CN104695250B - A kind of polyphenol fabric-modifying agent and preparation method thereof - Google Patents
A kind of polyphenol fabric-modifying agent and preparation method thereof Download PDFInfo
- Publication number
- CN104695250B CN104695250B CN201510097040.7A CN201510097040A CN104695250B CN 104695250 B CN104695250 B CN 104695250B CN 201510097040 A CN201510097040 A CN 201510097040A CN 104695250 B CN104695250 B CN 104695250B
- Authority
- CN
- China
- Prior art keywords
- polyphenol
- fabric
- preparation
- modifying agent
- stirred
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of polyphenol fabric-modifying agent and preparation method thereof, modifier comprises that vine polyphenol is that 5wt%-14wt%, gallic acid are that 3wt%-7wt%, chlorogenic acid are that 2wt%-6wt%, polyoxyethylene polyoxypropylene amidogen ether are that 7wt%-14wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 4wt%-8wt%, Tween-80 are that 5wt%-11wt%, CSL are that 3wt%-8wt%, glycerine are that 6wt%-12wt%, surplus are water. Described preparation method comprises the following steps: stir above-mentioned various materials by weight percentage (1), is stirred to evenly; (2) mixed liquor after step (1) is stirred is sheared with cutter again, after shearing, leave standstill, and be the polyphenol fabric-modifying agent of preparation. The modifier of preparation can effectively improve dye-uptake, degree of fixation and the fastness to soaping of real silk fabric.
Description
Technical field
The invention belongs to field of textiles, relate to a kind of modifier and preparation method thereof, particularly relate to a kind of polyphenol fabricModifier and preparation method thereof.
Background technology
Cellulose fibre is electronegative in dye bath, and great majority are all anionic property (acidity is dyed for dying cotton dyestuffMaterial, reactive dye, direct dyes and leuco vat dye etc.), due to electrostatic repulsion, on dyestuff, dye and be suppressed, dyeIn bath, often need to add a large amount of neutral electrolytes to improve dyestuff dye-uptake. These electrolyte are discharged with dyeing waste liquid, giveEnvironment has caused great pollutional load. Cellulose fibre is carried out to modification, contain different activities group (as epoxy by useBase, active halogen, ethoxylate or amine) ammonia or reactive cation modifier pretreatment, reduce or eliminate negative electricity on fiberLotus effect, can improve the ability of fibers adsorption dyestuff.
It is more that real silk fabric carries out the method for modification, how effectively to improve upper for reactive dye of real silk fabricDye rate, degree of fixation and fastness to soaping, remain at present a difficult problem to be solved.
Summary of the invention
The technical problem solving: the object of this invention is to provide a kind of novel agent of polyphenol fabric-modifying and preparation side thereofMethod, through after modifier treatment, improves dye-uptake, degree of fixation and the fastness to soaping of real silk fabric.
Technical scheme: the invention discloses a kind of polyphenol fabric-modifying agent and preparation method thereof, described polyphenol fabric changesProperty agent comprises the composition of following weight percentage:
Vine polyphenol 5wt%-14wt%,
Gallic acid 3wt%-7wt%,
Chlorogenic acid 2wt%-6wt%,
Polyoxyethylene polyoxypropylene amidogen ether 7wt%-14wt%,
Two hydrogenated-tallow group alkyl dimethyl ammonium chloride 4wt%-8wt%,
Tween-80 5wt%-11wt%,
CSL 3wt%-8wt%,
Glycerine 6wt%-12wt%,
Surplus is water.
Described a kind of polyphenol fabric-modifying agent, comprises the composition of following weight percentage:
Vine polyphenol 7wt%-12wt%,
Gallic acid 4wt%-6wt%,
Chlorogenic acid 3wt%-5wt%,
Polyoxyethylene polyoxypropylene amidogen ether 9wt%-13wt%,
Two hydrogenated-tallow group alkyl dimethyl ammonium chloride 5wt%-7wt%,
Tween-80 8wt%-10wt%,
CSL 4wt%-6wt%,
Glycerine 7wt%-10wt%,
Surplus is water.
Described a kind of polyphenol fabric-modifying agent, comprises the composition of following weight percentage:
Vine polyphenol 9wt%,
Gallic acid 5wt%,
Chlorogenic acid 4wt%,
Polyoxyethylene polyoxypropylene amidogen ether 11wt%,
Two hydrogenated-tallow group alkyl dimethyl ammonium chloride 6wt%,
Tween-80 9wt%,
CSL 5wt%,
Glycerine 9wt%,
Surplus is water.
A preparation method for polyphenol fabric-modifying agent, described preparation method comprises the following steps:
(1) getting respectively by weight percentage vine polyphenol is that 5wt%-14wt%, gallic acid are 3wt%-7wt%, chlorogenic acidFor 2wt%-6wt%, polyoxyethylene polyoxypropylene amidogen ether are that 7wt%-14wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are 4wt%-8wt%, Tween-80 are that 5wt%-11wt%, CSL are that 3wt%-8wt%, glycerine are that 6wt%-12wt%, surplus are water,Above-mentioned various materials are stirred, be stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 4000-7000rpm, shear time is 20min-50min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
The preparation method of described a kind of polyphenol fabric-modifying agent, cutter rotating speed is 5000rpm.
The preparation method of described a kind of polyphenol fabric-modifying agent, shear time is 40min.
Beneficial effect: after real silk fabric is processed by polyphenol fabric-modifying agent of the present invention, it is upper to reactive dyeDye rate, degree of fixation and fastness to soaping and be all greatly improved, chlorogenic acid and polyoxy in fabric-modifying agent of the present inventionTwo kinds of compositions of ethene polyoxypropylene amidogen ether, have larger impact to the effect that improves the agent of polyphenol fabric-modifying.
Detailed description of the invention
Embodiment 1
(1) getting respectively by weight percentage vine polyphenol is that 14wt%, gallic acid are that 3wt%, chlorogenic acid are 6wt%, polyoxyEthene polyoxypropylene amidogen ether is that 7wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 8wt%, Tween-80 are 11wt%, stearoylCalcium lactate is that 3wt%, glycerine are that 12wt%, surplus are water, and above-mentioned various materials are stirred, and is stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
Embodiment 2
(1) getting respectively by weight percentage vine polyphenol is that 5wt%, gallic acid are that 7wt%, chlorogenic acid are 2wt%, polyoxyEthene polyoxypropylene amidogen ether is that 14wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 4wt%, Tween-80 are 5wt%, stearoylCalcium lactate is that 8wt%, glycerine are that 6wt%, surplus are water, and above-mentioned various materials are stirred, and is stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
Embodiment 3
(1) getting respectively by weight percentage vine polyphenol is that 7wt%, gallic acid are that 6wt%, chlorogenic acid are 3wt%, polyoxyEthene polyoxypropylene amidogen ether is that 13wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 5wt%, Tween-80 are 8wt%, stearoylCalcium lactate is that 6wt%, glycerine are that 10wt%, surplus are water, and above-mentioned various materials are stirred, and is stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
Embodiment 4
(1) getting respectively by weight percentage vine polyphenol is that 12wt%, gallic acid are that 4wt%, chlorogenic acid are 5wt%, polyoxyEthene polyoxypropylene amidogen ether is that 9wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 7wt%, Tween-80 are 10wt%, stearoylCalcium lactate is that 4wt%, glycerine are that 7wt%, surplus are water, and above-mentioned various materials are stirred, and is stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
Embodiment 5
(1) getting respectively by weight percentage vine polyphenol is that 9wt%, gallic acid are that 5wt%, chlorogenic acid are 4wt%, polyoxyEthene polyoxypropylene amidogen ether is that 11wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 6wt%, Tween-80 are 9wt%, stearoylCalcium lactate is that 5wt%, glycerine are that 9wt%, surplus are water, and above-mentioned various materials are stirred, and is stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
Comparative example 1
(1) getting respectively by weight percentage vine polyphenol is that 14wt%, gallic acid are 3wt%, two hydrogenated-tallow group diformazanAmmonium chloride is that 8wt%, Tween-80 are that 11wt%, CSL are that 3wt%, glycerine are that 12wt%, surplus are water, by above-mentionedVarious materials stir, be stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
Comparative example 2
(1) getting respectively by weight percentage vine polyphenol is that 14wt%, gallic acid are that 3wt%, chlorogenic acid are 6wt%, polyoxyEthene polyoxypropylene amidogen ether is that 7wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are that 8wt%, Tween-80 are that 11wt%, glycerine are12wt%, surplus are water, and above-mentioned various materials are stirred, and are stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 5000rpm,Shear time is 40min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
By 10 times of the modifier dilutions of the above embodiments and comparative example, real silk fabric is placed in to dilution, in temperatureBe to soak 4h at 70 DEG C, dry post-drying. Real silk fabric is dyeed, dyestuff is orange active dye again, measures through placeDye-uptake, degree of fixation and the fastness to soaping of the real silk fabric after reason. Situation is as follows:
| Dye-uptake | Degree of fixation | Fastness to soaping | |
| Embodiment 1 | 79.5% | 75.5% | 4 grades |
| Embodiment 2 | 76.9% | 78.2% | 4 grades |
| Embodiment 3 | 86.2% | 83.4% | 4 grades |
| Embodiment 4 | 84.6% | 80.1% | 4 grades |
| Embodiment 5 | 90.5% | 86.6% | 5 grades |
| Comparative example 1 | 59.2% | 63.8% | 3 grades 3 --> |
| Comparative example 2 | 64.6% | 67.3% | 3 grades |
Chlorogenic acid, polyoxyethylene polyoxypropylene amidogen ether, CSL have the modified effect of polyphenol fabric-modifying agentVery large impact, add after three kinds of above-mentioned compositions fabric dye-uptake, degree of fixation and fastness to soaping after its modificationAll obtain promoting greatly.
Claims (6)
1. a polyphenol fabric-modifying agent, is characterized in that described polyphenol fabric-modifying agent comprises the one-tenth of following weight percentagePoint:
Vine polyphenol 5wt%-14wt%,
Gallic acid 3wt%-7wt%,
Chlorogenic acid 2wt%-6wt%,
Polyoxyethylene polyoxypropylene amidogen ether 7wt%-14wt%,
Two hydrogenated-tallow group alkyl dimethyl ammonium chloride 4wt%-8wt%,
Tween-80 5wt%-11wt%,
CSL 3wt%-8wt%,
Glycerine 6wt%-12wt%,
Surplus is water.
2. a kind of polyphenol fabric-modifying according to claim 1 agent, is characterized in that described polyphenol fabric-modifying agent bagDraw together the composition of following weight percentage:
Vine polyphenol 7wt%-12wt%,
Gallic acid 4wt%-6wt%,
Chlorogenic acid 3wt%-5wt%,
Polyoxyethylene polyoxypropylene amidogen ether 9wt%-13wt%,
Two hydrogenated-tallow group alkyl dimethyl ammonium chloride 5wt%-7wt%,
Tween-80 8wt%-10wt%,
CSL 4wt%-6wt%,
Glycerine 7wt%-10wt%,
Surplus is water.
3. a kind of polyphenol fabric-modifying according to claim 2 agent, is characterized in that described polyphenol fabric-modifying agent bagDraw together the composition of following weight percentage:
Vine polyphenol 9wt%,
Gallic acid 5wt%,
Chlorogenic acid 4wt%,
Polyoxyethylene polyoxypropylene amidogen ether 11wt%,
Two hydrogenated-tallow group alkyl dimethyl ammonium chloride 6wt%,
Tween-80 9wt%,
CSL 5wt%,
Glycerine 9wt%,
Surplus is water.
4. a preparation method for polyphenol fabric-modifying agent, is characterized in that, described preparation method comprises the following steps:
(1) getting respectively by weight percentage vine polyphenol is that 5wt%-14wt%, gallic acid are that 3wt%-7wt%, chlorogenic acid are2wt%-6wt%, polyoxyethylene polyoxypropylene amidogen ether are that 7wt%-14wt%, two hydrogenated-tallow group alkyl dimethyl ammonium chloride are 4wt%-8wt%, Tween-80 are that 5wt%-11wt%, CSL are that 3wt%-8wt%, glycerine are that 6wt%-12wt%, surplus are water,Above-mentioned various materials are stirred, be stirred to evenly;
(2) mixed liquor after step (1) is stirred is sheared with cutter again, and cutter rotating speed is 4000-7000rpm, shear time is 20min-50min, after shearing, leaves standstill, and is the polyphenol fabric-modifying agent of preparation.
5. the preparation method of a kind of polyphenol fabric-modifying according to claim 4 agent, is characterized in that described preparation sideIn method, cutter rotating speed is 5000rpm.
6. the preparation method of a kind of polyphenol fabric-modifying according to claim 4 agent, is characterized in that described preparation sideIn method, shear time is 40min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510097040.7A CN104695250B (en) | 2015-03-05 | 2015-03-05 | A kind of polyphenol fabric-modifying agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510097040.7A CN104695250B (en) | 2015-03-05 | 2015-03-05 | A kind of polyphenol fabric-modifying agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104695250A CN104695250A (en) | 2015-06-10 |
| CN104695250B true CN104695250B (en) | 2016-05-25 |
Family
ID=53342767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510097040.7A Active CN104695250B (en) | 2015-03-05 | 2015-03-05 | A kind of polyphenol fabric-modifying agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104695250B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102383321A (en) * | 2011-09-07 | 2012-03-21 | 浙江理工大学 | Method for improving light fastness of natural dye stuff dyed fabrics |
| CN102715170A (en) * | 2012-06-12 | 2012-10-10 | 陕西科技大学 | Cationic antimicrobial and preparation method and application thereof |
| CN102965927A (en) * | 2012-12-07 | 2013-03-13 | 辽东学院 | Tussah silk fiber or fabric cation modified finishing agent thereof and modified technique thereof |
| CN103183340A (en) * | 2013-03-27 | 2013-07-03 | 复旦大学 | Ultra-high-modulus and high-strength oxidized graphene film and preparation method thereof |
| CN103572591A (en) * | 2013-11-15 | 2014-02-12 | 复旦大学 | Method for surface modification on carbon fibers |
| CN103911867A (en) * | 2014-04-02 | 2014-07-09 | 江南大学 | Method for improving color fastness of protein fiber product through enzymic method |
-
2015
- 2015-03-05 CN CN201510097040.7A patent/CN104695250B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102383321A (en) * | 2011-09-07 | 2012-03-21 | 浙江理工大学 | Method for improving light fastness of natural dye stuff dyed fabrics |
| CN102715170A (en) * | 2012-06-12 | 2012-10-10 | 陕西科技大学 | Cationic antimicrobial and preparation method and application thereof |
| CN102965927A (en) * | 2012-12-07 | 2013-03-13 | 辽东学院 | Tussah silk fiber or fabric cation modified finishing agent thereof and modified technique thereof |
| CN103183340A (en) * | 2013-03-27 | 2013-07-03 | 复旦大学 | Ultra-high-modulus and high-strength oxidized graphene film and preparation method thereof |
| CN103572591A (en) * | 2013-11-15 | 2014-02-12 | 复旦大学 | Method for surface modification on carbon fibers |
| CN103911867A (en) * | 2014-04-02 | 2014-07-09 | 江南大学 | Method for improving color fastness of protein fiber product through enzymic method |
Non-Patent Citations (1)
| Title |
|---|
| 单宁在染整中的应用;吴娟 等;《印染助剂》;20080220;第25卷(第02期);第1-4页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104695250A (en) | 2015-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101597868B (en) | Brocade fabric active and neutral dye combination catalytic fixation printing technique | |
| CN102558552B (en) | Preparation method of formaldehyde-free color fixative | |
| CN102619101B (en) | Short-process low-temperature dyeing aid and preparation method thereof | |
| CN103409244B (en) | Soaping enzyme, soaping method thereof and application of soaping enzyme in washed and dyed fabric | |
| CN105239425B (en) | A kind of acid dyes levelling agent for collecting the hyperchromic fixation one of level dyeing and preparation method thereof | |
| CN103952836A (en) | Producing method of antibiosis and fragrant spun silk cotton fabric | |
| CN103981744B (en) | A kind of salt-free dyeing method of calcium alginate fibre | |
| CN103966033A (en) | Color-protecting laundry detergent and preparation method thereof | |
| CN103485198A (en) | Active dye-decamethylcyclopentasiloxane suspension system dyeing process of cotton fabric | |
| CN102995471A (en) | Textile color fixing agent | |
| CN102677489B (en) | High color fastness cotton fabric dyeing method capable of effectively saving water and reducing pollution | |
| CN102767100A (en) | Printing gum composition and printing paste | |
| CN105970697A (en) | Color fixing process method for natural dyeing of textiles | |
| CN105821683A (en) | Method for preventing printing-free areas of positive-ion-modified cotton fabric from staining | |
| CN105926316A (en) | Novel environment-friendly dyeing method for jeans apparel | |
| CN104695250B (en) | A kind of polyphenol fabric-modifying agent and preparation method thereof | |
| CN103952014A (en) | Composite reactive blue dye and application thereof | |
| CN109944093A (en) | One bath process of erosion wool dyeing of cotton knitted fabric | |
| CN108707991A (en) | A kind of preparation method for the regenerated celulose fibre that natural dye can contaminate | |
| CN108085811A (en) | Composite covered yarn and preparation method thereof | |
| CN106758415B (en) | A kind of active dye fixing agent and preparation method thereof | |
| CN105178065A (en) | Denim accelerating agent and preparation method thereof | |
| CN106702791A (en) | Silk fabric color fixing agent and preparation method thereof | |
| CN107829317B (en) | A kind of high-efficiency activated dyestuff loose colour remover and its padding process | |
| CN105544254A (en) | Special cleaning solution for dyed fabrics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181219 Address after: 215000 Sigubang No. 1, Shengze Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Suzhou Xinmin silk Co., Ltd. Address before: 215000 No. 287 Xuefu Road, North International Education Park, Suzhou high tech Zone, Jiangsu Patentee before: Suzhou Institute of Trade & Commerce |
|
| TR01 | Transfer of patent right |