CN104694836B - A kind of antiacid steel plate for structural steelwork - Google Patents
A kind of antiacid steel plate for structural steelwork Download PDFInfo
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- CN104694836B CN104694836B CN201510126225.6A CN201510126225A CN104694836B CN 104694836 B CN104694836 B CN 104694836B CN 201510126225 A CN201510126225 A CN 201510126225A CN 104694836 B CN104694836 B CN 104694836B
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- cooldown rate
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- room temperature
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 117
- 239000010959 steel Substances 0.000 title claims abstract description 117
- 230000001458 anti-acid effect Effects 0.000 title claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 238000005516 engineering process Methods 0.000 claims abstract description 9
- 238000005096 rolling process Methods 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 229910052802 copper Inorganic materials 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 8
- 238000005496 tempering Methods 0.000 claims abstract description 8
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 43
- 229910000859 α-Fe Inorganic materials 0.000 claims description 24
- 229910001562 pearlite Inorganic materials 0.000 claims description 23
- 230000006835 compression Effects 0.000 claims description 14
- 238000007906 compression Methods 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 238000010791 quenching Methods 0.000 claims description 14
- 230000000171 quenching effect Effects 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- 229940069428 antacid Drugs 0.000 abstract description 4
- 239000003159 antacid agent Substances 0.000 abstract description 4
- 238000010276 construction Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
Embodiment | Tensile strength, MPa | Yield strength, MPa | Elongation percentage, % | The thickness direction contraction percentage of area, % | -20 DEG C of Charpy-V impact powers, J | CLR, % | CTR, % | CSR,% | SSC |
Embodiment 1 | 455 | 314 | 33 | 60.5 | 230 | 0 | 0 | 0 | Flawless |
Embodiment 2 | 457 | 322 | 36 | 63.7 | 245 | 0 | 0 | 0 | Flawless |
Embodiment 3 | 482 | 335 | 39.5 | 70.0 | 255 | 0 | 0 | 0 | Flawless |
Claims (3)
- null1. the antiacid steel plate for structural steelwork,This steel plate thickness is more than 40mm,It is characterized in that: the composition of this steel plate and mass percent be: C:0.27-0.29%、Mn:0.35-0.37%、Si:0.17-0.19%、P:0.006-0.008%、S:0.002-0.005%、Nb:0.03-0.05%、V:0.04-0.06%、Ti:0.15-0.17%、Al:0.018-0.019%、N≤0.006%、H≤0.00020%,Cu:0.022-0.024%,Ni:1.65-1.67%,Cr:0.54-0.56%,Mo:0.13-0.15%,Surplus is Fe and inevitable impurity;Adopting the Technology for Heating Processing of normalizing-secondary normalizing-tempering to carry out heat treatment after this steel plate rolling, described normalizing temperature is 930-950 DEG C, adopts the first refrigerating work procedure to be cooled to room temperature;Described secondary normalizing temperature is 760-780 DEG C, adopts the second refrigerating work procedure to be cooled to room temperature;Described temperature is 640-660 DEG C, adopts the 3rd refrigerating work procedure to be cooled to room temperature;Described first refrigerating work procedure: first adopt water-cooled, with the cooldown rate of 12-15 DEG C/s, steel is cooled to 720-750 DEG C, then air cooling is to 650-670 DEG C, adopt compression air or vaporific quenching liquid, with the cooldown rate of 9-11 DEG C/s, steel is cooled to 420-440 DEG C again, finally adopt the air-cooled cooldown rate with 4-6 DEG C/s that steel is cooled to room temperature;Described second refrigerating work procedure: first adopt water-cooled, with the cooldown rate of 11-13 DEG C/s, steel is cooled to 620-640 DEG C, so adopt the air-cooled cooldown rate with 4-6 DEG C/s that steel is cooled to 490-510 DEG C, then adopt water-cooled, with the cooldown rate of 7-9 DEG C/s, steel is cooled to room temperature;Described 3rd refrigerating work procedure: first adopt the air-cooled cooldown rate with 5-7 DEG C/s that steel is cooled to 510-530 DEG C, adopt water-cooled, with the cooldown rate of 11-13 DEG C/s, steel is cooled to 370-390 DEG C again, finally adopt compression air or vaporific quenching liquid, with the cooldown rate of 7-9 DEG C/s, steel is cooled to room temperature;Making first-phase in this steel plate be ferrite by above heat treatment, second-phase is pearlite, is 11.5-11.7% on surface to 1/4 thickness place second-phase percentage by volume, and 1/4 thickness is 3.5-3.7% to center second-phase percentage by volume, and without banded structure;Being 4.5-4.7 μm on surface to 1/4 thickness place ferrite average crystal grain diameter, pearlite colony average diameter is 5.0-5.3 μm, and 1/4 thickness is 4.0-4.3 μm to center ferrite average crystal grain diameter, and pearlite colony average diameter is 6.0-6.3 μm.
- 2. the antiacid steel plate for structural steelwork as claimed in claim 1, it is characterized in that: the composition of this steel plate and mass percent be: C:0.27%, Mn:0.35%, Si:0.17%, P:0.006%, S:0.002%, Nb:0.03%, V:0.04%, Ti:0.15%, Al:0.018%, N:0.006%, H:0.00020%, Cu:0.022%, Ni:1.65%, Cr:0.54%, Mo:0.13%, surplus is Fe and inevitable impurity;Adopting the Technology for Heating Processing of normalizing-secondary normalizing-tempering to carry out heat treatment after this steel plate rolling, described normalizing temperature is 930 DEG C, adopts the first refrigerating work procedure to be cooled to room temperature;Described secondary normalizing temperature is 760 DEG C, adopts the second refrigerating work procedure to be cooled to room temperature;Described temperature is 640 DEG C, adopts the 3rd refrigerating work procedure to be cooled to room temperature;Described first refrigerating work procedure: first adopt water-cooled, with the cooldown rate of 12 DEG C/s, steel is cooled to 720 DEG C, then air cooling is to 650 DEG C, adopt compression air or vaporific quenching liquid, with the cooldown rate of 9 DEG C/s, steel is cooled to 420 DEG C again, finally adopt the air-cooled cooldown rate with 4 DEG C/s that steel is cooled to room temperature;Described second refrigerating work procedure: first adopt water-cooled, with the cooldown rate of 11 DEG C/s, steel is cooled to 620 DEG C, so adopt the air-cooled cooldown rate with 4 DEG C/s that steel is cooled to 490 DEG C, then adopt water-cooled, with the cooldown rate of 7 DEG C/s, steel is cooled to room temperature;Described 3rd refrigerating work procedure: first adopt the air-cooled cooldown rate with 5 DEG C/s that steel is cooled to 510 DEG C, adopt water-cooled, with the cooldown rate of 11 DEG C/s, steel is cooled to 370 DEG C again, finally adopt compression air or vaporific quenching liquid, with the cooldown rate of 7 DEG C/s, steel is cooled to room temperature;Making first-phase in this steel plate be ferrite by above heat treatment, second-phase is pearlite, is 11.5% on surface to 1/4 thickness place second-phase percentage by volume, and 1/4 thickness is 3.5% to center second-phase percentage by volume, and without banded structure;Being 4.5 μm on surface to 1/4 thickness place ferrite average crystal grain diameter, pearlite colony average diameter is 5.0 μm, and 1/4 thickness is 4.0 μm to center ferrite average crystal grain diameter, and pearlite colony average diameter is 6.0 μm.
- 3. the antiacid steel plate for structural steelwork as claimed in claim 1, it is characterized in that: the composition of this steel plate and mass percent be: C:0.29%, Mn:0.37%, Si:0.19%, P:0.008%, S:0.005%, Nb:0.05%, V:0.06%, Ti:0.17%, Al:0.19%, N:0.001%, H:0.0001%, Cu:0.024%, Ni:1.67%, Cr:0.56%, Mo:0.15%, surplus is Fe and inevitable impurity;Adopting the Technology for Heating Processing of normalizing-secondary normalizing-tempering to carry out heat treatment after this steel plate rolling, described normalizing temperature is 950 DEG C, adopts the first refrigerating work procedure to be cooled to room temperature;Described secondary normalizing temperature is 780 DEG C, adopts the second refrigerating work procedure to be cooled to room temperature;Described temperature is 660 DEG C, adopts the 3rd refrigerating work procedure to be cooled to room temperature;Described first refrigerating work procedure: first adopt water-cooled, with the cooldown rate of 15 DEG C/s, steel is cooled to 750 DEG C, then air cooling is to 670 DEG C, adopt compression air or vaporific quenching liquid, with the cooldown rate of 11 DEG C/s, steel is cooled to 440 DEG C again, finally adopt the air-cooled cooldown rate with 6 DEG C/s that steel is cooled to room temperature;Described second refrigerating work procedure: first adopt water-cooled, with the cooldown rate of 13 DEG C/s, steel is cooled to 640 DEG C, so adopt the air-cooled cooldown rate with 6 DEG C/s that steel is cooled to 510 DEG C, then adopt water-cooled, with the cooldown rate of 9 DEG C/s, steel is cooled to room temperature;Described 3rd refrigerating work procedure: first adopt the air-cooled cooldown rate with 7 DEG C/s that steel is cooled to 530 DEG C, adopt water-cooled, with the cooldown rate of 13 DEG C/s, steel is cooled to 390 DEG C again, finally adopt compression air or vaporific quenching liquid, with the cooldown rate of 9 DEG C/s, steel is cooled to room temperature;Making first-phase in this steel plate be ferrite by above heat treatment, second-phase is pearlite, is 11.7% on surface to 1/4 thickness place second-phase percentage by volume, and 1/4 thickness is 3.7% to center second-phase percentage by volume, and without banded structure;Being 4.7 μm on surface to 1/4 thickness place ferrite average crystal grain diameter, pearlite colony average diameter is 5.3 μm, and 1/4 thickness is 4.3 μm to center ferrite average crystal grain diameter, and pearlite colony average diameter is 6.3 μm.
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CN201510126225.6A CN104694836B (en) | 2015-03-23 | 2015-03-23 | A kind of antiacid steel plate for structural steelwork |
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CN104694836B true CN104694836B (en) | 2016-07-06 |
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CN108048742A (en) * | 2017-12-07 | 2018-05-18 | 安徽科汇钢结构工程有限公司 | A kind of industrial premises high-performance steel plate material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102732799A (en) * | 2012-07-09 | 2012-10-17 | 武汉钢铁(集团)公司 | Acid corrosion resistant steel for soleplate in hull and production method thereof |
CN103526129A (en) * | 2013-09-27 | 2014-01-22 | 济钢集团有限公司 | Thick-specification acid-corrosion-resisting X65 pipeline steel plate and manufacturing method thereof |
CN104388837A (en) * | 2014-12-19 | 2015-03-04 | 山东钢铁股份有限公司 | Acid-corrosion-resistant X70 pipeline steel plate and manufacturing method thereof |
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JP2011202214A (en) * | 2010-03-25 | 2011-10-13 | Jfe Steel Corp | Thick high tensile strength steel plate having excellent low temperature toughness in multilayer weld zone and method for producing the same |
JP5625694B2 (en) * | 2010-09-30 | 2014-11-19 | Jfeスチール株式会社 | High-strength, high-toughness thick-walled steel plate with excellent material uniformity in the steel plate and method for producing the same |
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CN102732799A (en) * | 2012-07-09 | 2012-10-17 | 武汉钢铁(集团)公司 | Acid corrosion resistant steel for soleplate in hull and production method thereof |
CN103526129A (en) * | 2013-09-27 | 2014-01-22 | 济钢集团有限公司 | Thick-specification acid-corrosion-resisting X65 pipeline steel plate and manufacturing method thereof |
CN104388837A (en) * | 2014-12-19 | 2015-03-04 | 山东钢铁股份有限公司 | Acid-corrosion-resistant X70 pipeline steel plate and manufacturing method thereof |
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