CN104693915A - Preparation and application of cultural-relic color-painting reinforcing material - Google Patents
Preparation and application of cultural-relic color-painting reinforcing material Download PDFInfo
- Publication number
- CN104693915A CN104693915A CN201310659363.1A CN201310659363A CN104693915A CN 104693915 A CN104693915 A CN 104693915A CN 201310659363 A CN201310659363 A CN 201310659363A CN 104693915 A CN104693915 A CN 104693915A
- Authority
- CN
- China
- Prior art keywords
- reinforcing material
- color
- painting
- cultural
- colored drawing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4838—Halogenated polymers
- C04B41/4842—Fluorine-containing polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4853—Epoxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The present invention relates to preparation and application of a cultural-relic color-painting reinforcing material. The preparation comprises the following steps: pouring a waterborne fluorocarbon coating with a solid content of 47% and waterborne epoxy resin with the solid content of 20% into pure water in proportion, carrying out constant stirring, and then adding an additive for reaction so as to obtain an ultraviolet-light-absorbing protective glue solution which forms an emulsion. The cultural-relic color-painting reinforcing material of the invention overcomes the defects that the values of the cultural relics are influenced and the like because single usage of conventional color-painting reinforcing materials like an inorganic reinforcing material, an organic reinforcing material and a novel reinforcing material influences the appearance, strength, life and the like of color paintings. The cultural-relic color-painting reinforcing material prepared in the invention has the properties of dust prevention performance, water resistance, acid resistance, strong anti-aging ability, strong adhesive force and appropriate hardness and can reinforce and protect fragile, crisp and loose cultural-relic color-painting layers, so various mechanical strengths and mechanical properties of the color-painting layer bodies are effectively improved.
Description
Technical field
The invention belongs to Techniques of Relics Protection field, be specifically related to a kind of preparations and applicatio of historical relic colored drawing reinforcement material.
Background technology
Historical relic colored drawing gives the very important art of historical relic and history archaeological information, and therefore, the colored drawing of cultural artifact surface especially seems precious.Because the basic material making historical relic colored drawing is originally aging, phenomenons such as causing colored drawing to occur crisp powder, fade, warp, come off.
Before making the present invention, colored drawing reinforcement material has inorganic reinforcing material, organic reinforcement material, novel reinforced material.Wherein inorganic reinforcing material comprises liming, hydrated barta alkaline-earth silicate and silicofluoride etc., organic reinforcement material comprises the matrix material etc. of silicon ester, siloxanes, epoxy resin, acrylic resin, silicone resin, organic fluorine material and organopolysiloxane-polyacrylic ester, and novel reinforced material has nano material, Biomimetic Inorganic Materials etc.Often there is various drawback, such as affect the outward appearance, intensity, life-span etc. of colored drawing, and then affect the value of historical relic in single protecting materials after reinforcing historical relic colored drawing.
Summary of the invention
The object of the invention is to overcome above-mentioned defect, a kind of preparations and applicatio of historical relic colored drawing reinforcement material is provided.
Technical scheme of the present invention is:
A preparation method for historical relic colored drawing reinforcement material, its technical characteristics is that the proportioning raw materials of reinforcement material is:
; Described aqueous fluorine-carbon paint is solid content 47%; Described aqueous epoxy resins is solid content 20%; Described admixture is UV-531+Ti (OC
2h
5)
4mixture; The preparation method of reinforcement material is: pour in pure water by aqueous fluorine-carbon paint and aqueous epoxy resins, constantly stir, then add admixture, and the ultraviolet absorption protection glue that reaction generates, forms emulsion.
Another technical scheme of the present invention is:
An application for historical relic colored drawing reinforcement material, its technical characteristics is that reinforcement material loads watering can, is evenly sprayed on ancient architecture color painting in an atomized manner, archeological site is unearthed, and colored drawing is made pottery, the surface of collection colored drawing pottery.
Colored drawing reinforcement material of the present invention has dust-proof, water-fast, acidproof, that resistance of aging strong, strong adhesion, hardness are suitable performance; fragility can be made, loose historical relic painted layer is able to reinforcement protection; the various physical strengths of painted layer body, mechanical property are all effectively improved; more be beneficial to the permanent preservation of historical relic; painted layer original appearance after its process is simple and unsophisticated; chromatic aberration is minimum, meets the principle " keeping original appearance, restoring the old as the old " in historical relic's protection.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.Embodiment is for explanation and unrestricted the present invention.
Embodiment 1:
Aqueous fluorine-carbon paint preferred adopted in the present invention, aqueous epoxy resins, admixture [UV-531+Ti (OC
2h
5)
4mixture] all obtain by commercial channel.
In the present invention, the preparation method of historical relic colored drawing reinforcement material is as follows:
(1) under room temperature, take 10g solid content be 47% aqueous fluorine-carbon paint and 10g solid content be 20% water-base epoxy add under ultrasonic agitation and mechanical stirring in 977g pure water, mechanical stirring speed is 200rpm, and ultrasonic frequency is 40KHz, churning time is 10min, forms emulsion.
(2) 3g admixture is put into above-mentioned emulsion, admixture is UV-531+Ti (OC
2h
5)
4mixture.Under stirring, ultraviolet absorbers is dispersed in emulsion, obtains final historical relic colored drawing reinforcement material.
Embodiment 2:
According to historical relic colored drawing reinforcement material prepared by embodiment 1, be applied to the protection of ancient architecture colour painting.
Guard method: reinforcement material is loaded watering can, is evenly sprayed at ancient architecture color painting surface in an atomized manner, can assist external force gently in the extruding of colored drawing surface, then naturally dry.
Embodiment 3:
According to historical relic colored drawing reinforcement material prepared by embodiment 1, be applied to the protection of the unearthed colored drawing pottery of archeological site (wet environment).
Guard method: reinforcement material is loaded watering can, be evenly sprayed in an atomized manner moist colored drawing pottery surface, after it dries naturally, desirable go out colored drawing pottery.
Embodiment 4:
According to historical relic colored drawing reinforcement material prepared by embodiment 1, be applied to the protection of collection (dry environment) colored drawing pottery.
Guard method: reinforcement material is loaded watering can, is evenly sprayed at colored drawing pottery surface in an atomized manner, can assist external force gently in the extruding of colored drawing surface, then naturally dry.
The environment protection type single-component fluorine carbon emulsion coating that in the present invention, aqueous fluorine-carbon paint is main component with the water-based fluorocarbon resin of excellent performance, by Dalian, Zhen Bang company limited provides; Aqueous epoxy resins belongs to II type aqueous epoxy resin systems, and be made up of the solid epoxy emulsion of high molecular and aqueous epoxy curing agent, by Taihu Lake, Yixing, antiseepage company limited provides; Admixture is the combination product of UV light absorber and nano titanium oxide, and wherein ultraviolet absorbers is UV-531, and chemical name is Octabenzone, it and Ti (OC
2h
5)
4all provided by bright Chemical Company of Nanjing Holley.
The outfit method of above-mentioned historical relic colored drawing reinforcement material is:
According to the percent mass proportioning of above-mentioned raw materials, aqueous fluorine-carbon paint and aqueous epoxy resins are poured in pure water, constantly stirs, then add admixture (pre-configured UV-531 and Ti (OC
2h
5)
4the ultraviolet absorption protection glue that reaction generates), form emulsion.
Above-mentioned historical relic colored drawing reinforcement material to fragile, that loose colored drawing carries out reinforcement protection using method is: adopt watering can, be evenly sprayed at painted layer surface in an atomized manner, can assist external force gently in the extruding of colored drawing surface, then naturally dry.
This reinforcement material applicable historical relic colored drawing type has: ancient architecture color painting, archeological site are unearthed, and colored drawing is made pottery (wet environment), collection colored drawing pottery (dry environment).
Claims (2)
1. a preparation method for historical relic colored drawing reinforcement material, is characterized in that the proportioning raw materials of reinforcement material is:
; Described aqueous fluorine-carbon paint is solid content 47%; Described aqueous epoxy resins is solid content 20%; Described admixture is UV-531+Ti (OC
2h
5)
4mixture; The preparation method of reinforcement material is: pour in pure water by aqueous fluorine-carbon paint and aqueous epoxy resins, constantly stir, then add admixture, and the ultraviolet absorption protection glue that reaction generates, forms emulsion.
2. the application of a kind of historical relic colored drawing reinforcement material according to claim 1, is characterized in that reinforcement material loads watering can, is evenly sprayed on ancient architecture color painting in an atomized manner, archeological site is unearthed, and colored drawing is made pottery, the surface of collection colored drawing pottery.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310659363.1A CN104693915A (en) | 2013-12-09 | 2013-12-09 | Preparation and application of cultural-relic color-painting reinforcing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310659363.1A CN104693915A (en) | 2013-12-09 | 2013-12-09 | Preparation and application of cultural-relic color-painting reinforcing material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104693915A true CN104693915A (en) | 2015-06-10 |
Family
ID=53341483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310659363.1A Pending CN104693915A (en) | 2013-12-09 | 2013-12-09 | Preparation and application of cultural-relic color-painting reinforcing material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104693915A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647289A (en) * | 2015-07-17 | 2016-06-08 | 苏州吉人高新材料股份有限公司 | Ceramic painted relic reinforcing paint and preparation method thereof |
| CN115178509A (en) * | 2022-07-11 | 2022-10-14 | 南京博物院 | Sizing material colored drawing cultural relic reinforcement and surface clay cleaning method considering archaeological unearthing |
-
2013
- 2013-12-09 CN CN201310659363.1A patent/CN104693915A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647289A (en) * | 2015-07-17 | 2016-06-08 | 苏州吉人高新材料股份有限公司 | Ceramic painted relic reinforcing paint and preparation method thereof |
| CN105647289B (en) * | 2015-07-17 | 2018-08-31 | 苏州吉人高新材料股份有限公司 | A kind of ceramic polychrome cultural relics doped coating and preparation method thereof |
| CN115178509A (en) * | 2022-07-11 | 2022-10-14 | 南京博物院 | Sizing material colored drawing cultural relic reinforcement and surface clay cleaning method considering archaeological unearthing |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150610 |
|
| WD01 | Invention patent application deemed withdrawn after publication |