CN102634105B - Soft halogen-free flame-retardant cable material - Google Patents
Soft halogen-free flame-retardant cable material Download PDFInfo
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- CN102634105B CN102634105B CN201110036169.9A CN201110036169A CN102634105B CN 102634105 B CN102634105 B CN 102634105B CN 201110036169 A CN201110036169 A CN 201110036169A CN 102634105 B CN102634105 B CN 102634105B
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- Prior art keywords
- retardant cable
- type non
- halogen flame
- soft type
- parts
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 38
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000000463 material Substances 0.000 title abstract description 14
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 19
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 6
- 239000000314 lubricant Substances 0.000 claims abstract description 6
- 230000002195 synergetic effect Effects 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 32
- 229910052736 halogen Inorganic materials 0.000 claims description 26
- 150000002367 halogens Chemical class 0.000 claims description 26
- 239000003921 oil Substances 0.000 claims description 11
- 239000003112 inhibitor Substances 0.000 claims description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 9
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 8
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 8
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 8
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000005662 Paraffin oil Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 claims description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 5
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 239000012796 inorganic flame retardant Substances 0.000 abstract 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 8
- 238000012360 testing method Methods 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- MSAVICZWFPQFPO-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.C=C.CC(O)=O MSAVICZWFPQFPO-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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- Insulated Conductors (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
A soft halogen-free flame-retardant cable material comprises the following components by weight: 20-40 parts of polyolefin resin, 1-10 parts of thermoplastic elastomers, 1-10 parts of filling oil, 2-10 parts of compatilizers, 40-60 parts of inorganic flame retardants, 3-10 parts of synergistic flame retardants, 1-5 parts of lubricants, 0.4-1.2 parts of coupling agents, and 0.1-0.5 parts of anti-oxidants. By blending of the low-hardness thermoplastic elastomer and the polyolefin resin, the soft halogen-free flame-retardant cable material of the invention not only has maintained good mechanical properties, but also has greatly improved softness, and the application range of the cable material is expanded.
Description
[technical field]
The present invention relates to a kind of CABLE MATERIALS, be specifically related to a kind of soft type non-halogen flame-retardant cable.
[background technology]
Because polyolefine has that relative density is little, the feature such as chemical proofing, water-tolerant, good physical strength, electrical insulating property, there is elasticity and simultaneously can keep the polyolefin compositions of good thermoplastic property to be widely used in various fields, for example, can be used for film, tubing, sheet material, various moulded products, electric wire medium.
When polyolefine is applied in electric wire, polyolefine non-halogen flame-retardant cable is in order to increase its flame retardant resistance, can fill a large amount of inorganic type fire retardant materials, as magnesium hydroxide, aluminium hydroxide etc. is used for fire-retardant, but when inserting a large amount of inorganic anti-flaming material, cause cable material hardness to increase, be not suitable for the occasion of requirement cable softness.
In view of this, be necessary to develop in fact a kind of soft type non-halogen flame-retardant cable, this soft type non-halogen flame-retardant cable, outside the good mechanical property of maintenance, has improved its pliability, has expanded the use range of CABLE MATERIALS.
[summary of the invention]
Therefore, the object of this invention is to provide a kind of soft type non-halogen flame-retardant cable, this soft type non-halogen flame-retardant cable, outside the good mechanical property of maintenance, has improved its pliability, has expanded the use range of CABLE MATERIALS.
In order to achieve the above object, soft type non-halogen flame-retardant cable of the present invention, its composition represents to comprise by weight:
20～40 parts of polyolefin resines
1～10 part of thermoplastic elastomer
1～10 part of extending oil
2～10 parts of compatilizers
40～60 parts of inorganic combustion inhibitors
3～10 parts of synergistic flame retardants
1～5 part of lubricant
0.4～1.2 part of coupling agent
0.1～0.5 part, oxidation inhibitor.
Preferably, said polyolefins resin is one or more mixtures in ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-octene copolymer.
Preferably, above-mentioned thermoplastic elastomer is a kind of or its mixture in styrene analog thermoplastic elastomer, polyethylene kind thermoplastic elastomer.
Preferably, above-mentioned extending oil is a kind of or its mixture in paraffin oil, naphthenic oil.
Preferably, above-mentioned compatilizer is a kind of or its mixture in POE-g-MAH (maleic anhydride functional group grafted ethene-octene copolymer), EVA-g-MAH (maleic anhydride functional group grafted ethene-acetate ethylene copolymer).
Preferably, above-mentioned inorganic combustion inhibitor is a kind of or its mixture in magnesium hydroxide, aluminium hydroxide.
Preferably, above-mentioned synergistic flame retardant is one or more mixtures in zinc borate, zinc oxide, red phosphorus.
Preferably, above-mentioned lubricant is one or more mixtures in EBS (ethylene bis stearic acid amide), Zinic stearas, calcium stearate, polyethylene wax.
Preferably, above-mentioned coupling agent is one or more mixtures in silane coupling agent KH172, Silane coupling agent KH550, silane coupling agent KH171.
Preferably, above-mentioned oxidation inhibitor is one or more mixtures in antioxidant 1010, antioxidant 1076, irgasfos 168.
Preferably, this its composition of soft type non-halogen flame-retardant cable represents to comprise by weight:
23 parts of ethylene-vinyl acetate copolymers
5 parts of styrene analog thermoplastic elastomers
5 parts of paraffin oils
3.5 parts of POE-g-MAH
57 parts of magnesium hydroxides
3.5 parts of zinc borates
2 parts of EBS
0.5 part of KH172
0.5 part of antioxidant 1010.
Preferably, this its composition of soft type non-halogen flame-retardant cable represents to comprise by weight:
31 parts of ethylene-octene copolymers
5 parts of styrene analog thermoplastic elastomers
5 parts of paraffin oils
3 parts of POE-g-MAH
25 parts of magnesium hydroxides
25 parts, aluminium hydroxide
3 parts of zinc borates
2 parts of EBS
0.5 part of KH172
0.5 part of antioxidant 1010.
Soft type non-halogen flame-retardant cable of the present invention, by adopting soft thermoplastic elastomer and polyolefin resin blend, outside the good mechanical property of maintenance, its flexibility is promoted greatly, has expanded the use range of CABLE MATERIALS.
[embodiment]
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
Get various added ingredientss, in the present embodiment, polyolefin resin adopts ethylene-vinyl acetate copolymer, and thermoplastic elastomer adopts styrene analog thermoplastic elastomer, extending oil adopts paraffin oil, compatilizer adopts POE-g-MAH, and inorganic combustion inhibitor adopts magnesium hydroxide, and synergistic flame retardant adopts zinc borate, lubricant adopts EBS, coupling agent adopts silane coupling agent KH172, and oxidation inhibitor adopts antioxidant 1010, by following compositing formula, all raw materials is carried out to blend:
23 parts of ethylene-vinyl acetate copolymers
5 parts of styrene analog thermoplastic elastomers
5 parts of paraffin oils
3.5 parts of POE-g-MAH
57 parts of magnesium hydroxides
3.5 parts of zinc borates
2 parts of EBS
0.5 part of KH172
0.5 part of antioxidant 1010
Again this blend composition is passed through to forcing machine mixing granulator, gained mixing granulator is made finished product through injection molding, and finally, by mechanical property, oxygen index, the shore hardness of national standard test gained finished product, result is as shown in table 1:
The performance data table of the soft type non-halogen flame-retardant cable that table 1: embodiment 1 provides
| Performance | Testing method | Test result |
| Tensile strength/MPa (200mm/min) | GB/T1040-2006 | 10.6 |
| Elongation at break/(200mm/min) | GB/T1040-2006 | 187 |
| Oxygen index | GB/T2408-2009 | 37 |
| Shore hardness | - | 92A |
Embodiment 2
Get various added ingredientss, in the present embodiment, polyolefin resin adopts ethylene-vinyl acetate copolymer, and thermoplastic elastomer adopts styrene analog thermoplastic elastomer, extending oil adopts paraffin oil, compatilizer adopts POE-g-MAH, and inorganic combustion inhibitor adopts the mixture of magnesium hydroxide and aluminium hydroxide, and synergistic flame retardant adopts zinc borate, lubricant adopts EBS, coupling agent adopts silane coupling agent KH172, and oxidation inhibitor adopts antioxidant 1010, by following compositing formula, all raw materials is carried out to blend:
31 parts of ethylene-octene copolymers
5 parts of styrene analog thermoplastic elastomers
5 parts of paraffin oils
3 parts of POE-g-MAH
25 parts of magnesium hydroxides
25 parts, aluminium hydroxide
3 parts of zinc borates
2 parts of EBS
0.5 part of KH172
0.5 part of antioxidant 1010
Again this blend composition is passed through to forcing machine mixing granulator, gained mixing granulator is made finished product through injection molding, and finally, by mechanical property, oxygen index, the shore hardness of national standard test gained finished product, result is as shown in table 2:
The performance data table of the soft type non-halogen flame-retardant cable that table 2: embodiment 2 provides
| Performance | Testing method | Test result |
| Tensile strength/MPa (200mm/min) | GB/T1040-2006 | 9.5 |
| Elongation at break/(200mm/min) | GB/T1040-2006 | 220 |
| Oxygen index | GB/T2408-2009 | 30 |
| Shore hardness | - | 88A |
Compared to prior art, soft type non-halogen flame-retardant cable of the present invention is by adopting soft thermoplastic elastomer and polyolefin resin blend, outside keeping its good mechanical property, the pliability of this CABLE MATERIALS is greatly improved, thereby has expanded the use range of CABLE MATERIALS.
Claims (9)
1. a soft type non-halogen flame-retardant cable, is characterized in that, this its composition of soft type non-halogen flame-retardant cable represents to comprise by weight:
Described extending oil is a kind of or its mixture in paraffin oil, naphthenic oil, described inorganic combustion inhibitor is a kind of or its mixture in magnesium hydroxide, aluminium hydroxide, and described polyolefin resin is one or more mixtures in ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-octene copolymer.
2. soft type non-halogen flame-retardant cable according to claim 1, is characterized in that, described thermoplastic elastomer is a kind of or its mixture in styrene analog thermoplastic elastomer, polyethylene kind thermoplastic elastomer.
3. soft type non-halogen flame-retardant cable according to claim 1, is characterized in that, described compatilizer is a kind of or its mixture in POE-g-MAH, EVA-g-MAH.
4. soft type non-halogen flame-retardant cable according to claim 1, is characterized in that, described synergistic flame retardant is one or more mixtures in zinc borate, zinc oxide, red phosphorus.
5. soft type non-halogen flame-retardant cable according to claim 1, is characterized in that, described lubricant is one or more mixtures in EBS, Zinic stearas, calcium stearate, polyethylene wax.
6. soft type non-halogen flame-retardant cable according to claim 1, is characterized in that, described coupling agent is one or more mixtures in silane coupling agent KH172, Silane coupling agent KH550, silane coupling agent KH171.
7. soft type non-halogen flame-retardant cable according to claim 1, is characterized in that, described oxidation inhibitor is one or more mixtures in antioxidant 1010, antioxidant 1076, irgasfos 168.
8. according to the soft type non-halogen flame-retardant cable described in any one in claim 1 to 7, it is characterized in that, this its composition of soft type non-halogen flame-retardant cable represents to comprise by weight:
9. according to the soft type non-halogen flame-retardant cable described in any one in claim 1 to 7, it is characterized in that, this its composition of soft type non-halogen flame-retardant cable represents to comprise by weight:
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110036169.9A CN102634105B (en) | 2011-02-11 | 2011-02-11 | Soft halogen-free flame-retardant cable material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110036169.9A CN102634105B (en) | 2011-02-11 | 2011-02-11 | Soft halogen-free flame-retardant cable material |
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| Publication Number | Publication Date |
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| CN102634105A CN102634105A (en) | 2012-08-15 |
| CN102634105B true CN102634105B (en) | 2014-07-16 |
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| CN201110036169.9A Expired - Fee Related CN102634105B (en) | 2011-02-11 | 2011-02-11 | Soft halogen-free flame-retardant cable material |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102942734B (en) * | 2012-11-07 | 2014-08-13 | 扬州市好年华橡塑有限公司 | Flexible environment-friendly polyolefin cable material and preparation method of flexible environment-friendly polyolefin cable material |
| CN103374820A (en) * | 2013-07-26 | 2013-10-30 | 浙江鹏远新材料有限公司 | Antiskid woven cloth and preparation method thereof |
| CN103554621A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Modified polyethylene insulation material for refrigerator wire harnesses |
| CN103554644A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Modified EVA (ethylene-vinyl acetate) insulating material for damp-proof abrasion-resistance automobile wire harness |
| CN104177693A (en) * | 2014-08-20 | 2014-12-03 | 马鞍山市科宏塑业科技实业发展有限公司 | Halogen-free flame retardant polyethylene material and preparation method thereof |
| CN104403252A (en) * | 2014-11-17 | 2015-03-11 | 宁波市青湖弹性体科技有限公司 | Flexible halogen-free and flame-retardant TPE (thermoplastic elastomer) with low smoke density and preparation method of TPE |
| CN105778387B (en) * | 2014-12-18 | 2018-08-14 | 上海凯波特种电缆料厂有限公司 | A kind of 125 DEG C of halogen-free flame retarding elastomer material of thermoplasticity and preparation method thereof |
| CN104893070A (en) * | 2015-06-09 | 2015-09-09 | 苏州圣谱拉新材料科技有限公司 | High-temperature-resistant and corrosion-resistant polymer material |
| CN105440653B (en) * | 2015-12-30 | 2018-10-19 | 青岛科技大学 | Application of the silane coupling agent as fire retardant in flame retardant thermoplastic |
| CN109294148A (en) * | 2016-12-07 | 2019-02-01 | 中广核高新核材科技（苏州）有限公司 | The irradiation crosslinked polyolefin insulating material of low heat release high-temperature resistant |
| CN114672099B (en) * | 2022-02-22 | 2023-08-29 | 金发科技股份有限公司 | Magnesium hydroxide master batch and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486819A (en) * | 2009-03-05 | 2009-07-22 | 黑龙江沃尔德电缆有限公司 | Optical crosslinking halogen-free flame-retardant EPT rubber cable material and preparation thereof |
| CN101831100A (en) * | 2010-04-26 | 2010-09-15 | 大连圣迈新材料有限公司 | Low-smoke halogen-free flame retardant electronic wire material |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1286895C (en) * | 2003-12-16 | 2006-11-29 | 深圳市沃尔核材股份有限公司 | Halogen-free flame-retardant thermal-shrinkage sleeve materials and sleeve prepared thereby |
| JP5144007B2 (en) * | 2004-12-22 | 2013-02-13 | 古河電気工業株式会社 | Flame retardant resin composition and molded article using the same |
| CN101225224A (en) * | 2008-02-03 | 2008-07-23 | 银禧工程塑料（东莞）有限公司 | low-smoke halogen-free flame retardant thermoplastic elastomer alloy for flexible wire rod and preparation method thereof |
| CN101570618B (en) * | 2008-04-30 | 2010-10-27 | 北京诚联恺达科技有限公司 | Preparation method of thermotolerant high-elasticity halogen-free flame-resistant thermoplastic elastomer |
-
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486819A (en) * | 2009-03-05 | 2009-07-22 | 黑龙江沃尔德电缆有限公司 | Optical crosslinking halogen-free flame-retardant EPT rubber cable material and preparation thereof |
| CN101831100A (en) * | 2010-04-26 | 2010-09-15 | 大连圣迈新材料有限公司 | Low-smoke halogen-free flame retardant electronic wire material |
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