CN104708875B - Antifog heat insulating film - Google Patents
Antifog heat insulating film Download PDFInfo
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- CN104708875B CN104708875B CN201410045039.5A CN201410045039A CN104708875B CN 104708875 B CN104708875 B CN 104708875B CN 201410045039 A CN201410045039 A CN 201410045039A CN 104708875 B CN104708875 B CN 104708875B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 124
- 238000009413 insulation Methods 0.000 claims abstract description 64
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 46
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 45
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000002105 nanoparticle Substances 0.000 claims abstract description 37
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 24
- 239000011734 sodium Substances 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 23
- 239000011591 potassium Substances 0.000 claims abstract description 23
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 22
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 21
- 239000010410 layer Substances 0.000 claims description 131
- 239000000463 material Substances 0.000 claims description 60
- -1 acyloxy propane Chemical compound 0.000 claims description 47
- 239000011248 coating agent Substances 0.000 claims description 47
- 238000000576 coating method Methods 0.000 claims description 47
- 238000002955 isolation Methods 0.000 claims description 44
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 43
- 239000001294 propane Substances 0.000 claims description 40
- 239000012790 adhesive layer Substances 0.000 claims description 35
- 239000002245 particle Substances 0.000 claims description 35
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 26
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 24
- 239000011787 zinc oxide Substances 0.000 claims description 22
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 14
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 13
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 13
- 235000013339 cereals Nutrition 0.000 claims description 12
- 239000003292 glue Substances 0.000 claims description 8
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 8
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical group OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 229920005749 polyurethane resin Polymers 0.000 claims description 7
- 238000007711 solidification Methods 0.000 claims description 7
- 230000008023 solidification Effects 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 5
- 240000007594 Oryza sativa Species 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- WNXTZVMMNCCZTP-UHFFFAOYSA-N 2-hydroxyethyl 2-methylprop-2-enoate 5-hydroxy-2-methylpent-2-enoic acid Chemical compound OCCC=C(C(=O)O)C.C(C(=C)C)(=O)OCCO WNXTZVMMNCCZTP-UHFFFAOYSA-N 0.000 description 1
- IPGXHRDWHJEWBI-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate;4-hydroxy-2-methylidenebutanoic acid Chemical group OCCOC(=O)C=C.OCCC(=C)C(O)=O IPGXHRDWHJEWBI-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 241000255964 Pieridae Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical compound OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VSFOXJWBPGONDR-UHFFFAOYSA-M potassium;3-prop-2-enoyloxypropane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)CCCOC(=O)C=C VSFOXJWBPGONDR-UHFFFAOYSA-M 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- LDYPJGUPKKJBIB-UHFFFAOYSA-M sodium;3-prop-2-enoyloxypropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CCCOC(=O)C=C LDYPJGUPKKJBIB-UHFFFAOYSA-M 0.000 description 1
- 239000005439 thermosphere Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/14—Layered products comprising a layer of synthetic resin next to a particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
Abstract
An antifogging and heat insulating film comprisingA heat insulation layer and an anti-fog layer. The heat insulation layer is provided with a first surface and a second surface, and the first surface is opposite to the second surface. The antifogging layer is arranged on the first surface of the heat insulation layer and comprises a water-based antifogging agent and nanoparticles, the water-based antifogging agent is selected from a group consisting of Sodium 3-propenyl oxypropane-1-sulfonate (Sodium 3-Sulphosphopropyl acrylate), Potassium 3-propenyl-2-propenyl oxypropane-1-sulfonate (Potasssium 3-Sulphosphopropyl acrylate) and a combination thereof, and the nanoparticles are selected from silicon dioxide (SiO)2) Alumina (Al)2O3) Titanium dioxide (TiO)2) Zinc oxide (ZnO), and combinations thereof. The antifogging heat-insulating film provided by the invention can overcome the fogging phenomenon on the surface of an article in the prior art.
Description
Technical field
The present invention relates to a kind of thermal isolation film, more particularly to a kind of antifog thermal isolation film.
Background technology
Because global warming phenomenon is on the rise, advanced country there's no one who doesn't or isn't puts into a large sum of funds in section to solve to warm up problem
Energy science and technology and green energy resource, phenomenon is warmed up to slow down.Although in the recent period because the exploitation of shale oil and shale gas so that energy
Source crisis seemingly has slightly slow trend, but on long terms, fossil energy has a day of exhaustion eventually, and is excessively produced using fossil fuel
Raw greenhouse gases will cause global warming phenomenon further to deteriorate, therefore carbon reduction is still human society very urgent and must
The problem that must be put into all strength.
Majority building curtain or vehicle glass can stick thermal isolation film mostly at present, to completely cut off outside building or outside car
Radiant heat, and then reduce the burden of building or air conditioning for automobiles, improve the comfort level of indoor or occupant.But it is most
Thermal isolation film does not have antifog effect.When weather is clammy, the easy fogging of glass curtain in vehicle window or building and influence
Driver or the sight line of indoor occupant.
Additionally, for locomotive knight, when temperature is colder, its safety helmet lens or goggles are easily because breathing
And fogging.In addition in daily life, after personnel open hot water for a period of time in bathroom, mirror surfaces also can be because of vapor
Condense and form fumulus.Therefore, the fogging phenomenon of article surface can cause the inconvenience of user really.
The content of the invention
In view of this, in order to overcome the fogging phenomenon of article surface in the prior art, it is an object of the invention to propose one
Plant antifog thermal isolation film.
Comprising a thermal insulation layer and an anti-fog layer.Thermal insulation layer has a first surface and a second surface, and first surface is phase
For second surface.Anti-fog layer is arranged at the first surface of thermal insulation layer, and anti-fog layer includes water base antifoggant and nano-particle, water base
Antifoggant be selected from 3- propyl-s 2- alkene acyloxy propane -1- sodium sulfonates (Sodium 3-sulphonatopropyl acrylate),
3- propyl-s 2- alkene acyloxy propane -1- potassium sulfonates (Potassium 3-sulphonatopropyl acrylate) and combinations thereof institute
The group of composition, nano-particle is selected from silica (SiO2), aluminum oxide (Al2O3), titanium dioxide (TiO2), zinc oxide
And combinations thereof (ZnO) group for being constituted.
In one of concept of the invention, the thermal insulation layer of antifog thermal isolation film includes nanometer tungsten oxide or nano zircite
Particle, or its mixture particle, average grain diameter is in 20 nanometers to 70 nanometers of scope.
In one of concept of the invention, antifog thermal isolation film further includes a base material, is arranged at the second table of thermal insulation layer
Face.
In one of concept of the invention, antifog thermal isolation film further includes a pressure-sensing glue and a release layer, sequentially sets
In the exposed surface of the base material.
In one of concept of the invention, the material of base material is PET (PET).
In one of concept of the invention, the anti-fog layer of antifog thermal isolation film is made of in following method：
One anti-fog coating is provided, when the anti-fog coating is based on the gross weight of the anti-fog coating include 15% to 25% it
Between water base acryl polyurethane oligomer；
Water base acryl monomer between 15% to 25%, the water base acryl monomer is selected from hydroxy-ethyl acrylate
(hydroxyethyl acrylate), hydroxyethyl methacrylate (hydroxyethyl methacrylate), acrylic acid
(acrylic acid), methylene-bisacrylamide (methylenebisacrylamide), methyl methacrylate (methyl
) and combinations thereof methacrylate the group for being constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant is selected from 3- propyl- 2- alkene acyloxy propane -1- sulfonic acid
The group that sodium, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the nano-particle that the Nano sol is included is selected from silica, oxygen
Change the group that aluminium, titanium dioxide, zinc oxide and combinations thereof are constituted；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
The anti-fog coating is coated the first surface of the thermal insulation layer；
Drying coated anti-fog coating in the first surface；And
The anti-fog coating of the first surface is coated in solidification.
In one of concept of the invention, in it is above-mentioned dry anti-fog coating the step of, be in substantial 100 DEG C extremely
Temperature is held at a temperature of 110 DEG C 1 to 2 minute.
One of concept of the invention is a kind of antifog thermal isolation film, comprising thermal insulation layer, base material, anti-fog layer, pressure sensing adhesive layer
And release layer.Thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Base material be arranged at every
The first surface of thermosphere.Anti-fog layer is arranged on base material, and anti-fog layer includes water base antifoggant and nano-particle, and water base antifoggant is
Constituted selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof
Group, the nano-particle is the group constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof.Sense
Moulding layer is arranged at the second surface of thermal insulation layer, and release layer is then arranged in pressure sensing adhesive layer.
One of concept of the invention is a kind of antifog thermal isolation film, comprising heat-insulated pressure sensing adhesive layer, base material, anti-fog layer and from
Type layer.Heat-insulated pressure sensing adhesive layer has a first surface and a second surface, and first surface is relative to second surface.Base material is arranged at
The first surface of heat-insulated pressure sensing adhesive layer.Anti-fog layer is arranged on base material, and anti-fog layer includes water base antifoggant and nano-particle, water base
Antifoggant is selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof
The group for being constituted, the nano-particle is constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof
Group.Release layer is then arranged on the second surface of heat-insulated pressure sensing adhesive layer.
One of concept of the invention is a kind of antifog thermal isolation film, comprising thermal insulation layer, two base materials, anti-fog layer, pressure-sensing glue
Layer and release layer.Thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Two base materials are distinguished
It is arranged at the first surface and second surface of thermal insulation layer.Anti-fog layer is arranged on the base material of first surface, and anti-fog layer is included
Water base antifoggant and nano-particle, water base antifoggant are selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyls
The group that epoxide propane -1- potassium sulfonates and combinations thereof are constituted, the nano-particle is selected from silica, aluminum oxide, dioxy
Change the group that titanium, zinc oxide and combinations thereof are constituted.Pressure sensing adhesive layer is arranged on the base material of second surface, and release layer then sets
It is placed in pressure sensing adhesive layer.
One of concept of the invention is a kind of antifog thermal isolation film, comprising antifog thermal insulation layer, base material, pressure sensing adhesive layer and from
Type layer.Antifog thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Base material is arranged at anti-
The second surface of mist thermal insulation layer, the first surface of antifog thermal insulation layer is for exposed.Antifog thermal insulation layer includes water base antifoggant and receives
Rice corpuscles, water base antifoggant is selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- sulphurs
The group that sour potassium and combinations thereof is constituted, the nano-particle be selected from silica, aluminum oxide, titanium dioxide, zinc oxide and
The constituted group of its combination.In addition, antifog thermal insulation layer also includes nanometer tungsten oxide particle, or nano zirconia particles,
The average grain diameter of particle is in 20 nanometers to 70 nanometers of scope.Pressure sensing adhesive layer is arranged on base material, and release layer is then arranged at
In pressure sensing adhesive layer.
It is substantially in 200 to 800mJ/cm with intensity in one of concept of the invention2Scope in it is ultraviolet
Light carries out photocuring to the anti-fog coating for coating the first surface of thermal isolation film.
Below in conjunction with the drawings and specific embodiments, the present invention will be described in detail, but not as a limitation of the invention.
Brief description of the drawings
Fig. 1 is the schematic cross-sectional view of the first embodiment of the present invention；
Fig. 2 is the schematic cross-sectional view of the second embodiment of the present invention；
Fig. 3 is the schematic cross-sectional view of the third embodiment of the present invention；
Fig. 4 is the schematic cross-sectional view of the fourth embodiment of the present invention；
Fig. 5 is the schematic cross-sectional view of the fifth embodiment of the present invention；
Fig. 6 is the schematic cross-sectional view of the sixth embodiment of the present invention；
Fig. 7 is the schematic cross-sectional view of the seventh embodiment of the present invention.
Wherein, reference
10 antifog thermal isolation films
11 thermal insulation layers
111 first surfaces
112 second surfaces
12 anti-fog layers
13 base materials
14 pressure-sensing glues
15 release layers
20 antifog thermal isolation films
30 antifog thermal isolation films
40 antifog thermal isolation films
50 antifog thermal isolation films
51 heat-insulated pressure sensing adhesive layers
511 first surfaces
512 second surfaces
60 antifog thermal isolation films
70 antifog thermal isolation films
71 antifog thermal insulation layers
711 first surfaces
712 second surfaces
Specific embodiment
Structural principle of the invention and operation principle are described in detail below in conjunction with the accompanying drawings：
Fig. 1 is refer to, is the schematic cross-sectional view of first embodiment of the invention, a kind of antifog thermal isolation film 10 is disclosed, comprising one
The anti-fog layer 12 of thermal insulation layer 11 and.
Thermal insulation layer 11 has a first surface 111 and a second surface 112, and first surface 111 is relative to second surface
112。
Anti-fog layer 12 is arranged at the first surface 111 of thermal insulation layer 11, and anti-fog layer 12 includes water base antifoggant and nano-particle,
Water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and its
The constituted group of combination, nano-particle is constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof
Group.
In the present embodiment, the thermal insulation layer 11 of antifog thermal isolation film 10 includes nanometer tungsten oxide (WO3) particle, or it is nano oxidized
Zirconium particle, its average grain diameter is in 20 nanometers to 70 nanometers of scope.Experiment finds nanometer tungsten oxide particle surface plasma
Wavelength is between visible ray and infrared light intersection (780 nanometers).Due to nanometer tungsten oxide particle or nano zirconia particles, surface
With this kind of surface plasma wavelength characteristic, it is seen that light (380 nanometers to 780 nanometers of wavelength) is less than nano oxidized tungsten particle because of wavelength
The surface plasma wavelength of son or nano zirconia particles, thus can penetrate.But infrared light (being the main source of heat) is because of wavelength
On 780 nanometers, more than nanometer tungsten oxide particle or the surface plasma wavelength of nano zirconia particles, therefore incident ray
In most infrared light be reflected back, infrared light is not got in or in-car, substantially reduce indoor or vehicle interior temperature,
And then reach outdoor isolation or the outer heat energy of car and keep the requirement of its translucency.Except nanometer tungsten oxide particle or nano zircite grain
It is sub outer, other metal oxide nanoparticles, if any similar surfaces plasma wavelength between visible ray and infrared light intersection
(780 nanometers) or near, be also used to when thermal insulation layer 11.
Fig. 2 is refer to, is the schematic cross-sectional view of the second embodiment of the present invention, disclose a kind of antifog thermal isolation film 20.This reality
Apply example and further include a base material 13 with the antifog thermal isolation film 20 that the Main Differences of first embodiment are the present embodiment, be arranged at heat-insulated
The second surface 112 of layer 11.In the present embodiment, the material of base material is to select PET.
Fig. 3 is refer to, is the schematic cross-sectional view of the third embodiment of the present invention, disclose a kind of antifog thermal isolation film 30.This reality
Example is applied with the antifog thermal isolation film 30 that the Main Differences of second embodiment are the present embodiment and further includes a pressure-sensing glue 14 release with one
Layer 15, is sequentially arranged at the exposed surface of base material 13.The present embodiment can easily be attached at various articles through pressure-sensing glue 14
Surface.
Fig. 4 is refer to, is the schematic cross-sectional view of the fourth embodiment of the present invention, disclose a kind of antifog thermal isolation film 40, comprising
Thermal insulation layer 11, base material 13, anti-fog layer 12, pressure sensing adhesive layer 14 and release layer 15.
Thermal insulation layer 11 has a first surface 111 and a second surface 112, and first surface 111 is relative to second surface
112.Base material 13 is arranged at the first surface 111 of thermal insulation layer 11.Anti-fog layer 12 is arranged on base material 13, and anti-fog layer 12 is comprising water base
Antifoggant and nano-particle, water base antifoggant are selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy
The group that propane -1- potassium sulfonates and combinations thereof are constituted, the nano-particle be selected from silica, aluminum oxide, titanium dioxide,
The group that zinc oxide and combinations thereof is constituted.Pressure sensing adhesive layer 14 is arranged at the second surface 112 of thermal insulation layer 11, and release layer 15 then sets
It is placed in pressure sensing adhesive layer 14.
Fig. 5 is refer to, is the schematic cross-sectional view of the fifth embodiment of the present invention, disclose a kind of antifog thermal isolation film 50, comprising
Heat-insulated pressure sensing adhesive layer 51, base material 13, anti-fog layer 12 and release layer 15.
Heat-insulated pressure sensing adhesive layer 51 has a first surface 511 and a second surface 512, and first surface 511 is relative to second
Surface 512.Base material 13 is arranged at the first surface 511 of heat-insulated pressure sensing adhesive layer 51.Anti-fog layer 12 is arranged on base material 13, anti-fog layer
12 include water base antifoggant and nano-particle, and water base antifoggant is selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl-s
The group that 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted, the nano-particle is selected from silica, oxidation
The group that aluminium, titanium dioxide, zinc oxide and combinations thereof are constituted.Release layer 15 is then arranged at the second surface of heat-insulated pressure sensing adhesive layer
On 512.
Fig. 6 is refer to, is the schematic cross-sectional view of the sixth embodiment of the present invention, disclose a kind of antifog thermal isolation film 60, comprising
Thermal insulation layer 11, two base materials 13, anti-fog layer 12, pressure sensing adhesive layer 14 and release layer 15.
Thermal insulation layer 11 has a first surface 111 and a second surface 112, and first surface 111 is relative to second surface
112.Two base materials 13 are respectively arranged at the first surface 111 and second surface 112 of thermal insulation layer 11.Anti-fog layer 12 is arranged at positioned at
On the base material 13 on one surface 111, anti-fog layer 12 includes water base antifoggant and nano-particle, and water base antifoggant is selected from 3- propyl-s 2-
The group that alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted, it is described to receive
Rice corpuscles is the group constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof.Pressure sensing adhesive layer 14 sets
It is placed on the base material 13 of second surface 112, release layer 15 is then arranged in pressure sensing adhesive layer 14.
Fig. 7 is refer to, is the schematic cross-sectional view of the seventh embodiment of the present invention, disclose a kind of antifog thermal isolation film 70, comprising
Antifog thermal insulation layer 71, base material 13, pressure sensing adhesive layer 14 and release layer 15.
Antifog thermal insulation layer 71 has a first surface 711 and a second surface 712, and first surface 711 is relative to the second table
Face 712.Base material 13 is arranged at the second surface 712 of antifog thermal insulation layer 71, and the first surface 711 of antifog thermal insulation layer 71 is for naked
Dew.Antifog thermal insulation layer 12 include water base antifoggant and nano-particle, water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane-
The group that 1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted, the nano-particle is to be selected from
The group that silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof are constituted.In addition, antifog thermal insulation layer 71 is also wrapped
Particle containing nanometer tungsten oxide, or nano zirconia particles, its average grain diameter are in 20 nanometers to 70 nanometers of scope.Pressure-sensing glue
Layer 14 is arranged on base material 13, and release layer 15 is then arranged in pressure sensing adhesive layer 14.
In each embodiment of the invention, anti-fog layer 12 is made of in following method：
An anti-fog coating is provided, wherein including when based on the gross weight of anti-fog coating：
Water base acrylic polyurethane oligomer between 15% to 25%；
Water base acrylic monomer between 15% to 25%, the water base acrylic monomer is selected from hydroxy-ethyl acrylate, first
The group that base hydroxy-ethyl acrylate, acrylic acid, methylene-bisacrylamide, methyl methacrylate and combinations thereof are constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant is selected from 3- propyl- 2- alkene acyloxy propane -1- sulfonic acid
The group that sodium, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the nano-particle that the Nano sol is included is selected from silica, oxygen
Change the group that aluminium, titanium dioxide, zinc oxide and combinations thereof are constituted；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
Anti-fog coating is coated the first surface 111 of thermal insulation layer 11；
The drying coated anti-fog coating in first surface 111；And
The anti-fog coating of first surface 111 is coated in solidification.
In it is above-mentioned dry anti-fog coating the step of in, be held at a temperature of substantial 100 DEG C to 110 DEG C temperature 1 to 2 point
Clock.And be substantially in 250 to 450mJ/cm with intensity in curing schedule2Scope in ultraviolet light it is heat-insulated to coating
The anti-fog coating of the first surface 111 of layer 11 carries out photocuring.
The antifog thermal insulation layer 71 of the 7th embodiment is that further addition average grain diameter is at 20 nanometers in the anti-fog layer
To nanometer tungsten oxide particle or nano zirconia particles between 70 nanometers, and it is able to while having heat-insulated and antifog effect.
The thermal insulation layer of the various embodiments described above or the light transmittance of pressure-sensitive thermal insulation layer can be according to reality with infrared ray rejection rate
Sell commercial specification and adjust.Such as infrared ray rejection rate can be 70 percent, 80 percent or 90 percent
More than, but the present invention is not limited thereto, when the content of nanometer tungsten oxide particle or nano zirconia particles is higher, then infrared ray
Rejection rate it is just higher.Additionally, also can add a certain proportion of carbon black in thermal insulation layer or pressure-sensitive thermal insulation layer to adjust it
Light transmittance, such as light transmittance can be percent 20, percent 40 or percent 70, but the present invention is not limited thereto.
Certainly, the present invention can also have other various embodiments, ripe in the case of without departing substantially from spirit of the invention and its essence
Know those skilled in the art and work as and various corresponding changes and deformation, but these corresponding changes and change can be made according to the present invention
Shape should all belong to the protection domain of appended claims of the invention.
Claims (11)
1. a kind of antifog thermal isolation film, it is characterised in that include：
One thermal insulation layer, with a first surface and a second surface, the first surface is relative to the second surface；And
One anti-fog layer, is arranged at the first surface of the thermal insulation layer, and the anti-fog layer includes water base antifoggant and nano-particle, and this is water base
Antifoggant is selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof
The group for being constituted, the nano-particle is constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof
Group；
Wherein, the anti-fog layer is made of in following method：
One anti-fog coating is provided, is included when the anti-fog coating is based on the gross weight of the anti-fog coating：
Water base acrylic polyurethane oligomer between 15% to 25%；
Water base acrylic monomer between 15% to 25%, the water base acrylic monomer is selected from hydroxy-ethyl acrylate, methyl-prop
The group that olefin(e) acid hydroxyl ethyl ester, acrylic acid, methylene-bisacrylamide, methyl methacrylate and combinations thereof are constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates,
The group that 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the nano-particle that the Nano sol is included be selected from silica, aluminum oxide,
The group that titanium dioxide, zinc oxide and combinations thereof are constituted；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
The anti-fog coating is coated the first surface of the thermal insulation layer；
Drying coated anti-fog coating in the first surface；And
The anti-fog coating of the first surface is coated in solidification.
2. antifog thermal isolation film according to claim 1, it is characterised in that the thermal insulation layer includes nanometer tungsten oxide particle, or
Nano zirconia particles, its average grain diameter is in 20 nanometers to 70 nanometers of scope.
3. antifog thermal isolation film according to claim 2, it is characterised in that further include a base material, a pressure-sensing glue release with
Layer, the material of the base material is for PET and is arranged at the second surface of the thermal insulation layer, the pressure-sensing glue with should be from
Type layer is sequentially arranged at the exposed surface of the base material.
4. a kind of antifog thermal isolation film, it is characterised in that include：
One heat-insulated pressure sensing adhesive layer, with a first surface and a second surface, the first surface is relative to the second surface；
One base material, is arranged on the first surface of the heat-insulated pressure sensing adhesive layer；
One anti-fog layer, is arranged on the base material, and the anti-fog layer includes water base antifoggant and nano-particle, and the water base antifoggant is choosing
From the group that 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted
Group, the nano-particle is the group constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof；And
One release layer, is arranged at the second surface of the heat-insulated pressure sensing adhesive layer；
Wherein, the anti-fog layer is made of in following method：
One anti-fog coating is provided, is included when the anti-fog coating is based on the gross weight of the anti-fog coating：
Water base acrylic polyurethane oligomer between 15% to 25%；
Water base acrylic monomer between 15% to 25%, the water base acrylic monomer is selected from hydroxy-ethyl acrylate, methyl-prop
The group that olefin(e) acid hydroxyl ethyl ester, acrylic acid, methylene-bisacrylamide, methyl methacrylate and combinations thereof are constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates,
The group that 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the nano-particle that the Nano sol is included be selected from silica, aluminum oxide,
The group that titanium dioxide, zinc oxide and combinations thereof are constituted；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
The anti-fog coating is coated on the base material；
It is drying coated in the anti-fog coating on the base material；And
The anti-fog coating on the base material is coated in solidification.
5. antifog thermal isolation film according to claim 4, it is characterised in that the heat-insulated pressure sensing adhesive layer includes nano oxidized tungsten particle
Son or nano zirconia particles, average grain diameter is in 20 nanometers to 70 nanometers of scope.
6. a kind of antifog thermal isolation film, it is characterised in that include：
One thermal insulation layer, with a first surface and a second surface, the first surface is relative to the second surface；
One base material, is arranged on the first surface of the thermal insulation layer；
One anti-fog layer, is arranged on the base material, and the anti-fog layer includes water base antifoggant and nano-particle, and the water base antifoggant is choosing
From the group that 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted
Group, the nano-particle is the group constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof；
One pressure sensing adhesive layer, is arranged at the second surface of the thermal insulation layer；And
One release layer, is arranged in the pressure sensing adhesive layer；
Wherein, the anti-fog layer is made of in following method：
One anti-fog coating is provided, is included when the anti-fog coating is based on the gross weight of the anti-fog coating：
Water base acrylic polyurethane oligomer between 15% to 25%；
Water base acrylic monomer between 15% to 25%, the water base acrylic monomer is selected from hydroxy-ethyl acrylate, methyl-prop
The group that olefin(e) acid hydroxyl ethyl ester, acrylic acid, methylene-bisacrylamide, methyl methacrylate and combinations thereof are constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates,
The group that 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the nano-particle that the Nano sol is included be selected from silica, aluminum oxide,
The group that titanium dioxide, zinc oxide and combinations thereof are constituted；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
The anti-fog coating is coated on the base material；
It is drying coated in the anti-fog coating on the base material；And
The anti-fog coating on the base material is coated in solidification.
7. antifog thermal isolation film according to claim 6, it is characterised in that the thermal insulation layer is comprising nanometer tungsten oxide particle or receives
Rice Zirconia particles, its average grain diameter is in 20 nanometers to 70 nanometers of scope.
8. a kind of antifog thermal isolation film, it is characterised in that include：
One thermal insulation layer, with a first surface and a second surface, the first surface is relative to the second surface；
Two base materials, are respectively arranged on the first surface of the thermal insulation layer and the second surface；
One anti-fog layer, is arranged on the base material of the first surface, and the anti-fog layer includes water base antifoggant and nano-particle,
The water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and
The constituted group of its combination, the nano-particle is selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof institute
The group of composition；And
One pressure sensing adhesive layer, is arranged on the base material of the second surface；And
One release layer, is arranged in the pressure sensing adhesive layer；
Wherein, the anti-fog layer is made of in following method：
One anti-fog coating is provided, is included when the anti-fog coating is based on the gross weight of the anti-fog coating：
Water base acrylic polyurethane oligomer between 15% to 25%；
Water base acrylic monomer between 15% to 25%, the water base acrylic monomer is selected from hydroxy-ethyl acrylate, methyl-prop
The group that olefin(e) acid hydroxyl ethyl ester, acrylic acid, methylene-bisacrylamide, methyl methacrylate and combinations thereof are constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates,
The group that 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the nano-particle that the Nano sol is included be selected from silica, aluminum oxide,
The group that titanium dioxide, zinc oxide and combinations thereof are constituted；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
The anti-fog coating is coated on the base material of the first surface positioned at the thermal insulation layer；
It is drying coated in the anti-fog coating on the base material of the first surface；And
The anti-fog coating on the base material of the first surface is coated in solidification.
9. antifog thermal isolation film according to claim 8, it is characterised in that the heat-insulated pressure sensing adhesive layer includes nano oxidized tungsten particle
Son or nano zirconia particles, average grain diameter is in 20 nanometers to 70 nanometers of scope.
10. a kind of antifog thermal isolation film, it is characterised in that include：
One antifog thermal insulation layer, comprising water base antifoggant and nano-particle, the water base antifoggant is selected from 3- propyl- 2- alkene acyloxy third
The group that alkane -1- sodium sulfonates, 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted, the nano-particle is to be selected from
The group that silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof are constituted；The antifog thermal insulation layer further includes nano oxygen
Change tungsten particle or nano zirconia particles；The antifog thermal insulation layer further includes a first surface and a second surface, the first surface
It is for exposed relative to the second surface and the first surface；
One base material, is arranged at the second surface of the antifog thermal insulation layer；
One pressure sensing adhesive layer, is arranged on the base material；And
One release layer, is arranged in the pressure sensing adhesive layer；
Wherein, the antifog thermal insulation layer is made of in following method：
One anti-fog coating is provided, is included when the anti-fog coating is based on the gross weight of the anti-fog coating：
Water base acrylic polyurethane oligomer between 15% to 25%；
Water base acrylic monomer between 15% to 25%, the water base acrylic monomer is selected from hydroxy-ethyl acrylate, methyl-prop
The group that olefin(e) acid hydroxyl ethyl ester, acrylic acid, methylene-bisacrylamide, methyl methacrylate and combinations thereof are constituted；
Water base antifoggant between 2% to 5%, the water base antifoggant be selected from 3- propyl- 2- alkene acyloxy propane -1- sodium sulfonates,
The group that 3- propyl- 2- alkene acyloxy propane -1- potassium sulfonates and combinations thereof are constituted；
Water base wetting agent between 0.2 to 0.5%；
Water base defoamer between 0.5 to 2.5%；
Water base levelling agent between 0.1 to 0.5%；
Water base between 0.2 to 2% shakes change agent, and this is water base to shake that to become agent be the polyurethane resin into polyether-type；
Silane coupling agent between 1 to 3%；
Water base adherence accelerator between 5% to 10%；
Nano sol between 15% to 25%, the Nano sol includes nanometer tungsten oxide particle or nano zirconia particles, and
The Nano sol is also comprising the nanometer of the group constituted selected from silica, aluminum oxide, titanium dioxide, zinc oxide and combinations thereof
Particle；
Water base smooth initiator between 1% to 2%；And
The water of balanced contents；
The anti-fog coating is coated on the base material；
It is drying coated in the anti-fog coating on the base material；And
The anti-fog coating on the base material is coated in solidification.
11. antifog thermal isolation films according to claim 10, it is characterised in that nanometer tungsten oxide particle or nano zircite grain
Son, average grain diameter is in 20 nanometers to 70 nanometers of scope.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW102223653 | 2013-12-13 | ||
| TW102223653U TWM483172U (en) | 2013-12-13 | 2013-12-13 | Fog prevention heat insulation film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104708875A CN104708875A (en) | 2015-06-17 |
| CN104708875B true CN104708875B (en) | 2017-06-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410045039.5A Active CN104708875B (en) | 2013-12-13 | 2014-02-07 | Antifog heat insulating film |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN104708875B (en) |
| TW (1) | TWM483172U (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3489053T3 (en) * | 2016-07-20 | 2022-01-10 | Nippon Sheet Glass Company, Limited | Windshield |
| CN106476379B (en) * | 2016-09-21 | 2018-08-17 | 东莞市联洲知识产权运营管理有限公司 | A kind of heat-insulated antifog film of vehicle glass |
| CN109666176A (en) * | 2018-12-20 | 2019-04-23 | 何琛邦 | A kind of preparation method of anti-blue light antifogging and dustproof film |
| CN110564311B (en) * | 2019-09-17 | 2021-06-08 | 浙江派菲特新材料科技有限公司 | Preparation method of impact-resistant low-whitening instant adhesive |
| CN111529988B (en) * | 2020-04-16 | 2021-12-03 | 江苏斯迪克新材料科技股份有限公司 | Medical antifogging protective mask |
| CN111560210B (en) * | 2020-04-16 | 2021-11-16 | 江苏斯迪克新材料科技股份有限公司 | Antifog medical isolation face guard of wear-type high definition |
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| Publication number | Publication date |
|---|---|
| CN104708875A (en) | 2015-06-17 |
| TWM483172U (en) | 2014-08-01 |
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