CN104674608B - A kind of preparation method of environmental protection package paper - Google Patents

A kind of preparation method of environmental protection package paper Download PDF

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Publication number
CN104674608B
CN104674608B CN201510059795.8A CN201510059795A CN104674608B CN 104674608 B CN104674608 B CN 104674608B CN 201510059795 A CN201510059795 A CN 201510059795A CN 104674608 B CN104674608 B CN 104674608B
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paper
slurry
coating
agent
parts
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CN104674608A (en
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宋俊富
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SHANGHAI JUNYUAN INDUSTRIAL Co Ltd
Spring Source New Material (shanghai) Co Ltd
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SHANGHAI JUNYUAN INDUSTRIAL Co Ltd
Spring Source New Material (shanghai) Co Ltd
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Abstract

The present invention relates to pulp technology for making paper, specifically a kind of preparation method of environmental protection package paper, compared with prior art, employ new preparation technology and prepare formula, not only improve the water-resistance of wrapping paper, solvent resistance but also cause that wrapping paper color is full bright-coloured, simultaneously as it is degradable resin so that the environmental-protecting performance of wrapping paper is also improved that material therefor is most.

Description

A kind of preparation method of environmental protection package paper
Technical field
The present invention relates to pulp technology for making paper, specifically a kind of preparation method of environmental protection package paper.
Background technology
As the development of society, humanistic culture also improve constantly, various red-letter days are also to come thick and fast, and so far must Few is exactly festive gift, and the packaging of gift is then to show present value and exquisite best external expression.But it is conventional at present Wrapping paper cause that water-resistance is poor, rough surface due to its fiber essential reason, it is impossible to meet the demand of client, one manufactured for this The environmental protection package paper with stronger water-resistance and solvent resistance and the bright-coloured light of surface color is planted extremely to be necessary.
The content of the invention
Instant invention overcomes the deficiencies in the prior art, there is provided one kind has stronger water-resistance and solvent resistance and surface The preparation method of the environmental protection package paper of bright-colored light.
In order to achieve the above object, the present invention devises a kind of manufacture method of environmental protection package paper, comprises the following steps:It is former Paper is manufactured paper with pulp, chromatograph is coated with, embossed and surface layer are coated with, it is characterised in that:
The surface layer coating, comprises the following steps:
Step 1, completes the preparation of investment precoat in a reservoir, and investment precoat is by weight ratio by 80-100 parts Gloss oil, the scratch resistance agent composition of 0-20 parts of water and 0-4 part, the gloss oil is polyacrylate resin or polyurethane resin.Institute It is a kind of trifunctional group cross-linking agent to state scratch resistance agent;
Step 2, is put into embossed paper in Kohler coater, using feeding roller by by the face after 200 mesh sieve net filtrations Coating applies on paper, with airblade coating by coating weight control in 8-15g/m2, while using blast 7-12kPa's Air knife blows out unnecessary coating, forms coating, and temperature in use will be after 110-130 DEG C of drying room will complete surface layer coating afterwards Dried to 4%-6% into paper moisture, form environmental protection package paper, and wind preservation;
The body paper is manufactured paper with pulp, and is comprised the following steps:
Step 1, the preparation of slurry:Prepared including slurry, prepared by dyestuff, auxiliary material liquid is prepared and with slurry;
(1)It is 1 from ratio:The masson pine that 1 softwood pulp and hardwood pulp is made, will bleach sulphur Hydrochlorate wood pulp carries out fibrosis in hydrabrusher, the wood pulp of fibrosis then is sent into upper storage stock tank one, in pulping process The middle masson pine that will have been accomplished fluently is put into lower storage stock tank, and the masson pine that will be accomplished fluently by pump for mortar transmission is sent to cone Defibrination is carried out in shape fiberizer, the masson pine after defibrination forms slurry, slurry is sent to upper storage stock tank two, using upper Slurry is placed into lower storage stock tank by the slurry position control switch in storage stock tank two, defibrination is circulated, until the beating degree of slurry Reach in the range of 22-24 ° of SR, the slurry for then finishing defibrination is sent to stand-by in upper storage stock tank two again, and makes slurry Refining concentration is maintained at 3.5%-4.0% and forms defibrination slurry;
(2)Demand according to required dyestuff selects dye formulation, weighs dyestuff and color fixing agent, reuses temperature in 90-95 DEG C hot water dyestuff is completely dissolved in dye barrel and heat preservation for standby use, color fixing agent is stand-by with 10 times of water dilution;The dye In the range of 0.0-5.0%, the color fixing agent consumption percentage by weight is in the range of 0.0-5.0% for the consumption of material;The dyestuff It is a kind of cation surfactant of resinous type to belong to direct dyes type color fixing agent;
(3)Relevant auxiliary agent is weighed, relevant auxiliary agent dissolving, dilution is then carried out in special container, and forms auxiliary material liquid to treat With in the range of 0.2%-3.0%, the auxiliary agent includes sizing agent, aluminum sulfate, reinforcement to the consumption percentage by weight of each auxiliary material liquid Agent, retention agent.Wherein sizing agent mainly has emulsification rosin alkyl ketene dimer, modified resin;Reinforcing agent, retention agent, mainly There are high molecular weight water soluble polymer and cationic starch type;
(4)First by the slurry of milled feeding with stock tank, then will be slow by the dye solution of 200 mesh sieve net filtrations It is slow to add with stock tank, it is described with the propeller that strength is provided with stock tank, slurry is sufficiently mixed and tieed up with dyestuff by propeller Hold 10 minutes, be subsequently adding color fixing agent liquid to dyeing and terminate, then auxiliary material liquid is slowly added into order with stock tank, it is described auxiliary Material order of addition is sizing agent, aluminum sulfate, reinforcing agent, is finally retention agent.Different auxiliary material was added at intervals of 5-10 minutes, was protected Hold with stock tank concentration in the range of 3.0%-3.5%, it is with slurry after the completion of, complete slurry and be sent to copy forebay one and to destroy forebay two;
Step 2, will copy the concentration dilution of slurry in forebay two and stablizes in 1.5% using consistencyregulator, will be modulated The slurry for having saved concentration uses flow control valve to be sent in fan pump with constant slurry amount, and fan pump sends flow control valve Slurry is diluted in the range of 0.06%-0.20% with substantial amounts of recycle-water, and the cushioning effect using slurry-stablizing case is stable by slurry Streaming to the system of manufacturing paper with pulp carries out treatment of manufacturing paper with pulp;
Step 3, treatment of manufacturing paper with pulp comprises the following steps:
(1)Using two excessive paddle garden net formers of following currents in double cylinder multi-cylinder paper machines, slurry is set to enter profit in the net of garden Drainage shaping is carried out with liquid level difference, l Water Paper page is produced, the online concentration of slurry is in the range of 0.06%-0.20%;
(2)The part moisture of l Water Paper page is squeezed out using a pair of the pressure roller and carrying roller in double cylinder multi-cylinder paper machines, is passed through The moisture content of l Water Paper page is 60-65% after squeezing;
(3)The use of many surface temperatures is that 70-115 DEG C of drying cylinder carries out continuous drying to completing the l Water Paper page after squeezing, makes After must drying into paper moisture be 2%-4%;
(4)Ornamenting is carried out to paper using cooling cylinder;Completion cooling cylinder ornamenting is preserved to form reel as a roll into paper Into paper.
The chromatograph coating, comprises the following steps:
Step 1, carries out the preparation of white material in a reservoir, and the white material is by weight ratio by 40-60 parts of water, 15-40 Part kaolin, 0-30 part of calcium carbonate, 0-20 part of titanium dioxide, 0.05-0.5 parts of dispersant constitutes, and constitute it is white The coating solids of material are 40%-60%, and kaolin, calcium carbonate and titanium dioxide are coating rank in the white material, and its whiteness will More than or equal to 90 °, powder granule is less than 2 μm, and powder granule content is more than or equal to 90%, and described dispersant is aqueous The conventional dispersant of pigment;
Step 2, the white material that chromatograph coating has been prepared by 25-45 parts by weight ratio, 0-20 parts of mill base, 30-60 parts Link stuff, 0-20 parts of water configures form in a reservoir, and the coating solids of the chromatograph coating for having configured are 25%-50%, Described mill base is commodity print paste, and described link stuff is polyacrylate resin or carboxylic styrene butadiene latex;
Step 3, carries out chromatograph coating process in coating machine, and reel into paper is put into coating machine, will using feeding roller Apply on paper, with airblade coating by coating weight control in 10-15g/ by the chromatograph coating after 200 mesh sieve net filtrations m2, while the air knife using blast in 7-12kPa blows out unnecessary coating, coating forming, temperature in use is in 110- afterwards 130 DEG C of drying room will complete being dried to 4%-6% into paper moisture after chromatograph is coated with, and form coated paper.
The embossed is specific as follows, the coated paper for preserving will be wound first and is placed in embossing machine, and it is adjusted Wet, damping moisture is 5-10g/m2, then embossed, using drying cylinder by the paper drying after embossing after the completion of embossing, and wind Form embossed paper.
The present invention compared with prior art, devises a kind of preparation method of environmental protection package paper, employs new preparation work Skill is formulated with preparing, and is not only improved the water-resistance of wrapping paper, solvent resistance but also is caused that wrapping paper color is full bright-coloured, while Because material therefor majority is degradable resin so that the environmental-protecting performance of wrapping paper is also improved.
Brief description of the drawings
Fig. 1 in the present invention body paper manufacture paper with pulp detail flowchart.
Fig. 2 is chromatograph coating, embossing, surface layer coating and product handling system process chart in the present invention.
Specific embodiment
It is existing in conjunction with the accompanying drawings and embodiments that the invention will be further described.
Now with red environmental protection package paper as embodiment:
The present invention is a kind of manufacture method of environmental protection package paper, including body paper manufacture paper with pulp, chromatograph coating, embossed and surface layer Coating, the surface layer coating, comprises the following steps:
Step 1, in a reservoir complete investment precoat preparation, investment precoat be by weight ratio by 80 parts of gloss oil, 18 parts of water and 2 parts of scratch resistance agent compositions, the gloss oil is polyurethane resin, and scratch resistance agent is a kind of trifunctional group cross-linking agent;
Step 2, is put into embossed paper in Kohler coater, using feeding roller by by the face after 200 mesh sieve net filtrations Coating applies on paper, with airblade coating by coating weight control in 12g/m2, while using blast 9kPa air knife Unnecessary coating is blown out, coating is formed, afterwards temperature in use after 115 DEG C of drying room will complete surface layer coating into paper water Divide drying to 5%, form environmental protection package paper, and wind preservation.
Body paper is manufactured paper with pulp in the present invention, is comprised the following steps:
Step 1, the preparation of slurry:Prepared including slurry, prepared by dyestuff, auxiliary material liquid is prepared and with slurry;
(1)500kg bleached sulphates softwood pulp and 500kg BRATSKs are weighed, sulphur will be bleached Hydrochlorate wood pulp carries out fibrosis in hydrabrusher, the wood pulp of fibrosis then is sent into upper storage stock tank one, in pulping process The middle masson pine that will have been accomplished fluently is put into lower storage stock tank, and the masson pine that will be accomplished fluently by pump for mortar transmission is sent to cone Defibrination is carried out in shape fiberizer, the masson pine after defibrination forms slurry, slurry is sent to upper storage stock tank two, using upper Slurry is placed into lower storage stock tank by the slurry position control switch in storage stock tank two, defibrination is circulated, until the beating degree of slurry Reach in the range of 23 ° of SR, the slurry for then finishing defibrination is sent to stand-by in upper storage stock tank two again, and makes the defibrination of slurry Concentration is maintained at 3.8% formation defibrination slurry;
(2)Demand according to required dyeing selects dye formulation, weighs dyestuff and color fixing agent, reuses temperature at 95 DEG C Hot water dyestuff is completely dissolved in dye barrel and heat preservation for standby use, color fixing agent is stand-by with 10 times of water dilution;The dyestuff It is red, consumption is 28kg, the color fixing agent consumption is 28kg;The dye type belongs to direct dyes type, color fixing agent It is a kind of cationic surfactant of resin type;
(3)Weigh relevant auxiliary agent and relevant auxiliary agent dissolving carried out in special container, dilutes stand-by, and form auxiliary material liquid, Consumption about auxiliary agent is:Sizing agent 20kg, aluminum sulfate 20kg, dry reinforcing agent 30kg, cationic starch 10kg are described to apply Jelly is conventional emulsification rosin alkyl ketene dimer, the reinforcing agent that dry reinforcing agent is high molecular weight water soluble polymer type;
(4)Then the slurry feeding of milled will be delayed with stock tank by the dye solution of 200 mesh sieve net filtrations first It is slow to add with stock tank, slurry is sufficiently mixed with dyestuff, and continue dyeing 10 minutes, to be subsequently adding color fixing agent, keep matching somebody with somebody The slurry concentration of slurry is in the range of 3.3%, it is with slurry after the completion of will complete slurry and be sent to copy forebay one and to destroy forebay two;It is described auxiliary Feed liquid addition sequence is:Sizing agent, aluminum sulfate, reinforcing agent, retention agent.General auxiliary agent input was at intervals of 8 minutes.The slurry Concentration is the percentage by weight by wood pulp material.
Step 2, the concentration dilution and stabilization of slurry in forebay two will be copied 1.5% using consistencyregulator, will be adjusted The slurry of good concentration uses flow control valve to be sent in fan pump with constant slurry amount, the slurry that fan pump sends flow control valve Material is diluted to 0.08% with substantial amounts of recycle-water, and slurry is smoothly streamed to the system of manufacturing paper with pulp using the cushioning effect of slurry-stablizing case enters Capable treatment of manufacturing paper with pulp;
Step 3, treatment of manufacturing paper with pulp comprises the following steps:
(1)Using two excessive paddle garden net formers of following currents in double cylinder multi-cylinder paper machines, slurry is set to enter profit in the net of garden Drainage shaping is carried out with liquid level difference, l Water Paper page is produced, the online concentration of slurry is 0.08%;
(2)The part moisture of l Water Paper page is squeezed out out pressure using a pair of the pressure roller and carrying roller in double cylinder multi-cylinder paper machines The moisture content for squeezing l Water Paper page is 63%;
(3)The use of many surface temperatures is that 70-115 DEG C of drying cylinder carries out continuous drying to completing the l Water Paper page after squeezing, makes After must drying into paper moisture be 3%;The dryer temperature is to be raised to 115 DEG C by 70 DEG C to eventually pass back to 100 DEG C to be formed Temperature curve;
(4)Ornamenting is carried out to paper using cooling cylinder;Completion cooling cylinder ornamenting is preserved to form reel as a roll into paper Into paper.
Chromatograph coating, comprises the following steps in the present invention:
Step 1, carries out the preparation of white material in a reservoir, the white material by weight ratio by 43 parts of water, 25 parts Kaolin, 15 parts of calcium carbonate, 15 parts of titanium dioxide, 0.2 part of dispersant composition, and the coating of the white material of composition contain admittedly It is 51% to measure, and kaolin, calcium carbonate and titanium dioxide are coating rank in the white material, and its whiteness is greater than or equal to 90 °, Powder granule is less than 2 μm, and powder granule content is more than or equal to 90%, the dispersion that described dispersant is commonly used for aqueous pigment Agent.
Step 2, the white material that chromatograph coating has been prepared by 25 parts, 18 parts of red mill bases, 45 parts of link stuff, 12 parts Water configure form in a reservoir, the coating solids of the chromatograph coating for having configured are 40%, and described mill base is commodity stamp Mill base, described link stuff is carboxylic styrene butadiene latex;
Step 3, carries out chromatograph coating process in coating machine, and reel into paper is put into coating machine, will using feeding roller Apply on paper, with airblade coating by coating weight control in 12g/m by the chromatograph coating after 200 mesh sieve net filtrations2, together Shi Liyong blast blows out unnecessary coating in the air knife of 9kPa, forms coating, afterwards drying room of the temperature in use at 115 DEG C Being dried to 5% into paper moisture after chromatograph is coated with will be completed, form coated paper.
The embossed is specific as follows, the coated paper for preserving will be wound first and is placed in embossing machine, and it is adjusted Wet, damping moisture is 7g/m2, then embossed, using drying cylinder by the paper drying after embossing after the completion of embossing, and wind shape Into embossed paper.
The present invention compared with prior art, devises a kind of preparation method of environmental protection package paper, employs new preparation work
Skill is formulated with preparing, and is not only improved the water-resistance of wrapping paper, solvent resistance but also is caused that wrapping paper color is full It is bright-coloured, simultaneously as it is degradable resin so that the environmental-protecting performance of wrapping paper is also improved that material therefor is most.

Claims (3)

1. a kind of manufacture method of environmental protection package paper, comprises the following steps:Body paper is manufactured paper with pulp, chromatograph is coated with, embossed and surface layer Coating, it is characterised in that:The surface layer coating, comprises the following steps:
Step 1, in a reservoir complete investment precoat preparation, investment precoat be by weight ratio by 80-100 parts of gloss oil, 0-20 parts of water and 0-4 parts of scratch resistance agent composition, the gloss oil are polyacrylate resin or polyurethane resin, and described is anti- It is a kind of crosslinking agent of trifunctional to scrape agent;
Step 2, is put into embossed paper in Kohler coater, will be applied by the surface layer after 200 mesh sieve net filtrations using feeding roller Material applies on paper, with airblade coating by coating weight control in 8-15g/m2, while using blast 7-12kPa air knife Unnecessary coating is blown out, coating is formed, afterwards temperature in use after 110-130 DEG C of drying room will complete surface layer coating into Paper moisture is dried to 4%-6%, forms environmental protection package paper, and wind preservation;
The body paper is manufactured paper with pulp, and is comprised the following steps:
Step 1, the preparation of slurry:Comprise the following steps:
Step a:It is 1 from ratio:The masson pine that 1 softwood pulp and hardwood pulp is made, will bleach sulphur Hydrochlorate wood pulp carries out fibrosis in hydrabrusher, and the masson pine of fibrosis then is sent into upper storage stock tank one, The masson pine that will have been accomplished fluently in pulping process is put into lower storage stock tank, by sending stock pump by the bleaching sulphur of fibrosis Hydrochlorate wood pulp carries out defibrination in being sent to conical refiner, and the masson pine after defibrination forms slurry, and slurry is sent to Storage stock tank two, lower storage stock tank is placed into using the slurry position control switch in upper storage stock tank two by slurry, is circulated defibrination, directly Beating degree to slurry is reached in the range of 22-24 ° of SR, and the slurry for then finishing defibrination is sent in upper storage stock tank two again It is stand-by, and the refining concentration of slurry is maintained at 3.5%-4.0% formation defibrination slurries;
Step b:Demand according to required dyeing selects dye formulation, weighs dyestuff and color fixing agent, reuses temperature in 90-95 DEG C hot water dyestuff is completely dissolved in dye barrel and heat preservation for standby use, color fixing agent is stand-by with 10 times of water dilution;The dye In the range of 0.0-5.0%, the color fixing agent consumption is in the range of 0.0-5.0% for the consumption of material;The dyestuff belongs to directly dye Material type, the color fixing agent is a kind of cationic surfactant of resinous type;
Step c:Auxiliary agent is weighed, auxiliary agent dissolving is carried out in special container, is diluted stand-by, and form auxiliary material liquid, the auxiliary material The consumption percentage by weight of liquid is in the range of 0.2%-3.0%;Described relevant auxiliary agent includes sizing agent, reinforcing agent, retention Agent, aluminum sulfate, are all the general auxiliary agents of papermaking;The sizing agent mainly has emulsification rosin, alkyl ketene dimer, modified tree Fat;
The reinforcing agent, retention agent, mainly there is high molecular weight water soluble polymer and cationic starch;
Step d:First by the slurry feeding of milled with stock tank, then by by the dye solution of 200 mesh sieve net filtrations It is slowly added into in stock tank, it is described with the propeller that strength is provided with stock tank, slurry and dyestuff are sufficiently mixed simultaneously by propeller Maintain 10 minutes, be subsequently adding color fixing agent liquid to dyeing and terminate, then auxiliary material liquid is slowly added into order with stock tank, it is described Auxiliary material order of addition is sizing agent, aluminum sulfate, reinforcing agent, is finally retention agent;Different auxiliary feed liquid is added at intervals of 5-10 points Clock, auxiliary material liquid should be by 200 mesh sieve net filtrations before adding;Holding concentration with slurry is with slurry complete in 3.0%-3.5% scopes Slurry will be completed after it is sent to copy forebay one and to destroy forebay two;
Step 2, will copy the concentration dilution of slurry in forebay two and stablizes in 1.5% using consistencyregulator, will be adjusted good The slurry of concentration uses flow control valve to be sent in fan pump with constant slurry amount, the slurry that fan pump sends flow control valve It is diluted in the range of 0.06%-0.20% with recycle-water, the cushioning effect using slurry-stablizing case enters pulp flow to the system of manufacturing paper with pulp Capable treatment of manufacturing paper with pulp;
Step 3, treatment of manufacturing paper with pulp comprises the following steps:
(1)Using two excessive paddle garden net formers of following currents in double cylinder multi-cylinder paper machines, slurry is entered in the net of garden and utilize liquid Potential difference carries out drainage shaping, produces l Water Paper page, and the online concentration of slurry is in the range of 0.06%-0.20%;
(2)The part moisture of l Water Paper page is squeezed out using a pair of the pressure roller and carrying roller in double cylinder multi-cylinder paper machines, goes out carrying roller L Water Paper page moisture is 60-65%;
(3)It is that 70-115 DEG C of drying cylinder is dried to the l Water Paper page after completion squeezing by many surface temperatures so that after drying Into paper moisture be 2%-4%;
(4)Ornamenting is carried out to paper using cooling cylinder;
(5)Completion cooling cylinder ornamenting is preserved to form reel into paper as a roll into paper.
2. the manufacture method of a kind of environmental protection package paper as described in claim 1, it is characterised in that the chromatograph coating, bag Include following steps:
Step 1, carries out the preparation of white material in a reservoir, and the white material is by weight ratio by 40-60 parts of water, 15-40 parts Kaolin, 0-30 parts of calcium carbonate, 0-20 parts of titanium dioxide, 0.05-0.5 parts dispersant composition, and composition white material Coating solids be 40%-60%, kaolin, calcium carbonate and titanium dioxide are coating rank in the white material, and its whiteness is big In or equal to 90 °, powder granule is less than 2 μm, and powder granule content is not less than 90%, and described dispersant is normal for aqueous pigment Dispersant;
Step 2, the white material that chromatograph coating has been prepared by 25-45 parts by weight ratio, 0-20 parts of mill base, 30-60 parts of company Ramming material, 0-20 parts of water configures form in a reservoir, and the coating solids of the chromatograph coating for having configured are 25%-50%, described Mill base be commodity print paste, described link stuff is polyacrylate resin or carboxylic styrene butadiene latex;
Step 3, carries out chromatograph coating process in coating machine, and reel into paper is put into coating machine, will be passed through using feeding roller Chromatograph coating after 200 mesh sieve net filtrations applies on paper, with airblade coating by coating weight control in 10-15g/m2, together Shi Liyong blast blows out unnecessary coating in the air knife of 7-12kPa, forms coating, and temperature in use is at 110-130 DEG C afterwards Drying room will complete being dried to 4%-6% into paper moisture after chromatograph coating, form coated paper.
3. the manufacture method of a kind of environmental protection package paper as described in claim 1, it is characterised in that:The embossed tool Body is as follows, the coated paper for preserving will be wound first and is placed in embossing machine, and damping is carried out to it, and damping moisture is 5-10g/m2, Then embossed, using drying cylinder by the paper drying after embossing after the completion of embossing, and winding forms embossed paper.
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CN105064114A (en) * 2015-08-13 2015-11-18 合肥龙发包装有限公司 High-strength packaging paper
CN105064115A (en) * 2015-08-13 2015-11-18 合肥龙发包装有限公司 High-folding-resistance packaging paper
CN108149511B (en) * 2017-12-22 2020-12-15 淄博欧木特种纸业有限公司 High-weather-resistance dip-dyed plain-color decorative base paper and preparation method thereof
CN108660851A (en) * 2018-05-18 2018-10-16 俞小峰 A kind of environment protecting paper and preparation method thereof
CN109183512A (en) * 2018-08-16 2019-01-11 何炽斌 A kind of production method of dye pure natural colorful paper processed
CN112012035A (en) * 2020-09-24 2020-12-01 惠州市源江印刷有限公司 Manufacturing method of environment-friendly deoxygenation drying packaging paper

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JPH1181195A (en) * 1997-09-03 1999-03-26 Tanakaya Inc Buffer paper and its production
KR20030097189A (en) * 2002-06-20 2003-12-31 이상욱 Apparatus of function tissue
CN201128843Y (en) * 2007-08-27 2008-10-08 王健成 Gift wrapping paper having surface
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