CN104673339B - A kind of device that agricultural crop straw is carried out smokeless carbonization process - Google Patents

A kind of device that agricultural crop straw is carried out smokeless carbonization process Download PDF

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Publication number
CN104673339B
CN104673339B CN201510076144.XA CN201510076144A CN104673339B CN 104673339 B CN104673339 B CN 104673339B CN 201510076144 A CN201510076144 A CN 201510076144A CN 104673339 B CN104673339 B CN 104673339B
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China
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carbonization process
crop straw
agricultural crop
bell
ppr
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CN104673339A (en
Inventor
姜军
徐仁扣
李忠意
袁金华
刘源
刘兆东
许晨阳
张海云
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Institute of Soil Science of CAS
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Institute of Soil Science of CAS
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/18Modifying the properties of the distillation gases in the oven
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Abstract

A kind of device that agricultural crop straw carries out smokeless carbonization process, forms including retort and purifier two parts;Described retort includes the bell clamping insulation material asbestos board, body of heater shell, carbonization chamber, base plate, ash mouth, chimney, fire door and air inlet;Described purifier includes flue gas threeway, axial flow AC blower fan, PPR adaptor, spray head, corrugated tube, PPR threeway, controls ball valve, magnetically-actuated circulating pump, outside ball valve, stainless steel frame and collecting vessel.The air pollution problems inherent of carbonization process is greatly solved, and a large amount of PM2.5 and PM10 particulate matters of generation are completely absorbed totally through spray and spiral purifying level two.Produce the biomass carbon quality obtained higher.Owing in whole carbonization process, the input quantity of oxygen is little, it is to avoid Artificial Control oxygen feeding amount holds inaccurate drawback, and in addition to fire door can produce minimal amount of ash owing to igniting, remaining straw all obtains uniform carbonization, substantially do not have ash in biomass carbon.

Description

A kind of device that agricultural crop straw is carried out smokeless carbonization process
Technical field
The present invention relates to straw environment protection charring process field, be specifically related to a kind of device that agricultural crop straw is carried out smokeless environment-friendly carbonization process.
Background technology
China is a large agricultural country, agricultural production can produce a large amount of agricultural crop straw, as a example by Caulis et Folium Oryzae, the yield of national Oryza glutinosa in 2012 is about 2.01 hundred million tons of (Chinese agriculture yearbooks, 2012), Caulis et Folium Oryzae along with 1-1.5kg is produced (Karimi etc., 2006, Biomass and by per kilogram Oryza glutinosa Bioenergy), therefore annual Caulis et Folium Oryzae yield 2.01-3.01 hundred million tons.If by Returning Application of Crop Straw, on the one hand quantity is the biggest and unrealistic;The more important thing is, the most of Organic substance being restored to field will gradually be decomposed by the microorganisms, and discharge CH in air4、N2O and CO2Isothermal chamber gas (Zou etc., 2005, Global Biogeochemical Cycles).Directly being burnt by crop material, will produce the particulate matters such as substantial amounts of PM2.5 and PM10, at crop harvesting a large amount of crop straw burning in season, the PM2.5 of generation has become the important sources of atmosphere pollution, more becomes the most nationwide problem of environmental pollution.Field naked light burns the PM2.5 of Semen Tritici aestivi, Semen Maydis and rice straw generation up to 7.2-39.0 g/kg (Zhu Bin etc., 2005, Research of Environmental Sciences), the research such as Wang shows, biomass combustion has respectively reached 3.0-16.8% and 4.0-19.0% (Wang etc. to the contribution of PM2.5 in Beijing and Guangzhou air, 2007, Atmospheric Environment)。
Under conditions of anaerobism or anoxybiotic, organic materials is pyrolyzed, the solid matter of a kind of similar black wood charcoal, commonly referred to as biomass carbon (Lehmann, 2007, Nature) can be generated.Biomass carbon is organic materials products of incomplete combustion, and it is rich in the nutrient needed for the crops such as K, Ca, Mg and P, can improve soil fertility (Lehmann and Rondon, 2006, Biological Approaches to Sustainable Soil Systems);And be typically alkalescence, can serve as the modifying agent of acid ground, reduce soil aciditiy (Yuan etc., 2011, Bioresource Technology), the yield of crops is improved;Biomass carbon surface, with a large amount of negative charges, significantly improves nitrogenous fertilizer and phosphate fertilizer utilization efficiency (Jiang Jun etc., patent of invention, ZL 201210488366.9 by changing soil property;Jiang etc., 2015, Soil and Tillage Research).Biomass carbon specific surface area and surface charge density are high simultaneously, have the strongest absorption property rich in organo-functional group, heavy metal and organic pollution, can be used on organic and inorganic wastewater process (Pan etc., 2014, Chemosphere;Yuan Min etc., 2012, ecological and rural environment science journal) it can also be used to reparation (Jiang etc., 2012, Journal of of heavy-metal contaminated soil Hazardous Materials;Jiang etc., 2012, Chemosphere).And carbon can effectively be sealed up for safekeeping by biomass carbon, the biomass carbon in being manured into soil has the highest stability, is difficult to be decomposed (Steinbeiss etc., 2009, Soil Biology & by soil microorganism Biochemistry), biomass carbon is to increasing carbon base in soil reserves, reduce Global Emissions of Greenhouse Gas, ecosystem carbon is maintained to balance significant (Lehmann, 2007, Nature), biomass carbon possibly even becomes the important way (Pan Genxing etc. of the carbon transaction alleviating climate change, 2010, ecological and rural environment journal).
But the PM2.5 produced during straw smoldering is 2.4-11.5 times of naked light, up to 67.6-104.6 g/kg (Zhu Bin etc., 2005, Research of Environmental Sciences).If biomass carbon preparation process is not taked the measure of purifying smoke, will result in more serious air pollution on the contrary.It addition, the many devices being currently used for preparing biomass carbon use Outside Heating Method, needing to consume mass energy, if utilizing the heat of release in agricultural wastes pyrolytic process to make its carbonization, also will be substantially reduced energy resource consumption and the preparation cost of biomass carbon.
Summary of the invention
Solve the technical problem that:The invention provides a kind of device that agricultural crop straw is carried out smokeless carbonization process.The biomass carbon utilizing crop material to produce can be used for improveing soil, processing waste water, seal carbon etc. up for safekeeping.This device is the feature produced according to crop material smoldering and flue gas, improve our existing straw carbonizing apparatus (Utility modelPatent, CN201962245U), increase flue gas purification system, be finally reached optimization carbonization process, improve biomass carbon product quality, eliminate the purpose of the airborne particulates (PM2.5 and PM10) produced in carbonization process.
Technical scheme:A kind of device that agricultural crop straw carries out smokeless carbonization process, forms including retort and purifier two parts;Described retort includes the bell clamping insulation material asbestos board, body of heater shell, carbonization chamber, base plate, and ash mouth, chimney, fire door and air inlet, carbonization chamber bottom is provided with stoveGrateInsulation material refractory brick it is filled with between body of heater shell and carbonization chamber, air inlet is positioned on the opposite body of heater of fire door and ash mouth, the both sides on retort top are located at by chimney, and bell is rotationally connected with body of heater shell by hinge, and bell is closed by the buckle being located on body of heater shell, ash mouth is positioned at the bottom of body of heater, fire door is located on ash mouth, and whole body of heater is placed on base plate, and the central authorities of bell are provided with thermometer;Described purifier includes flue gas threeway, axial flow AC blower fan, PPR adaptor, spray head, corrugated tube, PPR threeway, control ball valve, magnetically-actuated circulating pump, outside ball valve, stainless steel frame and collecting vessel, described retort chimney is connected by drain flue with the flue gas threeway of purifier, and flue gas threeway is provided with axial flow AC blower fan, and axial flow AC blower fan is connected with PPR threeway by reducing the PPR adaptor of bore step by step, the another two ends of PPR threeway are connected with corrugated tube and spray head respectively, and spray head scalable water smoke size is also provided with control ball valve;Spray head is connected with collecting vessel bottom outside ball valve through hose connection magnetically-actuated circulating pump, the connect flexible pipe of the magnetically-actuated circulating pump other end;Corrugated tube imports collecting vessel around stainless steel frame spiral.
Described base plate bottom is provided with castor.
This device also includes that handle, described handle are connected with base plate.
The described lifter that also includes, described lifter is located at below hinge and is connected with bell so that bell folding with convenience.
Water in described corrugated tube is flowed into collecting vessel by action of gravity, and water quantity holding is the 1/4-3/4 of sectional area.
Described axial flow AC blower fan power is 220 v/10 w.
Described magnetically-actuated circulation pump power is 220 v/6 w, lift 1 m.
The operation principle of the present invention:Utilizing the feature of crop material spontaneous combustion, provide a small amount of oxygen by small-power axial flow AC blower fan in combustion, it is ensured that carbonization process homogeneity, AC blower fan is simultaneously by fume collection and introduce purifier.Magnetically-actuated circulating pump drives shower water to absorb most flue gas, and the negative pressure spraying formation also provides the partial oxidation needed for smoldering process.Residue flue gas is threadingly advanced by faint wind-force in corrugated tube, fully reacts with water and absorbed cleanly during being threadingly advanced.
Beneficial effect:1. the present invention utilizes agricultural wastes straw as raw material, and the biomass carbon of production can be used for improveing soil, processing waste water, seal the multiple purposes such as carbon up for safekeeping, and to improving grain yield, contaminated soil remediation, reduction of greenhouse gas discharge etc. all has important function.2. straw charring process need not external energy, and gas cleaning uses 10 watts of axial flow AC blower fans and 6 watts of magnetically-actuated circulating pumps, and work only power consumption 0.384 degree in 24 hours, and operation energy consumption is relatively low, with low cost.3. operation is simpler, after only needing to add materials in retort, lights material from fire door and closes fire door during operation.Need not the air quantity in manual control carbonization process, the oxygen that the negative pressure formed by AC blower fan and spray is provided maintains a small amount of oxygen needed for smoldering.Taking out biomass carbon Deng body of heater after cooling down, production process i.e. completes.4. the air pollution problems inherent of carbonization process is greatly solved, and a large amount of PM2.5 and PM10 particulate matters of generation are completely absorbed totally through spray and spiral purifying level two.5. produce the biomass carbon quality obtained higher.Owing in whole carbonization process, the input quantity of oxygen is little, avoiding Artificial Control oxygen feeding amount and hold inaccurate drawback, in addition to fire door can produce minimal amount of ash owing to igniting, remaining straw all obtains uniform carbonization, substantially not having ash in biomass carbon, this point can be from biomass carbon productFigure ( Figure 3Find in).
Accompanying drawing explanation
Figure 1A is the side-looking of straw smokeless environment-friendly carbonizing apparatusFigure
Figure 1B is that the master of straw smokeless environment-friendly carbonizing apparatus regardsFigure
In figure, 1, bell;2, hinge;3, lifter;4, shell;5, carbonization chamber;6, stoveGrate;7, base plate;8, castor;9, Hui Kou;10, handle;11, buckle;12, thermometer;13, chimney;14, fire door;15, air inlet;16, insulation material refractory brick;17, insulation material asbestos board
Figure 2It it is the signal of straw smokeless environment-friendly carbonizing apparatusFigureIn figure, 18, drain flue;19, flue gas threeway;20, axial flow AC blower fan;21, PPR adaptor;22, spray head;23, corrugated tube;24, PPR threeway;25, ball valve is controlled;26, magnetically-actuated circulating pump;27, outside ball valve;28, stainless steel frame;29, collecting vessel.In figureLetter A is represented left and right sides drain flue 18 and is interconnected by flue gas threeway 19.
Figure 3It is that the biomass carbon product that the biomass carbon material (0.45 mm wheat stalk charcoal) obtained obtains with common retort comparesFigure
Figure 4It is environmental background value, the monitoring result of fire door PM2.5 in environmental protection retort and common retort carbonization process.
Figure 5It is environmental background value, the monitoring result of fire door PM10 in environmental protection retort and common retort carbonization process.
Detailed description of the invention
Following example further illustrate present disclosure, but should not be construed as limitation of the present invention.Without departing from the spirit and substance of the case in the present invention, the amendment that the inventive method, step or condition are made and replacement, belong to the scope of the present invention.
If not specializing, the conventional means that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1:
A kind of device that agricultural crop straw carries out smokeless carbonization process, forms including retort and purifier two parts;Described retort includes the bell 1 clamping insulation material asbestos board 17, body of heater shell 4, carbonization chamber 5, base plate 7, and ash mouth 9, chimney 13, fire door 14 and air inlet 15, carbonization chamber 5 bottom is provided with stoveGrate6, insulation material refractory brick 16 it is filled with between body of heater shell 4 and carbonization chamber 5, air inlet 15 is positioned on the opposite body of heater of fire door 14 and ash mouth 9, the both sides on retort top are located at by chimney 13, and bell 1 is rotationally connected with body of heater shell 4 by hinge 2, and bell 1 is closed by the buckle 11 being located on body of heater shell 4, ash mouth 9 is positioned at the bottom of body of heater, fire door 14 is located on ash mouth 9, and whole body of heater is placed on base plate 7, and the central authorities of bell 1 are provided with thermometer 12;Described purifier includes flue gas threeway 19, axial flow AC blower fan 20, PPR adaptor 21, spray head 22, corrugated tube 23, PPR threeway 24, control ball valve 25, magnetically-actuated circulating pump 26, outside ball valve 27, stainless steel frame 28 and collecting vessel 29, described retort chimney 13 is connected by drain flue 18 with the flue gas threeway 19 of purifier, flue gas threeway 19 is provided with axial flow AC blower fan 20, axial flow AC blower fan 20 is connected with PPR threeway 24 by reducing the PPR adaptor 21 of bore step by step, the another two ends of PPR threeway 24 are connected with corrugated tube 23 and spray head 22 respectively, spray head 22 scalable water smoke size is also provided with control ball valve 25;Spray head 22 is connected with collecting vessel bottom outside ball valve 27 through hose connection magnetically-actuated circulating pump 26, the connect flexible pipe of magnetically-actuated circulating pump 26 other end;Corrugated tube 23 imports collecting vessel 29 around stainless steel frame 28 spiral.
Described base plate bottom is provided with castor 8.
Also include that handle 10, described handle 10 are connected with base plate 7.
The described lifter 3 that also includes, described lifter 3 is located at below hinge 2 and is connected with bell 1 so that bell 1 folding with convenience.
Water in described corrugated tube is flowed into collecting vessel by action of gravity, and water quantity holding is the 1/4-3/4 of sectional area.
Described axial flow AC blower fan power is 220 v/10 w.
Described magnetically-actuated circulation pump power is 220 v/6 w, lift 1 m.
Embodiment 2: the preparation of wheat stalk charcoal
Using the device described in embodiment 1, open bell 1, load agricultural crop straw such as wheat stalk, loading limit, limit is treaded, and is closely covered on body of heater by bell 1 by buckle 11 after filling;Thermometer 12 is injected body of heater by the aperture of bell central authorities;Open the fire door 14 being positioned at lower portion of furnace body, wheat stalk is lighted;Closing upper furnace door 14, open axial flow AC blower fan and magnetically-actuated circulating pump, wheat stalk is the most uniformly carbonization in retort, and after carbonization process completes, stove gradually cools down.After stove is cooled to ambient temperature, open fire door 14, go out charcoal from ash mouth 9.Time stove is no, by the castor 8 of handle 10 and bottom of furnace body, stove can be moved to storehouse and place.
In wheat stalk charcoal preparation process, to environmental background value, in environmental protection retort and common retort carbonization process, the monitoring result of fire door PM2.5 and PM10 shows, environmental protection retort fire door PM2.5 and PM10 concentration in operation process is the most consistent with environmental background value, it is meant that environmental protection retort does not the most produce the particulate matters such as PM2.5 and PM10 in whole carbonization operation process.And common retort in first 8 hours of carbonization, PM2.5 is all in the state (PM2.5 > 999.99 ppm) of quick-fried table, at the end of carbonization process is gradually, PM2.5 value is gradually decrease to background value.And PM10 reached the highest at 2nd hour, may is that the steam vapour amount that now carbonization process produces is maximum, be gradually lowered afterwards, remained stable at 3-21 hour, but also apparently higher than the PM10 value of background value and environmental protection retort.Therefore, producing substantial amounts of PM2.5 and PM10 particulate matter during compared to common retort carbonization wheat stalk, environmental protection retort is essentially without producing particulate matter in operation process, and pole protects atmospheric environment significantly.Additionally in environmental protection carbonization and common carbonizing production, content of ashes is respectively 14.55% and 31.17%, and the wheat straw biologic matter carbonaceous amount of environmental protection carbonization is significantly higher than common carbonization.
Embodiment 3: the preparation of Pericarppium arachidis hypogaeae charcoal
Use the device described in embodiment 1, open bell, at stoveGrateOne layer of upper berth Caulis et Folium Oryzae or wheat stalk, then load carbonization chamber by the Pericarppium arachidis hypogaeae stripping out kernel, fill, be compacted, cover tightly bell.Open the fire door being positioned at lower portion of furnace body, Caulis et Folium Oryzae or wheat stalk are lighted, then the Pericarppium arachidis hypogaeae that ignites;Close upper furnace door, open axial flow AC blower fan and magnetically-actuated circulating pump.After retort is cooled to ambient temperature, carbonization process i.e. completes, and opens fire door, goes out charcoal from Hui Kou.In environmental protection carbonization and common carbonizing production, content of ashes is respectively 12.31% and 23.48%, and the peanut hull biologic matter carbonaceous amount of environmental protection carbonization is also significantly greater than common carbonization.

Claims (7)

1. the device that agricultural crop straw is carried out smokeless carbonization process, it is characterised in that include retort and purifier two parts composition;nullDescribed retort includes the bell (1) clamping insulation material asbestos board (17),Body of heater shell (4),Carbonization chamber (5),Base plate (7),Ash mouth (9),Chimney (13),Fire door (14) and air inlet (15),Carbonization chamber (5) bottom is provided with grate (6),Insulation material refractory brick (16) it is filled with between body of heater shell (4) and carbonization chamber (5),Air inlet (15) is positioned on the opposite body of heater of fire door (14) and ash mouth (9),The both sides on retort top are located at by chimney (13),Bell (1) is rotationally connected with body of heater shell (4) by hinge (2),Bell (1) is closed by the buckle (11) being located on body of heater shell (4),Ash mouth (9) is positioned at the bottom of body of heater,Fire door (14) is located on ash mouth (9),Whole body of heater is placed on base plate (7),The central authorities of bell (1) are provided with thermometer (12);nullDescribed purifier includes flue gas threeway (19),Axial flow AC blower fan (20),PPR adaptor (21),Spray head (22),Corrugated tube (23),PPR threeway (24),Control ball valve (25),Magnetically-actuated circulating pump (26),Outside ball valve (27),Stainless steel frame (28) and collecting vessel (29),Described retort chimney (13) is connected by drain flue (18) with the flue gas threeway (19) of purifier,Flue gas threeway (19) is provided with axial flow AC blower fan (20),Axial flow AC blower fan (20) is connected with PPR threeway (24) by reducing the PPR adaptor (21) of bore step by step,The another two ends of PPR threeway (24) are connected with corrugated tube (23) and spray head (22) respectively,Spray head (22) scalable water smoke size is also provided with control ball valve (25);Spray head (22) is connected with collecting vessel bottom outside ball valve (27) through hose connection magnetically-actuated circulating pump (26), the connect flexible pipe of magnetically-actuated circulating pump (26) other end;Corrugated tube (23) imports collecting vessel (29) around stainless steel frame (28) spiral.
The device that agricultural crop straw is carried out smokeless carbonization process the most according to claim 1, it is characterised in that described base plate bottom is provided with castor (8).
The device that agricultural crop straw is carried out smokeless carbonization process the most according to claim 1, it is characterised in that also include that handle (10), described handle (10) are connected with base plate (7).
The device that agricultural crop straw is carried out smokeless carbonization process the most according to claim 1, characterized by further comprising lifter (3), described lifter (3) is located at hinge (2) lower section and is connected with bell (1) so that bell (1) folding with convenience.
5., according to the device that agricultural crop straw carries out smokeless carbonization process described in claim 1, it is characterised in that the water in described corrugated tube is flowed into collecting vessel by action of gravity, water quantity holding is the 1/4-3/4 of sectional area.
6. according to the device that agricultural crop straw is carried out smokeless carbonization process described in claim 1, it is characterised in that described axial flow AC blower fan power is 220 v/10 w.
7. according to the device that agricultural crop straw is carried out smokeless carbonization process described in claim 1, it is characterised in that described magnetically-actuated circulation pump power is 220 v/6 w, lift 1 m.
CN201510076144.XA 2015-02-12 2015-02-12 A kind of device that agricultural crop straw is carried out smokeless carbonization process Expired - Fee Related CN104673339B (en)

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CN107267175B (en) * 2017-07-04 2022-12-27 浙江大学 Gas circulation type crop straw cracking machine
CN108085083B (en) * 2017-12-21 2020-05-19 肇庆学院 Movable device and method for preparing biomass charcoal by field in-situ oxygen limitation

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CN2921014Y (en) * 2006-01-08 2007-07-11 商丘三利新能源有限公司 Pool type stalks comprehensive utilization carbonizing device
CN202272847U (en) * 2011-06-07 2012-06-13 上海盈汇飞新能源科技有限公司 Biomass liquid fuel preparation system
CN203768037U (en) * 2014-04-03 2014-08-13 福建省荔元活性炭实业有限公司 Automatic production system of activated carbon

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