CN104686520A - Acaricide composition containing stabilizing agent - Google Patents
Acaricide composition containing stabilizing agent Download PDFInfo
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- CN104686520A CN104686520A CN201310647927.XA CN201310647927A CN104686520A CN 104686520 A CN104686520 A CN 104686520A CN 201310647927 A CN201310647927 A CN 201310647927A CN 104686520 A CN104686520 A CN 104686520A
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- stabilizing agent
- composition containing
- acaricide composition
- active component
- acaricide
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Abstract
The invention relates to an acaricide composition, and concretely relates to the acaricide composition containing a stabilizing agent. The acaricide composition containing the stabilizing agent comprises the following components by weight percentage: 5-70% of active component, 0.1-30% of stabilizing agent, 1-30% of surfactant and 1-60% of carrier; wherein the active component is a substituent aniline pyrimidinyl group-containing E-type phenyl acrylic acid ester compound or its agriculturally acceptable salt and one or combination of other substances having acaricidal activity. The original drug in the acaricide is stable; the effect of the stabilizing agent in the acaricide composition is obvious, and pyriminostrobin preparation stability is increased. According to the invention, a tank-mix adjuvant is not required when the acaricide composition is used.
Description
Technical field
The present invention relates to miticide composition, specifically a kind of associativity miticide containing stabilizing agent.
Background technology
Chinese invention patent CN101906075A discloses the purposes of a kind of E-type phenyl acrylates compounds containing substituted anilino pyrimidine group and Control pests thereof, evil mite, wherein compound 9(is hereinafter referred to as chemical compounds I) can be used for preventing and treating various pests, evil mite, especially to mite class, there is outstanding control efficiency.
Chemical compounds I
But this chemical compounds I makes soluble concentrate when the purposes in conjunction with its physics and chemistry and Control pests thereof, evil mite, bin stability declines to a great extent when dispersibling finish.
Summary of the invention
The object of the present invention is to provide the associativity miticide containing stabilizing agent that a kind of insecticidal effect and stability are all good.
For achieving the above object, the present invention adopts technical scheme to be:
Containing an associativity miticide for stabilizing agent, comprise active component, stabilizing agent, surfactant and carrier; Each composition weight percentage composition is as follows: active component 5-70%, stabilizing agent 0.1-30%, surfactant 1-30%, carrier 1-60%;
Wherein, active component be containing the E-type phenyl acrylates compounds of substituted anilino pyrimidine group or its agriculturally acceptable salt or other there is the combination of one or more in the material of acaricidal activity.
Preferably, active component be phonetic mite amine or its agriculturally acceptable salt or other there is the combination of one or more in the material of acaricidal activity.
Further preferred, active component is phonetic mite amine.
Above-mentioned, other materials with acaricidal activity are propargite, carbosulfan, spiral shell mite ester, beta-cypermethrin.
Composition and the weight percentage of each component of preferred associativity miticide are as follows: active component 10-50%, stabilizing agent 1-25%, surfactant 1-30%, carrier 10-50%.
Composition and the weight percentage of each component of preferred associativity miticide are as follows: phonetic mite amine 5-30%, stabilizing agent 1-15%, surfactant 10-30%, carrier 25-60%.
Described stabilizing agent is selected from polyoxyethylene aryl phenyl ether, dioctyl sulfonic acid calcium succinate, Crodaret, triphenylethylene base polyoxyethylene ether sulfate, alkyl sorbose, triphenyl APEO, tributyl phosphate, epoxychloropropane etc.Stabilizing agent can be used alone, and two or more also can selecting wherein combinationally use; When combinationally using, adding of they can be selected arbitrarily than row.
Described surfactant is selected from anion surfactant and/or non-ionic surface active agent.Described anion surfactant is selected from such as fatty acid salt, polycarboxylate, alkylsulfonate, alkylaryl sulfonates, arylsulphonate or lignosulfonates; Wherein preferably alkylsulfonate, polycarboxylate and arylsulphonate etc.Described non-ionic surface active agent is selected from the compounds such as such as fatty alcohol polyethenoxy ether class, alkylphenol polyoxyethylene class, aliphatic amine polyoxyethylene ether class, vegetable and animals oils polyethenoxy ether class, alkyl glycoside class or cellulose ethers.Above-mentioned surfactant can be used alone or as a mixture.
Described carrier is mainly liquid-carrier.Described liquid-carrier is mainly selected from solvent naphtha-150(S-150), one or more material mixing in cyclohexanone, triethyl phosphate, octylpyrrolidone, 1-Methyl-2-Pyrrolidone, methyl oleate, methylated vegetable oils, machine oil.Specifically selecting of carrier can be determined according to the acaricidal formulation of associativity.
Obtain associativity miticide of the present invention by said components mixing, multiple formulation can be prepared into as required, such as, can be missible oil, dispersible finish, soluble concentrate etc.Associativity miticide of the present invention can by by each component of ormal weight with random order or mix simultaneously, the formulation needed for obtaining with processing method well-known to those skilled in the art.
Associativity miticide of the present invention has the following advantages: 1. the former drug stabilisation in associativity miticide; 2. the stabilizer function in associativity miticide obviously, improve phonetic mite amine preparation stability.3. associativity miticide of the present invention is when conbined usage, does not need to use tank-mix adjuvants.
Embodiment
Following examples are used for the present invention is described in further detail, but are not construed as limiting the invention, and composition of the present invention is only limitted to absolutely not these embodiments.Each raw material involved in formulation Example all has commercially available.Phonetic mite amine content 97-99%, rolls over hundred post doses and adds.Each material is measured all by weight and is added.
The phonetic mite amine soluble liquid of embodiment 1 15%
| The former medicine of phonetic mite amine (98%) | 15% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Dioctyl sulfonic acid calcium succinate | 5% |
| Triphenyl APEO | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Triethyl phosphate | Polishing to 100% |
The phonetic mite amine soluble liquid of reference examples 1 15%
| The former medicine of phonetic mite amine (98%) | 15% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Triethyl phosphate | Polishing to 100% |
[0025]processing method is sketched: by recipe requirements, first by adding in reactor after former medicine and solvent metering, starting stirring, stirring after dissolving completely, then add surfactant and continue to be stirred to the discharging of homogeneous phase transparent liquid, namely obtain 15% phonetic mite amine soluble liquid product.
The phonetic mite amine of embodiment 2 15% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 15% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Dioctyl sulfonic acid calcium succinate | |
| Triphenyl APEO | |
| 1-Methyl-2-Pyrrolidone | 30% |
| Methyl vegetable oil | Polishing to 100% |
The phonetic mite amine of reference examples 2 15% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 15% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Methyl vegetable oil | Polishing to 100% |
Processing method is sketched: by recipe requirements, first by adding in reactor after former medicine and solvent metering, starting stirring, stirring after dissolving completely, then add surfactant and continue to be stirred to the discharging of homogeneous phase transparent liquid, namely obtain 15% phonetic mite amine and dispersible finish product.
Phonetic mite amine 10% propargite of embodiment 3 10% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 10% |
| Propargite (90%) | 10% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Tributyl phosphate | 5% |
| Dioctyl sulfonic acid calcium succinate | |
| Triphenyl APEO | |
| Epoxychloropropane | |
| 1-Methyl-2-Pyrrolidone | 20% |
| Methyl vegetable oil | Polishing to 100% |
Phonetic mite amine 10% propargite of reference examples 3 10% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 10% |
| Propargite (90%) | 10% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Tributyl phosphate | 5% |
| 1-Methyl-2-Pyrrolidone | 20% |
| Methyl vegetable oil | Polishing to 100% |
Processing method is sketched: by recipe requirements, first by adding in reactor after former medicine and solvent metering, starting stirring, stirring after dissolving completely, add surfactant again to continue to be stirred to the discharging of homogeneous phase transparent liquid, namely obtain 10% phonetic mite amine 10% propargite and dispersible finish product.
Phonetic mite amine 10% carbosulfan of embodiment 4 10% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 10% |
| Carbosulfan (90%) | 10% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Dioctyl sulfonic acid calcium succinate | 5% |
| Triphenyl APEO | 5% |
| Tributyl phosphate | 5% |
| 1-Methyl-2-Pyrrolidone | 20% |
| Methyl vegetable oil | Polishing to 100% |
Phonetic mite amine 10% carbosulfan of reference examples 4 10% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 10% |
| Carbosulfan (90%) | 10% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| 1-Methyl-2-Pyrrolidone | 20% |
| Methyl vegetable oil | Polishing to 100% |
Processing method is sketched: by recipe requirements, first by adding in reactor after former medicine and solvent metering, starting stirring, stirring after dissolving completely, add surfactant again to continue to be stirred to the discharging of homogeneous phase transparent liquid, namely obtain 10% phonetic mite amine 10% carbosulfan and dispersible finish product.
Embodiment 5 10% phonetic mite amine 10% spiral shell mite ester dispersibles finish
| The former medicine of phonetic mite amine (98%) | 10% |
| Spiral shell mite ester (95%) | 10% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Dioctyl sulfonic acid calcium succinate | 5% |
| Triphenyl APEO | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Methyl vegetable oil | Polishing to 100% |
Reference examples 5 10% phonetic mite amine 10% spiral shell mite ester dispersibles finish
| The former medicine of phonetic mite amine (98%) | 10% |
| Spiral shell mite ester (95%) | 10% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Methyl vegetable oil | Polishing to 100% |
Processing method is sketched: by recipe requirements, first by adding in reactor after former medicine and solvent metering, starting stirring, stirring after dissolving completely, add surfactant again to continue to be stirred to the discharging of homogeneous phase transparent liquid, namely obtain 10% phonetic mite amine 10% spiral shell mite ester and dispersible finish product.
Phonetic mite amine 3% beta-cypermethrin of embodiment 6 12% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 12% |
| Beta-cypermethrin (95%) | 3% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| Dioctyl sulfonic acid calcium succinate | 5% |
| Triphenyl APEO | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Methyl vegetable oil | Polishing to 100% |
Phonetic mite amine 3% beta-cypermethrin of reference examples 6 12% dispersibles finish
| The former medicine of phonetic mite amine (98%) | 12% |
| Beta-cypermethrin (95%) | 3% |
| Sorbitan fatty acid ester | 5% |
| Polyoxyethylene sorbitan fatty acid ester | 5% |
| 1-Methyl-2-Pyrrolidone | 30% |
| Methyl vegetable oil | Polishing to 100% |
Processing method is sketched: by recipe requirements, first by adding in reactor after former medicine and solvent metering, starting stirring, stirring after dissolving completely, add surfactant again to continue to be stirred to the discharging of homogeneous phase transparent liquid, namely obtain 10% phonetic mite amine 10% beta-cypermethrin and dispersible finish product.
Embodiment stability test
The stability of test the various embodiments described above preparation, carries out the test of two control samples (being commercially available) simultaneously.Test condition is: store 14 days in 54 ± 2 DEG C of constant temperature ovens.Content after being stored by liquid-phase chromatographic analysis, utilizes following formulae discovery to obtain the resolution ratio of active constituent:
Computing formula: active constituent resolution ratio X is calculated as follows:
In formula:
M
0percentage composition before the storage of ┄ sample heat, %;
M
1percentage composition after the storage of ┄ sample heat, %.
The results are shown in table 1.
Table 1 embodiment and reference examples stability test contrast
The former medicine of phonetic mite amine is made 15% soluble concentrate and 15% and is dispersibled finish phonetic mite amination under the effect of stabilizing agent and have good stability and effectively can solve the floccule phenomenon of reference examples as can be seen from the table; The former medicine of phonetic mite amine and propargite and carbosulfan are made 20% and are dispersibled the floccule phenomenon that finish (1:1) can solve reference examples under the effect of stabilizing agent, and reduce the heat storage resolution ratio of propargite and carbosulfan; The former medicine of phonetic mite amine and spiral shell mite ester and beta-cypermethrin are made 20% and are dispersibled finish (1:1) and 15% and dispersible the floccule phenomenon that finish (4:1) can solve reference examples under the effect of stabilizing agent.
Claims (10)
1., containing an acaricide composition for stabilizing agent, it is characterized in that: acaricide composition comprises active component, stabilizing agent, surfactant and carrier; Each composition weight percentage composition is as follows: active component 5-70%, stabilizing agent 0.1-30%, surfactant 1-30%, carrier 1-60%;
Wherein, described active component is containing the E-type phenyl acrylates compounds of substituted anilino pyrimidine group or its agriculturally acceptable salt; Described active component be containing the E-type phenyl acrylates compounds of substituted anilino pyrimidine group or its agriculturally acceptable salt and other one or more there is the combination of the material of acaricidal activity.
2., by the acaricide composition containing stabilizing agent according to claim 1, it is characterized in that: in described composition the composition of each component and weight percentage as follows: active component 10-50%, stabilizing agent 1-25%, surfactant 1-30%, carrier 10-50%;
Wherein, described active component is phonetic mite amine or its agriculturally acceptable salt; Described active component be phonetic mite amine or its agriculturally acceptable salt and other one or more there is the combination of the material of acaricidal activity.
3., by the acaricide composition containing stabilizing agent described in claim 1 or 2, it is characterized in that: the described material that other have acaricidal activity is propargite, carbosulfan, spiral shell mite ester, beta-cypermethrin.
4., by the acaricide composition containing stabilizing agent according to claim 1, it is characterized in that: described active component is phonetic mite amine.
5., by the acaricide composition containing stabilizing agent described in claim 1 or 4, it is characterized in that: in described composition the composition of each component and weight percentage as follows: phonetic mite amine 5-30%, stabilizing agent 1-15%, surfactant 10-30%, carrier 25-60%.
6., by the acaricide composition containing stabilizing agent according to claim 1, it is characterized in that: described stabilizing agent is selected from the mixing of one or more in polyoxyethylene aryl phenyl ether, dioctyl sulfonic acid calcium succinate, Crodaret, triphenylethylene base polyoxyethylene ether sulfate, alkyl sorbose, triphenyl APEO, tributyl phosphate, epoxychloropropane.
7., by the acaricide composition containing stabilizing agent according to claim 1, it is characterized in that: described surfactant is selected from anion surfactant and/or non-ionic surface active agent, described carrier is liquid-carrier.
8., by the acaricide composition containing stabilizing agent according to claim 7, it is characterized in that: described anion surfactant is selected from the combination of one or more in fatty acid salt, polycarboxylate, alkylsulfonate, alkylaryl sulfonates, arylsulphonate, lignosulfonates.
9., by the acaricide composition containing stabilizing agent according to claim 8, it is characterized in that: described anion surfactant is selected from the combination of one or more in alkylsulfonate, polycarboxylate, arylsulphonate.
10., by the acaricide composition containing stabilizing agent according to claim 7, it is characterized in that: described non-ionic surface active agent is selected from the combination of one or more in fatty alcohol polyethenoxy ether class, alkylphenol polyoxyethylene class, aliphatic amine polyoxyethylene ether class, vegetable and animals oils polyethenoxy ether class, alkyl glycoside class, cellulose ethers.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857550A (en) * | 2015-12-11 | 2017-06-20 | 沈阳中化农药化工研发有限公司 | It is a kind of containing the bactericide for stablizing component |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| CN103355314A (en) * | 2013-08-02 | 2013-10-23 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing pyriminostrobin and etoxazole |
| CN103548833A (en) * | 2013-11-11 | 2014-02-05 | 陕西农心作物科技有限公司 | Acaricidal composition containing pyriminostrobin and propargite |
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2013
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| CN103355314A (en) * | 2013-08-02 | 2013-10-23 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing pyriminostrobin and etoxazole |
| CN103548833A (en) * | 2013-11-11 | 2014-02-05 | 陕西农心作物科技有限公司 | Acaricidal composition containing pyriminostrobin and propargite |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857550A (en) * | 2015-12-11 | 2017-06-20 | 沈阳中化农药化工研发有限公司 | It is a kind of containing the bactericide for stablizing component |
| CN106857550B (en) * | 2015-12-11 | 2019-11-12 | 沈阳中化农药化工研发有限公司 | It is a kind of containing the fungicide for stablizing component |
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| CN104686520B (en) | 2017-08-25 |
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Effective date of registration: 20160113 Address after: 110021 Liaodong Road, Tiexi District, Liaoning, No. 8-1, No. Applicant after: SHENYANG SINOCHEM PESTICIDE CHEMICAL RESEARCH AND DEVELOPMENT CO., LTD. Address before: 100031 Beijing, Xicheng District, the door of the revitalization of the main street, No. 28 Applicant before: Sinochem Corporation Applicant before: Shenyang Research Institute of Chemical Industry |
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