CN104673104A - Fireproof nontoxic adhesive for fiberboard - Google Patents

Fireproof nontoxic adhesive for fiberboard Download PDF

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Publication number
CN104673104A
CN104673104A CN201310633824.8A CN201310633824A CN104673104A CN 104673104 A CN104673104 A CN 104673104A CN 201310633824 A CN201310633824 A CN 201310633824A CN 104673104 A CN104673104 A CN 104673104A
Authority
CN
China
Prior art keywords
parts
methyl methacrylate
fiberboard
fire prevention
adhesion agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310633824.8A
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Chinese (zh)
Inventor
洪龙峰
孙均衡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Water World Environmental Protection Technology Co Ltd
Original Assignee
Qingdao Water World Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Water World Environmental Protection Technology Co Ltd filed Critical Qingdao Water World Environmental Protection Technology Co Ltd
Priority to CN201310633824.8A priority Critical patent/CN104673104A/en
Publication of CN104673104A publication Critical patent/CN104673104A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a fireproof nontoxic adhesive for a fiberboard. The adhesive comprises the following components in parts by weight: 60-80 parts of methyl methacrylate, 40-60 parts of methyl methacrylate beta-hydroxy ethyl, 5-10 parts of glycidyl methacrylate, 2-8 parts of propadiene rubber, 5-10 parts of ABS resin, 0.5-1 part of propyl gallate, 1-2 parts of salicylic acid, 3-5 parts of nano-sized silica, 1-3 parts of mica powder, 1-3 parts of calcium oxide, 1-3 parts of calcium chloride and 1-3 parts of paraffin. The adhesive has excellent flame retardance and fireproof performance; due to the paraffin, the dried adhesive film of the adhesive further has excellent waterproof performance; and furthermore, the adhesive is toxic and does not damage a user.

Description

For the fire prevention avirulent adhesion agent of fiberboard
Technical field
The invention belongs to a kind of tackiness agent, be specifically related to a kind of fire prevention avirulent adhesion agent for fiberboard, belong to technical field of chemistry and chemical engineering.
Background technology
21 century is a century of advocating environmental protection, people are more and more higher for the attention rate of health, in household fitment process, change existing floor tile, wood floors into from original concrete floor, not only substantially increase aesthetic measure at home, and also improve the living environment level of resident.
Wood floors tackiness agent in fitment process is absolutely necessary, people have toxicological harmless as selecting an one important standard using what select, but meanwhile, along with the frequent generation of the events such as fire flood, people progressively improve for the attention degree of fire-proof and water-proof, waterproof has also become flooring adhesive important selective goal, and particularly for wood floors, the material of its uniqueness decides a development trend of fire-type tackiness agent necessarily normal wood quality board adhesive.
Conventional refractory adhesive, can not life-time service usually containing certain toxicity, otherwise can cause certain harm to user is healthy.
Summary of the invention
The object of the present invention is to provide and a kind ofly have good fire-retardant fireproof performance, due to the effect of paraffin, its dry glued membrane also has the fire prevention avirulent adhesion agent for fiberboard of good water resistance.
In order to achieve the above object, this invention takes following technical scheme:
For a fire prevention avirulent adhesion agent for fiberboard, by weight, containing following material:
Methyl methacrylate 60 ~ 80 parts, methyl methacrylate beta-hydroxy ethyl ester 40 ~ 60 parts, glytidyl methacrylate 5 ~ 10 parts, propylene diene rubber 2 ~ 8 parts, ABS resin 5 ~ 10 parts, Tenox PG 0.5 ~ 1 part, Whitfield's ointment 1 ~ 2 part, nano silicon oxide 3 ~ 5 parts, mica powder 1 ~ 3 part, 1 ~ 3 part, calcium oxide, 1 ~ 3 part, calcium chloride 1 ~ 3 part of paraffin.
Described methyl methacrylate is colourless transparent liquid, and purity is not less than 99.5%.
Described methyl methacrylate beta-hydroxy ethyl ester is clear motile liquid, and purity is greater than 95%.
Described glytidyl methacrylate is liquid, and purity is greater than 96%.
The fineness of described mica powder, calcium oxide and calcium chloride is 250 ~ 400.
The described fire prevention avirulent adhesion agent for fiberboard is obtained by following steps:
(1) mica powder, calcium oxide, calcium chloride, nano silicon, paraffin, Whitfield's ointment, ABS resin are added in proportion mix as component A in methyl methacrylate liquid for subsequent use.
(2) Tenox PG, propylene diene rubber are added in methyl methacrylate beta-hydroxy ethyl ester liquid mix, for subsequent use as B component.
(3) component A, B component and glytidyl methacrylate three are added in container fully stir, mix, obtained finished product.
This invention gained stick has good fire-retardant fireproof performance, and due to the effect of paraffin, its dry glued membrane also has good water resistance.In use, can not discharge any toxic substance, toxic gas, even if at high temperature, dry glued membrane is also released without any toxic gas after decomposing.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described.
Embodiment 1:
For a fire prevention avirulent adhesion agent for fiberboard, by weight, containing following material:
Methyl methacrylate 60 ~ 80 parts, methyl methacrylate beta-hydroxy ethyl ester 40 ~ 60 parts, glytidyl methacrylate 5 ~ 10 parts, propylene diene rubber 2 ~ 8 parts, ABS resin 5 ~ 10 parts, Tenox PG 0.5 ~ 1 part, Whitfield's ointment 1 ~ 2 part, nano silicon oxide 3 ~ 5 parts, mica powder 1 ~ 3 part, 1 ~ 3 part, calcium oxide, 1 ~ 3 part, calcium chloride 1 ~ 3 part of paraffin.
In technique scheme, the described fire prevention avirulent adhesion agent for fiberboard is obtained by following steps:
(1) mica powder, calcium oxide, calcium chloride, nano silicon, paraffin, Whitfield's ointment, ABS resin are added in proportion mix as component A in methyl methacrylate liquid for subsequent use.
(2) Tenox PG, propylene diene rubber are added in methyl methacrylate beta-hydroxy ethyl ester liquid mix, for subsequent use as B component.
(3) component A, B component and glytidyl methacrylate three are added in container fully stir, mix, obtained finished product.
This fire prevention avirulent adhesion agent being used for fiberboard has good water resistance, does not discharge any toxic substance.
Embodiment 2:
For a fire prevention avirulent adhesion agent for fiberboard, by weight, containing following material:
Methyl methacrylate 70 parts, methyl methacrylate beta-hydroxy ethyl ester 50 parts, glytidyl methacrylate 8 parts, propylene diene rubber 6 parts, ABS resin 8 parts, Tenox PG 0.8 part, Whitfield's ointment 1.5 parts, nano silicon oxide 5 parts, mica powder 3 parts, 3 parts, calcium oxide, 1 part, calcium chloride 3 parts of paraffin.
This fire prevention avirulent adhesion agent being used for fiberboard has good water resistance.
Preparation method is with embodiment 1.
Embodiment 3:
For a fire prevention avirulent adhesion agent for fiberboard, by weight, containing following material:
Methyl methacrylate 80 parts, methyl methacrylate beta-hydroxy ethyl ester 60 parts, glytidyl methacrylate 10 parts, propylene diene rubber 7 parts, ABS resin 8 parts, Tenox PG 1 part, Whitfield's ointment 2 parts, nano silicon oxide 5 parts, mica powder 3 parts, 3 parts, calcium oxide, 3 parts, calcium chloride 3 parts of paraffin.
This fire prevention avirulent adhesion agent being used for fiberboard has good water-repellancy.
Preparation method is with embodiment 1.
Gained stick of the present invention has good fire-retardant fireproof performance, and due to the effect of paraffin, its dry glued membrane also has good water resistance.In use, can not discharge any toxic substance, toxic gas, even if at high temperature, dry glued membrane is also released without any toxic gas, is followed the fire prevention avirulent adhesion agent being mainly used in fiberboard after decomposing.
Invention can be understood further by the invention process given above; above embodiment is only several specific embodiment of the present invention; but design concept of the present invention is not limited thereto; all changes utilizing this design the present invention to be carried out to unsubstantiality, all should belong to the behavior of invading scope.

Claims (6)

1. a fire prevention avirulent adhesion agent for fiberboard, by weight, is made up of following material: methyl methacrylate 60 ~ 80 parts, methyl methacrylate beta-hydroxy ethyl ester 40 ~ 60 parts, glytidyl methacrylate 5 ~ 10 parts, propylene diene rubber 2 ~ 8 parts, ABS resin 5 ~ 10 parts, Tenox PG 0.5 ~ 1 part, Whitfield's ointment 1 ~ 2 part, nano silicon oxide 3 ~ 5 parts, mica powder 1 ~ 3 part, 1 ~ 3 part, calcium oxide, 1 ~ 3 part, calcium chloride 1 ~ 3 part of paraffin.。
2. the fire prevention avirulent adhesion agent of fiberboard according to claim 1, is characterized in that, described methyl methacrylate is colourless transparent liquid, and purity is not less than 99.5%.
3. the fire prevention avirulent adhesion agent of fiberboard according to claim 1, is characterized in that, described methyl methacrylate beta-hydroxy ethyl ester is clear motile liquid, and purity is greater than 95%.
4. the fire prevention avirulent adhesion agent of fiberboard according to claim 1, is characterized in that, described glytidyl methacrylate is liquid, and purity is greater than 96%.
5. the fire prevention avirulent adhesion agent of fiberboard according to claim 1, is characterized in that, the fineness of described mica powder, calcium oxide and calcium chloride is 250 ~ 400.
6., according to the fire prevention avirulent adhesion agent of the arbitrary described fiberboard of claim 1 to 5, it is characterized in that, be obtained by following steps:
(1) mica powder, calcium oxide, calcium chloride, nano silicon, paraffin, Whitfield's ointment, ABS resin are added in proportion mix as component A in methyl methacrylate liquid for subsequent use.
(2) Tenox PG, propylene diene rubber are added in methyl methacrylate beta-hydroxy ethyl ester liquid mix, for subsequent use as B component.
(3) component A, B component and glytidyl methacrylate three are added in container fully stir, mix, obtained finished product.
CN201310633824.8A 2013-11-29 2013-11-29 Fireproof nontoxic adhesive for fiberboard Pending CN104673104A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310633824.8A CN104673104A (en) 2013-11-29 2013-11-29 Fireproof nontoxic adhesive for fiberboard

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310633824.8A CN104673104A (en) 2013-11-29 2013-11-29 Fireproof nontoxic adhesive for fiberboard

Publications (1)

Publication Number Publication Date
CN104673104A true CN104673104A (en) 2015-06-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310633824.8A Pending CN104673104A (en) 2013-11-29 2013-11-29 Fireproof nontoxic adhesive for fiberboard

Country Status (1)

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CN (1) CN104673104A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105401256A (en) * 2015-12-30 2016-03-16 李栋军 Constructional flame-retardation fiber material
CN105645887A (en) * 2015-12-30 2016-06-08 王丽萍 High-efficiency constructional flame retardation fiber material
CN105712665A (en) * 2016-03-19 2016-06-29 贵州宏泰新材料有限责任公司 Sound-absorbing building material and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105401256A (en) * 2015-12-30 2016-03-16 李栋军 Constructional flame-retardation fiber material
CN105645887A (en) * 2015-12-30 2016-06-08 王丽萍 High-efficiency constructional flame retardation fiber material
CN105712665A (en) * 2016-03-19 2016-06-29 贵州宏泰新材料有限责任公司 Sound-absorbing building material and manufacturing method thereof

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Application publication date: 20150603