CN104672979A - Coating on electroplating apparatus as well as preparation method and application thereof - Google Patents
Coating on electroplating apparatus as well as preparation method and application thereof Download PDFInfo
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- CN104672979A CN104672979A CN201510071818.7A CN201510071818A CN104672979A CN 104672979 A CN104672979 A CN 104672979A CN 201510071818 A CN201510071818 A CN 201510071818A CN 104672979 A CN104672979 A CN 104672979A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a coating on electroplating apparatus, as well as a preparation method and application thereof, relates to the field of electroplating and base material surface coating and particularly relates to the field of ABS electroplating. The coating is composed of a base coat and a finishing coat, wherein the base coat is composed of a filler, a curing agent and a diluent, and the finishing coat is composed of a filler, a curing agent and a diluent; the coating can be used on the surface of the ABS plastic electroplated part with strong adhesive force and good sunscreen performance; the coating has corrosion resistance and wear resistance and further does not damage the clad layer on the surface of the electroplating apparatus; the coating is low in preparation cost and simple in process.
Description
Technical field
The invention discloses coating on a kind of electroplating device and preparation method thereof, purposes, relate to plating and substrate surface covering with paint field thereof, particularly relate to ABS field of electroplating.
Background technology
Along with the application of the developing rapidly of industry, plastic electroplating is increasingly extensive, become one of important means of surface decoration in plastic prod.Compared with metallic article, plastic electroplating goods not only can realize good metal-like, and can alleviate product weight, effectively improve plastics outward appearance and ornamental while, also improve its electricity, heat and anti-corrosion etc. in performance.At present both at home and abroad extensively electroplate on the frostings such as ABS, polypropylene, polysulfones, polycarbonate, nylon, phenolic glass fiber reinforced plastics, polystyrene, wherein especially most widely used with ABS plastic plating, electroplating effect is best.
Now in order to improve the diversity of ABS plastic plated item, on ABS plastic plated item, often carry out spraying one deck dazzle color coating material, the color of coating can carry out various change, but, at present, ABS plastic plated item carries out sprayed coating, often the sticking power of coating is low, corrosion-resistant, not wear-resisting, and coating often has partial injury to the electrolytic coating on ABS plastic plated item, reduces the work-ing life of ABS plastic plated item.
Summary of the invention
The invention discloses coating on a kind of electroplating device and preparation method thereof, purposes, this coating can be used on electroplating device, its strong adhesion, sun-proof performance is good, and this coating has erosion resistance, wear resistance, simultaneously to the coating not damaged on electroplating device surface, and the preparation of this coating is cheap, technique is simple.
The invention discloses the coating on a kind of electroplating device, this coating is made up of priming paint, finish paint two part, and described priming paint is made up of filler, solidifying agent, thinner, according to weight ratio, wherein filler is: pigment is 15 parts, and dispersion agent is 2 parts, PMA is 8 parts, and N-BUTYL ACETATE is 15 parts, and Hydroxylated acrylic resin is 60 parts, wherein solidifying agent is: Bayer N75 is 60 parts, PMA is 40 parts, and wherein thinner is: dimethylbenzene is 30 parts, and PMA is 10 parts, N-BUTYL ACETATE is 30 parts, and MEK is 30 parts; Described finish paint is made up of filler, solidifying agent, thinner, and according to weight ratio, wherein filler is: Hydroxylated acrylic resin is 35 parts, carbamide resin is 35 parts, and fine glass powder is 10 parts, and part powder is 2 parts, N-BUTYL ACETATE is 10 parts, MEK is 8 parts, and wherein solidifying agent is: Bayer N75 is 60 parts, and PMA is 40 parts, wherein thinner is: dimethylbenzene is 30 parts, PMA is 10 parts, and N-BUTYL ACETATE is 30 parts, and MEK is 30 parts.
The invention discloses the coating on a kind of electroplating device, described priming paint, the hydroxyl value of the Hydroxylated acrylic resin in filler is 30.
The invention discloses the coating on a kind of electroplating device, described priming paint, the ratio of filler, solidifying agent, thinner is 10: 1: 10.
The invention discloses the coating on a kind of electroplating device, described priming paint, part powder in filler is the high one's share of expenses for a joint undertaking amount segmented copolymer containing pigment affinity groups.
The invention discloses the coating on a kind of electroplating device, described finish paint, the hydroxyl value of the Hydroxylated acrylic resin in filler is 100.
The invention discloses the coating on a kind of electroplating device, described finish paint, the particle diameter of the fine glass powder in filler is 2-10um.
The invention discloses the coating on a kind of electroplating device, described finish paint, part powder in filler is the high one's share of expenses for a joint undertaking amount segmented copolymer containing pigment affinity groups.
The invention discloses the preparation method of the coating on a kind of electroplating device, wherein the preparation method of priming paint is:
(1) filler is: a, pigment 15 part, part powder 2 parts, PMA8 part drop in a mixing bowl successively, and 2000rpm fills part and is stirred to even pulpous state, puts into NORWA horizontal micron order sand mill NHE series sand machine and is ground to 100-300nm, be prepared into slurry A; B, 60 parts of Hydroxylated acrylic resins, 25 parts of slurry A, 15 parts of N-BUTYL ACETATEs put into production in cylinder successively, are stirred to complete uniform state, obtain mixture B;
(2) solidifying agent is: get 60 parts of Bayer N75, and PMA 40 parts mixes, and obtains mixture C;
(3) thinner is: by dimethylbenzene (30 parts), PMA (10 parts), MEK (30 parts), N-BUTYL ACETATE (30 parts) in mass ratio ratio mix, obtain mixture D;
(4) by B, C, D according to 10: 1: 10 ratio mix, continue application, at 60 DEG C, dry 30min, obtain the prime coat of this coating;
Wherein the preparation method of finish paint is:
(5) filler is: successively by 35 parts of Hydroxylated acrylic resins, 30 parts of carbamide resins, 10 parts of fine glass powder, 2 parts of dispersion agents, 10 parts of N-BUTYL ACETATEs, and 8 parts of MEK join production cylinder, are stirred to uniform state, obtain mixture E;
(6) solidifying agent is: by material 60 parts of Bayer N75, and after stirring after 40 parts of PMA mixing, obtains mixture F;
(7) thinner is: by dimethylbenzene 30 parts, PMA10 part, MEK30 part, N-BUTYL ACETATE 30% part, mix, obtain mixture G, release for subsequent use;
(8) by E, F, G according to 10: 1: 10 ratio mix, carry out the surface being coated on priming paint, and dry 180min at 80 DEG C, obtain the top coat layer of this coating.
The invention discloses the purposes of coating on a kind of electroplating device, its coating may be used for the surface of ABS plastic plated item.
Embodiment
The invention discloses the coating on a kind of electroplating device, preparation method, this coating by priming paint, finish paint two part form, the preparation process of this coating is:
Wherein the preparation method of priming paint is:
(1) filler is: a, pigment 15 part, part powder 2 parts, PMA8 part drop in a mixing bowl successively, and 2000rpm fills part and is stirred to even pulpous state, puts into NORWA horizontal micron order sand mill NHE series sand machine and is ground to 100-300nm, be prepared into slurry A; B, 60 parts of Hydroxylated acrylic resins, 25 parts of slurry A, 15 parts of N-BUTYL ACETATEs put into production in cylinder successively, are stirred to complete uniform state, obtain mixture B;
(2) solidifying agent is: get 60 parts of Bayer N75, and PMA 40 parts mixes, and obtains mixture C;
(3) thinner is: by dimethylbenzene (30 parts), PMA (10 parts), MEK (30 parts), N-BUTYL ACETATE (30 parts) in mass ratio ratio mix, obtain mixture D;
(4) by B, C, D according to 10: 1: 10 ratio mix, continue application, at 60 DEG C, dry 30min, obtain the prime coat of this coating;
Wherein the preparation method of finish paint is:
(5) filler is: successively by 35 parts of Hydroxylated acrylic resins, 30 parts of carbamide resins, 10 parts of fine glass powder, 2 parts of dispersion agents, 10 parts of N-BUTYL ACETATEs, and 8 parts of MEK join production cylinder, are stirred to uniform state, obtain mixture E;
(6) solidifying agent is: by material 60 parts of Bayer N75, and after stirring after 40 parts of PMA mixing, obtains mixture F;
(7) thinner is: by dimethylbenzene 30 parts, PMA10 part, MEK30 part, N-BUTYL ACETATE 30% part, mix, obtain mixture G;
(8) by E, F, G according to 10: 1: 10 ratio mix, carry out the surface being coated on priming paint, and dry 180min at 80 DEG C, obtain the top coat layer of this coating.
This coating may be used for the surface of ABS plastic plated item, its strong adhesion, and sun-proof performance is good, and this coating has erosion resistance, wear resistance, and simultaneously to the coating not damaged on electroplating device surface, and the preparation of this coating is cheap, technique is simple.
Claims (9)
1. the coating on electroplating device, this coating is made up of priming paint, finish paint two part, and described priming paint is made up of filler, solidifying agent, thinner, according to weight ratio, wherein filler is: pigment is 15 parts, and dispersion agent is 2 parts, PMA is 8 parts, and N-BUTYL ACETATE is 15 parts, and Hydroxylated acrylic resin is 60 parts, wherein solidifying agent is: Bayer N75 is 60 parts, PMA is 40 parts, and wherein thinner is: dimethylbenzene is 30 parts, and PMA is 10 parts, N-BUTYL ACETATE is 30 parts, and MEK is 30 parts; Described finish paint is made up of filler, solidifying agent, thinner, and according to weight ratio, wherein filler is: Hydroxylated acrylic resin is 35 parts, carbamide resin is 35 parts, and fine glass powder is 10 parts, and part powder is 2 parts, N-BUTYL ACETATE is 10 parts, MEK is 8 parts, and wherein solidifying agent is: Bayer N75 is 60 parts, and PMA is 40 parts, wherein thinner is: dimethylbenzene is 30 parts, PMA is 10 parts, and N-BUTYL ACETATE is 30 parts, and MEK is 30 parts.
2. the coating on a kind of electroplating device according to claim 1, is characterized in that: described priming paint, and the hydroxyl value of the Hydroxylated acrylic resin in filler is 30.
3. the coating on a kind of electroplating device according to claim 1, is characterized in that: described priming paint, and the ratio of filler, solidifying agent, thinner is 10: 1: 10.
4. the coating on a kind of electroplating device according to claim 1, is characterized in that: described priming paint, and part powder in filler is the high one's share of expenses for a joint undertaking amount segmented copolymer containing pigment affinity groups.
5. the coating on a kind of electroplating device according to claim 1, is characterized in that: described finish paint, and the hydroxyl value of the Hydroxylated acrylic resin in filler is 100.
6. the coating on a kind of electroplating device according to claim 1, is characterized in that: described finish paint, and the particle diameter of the fine glass powder in filler is 2-10um.
7. the coating on a kind of electroplating device according to claim 1, is characterized in that: described finish paint, and part powder in filler is the high one's share of expenses for a joint undertaking amount segmented copolymer containing pigment affinity groups.
8., as a preparation method for the coating on any one electroplating device in claim 1,2,3,4,5,6,7, wherein the preparation method of priming paint is:
(1) filler is: a, pigment 15 part, part powder 2 parts, PMA8 part drop in a mixing bowl successively, and 2000rpm fills part and is stirred to even pulpous state, puts into NORWA horizontal micron order sand mill NHE series sand machine and is ground to 100-300nm, be prepared into slurry A; B, 60 parts of Hydroxylated acrylic resins, 25 parts of slurry A, 15 parts of N-BUTYL ACETATEs put into production in cylinder successively, are stirred to complete uniform state, obtain mixture B;
(2) solidifying agent is: get 60 parts of Bayer N75, and PMA 40 parts mixes, and obtains mixture C;
(3) thinner is: by dimethylbenzene (30 parts), PMA (10 parts), MEK (30 parts), N-BUTYL ACETATE (30 parts) in mass ratio ratio mix, obtain mixture D;
(4) by B, C, D according to 10: 1: 10 ratio mix, continue application, at 60 DEG C, dry 30min, obtain the prime coat of this coating;
Wherein the preparation method of finish paint is:
(5) filler is: successively by 35 parts of Hydroxylated acrylic resins, 30 parts of carbamide resins, 10 parts of fine glass powder, 2 parts of dispersion agents, 10 parts of N-BUTYL ACETATEs, and 8 parts of MEK join production cylinder, are stirred to uniform state, obtain mixture E;
(6) solidifying agent is: by material 60 parts of Bayer N75, and after stirring after 40 parts of PMA mixing, obtains mixture F;
(7) thinner is: by dimethylbenzene 30 parts, PMA10 part, MEK30 part, N-BUTYL ACETATE 30% part, mix, obtain mixture G, release for subsequent use;
(8) by E, F, G according to 10: 1: 10 ratio mix, carry out the surface being coated on priming paint, and dry 180min at 80 DEG C, obtain the top coat layer of this coating.
9. as a purposes for the coating on any one electroplating device in claim 1,2,3,4,5,6,7, it is characterized in that: for the surface of ABS plastic plated item.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510071818.7A CN104672979B (en) | 2015-02-06 | 2015-02-06 | Coating on a kind of electroplating device and preparation method thereof, purposes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510071818.7A CN104672979B (en) | 2015-02-06 | 2015-02-06 | Coating on a kind of electroplating device and preparation method thereof, purposes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104672979A true CN104672979A (en) | 2015-06-03 |
| CN104672979B CN104672979B (en) | 2017-03-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510071818.7A Expired - Fee Related CN104672979B (en) | 2015-02-06 | 2015-02-06 | Coating on a kind of electroplating device and preparation method thereof, purposes |
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| CN (1) | CN104672979B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255235A (en) * | 2015-11-27 | 2016-01-20 | 常熟市地大探矿机械厂 | Drilling tool for reaming |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004091581A (en) * | 2002-08-30 | 2004-03-25 | Toyo Ink Mfg Co Ltd | Water-based coating composition |
| CN101096541A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | Dual-component priming paint |
| CN102391763A (en) * | 2011-07-26 | 2012-03-28 | 东来涂料技术（上海）有限公司 | Solvent-borne two-component electroplating primer for chromium-plated plastic and preparation method of solvent-borne two-component electroplating primer |
| CN104098994A (en) * | 2013-04-02 | 2014-10-15 | 江苏国松特种涂料有限公司 | Anticorrosion paint primer-finish composition |
-
2015
- 2015-02-06 CN CN201510071818.7A patent/CN104672979B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004091581A (en) * | 2002-08-30 | 2004-03-25 | Toyo Ink Mfg Co Ltd | Water-based coating composition |
| CN101096541A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | Dual-component priming paint |
| CN102391763A (en) * | 2011-07-26 | 2012-03-28 | 东来涂料技术（上海）有限公司 | Solvent-borne two-component electroplating primer for chromium-plated plastic and preparation method of solvent-borne two-component electroplating primer |
| CN104098994A (en) * | 2013-04-02 | 2014-10-15 | 江苏国松特种涂料有限公司 | Anticorrosion paint primer-finish composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255235A (en) * | 2015-11-27 | 2016-01-20 | 常熟市地大探矿机械厂 | Drilling tool for reaming |
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| Publication number | Publication date |
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| CN104672979B (en) | 2017-03-08 |
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Granted publication date: 20170308 Termination date: 20190206 |