CN104708875A - Antifog heat insulating film - Google Patents
Antifog heat insulating film Download PDFInfo
- Publication number
- CN104708875A CN104708875A CN201410045039.5A CN201410045039A CN104708875A CN 104708875 A CN104708875 A CN 104708875A CN 201410045039 A CN201410045039 A CN 201410045039A CN 104708875 A CN104708875 A CN 104708875A
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- CN
- China
- Prior art keywords
- water base
- layer
- acrylate
- fog
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 124
- 238000009413 insulation Methods 0.000 claims abstract description 82
- 239000002105 nanoparticle Substances 0.000 claims abstract description 40
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- VSFOXJWBPGONDR-UHFFFAOYSA-M potassium;3-prop-2-enoyloxypropane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)CCCOC(=O)C=C VSFOXJWBPGONDR-UHFFFAOYSA-M 0.000 claims abstract description 23
- 239000010410 layer Substances 0.000 claims description 130
- 238000002955 isolation Methods 0.000 claims description 48
- 239000000463 material Substances 0.000 claims description 48
- 239000011248 coating agent Substances 0.000 claims description 47
- 238000000576 coating method Methods 0.000 claims description 47
- 239000012790 adhesive layer Substances 0.000 claims description 39
- 239000002245 particle Substances 0.000 claims description 33
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 25
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 22
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 22
- LDYPJGUPKKJBIB-UHFFFAOYSA-M sodium;3-prop-2-enoyloxypropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CCCOC(=O)C=C LDYPJGUPKKJBIB-UHFFFAOYSA-M 0.000 claims description 22
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 16
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 14
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 7
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 229920005749 polyurethane resin Polymers 0.000 claims description 7
- 238000007711 solidification Methods 0.000 claims description 7
- 230000008023 solidification Effects 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- OFIZHEVXDIWONW-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid;sodium Chemical compound [Na].OS(=O)(=O)CCCOC(=O)C=C OFIZHEVXDIWONW-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000003595 mist Substances 0.000 description 4
- -1 acryl Chemical group 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/14—Layered products comprising a layer of synthetic resin next to a particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
Abstract
An antifogging and heat-insulating film comprises a heat-insulating layer and an antifogging layer. The heat insulation layer is provided with a first surface and a second surface, and the first surface is opposite to the second surface. The antifogging layer is arranged on the first surface of the heat insulation layer and comprises a water-based antifogging agent and nanoparticles, the water-based antifogging agent is selected from the group consisting of Sodium 3-sulfopropyl acrylate, Potassium 3-sulfopropyl acrylate and a combination thereof, and the nanoparticles are selected from the group consisting of SiO2、Al2O3、TiO2ZnO, and combinations thereof. The invention provides an antifogging heat-insulating filmThe fogging phenomenon on the surface of the article in the prior art can be overcome.
Description
Technical field
The present invention relates to a kind of thermal isolation film, particularly the antifog thermal isolation film of one.
Background technology
Because global warming phenomenon is on the rise, advanced country there's no one who doesn't or isn't drops into a large sum of funds in energy-conservation science and technology and green energy resource to solve the problem of warming up, and warms up phenomenon to slowing down.Although in the recent period because the exploitation of shale oil and shale gas; energy crisis is made seemingly to have slightly slow trend; but on long terms; fossil energy has exhausted one day eventually; and the greenhouse gases excessively using fossil fuel to produce will cause global warming phenomenon to worsen further, to be therefore still human society very urgent and must the problem of input with all strength in carbon reduction.
Current most buildings curtain or vehicle glass all can stick thermal isolation film mostly, with the radiant heat outside isolated building or outside car, and then reduce the burden of building or air conditioning for automobiles, improve comfort level that is indoor or occupant.But most thermal isolation film does not all have antifog effect.Clammy once weather, the glass curtain in vehicle window or building is easily tied mist and affects the sight line of driver or indoor occupant.
In addition, for locomotive knight, when temperature is colder, its safety helmet lens or goggles easily tie mist because of breathing.In addition in daily life, when personnel are after hot water a period of time is opened in bathroom, mirror surfaces also can form fumulus because of the condensation of steam.Therefore, the knot mist phenomenon of article surface can cause the inconvenience of user really.
Summary of the invention
In view of this, in order to overcome the knot mist phenomenon of article surface in prior art, the object of the invention is to propose a kind of antifog thermal isolation film.
Comprise a thermal insulation layer and an anti-fog layer.Thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Anti-fog layer is arranged at the first surface of thermal insulation layer, anti-fog layer comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropylacrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.
In one of them concept of the present invention, the thermal insulation layer of antifog thermal isolation film comprises nanometer tungsten oxide or nano zirconia particles, or its mixture particle, and average grain diameter is in the scope of 20 nanometer to 70 nanometers.
In one of them concept of the present invention, antifog thermal isolation film more comprises a base material, is arranged at the second surface of thermal insulation layer.
In one of them concept of the present invention, antifog thermal isolation film more comprises a pressure-sensing glue and a release layer, is sequentially arranged at the exposed surface of this base material.
In one of them concept of the present invention, the material of base material is PET.
In one of them concept of the present invention, the anti-fog layer of antifog thermal isolation film makes with following method:
One anti-fog coating is provided, when this anti-fog coating is based on the gross weight of this anti-fog coating, comprises the water base acryl polyurethane oligomer between 15% to 25%;
Water base acryl monomer between 15% to 25%, this water base acryl monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
This anti-fog coating is coated this first surface of this thermal insulation layer;
Drying coated in this anti-fog coating of this first surface; And
This anti-fog coating of this first surface is coated in solidification.
In one of them concept of the present invention, in the step of above-mentioned dry anti-fog coating, be hold temperature 1 to 2 minute at the temperature of 100 DEG C to 110 DEG C in fact.
One of them concept of the present invention is a kind of antifog thermal isolation film, comprises thermal insulation layer, base material, anti-fog layer, pressure sensing adhesive layer and release layer.Thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Base material is arranged at the first surface of thermal insulation layer.Anti-fog layer is arranged on base material, anti-fog layer comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.Pressure sensing adhesive layer is arranged at the second surface of thermal insulation layer, and release layer is then arranged in pressure sensing adhesive layer.
One of them concept of the present invention is a kind of antifog thermal isolation film, comprises heat insulation pressure sensing adhesive layer, base material, anti-fog layer and release layer.Heat insulation pressure sensing adhesive layer has a first surface and a second surface, and first surface is relative to second surface.Base material is arranged at the first surface of heat insulation pressure sensing adhesive layer.Anti-fog layer is arranged on base material, anti-fog layer comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropylacrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.Release layer is then arranged on the second surface of heat insulation pressure sensing adhesive layer.
One of them concept of the present invention is a kind of antifog thermal isolation film, comprises thermal insulation layer, two base materials, anti-fog layer, pressure sensing adhesive layer and release layer.Thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Two base materials are arranged at first surface and the second surface of thermal insulation layer respectively.Anti-fog layer is arranged at and is positioned on the base material of first surface, anti-fog layer comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.Pressure sensing adhesive layer is arranged at and is positioned on the base material of second surface, and release layer is then arranged in pressure sensing adhesive layer.
One of them concept of the present invention is a kind of antifog thermal isolation film, comprises antifog thermal insulation layer, base material, pressure sensing adhesive layer and release layer.Antifog thermal insulation layer has a first surface and a second surface, and first surface is relative to second surface.Base material is arranged at the second surface of antifog thermal insulation layer, and the first surface of antifog thermal insulation layer is for exposed.Antifog thermal insulation layer comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.In addition, antifog thermal insulation layer also comprises nanometer tungsten oxide particle, or nano zirconia particles, and the average grain diameter of particle is in the scope of 20 nanometer to 70 nanometers.Pressure sensing adhesive layer is arranged on base material, and release layer is then arranged in pressure sensing adhesive layer.
In one of them concept of the present invention, be in fact at 200 to 800 mJ/cm with intensity
2scope in the anti-fog coating of ultraviolet light to the first surface coating thermal isolation film carry out photocuring.
Describe the present invention below in conjunction with the drawings and specific embodiments, but not as a limitation of the invention.
Accompanying drawing explanation
Fig. 1 is the cross-sectional schematic of the first embodiment of the present invention;
Fig. 2 is the cross-sectional schematic of the second embodiment of the present invention;
Fig. 3 is the cross-sectional schematic of the third embodiment of the present invention;
Fig. 4 is the cross-sectional schematic of the fourth embodiment of the present invention;
Fig. 5 is the cross-sectional schematic of the fifth embodiment of the present invention;
Fig. 6 is the cross-sectional schematic of the sixth embodiment of the present invention;
Fig. 7 is the cross-sectional schematic of the seventh embodiment of the present invention.
Wherein, Reference numeral
10 antifog thermal isolation film
11 thermal insulation layers
111 first surfaces
112 second surfaces
12 anti-fog layers
13 base materials
14 pressure-sensing glue
15 release layers
20 antifog thermal isolation film
30 antifog thermal isolation film
40 antifog thermal isolation film
50 antifog thermal isolation film
51 heat insulation pressure sensing adhesive layer
511 first surfaces
512 second surfaces
60 antifog thermal isolation film
70 antifog thermal isolation film
71 antifog thermal insulation layers
711 first surfaces
712 second surfaces
Detailed description of the invention
Below in conjunction with accompanying drawing, structural principle of the present invention and operation principle are described in detail:
Please refer to Fig. 1, is the cross-sectional schematic of first embodiment of the invention, discloses a kind of antifog thermal isolation film 10, comprises thermal insulation layer 11 and an anti-fog layer 12.
Thermal insulation layer 11 has first surface 111 and a second surface 112, and first surface 111 is relative to second surface 112.
Anti-fog layer 12 is arranged at the first surface 111 of thermal insulation layer 11, anti-fog layer 12 comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium 3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.
In the present embodiment, the thermal insulation layer 11 of antifog thermal isolation film 10 comprises nanometer tungsten oxide (WO
3) particle, or nano zirconia particles, its average grain diameter is in the scope of 20 nanometer to 70 nanometers.Experiment finds that nanometer tungsten oxide particle surface plasma wavelength is between visible ray and infrared light intersection (780 nanometer).Due to nanometer tungsten oxide particle or nano zirconia particles, surface has this kind of surface plasma wavelength characteristic, visible ray (wavelength 380 nanometer to 780 nanometer), because wavelength is less than the surface plasma wavelength of nanometer tungsten oxide particle or nano zirconia particles, thus can penetrate.But infrared light (being the main source of heat) is because wavelength is on 780 nanometers, be greater than the surface plasma wavelength of nanometer tungsten oxide particle or nano zirconia particles, therefore in incident ray, most infrared light is reflected back, make infrared light can not enter in indoor or car, greatly reduce indoor or vehicle interior temperature, and then reach the outer or outer heat energy of car of isolating chamber and keep the requirement of its light transmission.Except nanometer tungsten oxide particle or nano zirconia particles, other metal oxide nanoparticles, if any similar surfaces plasma wavelength between visible ray and infrared light intersection (780 nanometer) or near, also can be used to when thermal insulation layer 11.
Please refer to Fig. 2, is the cross-sectional schematic of the second embodiment of the present invention, discloses a kind of antifog thermal isolation film 20.The Main Differences of the present embodiment and the first embodiment is that the antifog thermal isolation film 20 of the present embodiment more comprises a base material 13, is arranged at the second surface 112 of thermal insulation layer 11.In the present embodiment, the material of base material selects PET.
Please refer to Fig. 3, is the cross-sectional schematic of the third embodiment of the present invention, discloses a kind of antifog thermal isolation film 30.The Main Differences of the present embodiment and the second embodiment is that the antifog thermal isolation film 30 of the present embodiment more comprises pressure-sensing glue 14 and a release layer 15, is sequentially arranged at the exposed surface of base material 13.The present embodiment can be attached at the surface of various article easily through pressure-sensing glue 14.
Please refer to Fig. 4, is the cross-sectional schematic of the fourth embodiment of the present invention, discloses a kind of antifog thermal isolation film 40, comprises thermal insulation layer 11, base material 13, anti-fog layer 12, pressure sensing adhesive layer 14 and release layer 15.
Thermal insulation layer 11 has first surface 111 and a second surface 112, and first surface 111 is relative to second surface 112.Base material 13 is arranged at the first surface 111 of thermal insulation layer 11.Anti-fog layer 12 is arranged on base material 13, anti-fog layer 12 comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.Pressure sensing adhesive layer 14 is arranged at the second surface 112 of thermal insulation layer 11, and release layer 15 is arranged in pressure sensing adhesive layer 14.
Please refer to Fig. 5, is the cross-sectional schematic of the fifth embodiment of the present invention, discloses a kind of antifog thermal isolation film 50, comprises heat insulation pressure sensing adhesive layer 51, base material 13, anti-fog layer 12 and release layer 15.
Heat insulation pressure sensing adhesive layer 51 has first surface 511 and a second surface 512, and first surface 511 is relative to second surface 512.Base material 13 is arranged at the first surface 511 of heat insulation pressure sensing adhesive layer 51.Anti-fog layer 12 is arranged on base material 13, anti-fog layer 12 comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropylacrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.Release layer 15 is arranged on the second surface 512 of heat insulation pressure sensing adhesive layer.
Please refer to Fig. 6, is the cross-sectional schematic of the sixth embodiment of the present invention, discloses a kind of antifog thermal isolation film 60, comprises thermal insulation layer 11, two base material 13, anti-fog layer 12, pressure sensing adhesive layer 14 and release layer 15.
Thermal insulation layer 11 has first surface 111 and a second surface 112, and first surface 111 is relative to second surface 112.Two base materials 13 are arranged at first surface 111 and the second surface 112 of thermal insulation layer 11 respectively.Anti-fog layer 12 is arranged at and is positioned on the base material 13 of first surface 111, anti-fog layer 12 comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.Pressure sensing adhesive layer 14 is arranged at and is positioned on the base material 13 of second surface 112, and release layer 15 is arranged in pressure sensing adhesive layer 14.
Please refer to Fig. 7, is the cross-sectional schematic of the seventh embodiment of the present invention, discloses a kind of antifog thermal isolation film 70, comprises antifog thermal insulation layer 71, base material 13, pressure sensing adhesive layer 14 and release layer 15.
Antifog thermal insulation layer 71 has first surface 711 and a second surface 712, and first surface 711 is relative to second surface 712.Base material 13 is arranged at the second surface 712 of antifog thermal insulation layer 71, and the first surface 711 of antifog thermal insulation layer 71 is for exposed.Antifog thermal insulation layer 12 comprises water base antifoggant and nano particle, water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and described nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.In addition, antifog thermal insulation layer 71 also comprises nanometer tungsten oxide particle, or nano zirconia particles, and its average grain diameter is in the scope of 20 nanometer to 70 nanometers.Pressure sensing adhesive layer 14 is arranged on base material 13, and release layer 15 is arranged in pressure sensing adhesive layer 14.
In each embodiment of the present invention, anti-fog layer 12 makes with following method:
One anti-fog coating is provided, comprises time wherein based on the gross weight of anti-fog coating:
Water base acrylic polyurethane oligomer between 15% to 25%;
Water base acrylic monomer between 15% to 25%, this water base acrylic monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
Anti-fog coating is coated the first surface 111 of thermal insulation layer 11;
Drying coated in the anti-fog coating of first surface 111; And
The anti-fog coating of first surface 111 is coated in solidification.
In the step of above-mentioned dry anti-fog coating, be hold temperature 1 to 2 minute at the temperature of 100 DEG C to 110 DEG C in fact.And in curing schedule, be in fact at 250 to 450mJ/cm with intensity
2scope in the anti-fog coating of ultraviolet light to the first surface 111 coating thermal insulation layer 11 carry out photocuring.
The antifog thermal insulation layer 71 of the 7th embodiment is that in described anti-fog layer, add average grain diameter be further nanometer tungsten oxide particle between 20 nanometer to 70 nanometers or nano zirconia particles, and is had heat insulation and antifog effect simultaneously.
The thermal insulation layer of the various embodiments described above or the light transmittance of pressure-sensitive thermal insulation layer and infrared ray rejection rate can sell commercial specification according to actual and adjust.Such as infrared ray rejection rate can be more than 90 70 percent, 80 percent or percent, but the present invention is not as limit, and when the content of nanometer tungsten oxide particle or nano zirconia particles is higher, then ultrared rejection rate is just higher.In addition, also can add a certain proportion of carbon black to adjust its light transmittance in thermal insulation layer or pressure-sensitive thermal insulation layer, such as light transmittance can be percent 20, percent 40 or percent 70, but the present invention is not as limit.
Certainly; the present invention also can have other various embodiments; when not deviating from the present invention's spirit and essence thereof; those of ordinary skill in the art are when making various corresponding change and distortion according to the present invention, but these change accordingly and are out of shape the protection domain that all should belong to the claim appended by the present invention.
Claims (16)
1. an antifog thermal isolation film, is characterized in that, comprises:
One thermal insulation layer, have a first surface and a second surface, this first surface is relative to this second surface; And
One anti-fog layer, be arranged at the first surface of this thermal insulation layer, this anti-fog layer comprises water base antifoggant and nano particle, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and this nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof.
2. antifog thermal isolation film according to claim 1, is characterized in that, this thermal insulation layer comprises nanometer tungsten oxide particle, or nano zirconia particles, and its average grain diameter is in the scope of 20 nanometer to 70 nanometers.
3. antifog thermal isolation film according to claim 2, it is characterized in that, more comprise a base material, a pressure-sensing glue and a release layer, the material of this base material is PET and is arranged at the second surface of this thermal insulation layer, and this pressure-sensing glue and this release layer are sequentially arranged at the exposed surface of this base material.
4. the antifog thermal isolation film according to claims 1 to 3 any one, is characterized in that, this anti-fog layer makes with following method:
One anti-fog coating is provided, comprises when this anti-fog coating is based on the gross weight of this anti-fog coating:
Water base acrylic polyurethane oligomer between 15% to 25%;
Water base acrylic monomer between 15% to 25%, this water base acrylic monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
This anti-fog coating is coated this first surface of this thermal insulation layer;
Drying coated in this anti-fog coating of this first surface; And
This anti-fog coating of this first surface is coated in solidification.
5. an antifog thermal isolation film, is characterized in that, comprises:
One heat insulation pressure sensing adhesive layer, have a first surface and a second surface, this first surface is relative to this second surface;
One base material, is arranged on this first surface of this heat insulation pressure sensing adhesive layer;
One anti-fog layer, be arranged on this base material, this anti-fog layer comprises water base antifoggant and nano particle, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and this nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof; And
One release layer, is arranged at this second surface of this heat insulation pressure sensing adhesive layer.
6. antifog thermal isolation film according to claim 5, is characterized in that, this heat insulation pressure sensing adhesive layer comprises nanometer tungsten oxide particle or nano zirconia particles, and average grain diameter is in the scope of 20 nanometer to 70 nanometers.
7. the antifog thermal isolation film according to claim 5 or 6, is characterized in that, this anti-fog layer makes with following method:
One anti-fog coating is provided, comprises when this anti-fog coating is based on the gross weight of this anti-fog coating:
Water base acrylic polyurethane oligomer between 15% to 25%;
Water base acrylic monomer between 15% to 25%, this water base acrylic monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
This anti-fog coating is coated this first surface of this heat insulation pressure sensing adhesive layer;
Drying coated in this anti-fog coating of this first surface; And
This anti-fog coating of this first surface is coated in solidification.
8. an antifog thermal isolation film, is characterized in that, comprises:
One thermal insulation layer, have a first surface and a second surface, this first surface is relative to this second surface;
One base material, is arranged on this first surface of this thermal insulation layer;
One anti-fog layer, be arranged on this base material, this anti-fog layer comprises water base antifoggant and nano particle, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and this nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
One pressure sensing adhesive layer, is arranged at this second surface of this thermal insulation layer; And
One release layer, is arranged in this pressure sensing adhesive layer.
9. antifog thermal isolation film according to claim 8, is characterized in that, this thermal insulation layer comprises nanometer tungsten oxide particle or nano zirconia particles, and its average grain diameter is in the scope of 20 nanometer to 70 nanometers.
10. antifog thermal isolation film according to claim 8 or claim 9, it is characterized in that, this anti-fog layer makes with following method:
One anti-fog coating is provided, comprises when this anti-fog coating is based on the gross weight of this anti-fog coating:
Water base acrylic polyurethane oligomer between 15% to 25%;
Water base acrylic monomer between 15% to 25%, this water base acrylic monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
This anti-fog coating is coated this first surface of this thermal insulation layer;
Drying coated in this anti-fog coating of this first surface; And
This anti-fog coating of this first surface is coated in solidification.
11. 1 kinds of antifog thermal isolation film, is characterized in that, comprise:
One thermal insulation layer, have a first surface and a second surface, this first surface is relative to this second surface;
Two base materials, on this first surface being arranged at this thermal insulation layer respectively and this second surface;
One anti-fog layer, be arranged at and be positioned on this base material of this first surface, this anti-fog layer comprises water base antifoggant and nano particle, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and this nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof; And
One pressure sensing adhesive layer, is arranged at and is positioned on this base material of this second surface; And
One release layer, is arranged in this pressure sensing adhesive layer.
12. antifog thermal isolation film according to claim 11, is characterized in that, this heat insulation pressure sensing adhesive layer comprises nanometer tungsten oxide particle or nano zirconia particles, and average grain diameter is in the scope of 20 nanometer to 70 nanometers.
13. antifog thermal isolation film according to claim 11 or 12, it is characterized in that, this anti-fog layer makes with following method:
One anti-fog coating is provided, comprises when this anti-fog coating is based on the gross weight of this anti-fog coating:
Water base acrylic polyurethane oligomer between 15% to 25%;
Water base acrylic monomer between 15% to 25%, this water base acrylic monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
This anti-fog coating is coated this first surface of this thermal insulation layer;
Drying coated in this anti-fog coating of this first surface; And
This anti-fog coating of this first surface is coated in solidification.
14. 1 kinds of antifog thermal isolation film, is characterized in that, comprise:
One antifog thermal insulation layer, comprise water base antifoggant and nano particle, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form, and this nano particle is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof; This antifog thermal insulation layer more comprises nanometer tungsten oxide particle;
One base material, is arranged at the surface of this antifog thermal insulation layer;
One pressure sensing adhesive layer, is arranged on this base material; And
One release layer, is arranged in this pressure sensing adhesive layer.
15. antifog thermal isolation film according to claim 14, is characterized in that, nanometer tungsten oxide particle or nano zirconia particles, and average grain diameter is in the scope of 20 nanometer to 70 nanometers.
16. antifog thermal isolation film according to claims 14 or 15, it is characterized in that, this anti-fog layer makes with following method:
One anti-fog coating is provided, comprises when this anti-fog coating is based on the gross weight of this anti-fog coating:
Water base acrylic polyurethane oligomer between 15% to 25%;
Water base acrylic monomer between 15% to 25%, this water base acrylic monomer is selected from the group that hydroxyethyl acrylate, hydroxyethyl methacrylate, acrylic acid, methylenebisacrylamide, methyl methacrylate and combination thereof form;
Water base antifoggant between 2% to 5%, this water base antifoggant is selected from the group that Sodium3-sulphonatopropyl acrylate, Potassium3-sulphonatopropyl acrylate and combination thereof form;
Water base wetting agent between 0.2 to 0.5%;
Water base defoamer between 0.5 to 2.5%;
Water base levelling agent between 0.1 to 0.5%;
Water base between 0.2 to 2% shakes change agent, and this is water base shakes that to become agent be polyurethane resin into polyether-type;
Silane coupling agent between 1 to 3%;
Water base adherence promoter between 5% to 10%;
Nano sol between 15% to 25%, the nano particle that this Nano sol comprises is selected from SiO
2, Al
2o
3, TiO
2, the group that forms of ZnO and combination thereof;
Water base smooth initiator between 1% to 2%; And
The water of balanced contents;
This anti-fog coating is coated this first surface of this thermal insulation layer;
Drying coated in this anti-fog coating of this first surface; And
This anti-fog coating of this first surface is coated in solidification.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW102223653U TWM483172U (en) | 2013-12-13 | 2013-12-13 | Fog prevention heat insulation film |
| TW102223653 | 2013-12-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104708875A true CN104708875A (en) | 2015-06-17 |
| CN104708875B CN104708875B (en) | 2017-06-30 |
Family
ID=51792863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410045039.5A Active CN104708875B (en) | 2013-12-13 | 2014-02-07 | Antifog heat insulating film |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN104708875B (en) |
| TW (1) | TWM483172U (en) |
Cited By (5)
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| CN106476379A (en) * | 2016-09-21 | 2017-03-08 | 东莞市联洲知识产权运营管理有限公司 | A kind of heat-insulated antifog film of vehicle glass |
| CN109476217A (en) * | 2016-07-20 | 2019-03-15 | 日本板硝子株式会社 | The manufacturing method of windshield and windshield |
| CN109666176A (en) * | 2018-12-20 | 2019-04-23 | 何琛邦 | A kind of preparation method of anti-blue light antifogging and dustproof film |
| CN110564311A (en) * | 2019-09-17 | 2019-12-13 | 浙江派菲特新材料科技有限公司 | preparation method of impact-resistant low-whitening instant adhesive |
| CN111529988A (en) * | 2020-04-16 | 2020-08-14 | 江苏斯迪克新材料科技股份有限公司 | Medical antifogging protective mask |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111560210B (en) * | 2020-04-16 | 2021-11-16 | 江苏斯迪克新材料科技股份有限公司 | Antifog medical isolation face guard of wear-type high definition |
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Also Published As
| Publication number | Publication date |
|---|---|
| TWM483172U (en) | 2014-08-01 |
| CN104708875B (en) | 2017-06-30 |
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