CN104719305A - Bactericidal composition containing sedaxane and triazole - Google Patents
Bactericidal composition containing sedaxane and triazole Download PDFInfo
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- CN104719305A CN104719305A CN201310719763.7A CN201310719763A CN104719305A CN 104719305 A CN104719305 A CN 104719305A CN 201310719763 A CN201310719763 A CN 201310719763A CN 104719305 A CN104719305 A CN 104719305A
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Abstract
The invention discloses a bactericidal composition containing sedaxane and triazole. Effective active ingredients of the bactericidal composition consist of an active ingredient A and an active ingredient B, wherein the active ingredient A is sedaxane, the active ingredient B is triticonazole, ipconazole or prothioconazole, and the weight ratio of the active ingredient A to the active ingredient B is (1: 80) to (80: 1). The composition disclosed by the invention has relatively high activity to various diseases of a variety of crops and has an obvious synergistic effect, and the bactericidal spectrum is enlarged; the composition has the characteristics of small dosage, rainwater washing resistance and obvious synergism.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application of bactericidal composition in crop pest of a kind of fluorine-containing azoles ring bacterium amine and triazole type.
Technical background
Fluorine azoles ring bacterium amine (sedaxane), causes effect by suppressing germ succinate dehydrogenase.
In the real process of agricultural production, the problem that controlling disease the most easily produces is the generation of disease drug resistance.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistance disease.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect clearly, very high composite just less of synergy ratio.Study through inventor, find fluorine azoles ring bacterium amine and triticonazole, plant bacterium azoles or prothioconazoles is mutually composite, have good synergistic effect within the specific limits, and about fluorine azoles ring bacterium amine and triticonazole, plant bacterium azoles or prothioconazoles is relevant composite, there is not yet relevant report at home and abroad at present.
Summary of the invention
The object of the invention is to propose a kind of bactericidal composition with synergistic function, use cost is low, preventive effect is good fluorine-containing azoles ring bacterium amine and triazole type.
The present invention is achieved through the following technical solutions:
The bactericidal composition of a kind of fluorine-containing azoles ring bacterium amine and triazole type, containing active components A and active component B, active components A and active component B weight ratio are 1: 80 ~ 80: 1, and described active components A is selected from fluorine azoles ring bacterium amine, and active component B is selected from triticonazole, plants bacterium azoles or prothioconazoles; The weight ratio being preferably active components A and active component B is 1: 60 ~ 60: 1; The weight ratio being more preferably fluorine azoles ring bacterium amine and triticonazole is 1: 10 ~ 20: 1, and fluorine azoles ring bacterium amine is 1: 20 ~ 10: 1 with the weight ratio of kind bacterium azoles, and the weight ratio of fluorine azoles ring bacterium amine and prothioconazoles is 1: 10 ~ 20: 1.
Bactericidal composition of the present invention, can be processed into acceptable formulation in any sterilization on demand, wherein more preferably formulation is suspension seed-coating agent, wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, suspension emulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
Described fluorine-containing azoles ring bacterium amine and the bactericidal composition of triazole type are for preventing and treating the disease of crop; Described crop is cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop; Described disease is smut, powdery mildew, banded sclerotial blight, rust, apple scab, net blotch, root rot, damping off, bakanae disease, rice blast.
In bactericidal composition of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, simultaneously also relevant with target disease.In usual composition, the weight percentage of active component is 1% ~ 90% of gross weight, is preferably 5% ~ 80%.According to different preparation types, active component content scope is different.Liquids in general preparation contains the active substance of by weight 1% ~ 60%, is preferably 5% ~ 50%; Solid pharmaceutical preparation contains the active substance of by weight 5% ~ 80%, is preferably 10% ~ 80%.
At least containing a kind of surfactant in bactericidal composition of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 2% ~ 30% of total formulation weight amount, and surplus is solid or liquid diluent.
Bactericidal composition of the present invention can by user before use through diluting or directly using.Its preparation can be prepared by processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active component, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, disintegrant, defoamer etc.According to different dosage form, can also containing antifreeze known in those skilled in the art etc. in preparation.
Composition comprises following constituent content when making suspension seed-coating agent: active components A 0.1% ~ 50%, active ingredient B0.1% ~ 50%, wetting agent 1.0% ~ 3.0%, dispersant 1.0% ~ 8.0%, film forming agent 0.5% ~ 5%, warning colouration 0.1% ~ 15%, antifreeze 3% ~ 10%, thickener 0.05% ~ 2.0%, defoamer 0.01% ~ 2%, water add to 100%.
Composition comprises following component and content when making wetting powder: active components A 0.1% ~ 80%, active component B0.1% ~ 80%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, filler surplus.
Composition comprises following component and content when making water dispersible granules: active components A 0.1% ~ 80%, active component B0.1% ~ 80%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Composition comprises following component and content when making suspending agent: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, dispersant 1% ~ 10%, wetting agent 1% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Composition comprises following component and content when making suspension emulsion: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, emulsifier 1% ~ 10%, dispersant 1% ~ 10%, solvent 1% ~ 20%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Composition comprises following component and content when making aqueous emulsion: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, solvent 1% ~ 20%, emulsifier 1% ~ 12%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microemulsion: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Suspension seed-coating agent the key technical indexes of the present invention:
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
The invention has the advantages that:
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose; (2) pesticide usage amount reduces, and reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution; (3) fungicidal spectrum is expanded, to multiple diseases as smut, powdery mildew, banded sclerotial blight, rust, apple scab, net blotch, root rot, damping off, bakanae disease, rice blast etc. have greater activity.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1 ~ 9 suspension seed-coating agent
By wetting agent, dispersant, film forming agent, warning colouration, antifreeze (can add and can not add), thickener (can add and can not add), defoamer, mix through high speed shear, add trifluoro-benzene pyrimidine, active component B, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, surplus deionized water is supplied, and can obtain of the present invention kind of clothing suspending agent product, specifically in table 1,2.
The each component of table 1 embodiment 1 ~ 4 and content
The each component of table 2 embodiment 5 ~ 9 and content
Embodiment 10 ~ 18 wetting powder
By fluorine azoles ring bacterium amine, active component B, dispersant, wetting agent, filler mixing, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, namely can be made into wetting powder product of the present invention.Specifically in table 3.
The each component of table 3 embodiment 10 ~ 18 and content
Embodiment 19 ~ 27 water dispersible granules
Fluorine azoles ring bacterium amine, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained together the particle diameter needed through air-flow crushing, then add other auxiliary agents such as binding agent (can add and can not add), obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, water dispersible granules product of the present invention can being obtained, specifically in table 4.
The each component of table 4 embodiment 19 ~ 27 and content
Embodiment 28 ~ 36 suspending agent
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), mix through high speed shear, add fluorine azoles ring bacterium amine, active component B, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, surplus deionized water is supplied, and can obtain suspending agent product of the present invention, specifically in table 5.
The each component of table 5 embodiment 28 ~ 36 and content
Embodiment 37 ~ 45 aqueous emulsion
Fluorine azoles ring bacterium amine, active component B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, obtained aqueous emulsion product of the present invention.Specifically in table 6.
The each component of table 6 embodiment 37 ~ 45 and content
Embodiment 46 ~ 54 microemulsion
Fluorine azoles ring bacterium amine, active component B are dissolved in and are equipped with in the homogenizer of solvent, by emulsifier, antifreeze (can add and can not add), defoamer, join above-mentioned solution is housed homogenizer in, surplus deionized water gives strong mixing and homogenize after supplying, finally obtain the microemulsion product of the present invention that clear appearance is transparent.Specifically in table 7.
The each component of table 7 embodiment 46 ~ 54 and content
Active component triticonazole, kind bacterium azoles, prothioconazoles in table 1 ~ 7 are exchanged, can novel formulation be obtained.
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field trial.
Test method: determine that after the effective inhibition concentration scope of each medicament, medicament establishes 5 dosage process respectively by active constituent content through prerun, if clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelial growth rate method to measure medicament to the virulence of crop germ.Measure colony diameter by right-angled intersection method after 72h, calculate each process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value to (x), tries to achieve virulence regression equation (y=a+bx), and calculate the EC of often kind of medicament thus with method of least squares
50value.Calculate two medicament different ratio synergies ratio (SR) according to Wadley method, SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action simultaneously, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active components A and the ratio of active component B shared by combination;
A is fluorine azoles ring bacterium amine;
B is selected from triticonazole, the one of planting in bacterium azoles, prothioconazoles.
Application Example two:
For examination disease: smut of maize, test medicine provides by Shaanxi Meibang Pesticide Co., Ltd., experimental scheme: through effective inhibition concentration scope of both preliminary experiment determination fluorine azoles ring bacterium amine and triticonazole different ratio mixture.
Toxicity test result
Table 8 fluorine azoles ring bacterium amine and the composite toxicity test analysis of results table to smut of maize of triticonazole
As shown in Table 8, the proportioning of fluorine azoles ring bacterium amine and the composite control of maize smut of triticonazole is when 1 ︰ 80 ~ 80 ︰ 1, synergy ratio SR is all greater than 1.5, both explanations mixture in 1 ︰ 80 ~ 80 ︰ 1 scope all shows synergistic effect, the proportioning of fluorine azoles ring bacterium amine and triticonazole is 1: 10 ~ 20: 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.30.Testing through applicant the proportioning finding fluorine azoles ring bacterium amine and triticonazole is 20 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 5,1 ︰ 10, when wherein fluorine azoles ring bacterium amine and triticonazole weight ratio are 9:1, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example three:
For examination disease: rice blast, test medicine provides by Shaanxi Meibang Pesticide Co., Ltd., experimental scheme: through preliminary experiment determination fluorine azoles ring bacterium amine and effective inhibition concentration scope of planting the former medicine of bacterium azoles and the two different ratio mixture.
Toxicity test result
Table 9 fluorine azoles ring bacterium amine and the composite toxicity test analysis of results table to rice blast of kind bacterium azoles
As shown in Table 9, the proportioning of fluorine azoles ring bacterium amine and the composite control rice blast of kind bacterium azoles is when 1 ︰ 80 ~ 80 ︰ 1, synergy ratio SR is all greater than 1.5, both explanations mixture in 1 ︰ 80 ~ 80 ︰ 1 scope all shows synergistic effect, the proportioning of fluorine azoles ring bacterium amine and kind bacterium azoles is 1: 20 ~ 10: 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.30.Testing through applicant the proportioning finding fluorine azoles ring bacterium amine and plant bacterium azoles is 10 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 20, when wherein fluorine azoles ring bacterium amine is 1:4 with kind bacterium azoles weight ratio, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example four:
For examination disease: wheat sharp eyespot, test medicine provides by Shaanxi Meibang Pesticide Co., Ltd., experimental scheme: through effective inhibition concentration scope of preliminary experiment determination fluorine azoles ring bacterium amine and the former medicine of prothioconazoles and the two different ratio mixture.
Toxicity test result
Table 10 fluorine azoles ring bacterium amine and the composite toxicity test analysis of results table to wheat sharp eyespot of prothioconazoles
As shown in Table 10, the proportioning of fluorine azoles ring bacterium amine and the composite control wheat sharp eyespot of prothioconazoles is when 1 ︰ 80 ~ 80 ︰ 1, synergy ratio SR is all greater than 1.5, both explanations mixture in 1 ︰ 80 ~ 80 ︰ 1 scope all shows synergistic effect, the proportioning of fluorine azoles ring bacterium amine and prothioconazoles is 1: 10 ~ 20: 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25.Testing through applicant the proportioning finding fluorine azoles ring bacterium amine and prothioconazoles is 20 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 5,1 ︰ 10, when wherein fluorine azoles ring bacterium amine and prothioconazoles weight ratio are 4:1, synergy ratio is maximum, and synergistic effect is the most obvious.
Through test find: fluorine azoles ring bacterium amine and active component B composite after have obvious synergistic effect to the control of the smut in various crop, powdery mildew, banded sclerotial blight, rust, apple scab, net blotch, root rot, damping off, bakanae disease, rice blast, synergy ratio is all more than 1.5.
Effect experiment part: test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 3% fluorine azoles ring bacterium amine suspension seed-coating agent (commercial), 25g/L triticonazole suspension seed-coating agent (commercial), 10% kind of bacterium azole suspending agent (autogamy), 25% prothioconazoles missible oil (commercial).
Application Example five fluorine azoles ring bacterium amine and active component B and the composite control rice blast test of pesticide effectiveness thereof
This experimental establishment is at Shaanxi Province's Hanzhong City, and seed treatment is seed soaking prior to seeding.The investigation rice blast state of an illness before spray agent uses, in the first time dispenser of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times.Within after second time dispenser 7 days, 14 days, 30 days, investigate disease index respectively and calculate preventive effect.Experimental result is as follows:
Table 11 fluorine azoles ring bacterium amine and active component B and the composite control rice blast test of pesticide effectiveness thereof
As can be seen from Table 11, fluorine azoles ring bacterium amine and active component B and composite after effectively can prevent and treat rice blast, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example hexafluoro azoles ring bacterium amine and active component B and compositely prevent and treat the wheat rust test of pesticide effectiveness
This test arrangement is at Shaanxi Province's Weinan City, and seed treatment is seed soaking prior to seeding.The investigation wheat rust state of an illness before spray agent uses, in the first time dispenser of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times.Within after second time dispenser 3 days, 7 days, 15 days, investigate disease index respectively and calculate preventive effect.Experimental result is as follows:
Table 12 fluorine azoles ring bacterium amine and active component B and compositely prevent and treat the wheat rust test of pesticide effectiveness
As can be seen from Table 12, fluorine azoles ring bacterium amine and active component B and composite after effectively can prevent and treat wheat rust, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long, has no adverse effects in test scope of medication to target crop.
Application Example seven fluorine azoles ring bacterium amine and active component B and the composite control of maize smut test of pesticide effectiveness thereof
This test arrangement is in Xi'an City, Shanxi Province, and seed treatment is seed soaking prior to seeding.The investigation smut of maize state of an illness before spray agent uses, in the first time dispenser of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times.Within after second time dispenser 7 days, 14 days, 30 days, investigate disease index respectively and calculate preventive effect.Experimental result is as follows:
Table 13 fluorine azoles ring bacterium amine and active component B and the composite control of maize smut test of pesticide effectiveness thereof
As can be seen from Table 13, fluorine azoles ring bacterium amine and active component B and composite rear efficiency control of maize smut thereof, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example octafluoro azoles ring bacterium amine and active component B and the composite control cotton seedling blight test of pesticide effectiveness thereof
This test arrangement is in Dali County, Shaanxi Province, and seed treatment is seed soaking prior to seeding.The investigation cotton seedling blight state of an illness before spray agent uses, in the first time dispenser of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times.Within after second time dispenser 7 days, 14 days, 30 days, investigate disease index respectively and calculate preventive effect.Experimental result is as follows:
Table 14 fluorine azoles ring bacterium amine and active component B and the composite control cotton seedling blight test of pesticide effectiveness thereof
As can be seen from Table 14, fluorine azoles ring bacterium amine and active component B and composite after effectively can prevent and treat cotton seedling blight, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine fluorine azoles ring bacterium amine and active component B and compositely prevent and treat the wheat smut test of pesticide effectiveness
This test arrangement is at Shaanxi Province's Weinan City, and seed treatment is seed soaking prior to seeding.The investigation wheat smut state of an illness before spray agent uses, in the first time dispenser of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times.Within after second time dispenser 7 days, 14 days, 30 days, investigate disease index respectively and calculate preventive effect.Experimental result is as follows:
Table 15 fluorine azoles ring bacterium amine and active component B and compositely prevent and treat the wheat smut test of pesticide effectiveness
As can be seen from Table 15, fluorine azoles ring bacterium amine and active component B and composite after effectively can prevent and treat wheat smut, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, fluorine azoles ring bacterium amine and triticonazole, plant bacterium azoles, the composite rear preventive effect to Common Diseases such as the smut in various crop, powdery mildew, banded sclerotial blight, rust, apple scab, net blotch, root rot, damping off, bakanae disease, rice blast of prothioconazoles all 95% with on excellent, in single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the bactericidal composition of a fluorine-containing azoles ring bacterium amine and triazole type, it is characterized in that: effective active composition is active components A and active component B, the weight ratio of active components A and active component B is 1: 80 ~ 80: 1, described active components A is fluorine azoles ring bacterium amine, and active component B is triticonazole, plants bacterium azoles or prothioconazoles.
2. the bactericidal composition of fluorine-containing azoles ring bacterium amine according to claim 1 and triazole type, is characterized in that: the weight ratio of active components A and active component B is 1: 60 ~ 60: 1.
3. the bactericidal composition of fluorine-containing azoles ring bacterium amine according to claim 2 and triazole type, is characterized in that:
The weight ratio of fluorine azoles ring bacterium amine and triticonazole is 1: 10 ~ 20: 1;
Fluorine azoles ring bacterium amine is 1: 20 ~ 10: 1 with the weight ratio of kind bacterium azoles;
The weight ratio of fluorine azoles ring bacterium amine and triticonazole is 1: 10 ~ 20: 1.
4. the bactericidal composition of fluorine-containing azoles ring bacterium amine according to claim 1 and triazole type, is characterized in that: composition makes suspension seed-coating agent, wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, suspension emulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
5. the bactericidal composition of fluorine-containing azoles ring bacterium amine according to claim 4 and triazole type is for preventing and treating the purposes of crop pest.
6. purposes according to claim 5, is characterized in that: described disease is smut, powdery mildew, banded sclerotial blight, rust, apple scab, net blotch, root rot, damping off, bakanae disease or rice blast.
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| US20120108580A1 (en) * | 2010-04-14 | 2012-05-03 | Bayer Cropscience Ag | Use of Fungicidal Active Substances For Controlling Mycoses on Plants of the Palm Family |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101001527A (en) * | 2004-08-12 | 2007-07-18 | 辛根塔参与股份公司 | Fungicidal compositions |
| CN101965128A (en) * | 2008-02-05 | 2011-02-02 | 巴斯夫欧洲公司 | Plant health composition |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
| CN102143689A (en) * | 2008-09-03 | 2011-08-03 | 拜尔农作物科学股份公司 | Use of fungicidal compound compositions for controlling certain rust fungi |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Applicant after: Shaanxi Mei Bang Pharmaceutical Group Limited by Share Ltd Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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Application publication date: 20150624 |
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