendly Slipper and its processing method with healthcare function
CN107189177A (en) * 2017-07-25 2017-09-22 合肥达户电线电缆科技有限公司 A kind of CABLE MATERIALS of High-temperature-resandant andant cracking-resistant and preparation method thereof
CN108017871A (en) * 2017-12-29 2018-05-11 厦门本润科技有限公司 Environment-friendly TPE wire and cable material
CN108277932A (en) * 2018-01-16 2018-07-13 厦门防水博士建筑工程有限公司 A kind of tube edge percolating water repairerment technique
CN108473735A (en) * 2015-11-17 2018-08-31 Sabic环球技术有限责任公司 Polymer composition with improved impact strength
WO2018195755A1 (en) * 2017-04-25 2018-11-01 南通大学 Receiving plate with magnetic base for super clean bench
CN108892843A (en) * 2018-06-21 2018-11-27 安徽意力电缆有限公司 A kind of track traffic cable insulating sheath material and preparation method thereof
WO2018213950A1 (en) * 2017-05-20 2018-11-29 南通大学 Storage tray and pipettor stand having a magnetic base for clean bench
CN109054150A (en) * 2018-07-11 2018-12-21 安徽维尔特仪表线缆有限公司 A kind of Wear-resistant, high-temperature resistant cable jacket material and preparation method thereof
CN109593247A (en) * 2018-11-02 2019-04-09 浙江耀隆塑业有限公司 A kind of thermoplastic elastomer (TPE) and preparation method thereof suitable for road equipment
CN109971109A (en) * 2019-04-11 2019-07-05 广东科悦新材料有限公司 A kind of high sound-absorbing damping thermoplastic elastomer blend
CN110204809A (en) * 2019-04-17 2019-09-06 深圳市深捷通管业发展有限公司 A kind of Flame Retardant HDPE pipe and preparation method thereof
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CN111675846A (en) * 2020-06-13 2020-09-18 厦门毅兴行塑胶原料有限公司 Toughened PE (polyethylene) granules and preparation method and application thereof
CN111875865A (en) * 2020-08-03 2020-11-03 杭州科佳新材料股份有限公司 Super-flexible weather-resistant polyolefin special cable material and preparation method and application thereof
CN112012016A (en) * 2020-06-15 2020-12-01 江苏北化新橡新材料科技有限公司 Environment-friendly halogen-free polyolefin composite material for textilene mesh cloth and preparation method thereof
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CN113072813A (en) * 2021-03-18 2021-07-06 深圳市欧龙优新材料科技有限公司 High-temperature-resistant flexible polyolefin thermoplastic elastic material
CN114773712A (en) * 2022-05-24 2022-07-22 三杰节能新材料股份有限公司 Formula and manufacturing method of low-temperature-resistant flame-retardant outer protective pipe
CN115197489A (en) * 2022-06-10 2022-10-18 深圳市沃尔核材股份有限公司 Wire and cable material and preparation method thereof
CN117362803A (en) * 2023-10-30 2024-01-09 广东诚和信新材料有限公司 Flame-retardant PE composite material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1385466A (en) * 2001-05-16 2002-12-18 中国石油化工股份有限公司洛阳分公司 Novel thermoplastic elastomer and preparation process thereof
CN101161719A (en) * 2007-09-30 2008-04-16 上海金发科技发展有限公司 Special material for injection grade non-halogen flame-retardant wire plug and preparation method thereof
CN101177509A (en) * 2007-10-31 2008-05-14 华东理工大学 Polyolefin elastomer bottle cap lining material capable of being thermoplastically processed and preparation method thereof
CN101709132A (en) * 2009-08-24 2010-05-19 陕西易莱德新材料科技有限公司 Composite conductive polymer for flexible anode and preparation process thereof
CN103360663A (en) * 2013-07-06 2013-10-23 云南海燕建设有限公司 Waterproof roll of reactive sticky strong membrane and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1385466A (en) * 2001-05-16 2002-12-18 中国石油化工股份有限公司洛阳分公司 Novel thermoplastic elastomer and preparation process thereof
CN101161719A (en) * 2007-09-30 2008-04-16 上海金发科技发展有限公司 Special material for injection grade non-halogen flame-retardant wire plug and preparation method thereof
CN101177509A (en) * 2007-10-31 2008-05-14 华东理工大学 Polyolefin elastomer bottle cap lining material capable of being thermoplastically processed and preparation method thereof
CN101709132A (en) * 2009-08-24 2010-05-19 陕西易莱德新材料科技有限公司 Composite conductive polymer for flexible anode and preparation process thereof
CN103360663A (en) * 2013-07-06 2013-10-23 云南海燕建设有限公司 Waterproof roll of reactive sticky strong membrane and preparation method thereof

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104910573A (en) * 2015-06-26 2015-09-16 台橡（上海）实业有限公司 Thermoplastic elastomer medical film material
CN105037965A (en) * 2015-09-02 2015-11-11 大连科盟新材料有限公司 Halogen-free flame-retardant polyolefin thermoplastic elastomer
CN105273413A (en) * 2015-11-09 2016-01-27 安徽韧达高分子材料有限公司 Low-hardness high-strength TPE material and preparation method thereof
CN105273413B (en) * 2015-11-09 2018-04-13 安徽韧达高分子材料有限公司 A kind of soft high intensity TPE material and preparation method thereof
CN105295241B (en) * 2015-11-13 2018-02-02 宁波一舟塑胶有限公司 Ceramic polyvinyl chloride wire and cable material and preparation method thereof
CN105295241A (en) * 2015-11-13 2016-02-03 宁波一舟塑胶有限公司 Ceramic polyvinyl chloride wire and cable material and preparation method thereof
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