CN104672988B - Glazing-free double-PE water-based flexible ink and preparation method thereof - Google Patents
Glazing-free double-PE water-based flexible ink and preparation method thereof Download PDFInfo
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- CN104672988B CN104672988B CN201510109608.2A CN201510109608A CN104672988B CN 104672988 B CN104672988 B CN 104672988B CN 201510109608 A CN201510109608 A CN 201510109608A CN 104672988 B CN104672988 B CN 104672988B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention belongs to the technical field of ink preparation, and particularly relates to glazing-free double-PE water-based flexible ink and a preparation method thereof. The glazing-free double-PE water-based flexible ink comprises the following raw materials in percentage by weight: 40-60% of varnish and 40-60% of water-based color paste, wherein the varnish comprises the following raw materials in percentage by weight: 60-80% of soft emulsion, 0-10% of hard emulsion, 0-25% of water-soluble resin liquid, 1-3% of a scratch-resistant agent, 1-3% of a crosslinking agent, 0-3% of a water-resistant agent, 0-1% of a leveling agent, 0-8% of a film-forming auxiliary agent, 0.1-0.5% of a defoaming agent and the balance of deionized water. The glazing-free double-PE water-based flexible ink omits a glazing process in the printing process, so that the cost is saved, and a double-PE paper cup printed by using the ink is high in gloss, colorful, beautiful, water-proof, wear-resistant, high-temperature-resistant and freezing-resistant.
Description
Technical field
The invention belongs to ink preparing technical field, more particularly to one kind exempts from the double PE water-based flexographic inks of glazing and its preparation
Method.
Background technology
The fast foods such as McDonald, Pepsi widely use dual-PE paper cups, paper bowl and fiber drum etc. for containing Hot Coffee, cold drink etc.,
Erie's Yoghourt etc. also begins to use dual-PE paper cups.For the needs of brand, the pattern being beautifully printed is needed.And the needs of environmental protection,
Manufacturer has required that must be printed by printing enterprise using water color ink.
As double PE body paper are the products that the two-sided film of former wood pulp paper is obtained, PE film tensions are low, will print on its surface
The water color ink of brush high surface tension, it is easy to produce leaflet ink poor adhesive force, it is not water-fast, not high-low temperature resistant etc. it is existing
As.
At present, in prior art, dual-PE paper cups printing water color ink used typically can be contacted by colored ink and with food
Oil polish two parts composition, wherein colored ink has the performance such as nonpoisonous and tasteless, bright in luster, can meet substantially client will
Ask, if but due to the colored ink not oil polish, not wear-resisting, non-watertight, the not disadvantage such as high-low temperature resistant is there is, so as to necessary
There is oil polish technique, this adds increased the production cost of printing house.
The content of the invention
An object of the present invention is：In view of the shortcomings of the prior art, there is provided oil polish technique after a kind of removal,
That saves production cost exempts from the double PE water-based flexographic inks of glazing.
To solve above-mentioned technical problem, the technical scheme is that：
One kind exempts from the double PE water-based flexographic inks of glazing, the raw material group by the following percentage by weight of water-based flexographic ink
Into：Varnish 40～60% and aqueous color paste 40～60%；Wherein, raw material group of the varnish by following percentage by weight
Into：Soft emulsion 60～80%, hard emulsion 0～10%, water-soluble resin liquid 0～25%, scratch resistance agent 1～3%, cross-linking agent 1
～3%, water repellent agent 0～3%, levelling agent 0～1%, coalescents 0～8%, defoamer 0.1～0.5%, remaining is deionization
Water.
Used as a kind of improvement, the soft emulsion is minimum film formation temperature<10 DEG C of acrylic emulsion or minimum film forming temperature
Degree<10 DEG C of self-crosslinking aqueous acrylic resin liquid；The JONCRYL 624 of the preferably German BASF of acrylic emulsion,
R20, R20B, RX20, RX30 of JONCRYL 617, JONCRYL 74 or Korea Han Hua；Self-crosslinking aqueous acrylic resin liquid is excellent
Elect Neocryl A-1092, the Neocryl A-2092 or Neocryl A-1127 of U.S.'s DSM as.
Used as a kind of improvement, the hard emulsion is minimum film formation temperature>80 DEG C of acrylic emulsion or minimum film forming temperature
Degree>80 DEG C of self-crosslinking aqueous acrylic resin liquid；The JONCRYL 89 and JONCRYL 90 or Korea Spro of preferably German BASF
The R90 of state Han Hua；Self-crosslinking aqueous acrylic resin liquid is preferably the Neocryl A-1091 and Neocryl of U.S.'s DSM
A-2091。
Soft emulsion can give the certain pliability of ink film and durability, and hard emulsion can make that ink setting speed is fast, light
Damp high, hardness is high, stain resistance is good, be difficult to after-tack under high temperature, and both are used in mixed way can make ink have higher gloss and hard
Degree, and there is certain pliability and durability, heat-resisting, fast light, ageing-resistant, stain resistant is good.
As a kind of improvement, amination aqueous solution of the water-soluble resin liquid for solid styrene-acrylic resin；Preferably JONCRYL
HPD96、JONCRYL HPD96MEA、JONCRYL 61；Water-soluble resin liquid filming performance is good, and during printing, solubility is good.
Used as a kind of improvement, the scratch resistance agent is supra polymer polydimethylsiloxane；Preferably Dow corning
DC51；Scratch resistance agent is used to increase the flatness and wear resistance of ink, can reduce the coefficient of friction of ink, anti, greatly
Improve greatly the wear resistance of ink.
Used as a kind of improvement, the cross-linking agent is Zinc Oxide ammonia solution；The ZincOxide of preferably German BASF
Solution#1；Cross-linking agent can promote the combination of each composition, so as to provide the cohesive force of ink.
Used as a kind of improvement, the water repellent agent is polysiloxane solution；The preferably DC85 of Dow corning；Water repellent agent can
The water solublity after ink setting film forming is reduced, moisture-resisting friction and the picking strength of dual-PE paper cups is improved, is effectively improved dual-PE paper cups
Printability, reduce hair loss, the phenomenon such as fall the effect of ink.
Used as a kind of improvement, the levelling agent is octyl phenol, nonyl phenol ethoxy compound class, acetylenic diols or polyethers silicon
The special OT-75 of oxygen alkanes, preferably U.S.'s cyanogen, the Surfynol 104E of U.S.'s gas, the BYK-301 of Germany Bi Ke, levelling agent
Can promote ink that a smooth, smooth, uniform film is formed during drying and forming-film, can effectively reduce the surface of ink
Power, improves its levelability and uniformity.
Used as a kind of improvement, the coalescents include Propylene Glycol, glycerol, diethylene glycol ether or dipropylene glycol methyl ether
In one or more；Due to the higher cracking that can cause ink film of the minimum film formation temperature of hard emulsion, coalescents because
Its dissolution to latex particle and soften particle surface, promote the easy compressive deformation of polymer particle, merge film forming, it is to avoid
Crack performance.
Used as a kind of improvement, the defoamer is polysiloxane-based defoamer, the preferably DC65 of Dow corning, Germany
The high TEGO Foamex 825 of enlightening, defoamer be used for effectively prevent water color ink production and printing process in produce bubble and
Eliminate the bubble for producing.
Aqueous color paste is preferably outsourcing import aqueous color paste finished product, the Hostafine series aqueouss colors of such as German Clariant
Slurry, preferably Yellow GR, Yellow HR, Red HF3S, Red FGR, Red F5RK, Red P2GL, Magenta E,
Violet RL, Blue B2G, Green GN or Black T 30, the ultra-fine environment-protective water of Bayer Levanyl series of Bayer Bitterfeld GmbH
Property dispersible pigment color paste, preferably LEVANYL Black N-LF, LEVANYL Blue G-LF, LEVANYL Green G-LF,
LEVANYL Red BB-LF, LEVANYL Violet BN-LF or LEVANYL Yellow GN-LF.Aqueous color paste it is main into
It is divided into the composition such as macromolecule dispersing agent, water, toner, defoamer, forms through sand mill grinding after premix.Macromolecule dispersing agent can
Shorten jitter time of the toner in dispersion, improve the glossiness of ink, tinting strength, tinting power and covering power, improve its color developing and
Toning property, prevents floating, flocculation and settles.
Another object of the present invention is to provide a kind of preparation method for exempting from the double PE water-based flexographic inks of glazing.
A kind of preparation method for exempting from the double PE water-based flexographic inks of glazing, the preparation method are comprised the following steps：
(1) preparation of varnish：Soft emulsion, hard emulsion, water-soluble resin liquid, scratch resistance agent, crosslinking are weighed in proportion
Agent, water repellent agent, levelling agent, coalescents, defoamer and deionized water, mix homogeneously, standby in a kettle.；
(2) by the varnish mix homogeneously in aqueous color paste and step (1), fineness≤5 μm are then ground to, are obtained final product.
As a result of above-mentioned technical proposal, the invention has the beneficial effects as follows：
1st, one kind that the present invention is provided exempts from the double PE water-based flexographic inks of glazing, and using water-based raw material, Diamond Search is discharged,
To free of air pollution, leaflet no solvent residue, without other to human body poisonous and harmful substance, meet European printed apcksging material
94/62/EEC standards and European Union ROHS instruction standards.
2nd, there is high glaze, bright-coloured U.S. using the leaflet for exempting from the double PE water-based flexographic inks printings of glazing that the present invention is provided
The performance such as sight, waterproof, wear-resisting, high temperature resistant, freeze-resistant.
3rd, one kind that the present invention is provided exempts from after the double PE water-based flexographic inks of glazing need not print oil polish again, simplifies system
Standby technique, reduces printing house ink cost more than 1/3rd, while also energy-saving.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to only to explain the present invention
Limit the present invention.
Embodiment one
One kind exempts from double PE water-based flexographic inks (redness) of glazing
Comprise the following raw materials by weight percent：Varnish 40% and aqueous color paste 60%；Wherein, varnish is by following
The raw material composition of percentage by weight：JONCRYL 624 60%, JONCRYL 89 10%, JONCRYL HPD96 25%, DC51
1%, Zinc Oxide Solution#1 1%, DC85 1%, OT-75 0.1%, Propylene Glycol 1%, DC65 0.1%, go from
Sub- water 0.8%；Aqueous color paste is comprised the following raw materials by weight percent：Red HF3S30% and Red FGR 70%.
Its preparation method is：
(1) preparation of varnish：According to aforementioned proportion weigh JONCRYL 624, JONCRYL 89, JONCRYL HPD96,
DC51, Zinc Oxide Solution#1, DC85, OT-75, Propylene Glycol, DC65 and deionized water, stir evenly in adding reactor,
It is standby；
(2) preparation of aqueouss redness mill base：Red HF3S and Red FGR7 mixings are weighed according to aforementioned proportion, it is standby；
(3) the aqueouss redness mill base in the varnish in step (1) and step (2) is mixed in dispersion cup, obtains pre-
Mixed thing, is then ground to pre-composition Horizontal sand ink machine below 5 microns of fineness, obtains final product redness and exempts from the double PE aqueous flexible plates oil of glazing
Ink.
Embodiment two
One kind exempts from double PE water-based flexographic inks (yellow) of glazing
Comprise the following raw materials by weight percent：Varnish 45% and aqueous color paste 55%；Wherein, varnish is by following
The raw material composition of percentage by weight：JONCRYL 617 65%, JONCRYL 90 8%, JONCRYL HPD96MEA 20%,
DC51 1.5%, Zinc Oxide Solution#1 1.5%, Surfynol 104E 0.3%, diethylene glycol ether 2%,
TEGO Foamex 825 0.2%, deionized water 1.5%；Aqueous color paste is comprised the following raw materials by weight percent：Yellow
GR 40% and Yellow HR 60%.
Its preparation method is：
(1) preparation of varnish：JONCRYL 617, JONCRYL 90, JONCRYL are weighed according to aforementioned proportion
HPD96MEA, DC51, Zinc Oxide Solution#1, Surfynol 104E, diethylene glycol ether, TEGO Foamex
825 and deionized water, stir evenly in adding reactor, it is standby；
(2) preparation of aqueouss yellow mill base：Yellow GR and Yellow HR mixings are weighed according to aforementioned proportion, it is standby；
(3) the aqueouss yellow mill base in the varnish in step (1) and step (2) is mixed in dispersion cup, obtains pre-
Mixed thing, is then ground to pre-composition Horizontal sand ink machine below 5 microns of fineness, obtains final product yellow and exempts from the double PE aqueous flexible plates oil of glazing
Ink.
Embodiment three
One kind exempts from double PE water-based flexographic inks (blueness) of glazing
Comprise the following raw materials by weight percent：Varnish 50% and aqueous color paste 50%；Wherein, varnish is by following
The raw material composition of percentage by weight：JONCRYL 74 70%, JONCRYL 89 3%, JONCRYL 61 15%, DC51 2%,
Zinc Oxide Solution#1 2%, DC85 2%, BYK-301 0.3%, glycerol 3%, DC65 0.3%, deionization
Water 3.4%；Aqueous color paste is comprised the following raw materials by weight percent：Blue B2G 50% and LEVANYL Blue G-LF
50%.
Its preparation method is：
(1) preparation of varnish：According to aforementioned proportion weigh JONCRYL 74, JONCRYL 89, JONCRYL61, DC51,
Zinc Oxide Solution#1, DC85, BYK-301, glycerol, DC65 and deionized water, stir evenly in adding reactor, standby
With；
(2) preparation of aqueouss blueness mill base：Blue B2G and LEVANYL Blue G-LF are weighed according to aforementioned proportion to mix
It is even, it is standby；
(3) the aqueouss blueness mill base in the varnish in step (1) and step (2) is mixed in dispersion cup, obtains pre-
Mixed thing, is then ground to pre-composition Horizontal sand ink machine below 5 microns of fineness, obtains final product redness and exempts from the double PE aqueous flexible plates oil of glazing
Ink.
Example IV
One kind exempts from double PE water-based flexographic inks (black) of glazing
Comprise the following raw materials by weight percent：Varnish 55% and aqueous color paste 45%；Wherein, varnish is by following
The raw material composition of percentage by weight：JONCRYL 617 75%, JONCRYL 90 5%, JONCRYL HPD96MEA 5%,
DC51 2.5%, Zinc Oxide Solution#1 2.5%, DC85 2.5%, OT-75 0.5%, dipropylene glycol methyl ether
4%, TEGO Foamex 825 0.4%, deionized water 2.6%；Aqueous color paste is comprised the following raw materials by weight percent：
Black T 30 20% and LEVANYL Black N-LF 80%
Its preparation method is：
(1) preparation of varnish：JONCRYL 617, JONCRYL 90, JONCRYL are weighed according to aforementioned proportion
HPD96MEA, DC51, Zinc Oxide Solution#1, DC85, OT-75, dipropylene glycol methyl ether, 825 and of TEGO Foamex
Deionized water, stirs evenly in adding reactor, standby；
(2) preparation of aqueous black mill base：Black T 30 and LEVANYL Black N-LF are weighed according to aforementioned proportion,
Mix, it is standby；
(3) the aqueous black mill base in the varnish in step (1) and step (2) is mixed in dispersion cup, obtains pre-
Mixed thing, is then ground to pre-composition Horizontal sand ink machine below 5 microns of fineness, obtains final product yellow and exempts from the double PE aqueous flexible plates oil of glazing
Ink.
Embodiment five
One kind exempts from double PE water-based flexographic inks (purple) of glazing
Comprise the following raw materials by weight percent：Varnish 60% and aqueous color paste 40%；Wherein, varnish is by following
The raw material composition of percentage by weight：JONCRYL 74 80%, DC51 3%, Zinc Oxide Solution#1 3%, DC85
3%, BYK-301 1%, glycerol 8%, DC65 0.5%, deionized water 1.5%；Aqueous color paste is by following percentage by weight
Raw material is constituted：Violet RL 80% and LEVANYL Violet BN-LF 20%.
Its preparation method is：
(1) preparation of varnish：JONCRYL 74, DC51, Zinc Oxide Solution# are weighed according to aforementioned proportion
1st, DC85, BYK-301, glycerol, DC65 and deionized water, stir evenly in adding reactor, standby；
(2) preparation of aqueouss purple mill base：Violet RL and LEVANYL Violet BN-LF are weighed according to aforementioned proportion
Mix, it is standby；
(3) the aqueouss purple mill base in the varnish in step (1) and step (2) is mixed in dispersion cup, obtains pre-
Mixed thing, is then ground to pre-composition Horizontal sand ink machine below 5 microns of fineness, obtains final product purple and exempts from the double PE aqueous flexible plates oil of glazing
Ink.
Embodiment six
One kind exempts from double PE water-based flexographic inks (green) of glazing
Comprise the following raw materials by weight percent：Neutral varnish 60% and neutral mill base 40%；Wherein, neutral inking
Oil is comprised the following raw materials by weight percent：JONCRYL 74 70%, JONCRYL 90 10%, JONCRYL 61 10%,
DC85 2%, DC51 2%, Zinc Oxide Solution#1 2%, BYK-301 1%, Propylene Glycol 3%；Aqueous color paste by
The raw material composition of following percentage by weight：Green GN 60% and LEVANYL Green G-LF 40%.
Its preparation method is：
(1) preparation of varnish：According to aforementioned proportion weigh JONCRYL 74, JONCRYL 90, JONCRYL61, DC85,
DC51, Zinc Oxide Solution#1, BYK-301 and Propylene Glycol, stir evenly in adding reactor, standby；
(2) preparation of water soluble green mill base：Green GN and LEVANYL Green G-LF are weighed according to aforementioned proportion, is mixed
It is even, it is standby；
(3) the water soluble green mill base in the varnish in step (1) and step (2) is mixed in dispersion cup, obtains pre-
Mixed thing, is then ground to pre-composition Horizontal sand ink machine below 5 microns of fineness, obtains final product green and exempts from the double PE aqueous flexible plates oil of glazing
Ink.
By the every test rating such as following table institute for exempting from the double PE water-based flexographic inks of glazing obtained by above-described embodiment 1-6
Show：
Fineness is tested：0-50 μm of Hegman grind gage.
The condition of water-fast test is：25 ± 2 DEG C, water soaks 30 minutes.
Rub resistance test condition be：Friction-resistant tester, friction velocity：106 beats/min, rub loading：2LB, during friction
Between：1 minute.
The condition of low temperature resistant test is：Mixture of ice and water soaks 30 minutes.
High temperature resistant test condition be:200 DEG C of heat-sealings.
As can be seen from the table, one kind that the present invention is provided exempts from the double PE water-based flexographic inks of glazing, and its fineness is thinner, waterproof,
It is wear-resisting, high-low temperature resistant.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (4)
1. one kind exempts from the double PE water-based flexographic inks of glazing, it is characterised in that the water-based flexographic ink is by following percentage by weight
Raw material composition：Varnish 40～60% and aqueous color paste 40～60%；Wherein, the varnish is by following percentage by weight
Raw material is constituted：Soft emulsion 60～80%, hard emulsion 0～10%, water-soluble resin liquid 0～25%, scratch resistance agent 1～3% are handed over
Connection agent 1～3%, water repellent agent 0～3%, levelling agent 0～1%, coalescents 0～8%, defoamer 0.1～0.5%, remaining is to go
Ionized water；The scratch resistance agent is supra polymer polydimethylsiloxane；The cross-linking agent is Zinc Oxide ammonia solution；The water repellent agent
For polysiloxane solution；The main component of the aqueous color paste is macromolecule dispersing agent, water, toner, defoamer；The water solublity
Amination aqueous solution of the resin liquid for solid styrene-acrylic resin；The soft emulsion is minimum film formation temperature<10 DEG C of acrylic emulsion
Or self-crosslinking aqueous acrylic resin liquid；The hard emulsion is minimum film formation temperature>80 DEG C of acrylic emulsion or self-crosslinking
Water-borne acrylic resin liquid.
2. one kind as claimed in claim 1 exempts from the double PE water-based flexographic inks of glazing, it is characterised in that the levelling agent is octyl group
Phenol, nonyl phenol ethoxy compound class, acetylenic diols or polyether silicone class；The defoamer is polysiloxane-based.
3. one kind as claimed in claim 1 exempts from the double PE water-based flexographic inks of glazing, it is characterised in that the coalescents are third
One or more in glycol, glycerol, diethylene glycol ether or dipropylene glycol methyl ether.
4. a kind of preparation method for exempting from the double PE water-based flexographic inks of glazing as claimed in claim 1, it is characterised in that the system
Preparation Method is comprised the following steps：
(1) preparation of varnish：Soft emulsion, hard emulsion, water-soluble resin liquid, scratch resistance agent, cross-linking agent, anti-is weighed in proportion
Water preparation, levelling agent, coalescents, defoamer and deionized water, mix homogeneously, standby in a kettle.；
(2) by the varnish mix homogeneously in aqueous color paste and step (1), fineness≤5 μm are then ground to, are obtained final product.
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Families Citing this family (12)
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| CN105086617B (en) * | 2015-08-04 | 2017-09-26 | 山东布瑞特油墨有限公司 | A kind of aqueous inner-printing ink of showering PE, PP and preparation method thereof |
| CN105199481A (en) * | 2015-10-21 | 2015-12-30 | 广州市三国水性油墨有限公司 | Double-PE water-based ink and preparation method thereof |
| CN105331191A (en) * | 2015-10-29 | 2016-02-17 | 苏州市博来特油墨有限公司 | Water-based flexible printing ink for paper box printing |
| CN105348914A (en) * | 2015-10-29 | 2016-02-24 | 苏州市博来特油墨有限公司 | Preparation method of water-based flexible printing ink for carton printing |
| CN106883676A (en) * | 2017-04-18 | 2017-06-23 | 青岛农业大学 | A kind of water-based flexographic ink and preparation method thereof |
| CN107674503B (en) * | 2017-09-15 | 2020-09-18 | 广东英科集团股份有限公司 | Irreversible room temperature color-changing ink and preparation method and application thereof |
| CN107523122A (en) * | 2017-09-20 | 2017-12-29 | 嘉兴莱斯登水墨有限公司 | Water-based double PE ink |
| CN107815176B (en) * | 2017-11-01 | 2021-01-19 | 福建省文松彩印有限公司 | Waterproof ink for printing corrugated case and preparation method thereof |
| CN110041750B (en) * | 2019-03-27 | 2022-06-03 | 山东华诺日化有限公司 | Full-aqueous ink and preparation method thereof |
| CN111040512A (en) * | 2019-12-26 | 2020-04-21 | 广东天龙油墨有限公司 | Water-based flexographic printing ink for thin film printing and preparation method thereof |
| CN112175446A (en) * | 2020-11-16 | 2021-01-05 | 黄展才 | Preparation method of water-based flexographic printing ink |
| CN115806753A (en) * | 2022-09-26 | 2023-03-17 | 上海合印科技股份有限公司 | Packaging box printing ink with protrusions and preparation method thereof |
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| CN102617771A (en) * | 2012-03-26 | 2012-08-01 | 田立壮 | Aqueous printing ink binding agent and ink as well as preparation methods thereof |
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| US7193002B2 (en) * | 1992-08-24 | 2007-03-20 | Applied Elastomerics, Inc. | Adherent gels, composites, and articles |
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| CN101328329A (en) * | 2007-06-22 | 2008-12-24 | 东莞市佳景印刷材料有限公司 | Aqueous flexible plate printing ink and preparation thereof |
| CN102617771A (en) * | 2012-03-26 | 2012-08-01 | 田立壮 | Aqueous printing ink binding agent and ink as well as preparation methods thereof |
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