CN104692750A - Rapid condensation high-strength flame retardant thermal insulation material and preparation method thereof - Google Patents

Rapid condensation high-strength flame retardant thermal insulation material and preparation method thereof Download PDF

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Publication number
CN104692750A
CN104692750A CN201510071322.XA CN201510071322A CN104692750A CN 104692750 A CN104692750 A CN 104692750A CN 201510071322 A CN201510071322 A CN 201510071322A CN 104692750 A CN104692750 A CN 104692750A
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thermal insulation
strength
insulation material
retarding
rapid coagulation
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CN201510071322.XA
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CN104692750B (en
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王化
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Hefei Institutes of Physical Science of CAS
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Hefei Institutes of Physical Science of CAS
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Abstract

The invention discloses a rapid condensation high-strength flame retardant thermal insulation material and a preparation method thereof. The rapid condensation high-strength flame retardant thermal insulation material is prepared from the following raw materials in percentage by weight: 5-55% of metallic oxide, 5-55% of phosphate, 1-10% of additive, 0.5-5% of fiber material, 0.5-50 of thermal insulation component and 5-50% of water. The rapid condensation high-strength flame retardant thermal insulation material is high in condensation speed; when the material is placed for 4 hours at a normal temperature, the compression strength of the thermal insulation material can reach 20MPa, and the breaking strength can reach 3.5MPa; and when the material is placed for 8 days at a normal temperature, the compression strength of the thermal insulation material can reach 60MPa, and the breaking strength can reach 10MPa. The thermal insulation material has good compatibility with concrete, cement and the like and high cold resistance and can be used under low temperature conditions of 0-10 DEG C. The rapid condensation high-strength flame retardant thermal insulation material can be directly sprayed to walls, roadway walls, tunnel walls and the like or is poured into a grinding tool with appointed size and shape and is compacted and shaped by vibration.

Description

A kind of rapid coagulation high-strength fire-retarding lagging material and preparation method thereof
Technical field
The present invention relates to building material field, be specifically related to a kind of rapid coagulation high-strength fire-retarding lagging material and preparation method thereof.
Background technology
At present, mainly there is following shortcoming in the cement and polystyrene particle lagging material that conventional construction wall, coal mine roadway, tunnel are conventional:
1, take cement as sizing agent, cohesive force is weak, and with the poor adhesive force in body of wall, coal mine roadway, tunnel etc., poor durability, easily comes off.
2, the ultimate compression strength of lagging material, folding strength are low, be subject to shearing force, pressure effect easily broken, come off.
3, cost is high.Because lagging material self-strength is low, need at construction wall, coal mine roadway, to smear polymers anti-cracking mortar between tunnel and lagging material, every square meter increases the tens of unit of cost.
4, working procedure complexity, long construction period, curing cycle are long.Generally need 4-7 procedure, and per pass inter process needs interval just can complete for several days, long construction period.And owing to adopting cement to be sizing agent, conventional curing cycle need reach more than 28 days.
5, hollowing, crackle is easily caused.Sizing agent is done, easy to crack, easy hollowing with cement.
Summary of the invention
The object of the present invention is to provide a kind of rapid coagulation, high-strength, fire-retardant, good heat-insulation effect, lagging material and preparation method thereof easily of constructing.Technical problems such as which solving intensity difference in background technology, cohesive force is weak, working procedure is complicated, long construction period, curing cycle are long.
For reaching above-mentioned purpose, the concrete scheme that the present invention adopts is:
Rapid coagulation, high-strength, flame-retardant thermal insulation material are made up of the raw material of following weight percents: metal oxide, one or more in aluminum oxide, magnesium oxide, ferric oxide, zinc oxide, and total content is 5-55%; Phosphoric acid salt, one or more in dipotassium hydrogen phosphate, potassium primary phosphate, Secondary ammonium phosphate, primary ammonium phosphate, potassiumphosphate, ammonium phosphate, total content is 5-55%; Auxiliary agent, flyash, Sodium Tetraborate, trisodium phosphate, Sodium Silicofluoride, total content is 1-10%; Filamentary material, one or more in cotton fibre, glass fibre, bamboo fibers, carbon fiber, ceramic fiber, total content is 0.5-5%; Heat insulation component: one or more in glass microballon, cenosphere, urethane, asbestos, rock wool, eps foam, XPS foam, EPP foam, aerogel, total content is 0.5-50%; Surplus is water.
Preparation method comprises the following steps:
(1) by formula rate by metal oxide, phosphoric acid salt, auxiliary agent, filamentary material, water, be uniformly mixed 3-5min.
(2) mixture (1) obtained and heat insulation component are uniformly mixed 1-2min by formula rate.
Beneficial effect of the present invention:
Rapid coagulation of the present invention, high-strength, flame-retardant thermal insulation material have following characteristic:
1, preparation process is without the need to sintering, energy-saving and environmental protection.
2, material rapid coagulation, time of coagulation can scope regulation and control in 10 seconds to 30 minutes.
3, normal temperature lower 4 hours ultimate compression strength can reach 20MPa; Folding strength can reach 3.5MPa.
4, normal temperature lower 8 days ultimate compression strength can reach 60MPa; Folding strength can reach 10MPa.
5, good with the consistency such as concrete, cement.
6, high winter resistance, can use under-10 DEG C of cold condition.
7, thermal conductivity is 0.084-0.23W/mK.
8, namely material sprays namely shaping.
This rapid coagulation, form of construction work that is high-strength, flame-retardant thermal insulation material have two kinds, are respectively:
1, by this lagging material direct spraying to body of wall, wall, tunnel wall etc.
2, this lagging material is poured into the grinding tool of specifying size shape, jolt ramming is shaping.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
Rapid coagulation high-strength fire-retarding lagging material is made up of the raw material of following weight percents: magnesium oxide 40%, ferric oxide 5%; Dipotassium hydrogen phosphate 10%, potassium primary phosphate 15%; Flyash 5%; Cotton fibre 5%; Glass microballon 5%, eps foam 5%; Water, total content is 10%.By metal oxide, phosphoric acid salt, auxiliary agent, filamentary material, water, be uniformly mixed 3-5min.The mixture obtained and insulation particle are uniformly mixed 1-2min.
The lagging material obtained condensation in 15 seconds, normal temperature lower 4 hours ultimate compression strength can reach 20MPa; Folding strength can reach 3.5MPa; Thermal conductivity is 0.084W/mK.
Embodiment 2
Rapid coagulation high-strength fire-retarding lagging material is made up of the raw material of following weight percents: magnesium oxide 40%, zinc oxide 5%; Dipotassium hydrogen phosphate 10%, potassium primary phosphate 15%; Sodium Tetraborate 5%; Carbon fiber 5%; XPS foam 5%, eps foam 5%; Water, total content is 10%.By metal oxide, phosphoric acid salt, auxiliary agent, filamentary material, water, be uniformly mixed 3-5min.The mixture obtained and insulation particle are uniformly mixed 1-2min.
The lagging material obtained condensation in 20 seconds, normal temperature lower 2 hours ultimate compression strength can reach 10MPa; Folding strength can reach 1.5MPa; Thermal conductivity is 0.12W/mK.
Obviously, those skilled in the art can carry out various change and modification to rapid coagulation of the present invention, high-strength, flame-retardant thermal insulation material and preparation method thereof and not depart from the spirit and scope of the present invention.Like this, if belong within the scope of the claims in the present invention and equivalent technologies thereof to these amendments of the present invention and modification, then the present invention is also intended to comprise these change and modification.

Claims (7)

1. a rapid coagulation high-strength fire-retarding lagging material, is characterized in that, is made up of the raw material of following weight percents: metal oxide 5-55%, phosphoric acid salt 5-55%, auxiliary agent 1-10%, filamentary material 0.5-5%, heat insulation component 0.5-50%, water 5-50%.
2. a preparation method for rapid coagulation high-strength fire-retarding lagging material as claimed in claim 1, is characterized in that comprising the following steps:
(1) by formula rate by metal oxide, phosphoric acid salt, auxiliary agent, filamentary material, water, be uniformly mixed 3-5min;
(2) mixture (1) obtained and heat insulation component are uniformly mixed 1-2min by formula rate.
3. rapid coagulation high-strength fire-retarding lagging material according to claim 1, is characterized in that, described metal oxide can be one or more in aluminum oxide, magnesium oxide, ferric oxide, zinc oxide.
4. rapid coagulation high-strength fire-retarding lagging material according to claim 1, is characterized in that, described phosphoric acid salt can be one or more in dipotassium hydrogen phosphate, potassium primary phosphate, Secondary ammonium phosphate, primary ammonium phosphate, potassiumphosphate, ammonium phosphate.
5. rapid coagulation high-strength fire-retarding lagging material according to claim 1, is characterized in that, described auxiliary agent is one or more in flyash, Sodium Tetraborate, trisodium phosphate, Sodium Silicofluoride.
6. rapid coagulation high-strength fire-retarding lagging material according to claim 1, is characterized in that, described filamentary material can be one or more in cotton fibre, glass fibre, bamboo fibers, carbon fiber, ceramic fiber.
7. rapid coagulation high-strength fire-retarding lagging material according to claim 1, it is characterized in that, described heat insulation component can be one or more in glass microballon, cenosphere, urethane, asbestos, rock wool, eps foam, XPS foam, EPP foam, aerogel.
CN201510071322.XA 2015-02-11 2015-02-11 Rapid condensation high-strength flame retardant thermal insulation material and preparation method thereof Active CN104692750B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105622072A (en) * 2015-12-25 2016-06-01 无锡信大气象传感网科技有限公司 Light solar cell support and preparation method thereof
TWI606992B (en) * 2017-02-23 2017-12-01 Guo Sheng Zhao Inorganic material ultra-high temperature insulation and cooling anti-corrosion coating
CN108610089A (en) * 2018-06-25 2018-10-02 宿迁德威新材料有限公司 It is a kind of can fast demoulding assembling thermal-insulating wall board material and preparation method thereof
CN110028300A (en) * 2019-04-18 2019-07-19 北京碧海舟腐蚀防护工业股份有限公司 Aqueous ceramic insulating mold coating and its application, corrosion-inhibiting coating
CN115636633A (en) * 2022-09-09 2023-01-24 山西广同丰新材料有限公司 Novel inorganic powder material for coal mine reinforcement

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN102924037A (en) * 2012-08-21 2013-02-13 曾小荣 Fire protection insulation board for building outer wall and method for producing fire protection insulation board
CN103193447A (en) * 2013-03-15 2013-07-10 十堰金砂墙体材料有限公司 Autoclaved aerated concrete brick prepared by utilizing pulverized fuel ash and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN102924037A (en) * 2012-08-21 2013-02-13 曾小荣 Fire protection insulation board for building outer wall and method for producing fire protection insulation board
CN103193447A (en) * 2013-03-15 2013-07-10 十堰金砂墙体材料有限公司 Autoclaved aerated concrete brick prepared by utilizing pulverized fuel ash and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105622072A (en) * 2015-12-25 2016-06-01 无锡信大气象传感网科技有限公司 Light solar cell support and preparation method thereof
TWI606992B (en) * 2017-02-23 2017-12-01 Guo Sheng Zhao Inorganic material ultra-high temperature insulation and cooling anti-corrosion coating
CN108610089A (en) * 2018-06-25 2018-10-02 宿迁德威新材料有限公司 It is a kind of can fast demoulding assembling thermal-insulating wall board material and preparation method thereof
CN110028300A (en) * 2019-04-18 2019-07-19 北京碧海舟腐蚀防护工业股份有限公司 Aqueous ceramic insulating mold coating and its application, corrosion-inhibiting coating
CN115636633A (en) * 2022-09-09 2023-01-24 山西广同丰新材料有限公司 Novel inorganic powder material for coal mine reinforcement

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