CN106977957A - It is a kind of specially to add TPE material of glass and preparation method thereof in encapsulated nylon - Google Patents
It is a kind of specially to add TPE material of glass and preparation method thereof in encapsulated nylon Download PDFInfo
- Publication number
- CN106977957A CN106977957A CN201710215983.4A CN201710215983A CN106977957A CN 106977957 A CN106977957 A CN 106977957A CN 201710215983 A CN201710215983 A CN 201710215983A CN 106977957 A CN106977957 A CN 106977957A
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- Prior art keywords
- parts
- glass
- tpe
- nylon
- thermoplastic elastomer
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- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 56
- 239000011521 glass Substances 0.000 title claims abstract description 32
- 239000004677 Nylon Substances 0.000 title claims abstract description 28
- 229920001778 nylon Polymers 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 62
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 229920000098 polyolefin Polymers 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 12
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 7
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims abstract 4
- 238000005303 weighing Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000012764 mineral filler Substances 0.000 claims description 6
- 239000008188 pellet Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 229920003188 Nylon 3 Polymers 0.000 claims 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical class C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229920000232 polyglycine polymer Polymers 0.000 claims 1
- 150000003440 styrenes Chemical class 0.000 description 20
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- 239000004416 thermosoftening plastic Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of TPE material and preparation method thereof for specially adding glass in encapsulated nylon, its raw material is as follows by weight：20 30 parts of styrene analog thermoplastic elastomer, 30 40 parts of white oil, 5 15 parts of polyolefin, 5 10 parts of polyolefin elastomer, 25 30 parts of compatilizer, 0 10 parts of filler.It is a kind of specially in TPE material of encapsulated nylon plus glass and preparation method thereof that the present invention is provided, surface of the higher polar component of concentration with nylon plus glass when the double materials of high temperature are moulded altogether in compatilizer make use of to form good adhesion, the problem of adhesion difference is easily peeled off when solving the encapsulated nylon of traditional TPE material plus glass, adds the purposes and commercial value of TPE material.
Description
Technical field
The present invention relates to TPE material technical field, more particularly to it is a kind of specially in encapsulated nylon add glass TPE material and its
Preparation method.
Background technology
Formula for encapsulated nylon (PA6, PA66) plus the TPE (thermoplastic elastomer (TPE)) of glass is typically by phenylethylene
The blend of the raw material such as thermoplastic elastomer (TPE) (SEBS), white oil, compatilizer and TPU (TPUE) composition,
Adhesive effect of such TPE intermingling materials when for moulding (i.e. encapsulated) altogether with the double materials of ABS, PC polar materials is fine, but
Adhesive effect when adding glass for encapsulated PA6 or PA66 is very poor, easily peels off, so limiting TPE material in encapsulated Buddhist nun
Application when dragon plus glass.Application solution of the TPE material when encapsulated nylon adds glass is the problem of we need to face.
The content of the invention
The invention aims to solve shortcoming present in prior art, and the one kind proposed specially adds in encapsulated nylon
TPE material of glass and preparation method thereof.
To achieve these goals, present invention employs following technical scheme：
A kind of specially to add the TPE material of glass in encapsulated nylon, its raw material is as follows by weight：Styrene analog thermoplastic elasticity
20-30 parts of body, 30-40 parts of white oil, 5-15 parts of polyolefin, 5-10 parts of polyolefin elastomer, 25-30 parts of compatilizer, filler 0-10
Part.
It is preferred that, the filler is mineral filler.
It is preferred that, the compatilizer is Polyolefin Grafted Maleic Anhydride.
It is a kind of specially in the preparation method of encapsulated nylon plus the TPE material of glass that the present invention is also provided, and comprises the following steps：
S1：Get the raw materials ready, each component raw material are weighed by weight ratio, are weighed in strict accordance with ratio, material is put after weighing
Purchase use；
S2：First the styrene analog thermoplastic elastomer for weighing up weight is added in high-speed stirred bucket, white oil is then added,
Allow styrene analog thermoplastic elastomer and white oil to be stirred 10 minutes in high-speed stirred bucket, promote styrene analog thermoplastic elastomer
Absorption to white oil；
S3：The addition of clout, then remaining raw material is separately added into, it is sufficiently mixed 10 minutes, obtains in high-speed stirred bucket
To mixing material；
S4：Mixing material is added in the hopper of double screw extruder, melting extrusion is heated by double screw extruder
Granulation, each area's temperature of extruder is set as between 150-220 DEG C, and TPE pellets are obtained after cooling.
It is a kind of specially in TPE material of encapsulated nylon plus glass and preparation method thereof that the present invention is provided, and make use of compatilizer
The higher polar component of middle concentration adds surface of the glass when the double materials of high temperature are moulded altogether to form good adhesion with nylon, solves
The problem of adhesion difference is easily peeled off when the encapsulated nylon of traditional TPE material adds glass, adds the purposes and business of TPE material
Value.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of specially to add the TPE material of glass in encapsulated nylon, its raw material is as follows by weight：Styrene analog thermoplastic elasticity
20 parts of body, 30 parts of white oil, 5 parts of polyolefin, 5 parts of polyolefin elastomer, 25 parts of compatilizer.
The filler is mineral filler.The compatilizer is Polyolefin Grafted Maleic Anhydride.
It is a kind of specially in the preparation method of encapsulated nylon plus the TPE material of glass that the present invention is also provided, and comprises the following steps：
S1：Get the raw materials ready, each component raw material are weighed by weight ratio, are weighed in strict accordance with ratio, material is put after weighing
Purchase use；
S2：First the styrene analog thermoplastic elastomer for weighing up weight is added in high-speed stirred bucket, white oil is then added,
Allow styrene analog thermoplastic elastomer and white oil to be stirred 10 minutes in high-speed stirred bucket, promote styrene analog thermoplastic elastomer
Absorption to white oil；
S3：The addition of clout, then remaining raw material is separately added into, it is sufficiently mixed 10 minutes, obtains in high-speed stirred bucket
To mixing material；
S4：Mixing material is added in the hopper of double screw extruder, melting extrusion is heated by double screw extruder
Granulation, each area's temperature of extruder is set as between 150-220 DEG C, and TPE pellets are obtained after cooling.
Embodiment 2
A kind of specially to add the TPE material of glass in encapsulated nylon, its raw material is as follows by weight：Styrene analog thermoplastic elasticity
24 parts of body, 34 parts of white oil, 10 parts of polyolefin, 7 parts of polyolefin elastomer, 26 parts of compatilizer, 4 parts of filler.
The filler is mineral filler.The compatilizer is Polyolefin Grafted Maleic Anhydride.
It is a kind of specially in the preparation method of encapsulated nylon plus the TPE material of glass that the present invention is also provided, and comprises the following steps：
S1：Get the raw materials ready, each component raw material are weighed by weight ratio, are weighed in strict accordance with ratio, material is put after weighing
Purchase use；
S2：First the styrene analog thermoplastic elastomer for weighing up weight is added in high-speed stirred bucket, white oil is then added,
Allow styrene analog thermoplastic elastomer and white oil to be stirred 10 minutes in high-speed stirred bucket, promote styrene analog thermoplastic elastomer
Absorption to white oil；
S3：The addition of clout, then remaining raw material is separately added into, it is sufficiently mixed 10 minutes, obtains in high-speed stirred bucket
To mixing material；
S4：Mixing material is added in the hopper of double screw extruder, melting extrusion is heated by double screw extruder
Granulation, each area's temperature of extruder is set as between 150-220 DEG C, and TPE pellets are obtained after cooling.
Embodiment 3
A kind of specially to add the TPE material of glass in encapsulated nylon, its raw material is as follows by weight：Styrene analog thermoplastic elasticity
28 parts of body, 38 parts of white oil, 13 parts of polyolefin, 8 parts of polyolefin elastomer, 28 parts of compatilizer, 8 parts of filler.
The filler is mineral filler.The compatilizer is Polyolefin Grafted Maleic Anhydride.
It is a kind of specially in the preparation method of encapsulated nylon plus the TPE material of glass that the present invention is also provided, and comprises the following steps：
S1：Get the raw materials ready, each component raw material are weighed by weight ratio, are weighed in strict accordance with ratio, material is put after weighing
Purchase use；
S2：First the styrene analog thermoplastic elastomer for weighing up weight is added in high-speed stirred bucket, white oil is then added,
Allow styrene analog thermoplastic elastomer and white oil to be stirred 10 minutes in high-speed stirred bucket, promote styrene analog thermoplastic elastomer
Absorption to white oil；
S3：The addition of clout, then remaining raw material is separately added into, it is sufficiently mixed 10 minutes, obtains in high-speed stirred bucket
To mixing material；
S4：Mixing material is added in the hopper of double screw extruder, melting extrusion is heated by double screw extruder
Granulation, each area's temperature of extruder is set as between 150-220 DEG C, and TPE pellets are obtained after cooling.
Embodiment 4
A kind of specially to add the TPE material of glass in encapsulated nylon, its raw material is as follows by weight：Styrene analog thermoplastic elasticity
30 parts of body, 40 parts of white oil, 15 parts of polyolefin, 10 parts of polyolefin elastomer, 30 parts of compatilizer, 10 parts of filler.
The filler is mineral filler.The compatilizer is Polyolefin Grafted Maleic Anhydride.
It is a kind of specially in the preparation method of encapsulated nylon plus the TPE material of glass that the present invention is also provided, and comprises the following steps：
S1：Get the raw materials ready, each component raw material are weighed by weight ratio, are weighed in strict accordance with ratio, material is put after weighing
Purchase use；
S2：First the styrene analog thermoplastic elastomer for weighing up weight is added in high-speed stirred bucket, white oil is then added,
Allow styrene analog thermoplastic elastomer and white oil to be stirred 10 minutes in high-speed stirred bucket, promote styrene analog thermoplastic elastomer
Absorption to white oil；
S3：The addition of clout, then remaining raw material is separately added into, it is sufficiently mixed 10 minutes, obtains in high-speed stirred bucket
To mixing material；
S4：Mixing material is added in the hopper of double screw extruder, melting extrusion is heated by double screw extruder
Granulation, each area's temperature of extruder is set as between 150-220 DEG C, and TPE pellets are obtained after cooling.
Various raw material proportionings difference can obtain the material of different performance, different ratio is combined into
Row test, obtains performance table as follows：
It is a kind of specially in TPE material of encapsulated nylon plus glass and preparation method thereof that the present invention is provided, and make use of compatilizer
The higher polar component of middle concentration adds surface of the glass when the double materials of high temperature are moulded altogether to form good adhesion with nylon, solves
The problem of adhesion difference is easily peeled off when the encapsulated nylon of traditional TPE material adds glass, adds the purposes and business of TPE material
Value.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (4)
1. a kind of specially add TPE material of glass and preparation method thereof in encapsulated nylon, it is characterised in that：Its raw material is by weight such as
Under：20-30 parts of styrene analog thermoplastic elastomer, 30-40 parts of white oil, 5-15 parts of polyolefin, 5-10 parts of polyolefin elastomer, phase
Hold 25-30 parts of agent, 0-10 parts of filler.
A kind of specially add the TPE material of glass in encapsulated nylon 2. according to claim 1, it is characterised in that：The filler
For mineral filler.
A kind of specially add the TPE material of glass in encapsulated nylon 3. according to claim 1, it is characterised in that：It is described compatible
Agent is Polyolefin Grafted Maleic Anhydride.
4. special described in a kind of claim 1 adds the preparation method of the TPE material of glass in encapsulated nylon, it is characterised in that：Bag
Include following steps：
S1：Get the raw materials ready, each component raw material are weighed by weight ratio, are weighed in strict accordance with ratio, material places standby after weighing
With；
S2：First the styrene analog thermoplastic elastomer for weighing up weight is added in high-speed stirred bucket, white oil is then added, allows benzene
Ethene analog thermoplastic elastomer and white oil are stirred 10 minutes in high-speed stirred bucket, promote styrene analog thermoplastic elastomer dialogue
The absorption of oil；
S3：The addition of clout, then remaining raw material is separately added into, it is sufficiently mixed 10 minutes, is mixed in high-speed stirred bucket
Condensation material；
S4：Mixing material is added in the hopper of double screw extruder, heating melting extrusion by double screw extruder granulates,
Each area's temperature of extruder is set as between 150-220 DEG C, and TPE pellets are obtained after cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710215983.4A CN106977957A (en) | 2017-04-01 | 2017-04-01 | It is a kind of specially to add TPE material of glass and preparation method thereof in encapsulated nylon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710215983.4A CN106977957A (en) | 2017-04-01 | 2017-04-01 | It is a kind of specially to add TPE material of glass and preparation method thereof in encapsulated nylon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106977957A true CN106977957A (en) | 2017-07-25 |
Family
ID=59345102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710215983.4A Pending CN106977957A (en) | 2017-04-01 | 2017-04-01 | It is a kind of specially to add TPE material of glass and preparation method thereof in encapsulated nylon |
Country Status (1)
| Country | Link |
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| CN (1) | CN106977957A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474560A (en) * | 2017-09-08 | 2017-12-15 | 绵阳凤面科技有限公司 | A kind of TPE material for specially adding glass in encapsulated nylon and preparation method thereof |
| CN108017917A (en) * | 2017-12-07 | 2018-05-11 | 遂宁市明川零贰零科技有限公司 | A kind of TPE material for specially adding glass in encapsulated nylon and preparation method thereof |
| CN109777092A (en) * | 2019-02-25 | 2019-05-21 | 江阴市龙山合成材料有限公司 | It is a kind of it is high flowing can be used for double-shot moulding PA6 modified material and preparation method thereof |
| WO2020000588A1 (en) * | 2018-06-26 | 2020-01-02 | 南通普力马弹性体技术有限公司 | Thermoplastic elastomer material |
| CN111073311A (en) * | 2019-12-23 | 2020-04-28 | 南京文斯特新材料有限公司 | Novel TPE nylon encapsulating material and preparation method thereof |
| CN111117052A (en) * | 2019-12-30 | 2020-05-08 | 顶塑实业（广东）有限公司 | Ultralow-hardness food contact thermoplastic elastomer and preparation method thereof |
| CN112694761A (en) * | 2020-12-25 | 2021-04-23 | 南京文斯特新材料有限公司 | High-fluidity high-binding-force TPE (thermoplastic elastomer) nylon encapsulated granules and preparation method thereof |
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| CN1930237A (en) * | 2004-03-05 | 2007-03-14 | Gls公司 | Block copolymer compositions for overmolding any nylon |
| CN102898764A (en) * | 2011-07-27 | 2013-01-30 | 上海凯波特种电缆料厂有限公司 | Super cold resistant and torsion tolerant elastomer TPE sheath material for wind power cables and preparation method thereof |
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| CN1930237A (en) * | 2004-03-05 | 2007-03-14 | Gls公司 | Block copolymer compositions for overmolding any nylon |
| CN102898764A (en) * | 2011-07-27 | 2013-01-30 | 上海凯波特种电缆料厂有限公司 | Super cold resistant and torsion tolerant elastomer TPE sheath material for wind power cables and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474560A (en) * | 2017-09-08 | 2017-12-15 | 绵阳凤面科技有限公司 | A kind of TPE material for specially adding glass in encapsulated nylon and preparation method thereof |
| CN108017917A (en) * | 2017-12-07 | 2018-05-11 | 遂宁市明川零贰零科技有限公司 | A kind of TPE material for specially adding glass in encapsulated nylon and preparation method thereof |
| WO2020000588A1 (en) * | 2018-06-26 | 2020-01-02 | 南通普力马弹性体技术有限公司 | Thermoplastic elastomer material |
| CN109777092A (en) * | 2019-02-25 | 2019-05-21 | 江阴市龙山合成材料有限公司 | It is a kind of it is high flowing can be used for double-shot moulding PA6 modified material and preparation method thereof |
| CN109777092B (en) * | 2019-02-25 | 2021-06-22 | 江阴市龙山合成材料有限公司 | High-fluidity PA6 modified material capable of being used for double-color injection molding and preparation method thereof |
| CN111073311A (en) * | 2019-12-23 | 2020-04-28 | 南京文斯特新材料有限公司 | Novel TPE nylon encapsulating material and preparation method thereof |
| CN111117052A (en) * | 2019-12-30 | 2020-05-08 | 顶塑实业（广东）有限公司 | Ultralow-hardness food contact thermoplastic elastomer and preparation method thereof |
| CN112694761A (en) * | 2020-12-25 | 2021-04-23 | 南京文斯特新材料有限公司 | High-fluidity high-binding-force TPE (thermoplastic elastomer) nylon encapsulated granules and preparation method thereof |
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Application publication date: 20170725 |