CN106189758B - Antifogging composition, antifogging sheet and antifogging coating - Google Patents
Antifogging composition, antifogging sheet and antifogging coating Download PDFInfo
- Publication number
- CN106189758B CN106189758B CN201510909500.1A CN201510909500A CN106189758B CN 106189758 B CN106189758 B CN 106189758B CN 201510909500 A CN201510909500 A CN 201510909500A CN 106189758 B CN106189758 B CN 106189758B
- Authority
- CN
- China
- Prior art keywords
- particle
- antifog
- extinction
- weight percentage
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 238000000576 coating method Methods 0.000 title claims description 59
- 239000011248 coating agent Substances 0.000 title claims description 57
- 239000002245 particle Substances 0.000 claims abstract description 88
- 239000011347 resin Substances 0.000 claims abstract description 34
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 239000010937 tungsten Substances 0.000 claims abstract description 24
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 24
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 polypropylene Polymers 0.000 claims abstract description 21
- 239000002105 nanoparticle Substances 0.000 claims abstract description 18
- 239000004417 polycarbonate Substances 0.000 claims abstract description 14
- 239000004743 Polypropylene Substances 0.000 claims abstract description 12
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 12
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 12
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 12
- 229920001155 polypropylene Polymers 0.000 claims abstract description 10
- 230000008033 biological extinction Effects 0.000 claims description 59
- 206010037660 Pyrexia Diseases 0.000 claims description 41
- 239000000853 adhesive Substances 0.000 claims description 38
- 230000001070 adhesive effect Effects 0.000 claims description 38
- 239000000126 substance Substances 0.000 claims description 24
- 229910000906 Bronze Inorganic materials 0.000 claims description 23
- 239000003522 acrylic cement Substances 0.000 claims description 23
- 239000010974 bronze Substances 0.000 claims description 23
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical group O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 22
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 22
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 21
- 239000008187 granular material Substances 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 239000000741 silica gel Substances 0.000 claims description 9
- 229910002027 silica gel Inorganic materials 0.000 claims description 9
- 239000003365 glass fiber Substances 0.000 claims description 8
- 125000000524 functional group Chemical group 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 7
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 5
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- MPSXZBZUSOMAQW-UHFFFAOYSA-N acetic acid;prop-1-ene Chemical group CC=C.CC(O)=O MPSXZBZUSOMAQW-UHFFFAOYSA-N 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 5
- 229930016911 cinnamic acid Natural products 0.000 claims description 5
- 235000013985 cinnamic acid Nutrition 0.000 claims description 5
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 5
- 238000007711 solidification Methods 0.000 claims description 5
- 230000008023 solidification Effects 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 238000013007 heat curing Methods 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims 3
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims 3
- 235000013339 cereals Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 229910052746 lanthanum Inorganic materials 0.000 abstract description 6
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 abstract description 6
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 abstract description 2
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 3
- 239000011152 fibreglass Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 21
- 239000000758 substrate Substances 0.000 description 18
- 239000011734 sodium Substances 0.000 description 11
- 239000011575 calcium Substances 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000005034 decoration Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000004836 Glue Stick Substances 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 5
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052787 antimony Inorganic materials 0.000 description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 5
- 229910052788 barium Inorganic materials 0.000 description 5
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
- 229910052794 bromium Inorganic materials 0.000 description 5
- 229910052792 caesium Inorganic materials 0.000 description 5
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 229910052733 gallium Inorganic materials 0.000 description 5
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 5
- 229910052740 iodine Inorganic materials 0.000 description 5
- 239000011630 iodine Substances 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229910052701 rubidium Inorganic materials 0.000 description 5
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 229910052712 strontium Inorganic materials 0.000 description 5
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- GVFOJDIFWSDNOY-UHFFFAOYSA-N antimony tin Chemical compound [Sn].[Sb] GVFOJDIFWSDNOY-UHFFFAOYSA-N 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 230000002085 persistent effect Effects 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000013464 silicone adhesive Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- XXLJGBGJDROPKW-UHFFFAOYSA-N antimony;oxotin Chemical compound [Sb].[Sn]=O XXLJGBGJDROPKW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2258—Oxides; Hydroxides of metals of tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An anti-fog composition comprising: 90-99.999% by weight of resin; and 0.001-10 wt% of light-absorbing heating particles, wherein the resin is polycarbonate, polymethyl methacrylate, glass fiber reinforced plastic or polypropylene, and the light-absorbing heating particles are tungsten-containing oxide nanoparticles, indium tin oxide, antimony tin oxide or lanthanum hexaboride. The light-absorbing heating particles can effectively convert light energy into heat energy, so that the antifogging composition with the antifogging function can be directly prepared into various antifogging articles, and the effect of maintaining the durability of the antifogging is achieved.
Description
Technical field
The present invention relates to a kind of composition, especially a kind of antifog composition, the present invention additionally comprises the antifog composition
Made antifog plate, and the anti-fog coating as made by the antifog composition.
Background technique
Aqueous vapor in air can be condensed in surface temperature naturally and substantially be lower than on the article of air, in body surface shape
At small-sized droplet, such natural phenomena often causes many inconvenience for life, such as: morning window-glass adheres to water mist, and
To shine upon and after evaporation drying, it is irritating water stain in being formed on glass；Not only in this, to the people for living in the low cold area of temperature
For the people, water mist condense the problem of be more likely to generate contingency, such as: being often condensed in glass for vehicle window fog is traffic safety
A big secret worry therefore how fog to be effectively prevent to be condensed on article, become considerable project.
In general, at present often using a fog remover or an electric heater with demisting, wherein user is in the article for being intended to demisting
Surface is coated with an antifoggant to form an antifog film, which includes interfacial agent and organic solvent, and when being formed, this is antifog
After film, it is possible to reduce aqueous vapor allows aqueous vapor to be not easy to condense to form drop in article surface, reach whereby in the surface tension of body surface
To antifog effect.In addition, user can also contact article surface using the electric heater, to improve the temperature of article surface,
Reduce the case where aqueous vapor in air is condensed in object to the cold generation.
However, the persistence of the antifoggant is not high, often after article surface is coated with the antifoggant for a period of time, i.e., because of object
Product generate friction with foreign object, cut and scrape, or so that the antifog film is fallen off by heavy rain Washing, and then lose to the antifog of article
Effect, thus when using the antifoggant with prevent fog article surface formed when, it is necessary to often repeatedly spray could maintain
Effectiveness, however, repeatedly spraying can even generate human health negative since the spray contains the organic matter solvent of high volatile
Face is rung.In addition, improving article temperature with the electric heater, it is necessary to provide electric power constantly to maintain article in a predetermined temperature, with
Prevent aqueous vapor from condensing to the cold, in this way, put into a large amount of energy cost in order to antifog, hence it is evident that in current environmentally friendly trend phase
It is contrary to.
In view of this, it is necessary to provide a kind of antifog composition, antifog plate and anti-fog coating, to solve in the past in order to prevent
The problem that fog is formed on article and uses the antifoggant and the electric heater.
Summary of the invention
The present invention provides a kind of antifog composition, which can convert light energy into thermal energy.
The present invention provides a kind of antifog plate, and the antifog plate is by antifog composition institute former above-mentioned.
The present invention provides a kind of anti-fog coating, which is formed by antifog composition above-mentioned.
The present invention provides a kind of antifog composition, it includes: by weight percentage for 90~99.999% resin, should
Resin is polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；And it is by weight percentage
0.001~10% extinction fever particle, the extinction generate heat particle for tungstenic oxide nano-particles, tin indium oxide, antimony oxide
Tin or lanthanum hexaboride.
Antifog composition of the invention, wherein the tungstenic oxide nano-particles are selected from by a tungsten oxide nanometer particle, and
Group composed by one tungsten bronze complex nanometer granule.
Antifog composition of the invention, wherein the chemical formula of the tungsten oxide nanometer particle is WOx, wherein 2.2≤x≤3.
Antifog composition of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is AyWOz, wherein A is
Major element, 0.01≤y≤1,2.2≤z≤3.
Antifog composition of the invention, wherein the chemical formula of the tungsten oxide nanometer particle is WO2.72。
Antifog composition of the invention, wherein A be lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), magnesium (Mg),
Calcium (Ca), strontium (Sr), barium (Ba), aluminium (Al), gallium (Ga), carbon (C), silicon (Si), tin (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine
(Br) or iodine (I).
Antifog composition of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3。
Antifog composition of the invention, wherein the particle size of the tungstenic oxide nano-particles is 1nm~500nm.
The present invention provides a kind of antifog plate, it includes: by weight percentage for 90~99.999% resin, the resin
For polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；It and is by weight percentage 0.001
~10% extinction fever particle, extinction fever particle are scattered in the resin, which generates heat particle for containing tungsten oxide
Nanoparticle, tin indium oxide, antimony tin or lanthanum hexaboride.
Antifog plate of the invention, wherein the antifog plate with a thickness of 10 μm~10mm, and the antifog plate include with weight hundred
Divide the extinction fever particle than meter 0.005~10%.
Antifog plate of the invention, wherein the tungstenic oxide nano-particles are selected from by a tungsten oxide nanometer particle and a tungsten
Group composed by bronze complex nanometer granule.
Antifog plate of the invention, wherein the chemical formula of the tungsten oxide nanometer particle is WOx, wherein 2.2≤x≤3.
Antifog plate of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is AyWOz, wherein A is main group
Element, 0.01≤y≤1,2.2≤z≤3.
Antifog plate of the invention, wherein the chemical formula of the tungsten oxide nanometer particle is WO2.72。
Antifog plate of the invention, wherein A is lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), magnesium (Mg), calcium
(Ca), strontium (Sr), barium (Ba), aluminium (Al), gallium (Ga), carbon (C), silicon (Si), tin (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine
(Br) or iodine (I).
Antifog plate of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3。
Antifog plate of the invention, wherein the particle size of the tungstenic oxide nano-particles is 1nm~500nm.
The present invention provides another antifog composition, it includes: by weight percentage for 90~99.999% adhesion
Agent, the sticker are a monomer or the oligomer comprising the monomer, which has selected from by siloxy, acrylic, amino
One functional group of group composed by formic acid ester group；And by weight percentage for 0.001~10% extinction generate heat particle, should
Extinction generates heat particle for tungstenic oxide nano-particles, tin indium oxide, antimony tin or lanthanum hexaboride.
Antifog composition of the invention, wherein the sticker is an oiliness acryl glue stick, an aqueous acryl gluing
Agent, a Polyurethane glue stick or an organic liquid silica gel.
Antifog composition of the invention, wherein the oiliness acryl glue stick is a thermoplasticity acryl glue stick, a heat
Solidity acryl glue stick or a polyalcohols type acryl glue stick.
Antifog composition of the invention, wherein the aqueous acryl glue stick is an acrylic acid adhesive, a cinnamic acid
Adhesive or an acetate propylene acid adhesive.
Antifog composition of the invention, wherein the organic liquid silica gel is an organic silicon adhesive, monomethyl organic silicone
Adhesive, an organosilicon alcohol acid adhesive or an acid-organosilicon crylic acid adhesive.
Antifog composition of the invention, wherein the tungstenic oxide nano-particles are selected from by a tungsten oxide nanometer particle, and
Group composed by one tungsten bronze complex nanometer granule.
Antifog composition of the invention, wherein the chemical formula of the tungsten oxide nanometer particle is WO2.72。
The antifog composition of the present invention, wherein the chemical formula of tungsten bronze complex nanometer granule is AyWOz, wherein A is
Lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminium (Al), gallium (Ga),
Carbon (C), silicon (Si), tin (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine (Br) or iodine (I), and 0.01≤y≤1,2.2≤z≤3.
Antifog composition of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3。
Antifog composition of the invention, wherein the partial size of extinction fever particle is 1nm~500nm.
The present invention provides a kind of anti-fog coating, includes: by weight percentage for 90~99.999% sticker, this is viscous
Agent be a monomer or the oligomer comprising the monomer, which has selected from by siloxy, acrylic, carbamate groups
One functional group of composed group；And by weight percentage for 0.001~10% extinction generate heat particle, the extinction fever
Particle is tungstenic oxide nano-particles, tin indium oxide, antimony tin or lanthanum hexaboride, wherein extinction fever particle dispersion
In the sticker, and via heat cure or ultraviolet light solidification an anti-fog coating is collectively formed.
Anti-fog coating of the invention, wherein the anti-fog coating with a thickness of 100nm~10mm.
Anti-fog coating of the invention, wherein the sticker is an oiliness acryl glue stick, an aqueous acryl gluing
Agent, a Polyurethane glue stick or an organic liquid silica gel.
Anti-fog coating of the invention, wherein the oiliness acryl glue stick is a thermoplasticity acryl glue stick, a thermosetting
Property acryl glue stick or a polyalcohols type acryl glue stick.
Anti-fog coating of the invention, wherein the aqueous acryl glue stick is an acrylic acid adhesive, a cinnamic acid glue
Stick or an acetate propylene acid adhesive.
Anti-fog coating of the invention, wherein the organic liquid silica gel is an organic silicon adhesive, monomethyl organic silicone glue
Stick, an organosilicon alcohol acid adhesive or an acid-organosilicon crylic acid adhesive.
Anti-fog coating of the invention, wherein the tungstenic oxide nano-particles are selected from by a tungsten oxide nanometer particle and one
Group composed by tungsten bronze complex nanometer granule.
Anti-fog coating of the invention, wherein the chemical formula of the tungsten oxide nanometer particle is WO2.72。
Anti-fog coating of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is AyWOz, wherein A is lithium
(Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminium (Al), gallium (Ga), carbon
(C), silicon (Si), tin (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine (Br) or iodine (I), and 0.01≤y≤1,2.2≤z≤3.
Anti-fog coating of the invention, wherein the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3。
Antifog composition of the invention includes the extinction fever particle for being by weight percentage 0.001~10%, the suction
Light fever particle can effectively absorb luminous energy, and be converted further into thermal energy.In addition, being included according to the antifog composition
The characteristic of resin or sticker, which separately can be further configured to the antifog plate by user (can also be in this
The anti-fog coating is formed on the anti-fog surface of substrate), the effect for the particle that can so generate heat by the extinction makes the antifog plate
The temperature of (or anti-fog coating) rises, and be condensed in aqueous vapor can not on the antifog plate (or anti-fog coating), and then reach antifog
Effect.
Also, it therefore is not necessary to be intended to antifog object by the antifog composition directly to be prepared to the various antifogging article of forming
Antifoggant easy to fall off is sprayed on product, and then is reached and maintained antifog persistent effect.
In addition, antifog plate above-mentioned or be formed with the substrate of the anti-fog coating more can be directly as such as window, eaves
Equal Building Decoration Materials are used, or existing Building Decoration Material is carried out to the processing of anti-fog coating, when sunlight is irradiated in by this
When window made of antifog plate (or window Jing Guo anti-fog coating processing), window makes in temperature because converting light energy into thermal energy
It rises, thereon to avoid fog condensation, compared to the fog for using electric heater removal window surface, using antifog plate of the invention
And the substrate for being formed with the anti-fog coating can achieve as Building Decoration Material and save antifog required the effect of expending energy.
Detailed description of the invention
Fig. 1: for the stereo appearance figure of the antifog plate of the present invention.
Fig. 2: for the cutaway view Amplified image of the antifog plate of the present invention.
Fig. 3: the photo figure for being polycarbonate plate E0 group after antifog test.
Fig. 4: for photo figure of the antifog plate E1 group of the present invention after antifog test.
Specific embodiment
For above and other objects, features and advantages of the invention can be clearer and more comprehensible, be cited below particularly it is of the invention compared with
Good embodiment, and cooperate institute's accompanying drawings, it is described in detail below:
The antifog composition of the present invention includes the extinction fever particle for being by weight percentage 0.001~10%, the extinction
Fever particle can convert light energy into thermal energy, have the effect of the antifog composition antifog.
In more detail, extinction fever particle is tungstenic oxide nano-particles, tin indium oxide (Indium Tin
Oxide, abbreviation ITO), antimony tin (Antimony Tin Oxide, abbreviation ATO) or lanthanum hexaboride (LaB6), or by above-mentioned
Group composed by compound.Wherein, the particle size of extinction fever particle is 1nm~500nm, and this contains tungsten oxide and receives
Rice corpuscles can be the combination of tungsten oxide nanometer particle, tungsten bronze complex nanometer granule or both.
In detail, the chemical formula of the tungsten oxide nanometer particle is WOx, wherein 2.2≤x≤3；The tungsten bronze compound is received
The chemical formula of rice corpuscles is AyWOz, wherein A be the periodic table of elements in major element, 0.01≤y≤1,2.2≤z≤3, preferably
Ground, A are lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminium (Al), gallium
(Ga), carbon (C), silicon (Si), tin (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine (Br) or iodine (I), the tungsten bronze compound nanometer
Particle can be Cs0.33WO3、K0.33WO3、K0.55WO3、Na0.5WO3Or Ba0.33WO3Nanoparticle.In first embodiment, the oxygen
Change tungsten nanoparticle is WO2.72Nanoparticle, which is then Cs0.33WO3Nanoparticle.
Can additionally comprise in the antifog composition of first embodiment of the invention is 90~99.999% by weight percentage
Resin, which can be polycarbonate (Polycarbonate, abbreviation PC), polymethyl methacrylate
(Polymethylmethacrylate, abbreviation PMMA), glass fibre reinforced plastic (Fiber Reinforced Plastic,
Abbreviation FRP) or polypropylene (Polypropylene, abbreviation PP)；In this way, can be according to contained resin type and its molecule
Amount is different, can form transparent, translucent or opaque antifog plate, and the antifog plate of different light transmittances respectively has different purposes,
In, the transparent antifog plate, which is presented, can be used as window or other perspective materials uses.
It please refers to shown in Fig. 1~2, this is the schematic diagram of the antifog plate of the present invention, which includes a resin plate 1 and several
Extinction fever particle 2, several extinctions fever particles 2 disperse in the resin plate 1, which includes to be by weight percentage
90~99.999% resin, and be by weight percentage 0.001~10% extinction fever particle 2, which has
One thickness d, preferably, the thickness d is 10 μm~10mm, and the antifog plate can have by weight percentage for 0.005~
10% extinction fever particle 2, wherein the thickness d of the antifog plate and the ratio of extinction fever particle 2 can mutually match
It closes, to reach preferable defogging effect, for example, when the thickness d is 10 μm, which preferably contains 100000ppm
The extinction fever particle of (being by weight percentage 10%)；When the thickness d is 1mm, which preferably contains
The extinction fever particle of 1000ppm (being by weight percentage 0.1%)；When the thickness d is 2mm, the antifog plate is preferable
Extinction fever particle containing 500ppm (being by weight percentage 0.05%)；When the thickness d is 10mm, the antifog plate
Extinction fever particle preferably containing 50ppm (being by weight percentage 0.005%).
The antifog plate can be shaped by the methods of extrusion forming process or die forming method, type, the extinction depending on the resin
Fever particle and the mixture homogeneity of resin and the purposes of the antifog plate are adjusted, and are herein seldom to be limited.For example:
When the resin is thermoplasticity resin (such as: polycarbonate, polypropylene or polymethyl methacrylate), first the extinction is generated heat
Particle 2 is fed at the charging of single screw extruder or double-screw compressor according to predetermined ratio simultaneously with the resin, and is extruded each
The antifog plate of kind thickness；When the material of the resin plate is thermoset resin (such as: glass fibre reinforced plastic), by specific ratio
The extinction fever particle of example makes an addition in unsaturated polyester (UP), and is uniformly mixed with the monomer of styrene, and reheating pours into mold
In, to form the antifog plate of the specific thickness d.In addition, shaping the antifog plate when resin is respectively PC, PMMA, FRP and PP
Processing temperature preferably be respectively 250~290 DEG C, 180~220 DEG C, 80~120 DEG C and 190~230 DEG C.
In addition, in the antifog composition of second embodiment of the invention, in addition to comprising as the aforementioned by weight percentage
Generate heat except particle for 0.001~10% extinction, separately may include by weight percentage for 90~99.999% it is viscous
Agent；In details of the words, which is a monomer or the oligomer comprising the monomer, which has selected from by siloxy, third
One functional group of group composed by olefin(e) acid base, carbamate groups.
The sticker can choose as an oiliness acryl glue stick, an aqueous acryl glue stick, a Polyurethane gluing
Agent or an organic liquid silica gel；For example, which can be a thermoplasticity acryl glue stick (Changxing
Material industry limited liability company, ETERAC 7106-X-58), a thermosetting acryl adhesive (Changxing material industry share
Co., Ltd, ETERAC 7232-BR-58) or a polyalcohols type acryl glue stick (Changxing material industry limited liability company,
ETERAC 7305-3-XC-50) (the characteristic system in relation to the oiliness acryl glue stick can be such as http://www.eternal-
Group.com/Product/Detail? shown in id=92&lang=tw)；The aqueous acryl glue stick can be a propylene
Sour adhesive (Changxing material industry limited liability company, ETERSOL 1137), cinnamic acid adhesive (Changxing material industry
Limited liability company, ETERSOL 6515T) or an acetate propylene acid adhesive (Changxing material industry limited liability company,
ETERSOL 3503)；The Polyurethane glue stick can be such as south treasured resin NP-35 or Changxing material industry limited liability company
(characteristic in relation to the Polyurethane glue stick can be such as http://www.nanpao.com.cn/chi/ by ETERAC 7786
Product1.asp? d2=8 and http://www.eternal-group.com/Product/Detail? id=88&lang=
Shown in tw)；The organic liquid silica gel can be an organic silicon adhesive (Gui Liguang limited liability company, Taiwan SHIN-ETSU HANTOTAI, KR-
282), monomethyl organic silicone adhesive (Gui Liguang limited liability company, Taiwan SHIN-ETSU HANTOTAI, KR-500), an organosilicon alcohol acid gluing
Agent (Gui Liguang limited liability company, Taiwan SHIN-ETSU HANTOTAI, KR-5206) or an acid-organosilicon crylic acid adhesive (Taiwan SHIN-ETSU HANTOTAI silicon benefit light stock
Part Co., Ltd, KR-9706) (the characteristic system in relation to the organic liquid silica gel can be such as http: //
Www.shinetsu.com.tw/html/pdt2.asp? shown in area=65&cat=212&sn=85).
Also, an anti-fog coating can be further made in the antifog composition of second embodiment of the invention, such as can use
Wet coating method is coated on the anti-fog surface of a substrate, continuous to form the anti-fog coating in the anti-fog surface via solidification.Citing
For, the material of the substrate is selected from glass, polycarbonate or polymethyl acrylate, and can according to the substrate material or
The composition of the antifog composition of the second embodiment, selection are coated on the substrate with knife coating, curtain coating, roll coating process or spray coating method
Anti-fog surface, separately can choose with thermal curing method or ultraviolet light solidification method to form the anti-fog coating, and the thickness of the anti-fog coating
Degree can be preferably 100nm~10mm, to reach excellent antifog effect.
An antifog door and window can be further made or any probably due to fog in the substrate for being formed with the anti-fog coating
And influence the structure (for example, eyeglass etc. of the lampshade of car light, glasses) of translucency, alternatively, user can also according to demand, with
Commercially available door and window is as the substrate, in forming the anti-fog coating on its anti-fog surface, can also obtain the antifog door and window.It is worth noting
, the anti-fog surface for being formed with the substrate of the anti-fog coating preferably can be that the substrate hold to contact Cryogenic air, and more
The surface easily to haze；By taking the door of chilled food showcase as an example, which can preferably be formed in the inner surface of this；
By taking the window of building as an example, which can preferably be formed in the outer surface of window to correspond to temperature change；In addition,
User can also select to be respectively formed the anti-fog coating in each surface of the substrate, without restriction in this.
Antifog composition of the invention includes the extinction fever particle for being by weight percentage 0.001~10%, the suction
Light fever particle can effectively absorb luminous energy, and be converted further into thermal energy.In addition, being included according to the antifog composition
The characteristic of resin or sticker, which separately can be further configured to the antifog plate by user (can also be in this
The anti-fog coating is formed on the anti-fog surface of substrate), the effect for the particle that can so generate heat by the extinction makes the antifog plate
The temperature of (or anti-fog coating) rises, and be condensed in aqueous vapor can not on the antifog plate (or anti-fog coating), and then reach antifog
Effect.
Also, it therefore is not necessary to be intended to antifog object by the antifog composition directly to be prepared to the various antifogging article of forming
Antifoggant easy to fall off is sprayed on product, and then is reached and maintained antifog persistent effect.
In addition, antifog plate above-mentioned or be formed with the substrate of the anti-fog coating more can be directly as such as window, eaves
Equal Building Decoration Materials are used, or existing Building Decoration Material is carried out to the processing of anti-fog coating, when sunlight is irradiated in by this
When window made of antifog plate (or window Jing Guo anti-fog coating processing), window makes in temperature because converting light energy into thermal energy
It rises, thereon to avoid fog condensation, compared to the fog for using electric heater removal window surface, using antifog plate of the invention
And the substrate for being formed with the anti-fog coating can achieve as Building Decoration Material and save antifog required the effect of expending energy.
In order to confirm that the antifog plate made by antifog composition of the invention has antifog effectiveness really, hereby carry out down
Column test:
Temperature and anti misting capability test
This test converts different experiment parameters respectively, tests the temperature and anti misting capability of each group and control group.Temperature examination
Proved recipe method was that each group is placed in room temperature environment, with halogen light irradiation 15 seconds (A0, A1 group) of 15 centimeters of 500W of distance
Or 30 seconds (B0~F0 and B1~F1 group), and the temperature value after each group irradiation is measured with infrared temperature measurer, it is antifog
Ability test method is that each group through halogen light irradiation is covered in the cup overthe openings for containing 80 DEG C of hot water, to visually observe
The corresponding relationship and test result of water mist adhesion condition, group and experimental variation are as shown in table 1 below in detail, and Fig. 3 and Fig. 4 then divide
The situation of E0 group and E1 group after antifog test is not presented.Wherein, A0~D0 and A1~D1 group are solid slab structure, the
E0 and E1 group is cored slab structure.Wherein F0 is the veneer clear glass of thickness 3mm, and F1 is coating 0.015mm thickness containing suction
Light exothermic material concentration is 10% single panel-shaped glass by weight percentage.
Table 1: the corresponding relationship and test result of group and experimental variation
By the result of this test it will be evident that after irradiation one set time of halogen lamp, added with 20~100000ppm's
The antifog plate (A1, B1, C1, D1, E1 and F1 group) of extinction fever particle, relative to the plate control group as made by resin
(A0, B0, C0, D0, E0 and F0 group), temperature significantly improves.It can be seen that antifog plate of the invention can incite somebody to action relative to control group
Halogen lamp luminous energy obtained is irradiated, thermal energy is efficiently converted into, is substantially increased the temperature of the antifog plate, prevents air whereby
In aqueous vapor condense to the cold thereon.Also, by Fig. 3 and Fig. 4 it is found that compared to control group (E0 group) covering after irradiating
When above hot water, surface is attached with apparent misty droplet, and surface is not for the antifog plate (E1 group) of the invention through irradiating
It has observed droplet generation, thus can demonstrate,prove the antifog plate of the present invention fog can be effectively prevented really and be formed in the antifog plate surface.
In conclusion antifog composition of the invention includes to generate heat by weight percentage for 0.001~10% extinction
Particle, extinction fever particle can effectively absorb luminous energy, and be converted further into thermal energy.In addition, according to the antifog combination
The antifog composition separately can be further configured to the antifog plate by the characteristic of resin or sticker that object is included, user
(anti-fog coating can also be formed on the anti-fog surface of the substrate), the effect for the particle that can so generate heat by the extinction,
Increase the temperature of the antifog plate (or anti-fog coating), be condensed in aqueous vapor can not on the antifog plate (or anti-fog coating), in turn
Achieve the effect that antifog.
Also, it therefore is not necessary to be intended to antifog object by the antifog composition directly to be prepared to the various antifogging article of forming
Antifoggant easy to fall off is sprayed on product, and then is reached and maintained antifog persistent effect.
In addition, antifog plate above-mentioned or be formed with the substrate of the anti-fog coating more can be directly as such as window, eaves
Equal Building Decoration Materials are used, or existing Building Decoration Material is carried out to the processing of anti-fog coating, when sunlight is irradiated in by this
When window made of antifog plate (or window by anti-fog coating processing), window makes in temperature because converting light energy into thermal energy
It rises, thereon to avoid fog condensation, compared to the fog for using electric heater removal window surface, using antifog plate of the invention
And the substrate for being formed with the anti-fog coating can achieve as Building Decoration Material and save antifog required the effect of expending energy.
The foregoing is merely a prefered embodiment of the invention, is not able to this and limits the protection scope that the present invention is implemented, therefore all ginsengs
Simple equivalent changes and modifications made by description of the invention are examined, protection scope of the present invention is still belonged to.
Claims (21)
1. a kind of antifog composition, it is characterised in that include: by weight percentage for 90~99.999% a resin, should
Resin is polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；And it is by weight percentage
0.001~10% extinction fever particle, the extinction generate heat particle for tungsten bronze complex nanometer granule, and the tungsten bronze is multiple
The chemical formula for closing object nanoparticle is Cs0.33WO3。
2. a kind of antifog composition, it is characterised in that include: by weight percentage for 90~99.999% a resin, should
Resin is polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；And it is by weight percentage
0.001~10% extinction fever particle, extinction fever particle is tungsten oxide nanometer particle, the tungsten oxide nanometer particle
Chemical formula be WO2.72。
3. antifog composition as claimed in claim 1 or 2, which is characterized in that wherein, the partial size of extinction fever particle is 1
The nm of nm~500.
4. a kind of antifog plate, it is characterised in that include: by weight percentage for 90~99.999% a resin, the resin
For polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；It and is by weight percentage 0.001
~10% extinction fever particle, extinction fever particle are scattered in the resin, and extinction fever particle is multiple for tungsten bronze
Object nanoparticle is closed, the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3。
5. a kind of antifog plate, it is characterised in that include: by weight percentage for 90~99.999% a resin, the resin
For polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；It and is by weight percentage 0.001
~10% extinction fever particle, extinction fever particle are scattered in the resin, and extinction fever particle is received for tungsten oxide
Rice corpuscles, the chemical formula of the tungsten oxide nanometer particle are WO2.72。
6. antifog plate as described in claim 4 or 5, which is characterized in that wherein, the antifog plate with a thickness of 10 μm~10
Mm, and the antifog plate includes by weight percentage 0.005~10% extinction fever particle.
7. antifog plate as described in claim 4 or 5, which is characterized in that wherein, the extinction generate heat particle partial size be 1 nm~
500 nm。
8. a kind of antifog composition, it is characterised in that include: by weight percentage for 90 ~ 99.999% a sticker, should
Sticker is a monomer or the oligomer comprising the monomer, which has selected from by siloxy, acrylic, carbamic acid
One functional group of group composed by ester group；And by weight percentage for 0.001 ~ 10% an extinction generate heat particle, should
Extinction generates heat particle for tungsten bronze complex nanometer granule, and the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3。
9. a kind of antifog composition, it is characterised in that include: by weight percentage for 90~99.999% a sticker,
The sticker is a monomer or the oligomer comprising the monomer, which has selected from by siloxy, acrylic, amino first
One functional group of group composed by perester radical；And by weight percentage for 0.001~10% an extinction generate heat grain
Son, the extinction generate heat particle for tungsten oxide nanometer particle, and the chemical formula of the tungsten oxide nanometer particle is WO2.72。
10. antifog composition as claimed in claim 8 or 9, which is characterized in that wherein, which is an oiliness pressure gram
Power adhesive, an aqueous acryl glue stick, a polyurethane adhesive or an organic liquid silica gel.
11. antifog composition as claimed in claim 10, which is characterized in that wherein, which is one
Thermoplasticity acryl glue stick, a thermosetting acryl adhesive or a polyalcohols type acryl glue stick.
12. antifog composition as claimed in claim 10, which is characterized in that wherein, which is one
Acrylic acid adhesive, a cinnamic acid adhesive or an acetate propylene acid adhesive.
13. antifog composition as claimed in claim 10, which is characterized in that wherein, which is one organic
Silicon adhesive, a methylsiloxane ketone adhesive, an organosilicon alcohol acid adhesive or an acid-organosilicon crylic acid adhesive.
14. antifog composition as claimed in claim 8 or 9, which is characterized in that wherein, the partial size of extinction fever particle is 1
The nm of nm~500.
15. a kind of anti-fog coating, it is characterised in that include: by weight percentage for 90 ~ 99.999% a sticker, should
Sticker is a monomer or the oligomer comprising the monomer, which has selected from by siloxy, acrylic, carbamic acid
One functional group of group composed by ester group；And by weight percentage for 0.001 ~ 10% an extinction generate heat particle, should
Extinction generates heat particle for tungsten bronze complex nanometer granule, and the chemical formula of tungsten bronze complex nanometer granule is Cs0.33WO3；Its
In, extinction fever particle is scattered in the sticker, and antifog to be collectively formed one via heat cure or ultraviolet light solidification
Coating.
16. a kind of anti-fog coating, it is characterised in that include: by weight percentage for 90~99.999% a sticker, should
Sticker is a monomer or the oligomer comprising the monomer, which has selected from by siloxy, acrylic, carbamic acid
One functional group of group composed by ester group；And by weight percentage for 0.001~10% an extinction generate heat particle,
The extinction generates heat particle for tungsten oxide nanometer particle, and the chemical formula of the tungsten oxide nanometer particle is WO2.72；Wherein, which sends out
Hot particle is scattered in the sticker, and via heat cure or ultraviolet light solidification an anti-fog coating is collectively formed.
17. the anti-fog coating as described in claim 15 or 16, which is characterized in that wherein, the anti-fog coating with a thickness of 100
The mm of nm~10.
18. the anti-fog coating as described in claim 15 or 16, which is characterized in that wherein, which is an oiliness pressure gram
Power adhesive, an aqueous acryl glue stick, a polyurethane adhesive or an organic liquid silica gel.
19. anti-fog coating as claimed in claim 18, which is characterized in that wherein, which is a heat
Plasticity acryl adhesive, a thermosetting acryl adhesive or a polyalcohols type acryl glue stick.
20. anti-fog coating as claimed in claim 18, which is characterized in that wherein, which is one third
Olefin(e) acid adhesive, a cinnamic acid adhesive or an acetate propylene acid adhesive.
21. anti-fog coating as claimed in claim 18, which is characterized in that wherein, which is an organosilicon
Adhesive, a methylsiloxane ketone adhesive, an organosilicon alcohol acid adhesive or an acid-organosilicon crylic acid adhesive.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW104116964 | 2015-05-27 | ||
| TW104116964 | 2015-05-27 | ||
| TW104137027 | 2015-11-10 | ||
| TW104137027A TWI576391B (en) | 2015-05-27 | 2015-11-10 | An USE OF A MIST-PROOF COMPOSITION FOR MIST-PROOF |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106189758A CN106189758A (en) | 2016-12-07 |
| CN106189758B true CN106189758B (en) | 2019-04-09 |
Family
ID=57453263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510909500.1A Active CN106189758B (en) | 2015-05-27 | 2015-12-10 | Antifogging composition, antifogging sheet and antifogging coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106189758B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10520588B2 (en) * | 2017-04-11 | 2019-12-31 | Ford Global Technologies, Llc | Maintaining clean laser lens windows using light absorbing materials |
| CN114031307B (en) * | 2021-12-06 | 2023-05-26 | 四川英诺维新材料科技有限公司 | Photothermal anti-fog glass plate and preparation method thereof |
| CN115466545A (en) * | 2022-09-26 | 2022-12-13 | 张磊 | Coating composition for intelligent lens and preparation method thereof |
| CN115505253A (en) * | 2022-10-18 | 2022-12-23 | 烟台佳隆纳米产业有限公司 | Heat absorption type antifogging lens and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320662A (en) * | 2011-07-04 | 2012-01-18 | 大连工业大学 | Cesium tungsten bronze powder and preparation method thereof |
| CN104250487A (en) * | 2013-06-28 | 2014-12-31 | 方俐善 | Organic dye enhanced transparent and heat-insulating coating material, preparation method and application thereof |
| CN104371281A (en) * | 2013-08-13 | 2015-02-25 | 台虹科技股份有限公司 | Light absorbing and heat accumulating composition and light absorbing and heat accumulating structure prepared therefrom |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5102969B2 (en) * | 2006-04-14 | 2012-12-19 | 出光興産株式会社 | Polycarbonate resin composition and molded plate thereof |
| US7952805B2 (en) * | 2006-08-22 | 2011-05-31 | 3M Innovative Properties Company | Solar control film |
| KR20110128861A (en) * | 2009-02-12 | 2011-11-30 | 바스프 에스이 | Polymer compositions containing nanoparticulate ir absorbers |
| CN102527621B (en) * | 2011-12-27 | 2014-07-09 | 浙江科创新材料科技有限公司 | Preparation method for haze-adjustable flexible transparent conductive film |
-
2015
- 2015-12-10 CN CN201510909500.1A patent/CN106189758B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320662A (en) * | 2011-07-04 | 2012-01-18 | 大连工业大学 | Cesium tungsten bronze powder and preparation method thereof |
| CN104250487A (en) * | 2013-06-28 | 2014-12-31 | 方俐善 | Organic dye enhanced transparent and heat-insulating coating material, preparation method and application thereof |
| CN104371281A (en) * | 2013-08-13 | 2015-02-25 | 台虹科技股份有限公司 | Light absorbing and heat accumulating composition and light absorbing and heat accumulating structure prepared therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106189758A (en) | 2016-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106189758B (en) | Antifogging composition, antifogging sheet and antifogging coating | |
| Zhang et al. | Preparation of colorful, infrared-reflective, and superhydrophobic polymer films with obvious resistance to dust deposition | |
| US20150323710A1 (en) | Biooptical and biofunctional properties, applications and methods of polylactic acid films | |
| JP3003581B2 (en) | A member that exhibits hydrophilicity in response to optical excitation of an optical semiconductor | |
| JP3077199B2 (en) | Photocatalytic hydrophilic coating composition | |
| Xu et al. | A robust and transparent hydrogel coating for sustainable antifogging with excellent self-cleaning and self-healing ability | |
| Du et al. | Structurally colored surfaces with antireflective, self-cleaning, and antifogging properties | |
| JP2004124058A (en) | Member having hydrophilic surface | |
| CN1422309A (en) | Transparent medium having angle-selective transmission or reflection properties and/or absorption properties | |
| JP2012526041A (en) | Super hydrophilic nanostructure | |
| CN101384926A (en) | Coating system | |
| CN104718168A (en) | Anti-soiling compositions, methods of applying, and application equipment | |
| CN104769023B (en) | For the nanometer titanium dioxide silicon coating for hindering dewdrop to be formed | |
| CN104130607B (en) | Antifogging coating, antifogging base material and method for producing antifogging base material | |
| CN104708875B (en) | Antifog heat insulating film | |
| JP5422836B2 (en) | Exothermic translucent sheet and exothermic translucent membrane roof structure | |
| Boström et al. | Durability tests of solution-chemically derived spectrally selective absorbers | |
| ES2682070T3 (en) | Glitter and manufacturing procedure | |
| TWI576391B (en) | An USE OF A MIST-PROOF COMPOSITION FOR MIST-PROOF | |
| US8696998B2 (en) | Biooptical and biofunctional properties, applications and methods of polylactic acid films | |
| JP2011195792A (en) | Exothermic light-transmitting sheet and exothermic light-transmitting film roof structure | |
| JP6797511B2 (en) | Aqueous infrared / ultraviolet shielding coating agent and infrared / ultraviolet shielding treatment method using this | |
| Jaoua‐Bahloul et al. | Solar spectral properties of PVC plastisol‐based films filled with various fillers | |
| TW313630B (en) | The surface substrate with light catalyst and hydrophilicity and its manufacturing method | |
| Syafiq et al. | Study of transmission and reflection of hydrophilic transparent nano-titanium dioxide coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |