CN104711063A - Novel composite solid fuel and preparation method thereof - Google Patents

Novel composite solid fuel and preparation method thereof Download PDF

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Publication number
CN104711063A
CN104711063A CN201510129384.1A CN201510129384A CN104711063A CN 104711063 A CN104711063 A CN 104711063A CN 201510129384 A CN201510129384 A CN 201510129384A CN 104711063 A CN104711063 A CN 104711063A
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China
Prior art keywords
parts
preparation
solid fuel
composite
composite additive
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CN201510129384.1A
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CN104711063B (en
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陈永林
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Huzhou Jiachuang Automation Technology Co Ltd
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HUZHOU KEDA CHEMICAL FUEL Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The invention discloses a novel composite solid fuel and a preparation method thereof. The novel composite solid fuel disclosed by the invention is composed of the following components in parts by weight: 3-5 parts of a stearic acid, 1-3 parts of glycerine, 20-30 parts of hexamethylene tetramine, 30-50 parts of ethanol, 20-30 parts of triethyl citrate, 10-20 parts of polyethylene glycol 400, 1-3 parts of potassium hydroxide, 1-3 parts of alum, 3-6 parts of paraffin wax, 6-8 parts of span-60, 2-10 parts of nitrocellulose, 4-8 parts of a composite additive, and 30-50 parts of water. The fuel disclosed by the invention is prepared by compounding various calorific-value components, and through the synergistic effect of the various calorific-value components, a defect that the calorific value of a single calorific-value component is too large or too small can be overcome, thereby obtaining a better application effect.

Description

A kind of NEW TYPE OF COMPOSITE solid fuel and preparation method thereof
Technical field
The invention belongs to chemical fuel technical field, more specifically relate to a kind of NEW TYPE OF COMPOSITE solid fuel and preparation method thereof.
Background technology
Going to other places, or carrying out outdoors, such as, warming oneself, roast, picnic etc., need to achieve the goal by fuel.If use the fuel such as common gasoline, diesel oil, then exist and carry inconvenience, the weak points such as security is bad.
The patent No. be 2013105548501 Chinese invention patent disclose a kind of solid fuel, proportioning disclosed in it is made up of according to a certain ratio hexamethylenetetramine, paraffin, stearic acid and ethanol, its main deficiency existed is: 1, composition is too simple, each other without good synergistic effect, and without other ancillary components, cause its raw material availability low, thermal value is little; 2, the stability of finished product is also bad, causes use not too convenient, also has potential safety hazard.
The patent No. be 2012103351689 Chinese patent disclose a kind of Solid fuel for picnic, proportioning disclosed in it is made up of ethanol, ethylene glycol, stearic acid, Zinic stearas, zinc sulfate, sodium hydroxide, potassium hydroxide and saltpetre; Its deficiency mainly existed is: 1, calorific value component is single, causes its use range to be subject to larger limitation; 2, do not contain stable in component and promote composition, the reliability that this makes it use is not enough, and the utilization ratio of raw material is not high.
Summary of the invention
The object of the invention is to the deficiency overcoming prior art existence, a kind of NEW TYPE OF COMPOSITE solid fuel and preparation method thereof is provided.
For achieving the above object, this invention takes following technical scheme:
A kind of NEW TYPE OF COMPOSITE solid fuel, with parts by weight, composed of the following components:
Stearic acid: 3 ~ 5, glycerol: 1 ~ 3, vulkacit H: 20 ~ 30,
Ethanol: 30 ~ 50, triethyl citrate: 20 ~ 30, poly(oxyethylene glycol) 400: 10 ~ 20,
Potassium hydroxide: 1 ~ 3, alum: 1 ~ 3, paraffin: 3 ~ 6, this coils-60:6 ~ 8,
Soluble cotton: 2 ~ 10, composite additive: 4 ~ 8, water: 30 ~ 50.
Described composite additive, with parts by weight, composed of the following components:
Sodium-chlor: 3 ~ 6, SODIUMNITRATE: 1 ~ 3, ferric oxide: 0.1 ~ 0.5,
Diatomite: 10 ~ 20, Zinic stearas: 0.3 ~ 0.5, sodium bicarbonate: 1 ~ 3.
The solid-fuelled preparation method of described NEW TYPE OF COMPOSITE, comprises following technological step:
(1) preparation of composite additive; By proportioning, each component is mixed;
(2) stearic acid, vulkacit H, paraffin and alum are put into grinder-mixer successively to pulverize, then mix, obtain powder mixture; Then add step (1) preparation-obtained composite additive, be uniformly dispersed;
(3) soluble cotton is dissolved in ethanol, after being uniformly dispersed, obtains glutinous thick liquid; Then add poly(oxyethylene glycol) 400 and glycerol, be uniformly dissolved;
(4) triethyl citrate, potassium hydroxide are distinguished soluble in water, stir;
(5) product of step (2), (3) (4) is put into together Mixer pot mixing, and add other components of residue, stir insulations 10 ~ 20 minutes at 60 ~ 80 DEG C, then mixture injected container, after normal temperature condensation finished product.
Compared with prior art, the present invention has following beneficial effect:
1, the present invention is composited by multiple calorific value component, acts synergistically between multiple calorific value component, can overcome the defect that the thermal value of single calorific value component is excessive or too small, thus obtains a preferably result of use;
2, the present invention adds adaptive additive in formula, it can form the molecular structure of long-chain with stearic acid, and make the stearic usage quantity as gelifying agent be reduced to original 1/6, coagulation force strengthens 6 times, the burning later stage is unlikely flame-out ahead of time, and heat can discharge completely; Meanwhile, adding of composite additive, also good combustion-supporting effect can be played;
3, add certain stablizer in the present invention's formula, weak molecular linkage can be formed with calorific value component and be combined, thus substantially increase stability in use of the present invention; Thus making its use range wider, security is higher.
4, this product raw material is easy to get, cheap, easily lights, and can not spontaneous combustion explode, firepower is strong, thermal value is high, safe and reliable; Can be used as the energy and be widely used in all respects such as industrial production, civilian, field work, tourism.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of NEW TYPE OF COMPOSITE solid fuel, with parts by weight, composed of the following components:
Stearic acid: 3, glycerol: 1, vulkacit H: 20,
Ethanol: 30, triethyl citrate: 20, poly(oxyethylene glycol) 400: 10,
Potassium hydroxide: 1, alum: 1, paraffin: 3, this dish-60:6,
Soluble cotton: 2, composite additive: 4, water: 30.
Described composite additive, with parts by weight, composed of the following components:
Sodium-chlor: 3, SODIUMNITRATE: 1, ferric oxide: 0.1,
Diatomite: 10, Zinic stearas: 0.3, sodium bicarbonate: 1.
Embodiment 2
A kind of NEW TYPE OF COMPOSITE solid fuel, with parts by weight, composed of the following components:
Stearic acid: 5, glycerol: 3, vulkacit H: 30,
Ethanol: 50, triethyl citrate: 30, poly(oxyethylene glycol) 400: 20,
Potassium hydroxide: 3, alum: 3, paraffin: 6, this dish-60:8,
Soluble cotton: 10, composite additive: 8, water: 50.
Described composite additive, with parts by weight, composed of the following components:
Sodium-chlor: 6, SODIUMNITRATE: 3, ferric oxide: 0.5,
Diatomite: 20, Zinic stearas: 0.5, sodium bicarbonate: 3.
Embodiment 3
A kind of NEW TYPE OF COMPOSITE solid fuel, with parts by weight, composed of the following components:
Stearic acid: 4, glycerol: 2, vulkacit H: 26,
Ethanol: 40, triethyl citrate: 25, poly(oxyethylene glycol) 400: 16,
Potassium hydroxide: 2, alum: 2, paraffin: 5, this dish-60:7,
Soluble cotton: 6, composite additive: 6, water: 40.
Described composite additive, with parts by weight, composed of the following components:
Sodium-chlor: 5, SODIUMNITRATE: 2, ferric oxide: 0.3,
Diatomite: 16, Zinic stearas: 0.4, sodium bicarbonate: 2.
The solid-fuelled preparation method of NEW TYPE OF COMPOSITE described in above-described embodiment 3, comprises following technological step:
(1) preparation of composite additive; By proportioning, each component is mixed;
(2) stearic acid, vulkacit H, paraffin and alum are put into grinder-mixer successively to pulverize, then mix, obtain powder mixture; Then add step (1) preparation-obtained composite additive, be uniformly dispersed;
(3) soluble cotton is dissolved in ethanol, after being uniformly dispersed, obtains glutinous thick liquid; Then add poly(oxyethylene glycol) 400 and glycerol, be uniformly dissolved;
(4) triethyl citrate, potassium hydroxide are distinguished soluble in water, stir;
(5) product of step (2), (3) (4) is put into together Mixer pot mixing, and add other components of residue, stir insulations 10 ~ 20 minutes at 60 ~ 80 DEG C, then mixture injected container, after normal temperature condensation finished product.

Claims (3)

1. a NEW TYPE OF COMPOSITE solid fuel, is characterized in that, with parts by weight, composed of the following components:
Stearic acid: 3 ~ 5, glycerol: 1 ~ 3, vulkacit H: 20 ~ 30,
Ethanol: 30 ~ 50, triethyl citrate: 20 ~ 30, poly(oxyethylene glycol) 400: 10 ~ 20,
Potassium hydroxide: 1 ~ 3, alum: 1 ~ 3, paraffin: 3 ~ 6, this coils-60:6 ~ 8,
Soluble cotton: 2 ~ 10, composite additive: 4 ~ 8, water: 30 ~ 50.
2. a kind of NEW TYPE OF COMPOSITE solid fuel according to claim 1, is characterized in that, described composite additive, with parts by weight, composed of the following components:
Sodium-chlor: 3 ~ 6, SODIUMNITRATE: 1 ~ 3, ferric oxide: 0.1 ~ 0.5,
Diatomite: 10 ~ 20, Zinic stearas: 0.3 ~ 0.5, sodium bicarbonate: 1 ~ 3.
3. the solid-fuelled preparation method of NEW TYPE OF COMPOSITE according to claim 1, is characterized in that, comprises following technological step:
(1) preparation of composite additive; By proportioning, each component is mixed;
(2) stearic acid, vulkacit H, paraffin and alum are put into grinder-mixer successively to pulverize, then mix, obtain powder mixture; Then add step (1) preparation-obtained composite additive, be uniformly dispersed;
(3) soluble cotton is dissolved in ethanol, after being uniformly dispersed, obtains glutinous thick liquid; Then add poly(oxyethylene glycol) 400 and glycerol, be uniformly dissolved;
(4) triethyl citrate, potassium hydroxide are distinguished soluble in water, stir;
(5) product of step (2), (3) (4) is put into together Mixer pot mixing, and add other components of residue, stir insulations 10 ~ 20 minutes at 60 ~ 80 DEG C, then mixture injected container, after normal temperature condensation finished product.
CN201510129384.1A 2015-03-24 2015-03-24 A kind of NEW TYPE OF COMPOSITE solid fuel and preparation method thereof Active CN104711063B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418648A (en) * 2017-06-13 2017-12-01 李萍 A kind of combustion-supporting agent for fuel coal with high stability
CN109280572A (en) * 2018-10-18 2019-01-29 梅万伦 A kind of method that the esterification of cleaned coal nitre prepares fuel
CN109536235A (en) * 2018-10-19 2019-03-29 鄞瑞扬 Solid-state bio-fuel-oil and preparation method thereof
CN114540094A (en) * 2022-03-31 2022-05-27 南京天诗新材料科技有限公司 Solid wax-based fuel and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2754535C1 (en) * 2020-05-22 2021-09-03 Алексей Анатольевич Дятлов Solid fuel

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CN1055194A (en) * 1990-03-27 1991-10-09 张政友 A kind of composite solid fuel
CN1095754A (en) * 1993-05-17 1994-11-30 吴涓 Solid fuel with sandal
CN1944603A (en) * 2006-11-02 2007-04-11 中国人民解放军总后勤部军需装备研究所 Solid alcohol fuel and its preparing method
CN101275095A (en) * 2008-04-29 2008-10-01 许学龙 Coal burning additive
CN101463284A (en) * 2009-01-14 2009-06-24 邓学军 Environment protection coal-saving synergistic agent
CN101475864A (en) * 2009-01-19 2009-07-08 赵楠 Non-sodium chloride environment-friendly type coal-saving combustion adjuvant special for cement
KR20100042318A (en) * 2008-10-16 2010-04-26 손수일 Process of manufacturing breket and pellet of cotton for biomass fuel
CN102796583A (en) * 2012-08-27 2012-11-28 湖南省鑫旺节能环保科技有限公司 Efficient clean briquette coal and preparation method thereof
CN103555384A (en) * 2013-11-11 2014-02-05 夏祖菊 Solid fuel
CN104419490A (en) * 2013-09-09 2015-03-18 哈尔滨市宏天锐达科技有限公司 Portable energy-saving solid fuel
CN104694192A (en) * 2014-12-30 2015-06-10 株洲醴陵旗滨玻璃有限公司 Diversified composite fuel for glass kiln

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1055194A (en) * 1990-03-27 1991-10-09 张政友 A kind of composite solid fuel
CN1095754A (en) * 1993-05-17 1994-11-30 吴涓 Solid fuel with sandal
CN1944603A (en) * 2006-11-02 2007-04-11 中国人民解放军总后勤部军需装备研究所 Solid alcohol fuel and its preparing method
CN101275095A (en) * 2008-04-29 2008-10-01 许学龙 Coal burning additive
KR20100042318A (en) * 2008-10-16 2010-04-26 손수일 Process of manufacturing breket and pellet of cotton for biomass fuel
CN101463284A (en) * 2009-01-14 2009-06-24 邓学军 Environment protection coal-saving synergistic agent
CN101475864A (en) * 2009-01-19 2009-07-08 赵楠 Non-sodium chloride environment-friendly type coal-saving combustion adjuvant special for cement
CN102796583A (en) * 2012-08-27 2012-11-28 湖南省鑫旺节能环保科技有限公司 Efficient clean briquette coal and preparation method thereof
CN104419490A (en) * 2013-09-09 2015-03-18 哈尔滨市宏天锐达科技有限公司 Portable energy-saving solid fuel
CN103555384A (en) * 2013-11-11 2014-02-05 夏祖菊 Solid fuel
CN104694192A (en) * 2014-12-30 2015-06-10 株洲醴陵旗滨玻璃有限公司 Diversified composite fuel for glass kiln

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418648A (en) * 2017-06-13 2017-12-01 李萍 A kind of combustion-supporting agent for fuel coal with high stability
CN107418648B (en) * 2017-06-13 2018-05-15 朱亚东 A kind of combustion-supporting agent for fuel coal with high stability
CN109280572A (en) * 2018-10-18 2019-01-29 梅万伦 A kind of method that the esterification of cleaned coal nitre prepares fuel
CN109536235A (en) * 2018-10-19 2019-03-29 鄞瑞扬 Solid-state bio-fuel-oil and preparation method thereof
CN114540094A (en) * 2022-03-31 2022-05-27 南京天诗新材料科技有限公司 Solid wax-based fuel and preparation method thereof

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Inventor after: Fang Ying

Inventor after: Su Jian

Inventor after: Lin Xiufen

Inventor after: Chen Yonglin

Inventor before: Chen Yonglin

GR01 Patent grant
TR01 Transfer of patent right
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Effective date of registration: 20190403

Address after: 313000 Building No. 1, 3558 Shushan Road, Wuxing District, Huzhou City, Zhejiang Province Huzhou Jiachuang Automation Technology Co., Ltd.

Patentee after: Huzhou best automation technology Co., Ltd.

Address before: 313000 No. 128, West Mountain Road, Wuxing Road, Huzhou, Zhejiang.

Patentee before: HUZHOU KEDA CHEMICAL FUEL CO., LTD.