CN104667474A - Environment-friendly efficient anti-explosion anti-flaming multifunctional water-based fire extinguishing agent - Google Patents
Environment-friendly efficient anti-explosion anti-flaming multifunctional water-based fire extinguishing agent Download PDFInfo
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- CN104667474A CN104667474A CN201510147771.8A CN201510147771A CN104667474A CN 104667474 A CN104667474 A CN 104667474A CN 201510147771 A CN201510147771 A CN 201510147771A CN 104667474 A CN104667474 A CN 104667474A
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
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Abstract
The invention discloses an environment-friendly efficient anti-explosion anti-flaming multifunctional water-based fire extinguishing agent, relates to a fire extinguishing composition, and in particular relates to a fire extinguishing composition generating a gas phase. The invention aims at providing a multifunctional water-based fire extinguishing agent which keeps the physicochemical indexes unchanged when being stored under high temperature of 65 DEG C and low temperature of -50 DEG C, is capable of effectively extinguishing various liquid and solid fires and has the advantages of being environmentally friendly, and having efficient, anti-explosion, anti-flaming and cold-resistant effects. The water-based fire extinguishing agent comprises diethylene glycol ethyl ether, alkylphenol polyoxyethylene ether, sulfenyl benzothiazole, ammonium phosphate, a fluorocarbon surfactant, calcium carbonate, magnesium stearate, antimonous oxide, carboxymethylcellulose and purified water. The water-based fire extinguishing agent is simple and convenient to prepare, good in fire extinguishing effect and long in retention time, and is applied to the field of fire extinguishing.
Description
Technical field
The present invention relates to a kind of fire-extinguishing composite, particularly relate to a kind of fire-extinguishing composite producing gas phase.
Background technology
The existing water-based extinguishing agent of China's fire-fighting domain all cannot meet effectively put out category-A (solid) fire, category-B (gasoline) liquid fire and alcohol solvent fire under the cold-resistant low temperature climatic condition in 65 degree of high temperature-50 degree, the charged fire of E class, high-quality fire extinguishing can use needs in f class edible oil, and effective shelf-life durations of extinguishing chemical is limited with the fire extinguishing scope of application.
Summary of the invention
The present invention is to solve above technical problem, and the one provided every physical and chemical index of long term storage under 65 DEG C of high temperature and-50 DEG C of cold-resistant low temperature climatic conditions is constant, effectively can put out the needs of each liquid and solid fire, there is environmental protection, efficient, explosion-proof, fire-retardant, cold-resistant multi-functional water-based extinguishing agent.
The multi-functional water-based extinguishing agent of a kind of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, comprises following component by mass fraction:
Diethylene glycol ether: 1.8-2.3 part,
Alkyl phenol Polyoxyalkylene ethers: 1.2-1.8 part:
Sulfurio benzo thiazole: 0.3-0.8 part,
Phosphate amine salt: 3.6-5.2 part,
Fluorocarbon surfactant: 2.2-3.6 part,
Calcium carbonate: 0.6-1.2 part,
Dolomol: 0.03-0.06 part,
Antimony oxide: 3.2-3.8 part;
Carboxymethyl cellulose: 1.8-3.2 part,
Pure water complements to 100 parts.
Further, the multi-functional water-based extinguishing agent of a kind of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, comprises following component by mass fraction:
Diethylene glycol ether: 1.9-2.2 part,
Alkyl phenol Polyoxyalkylene ethers 1.3-1.7 part,
Sulfurio benzo thiazole: 0.4-0.7 part,
Phosphate amine salt: 3.9-4.9 part,
Fluorocarbon surfactant: 2.4-3.3 part,
Calcium carbonate: 0.8-1.1 part,
Dolomol: 0.04-0.05 part,
Antimony oxide: 3.3-3.7 part;
Carboxymethyl cellulose: 2.0-3.0 part,
Pure water complements to 100 parts.
Further, the multi-functional water-based extinguishing agent of a kind of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, comprises following component by mass fraction:
Diethylene glycol ether: 2.0-2.1 part,
Alkyl phenol Polyoxyalkylene ethers: 1.4-1.6 part,
Sulfurio benzo thiazole: 0.5-0.6 part,
Phosphate amine salt: 4.2-4.6 part,
Fluorocarbon surfactant: 2.7-3.0 part,
Calcium carbonate: 0.9-1.0 part,
Dolomol: 0.04-0.05 part,
Antimony oxide: 3.4-3.6 part;
Carboxymethyl cellulose: 2.4-2.7 part,
Pure water complements to 100 parts.
The multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, its extinguishing mechanism is as follows:
L, extinguishing chemical are sprayed onto solid burning article flame, transient absorption heat, are steam at once, and thermal decomposition is interrupted, and flame stops immediately.
2, extinguishing chemical is injected into the surface of liquid comburant, and liquid is rapid expanding not only, and forms foam and film forming emulsion layer, makes flame and air insulated interrupt putting out a fire.
The multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention compared with prior art has following beneficial effect:
L, its Main Ingredients and Appearance of water-based extinguishing agent of the present invention are pollution-free degradable compound, thus can not cause environmental pollution.
2, water-based extinguishing agent of the present invention, not only not by the restriction that high/low temperature climatic environment uses, has function that is explosion-proof, fire-retardant, cooling simultaneously.
3, water-based extinguishing agent of the present invention is 5 times of national standard extinguishing grade, is 10 times of ABC dry powder extinguisher extinguishing grade.
4, water-based extinguishing agent of the present invention stores 10 years afterwards by GB17835-2008 standard, and each physical and chemical index of regulation test is constant, and having broken through China's water-based extinguishing agent can not the constant difficult problem of long term storage service property (quality).
Detailed description of the invention
By following examples, the multi-functional water-based extinguishing agent of a kind of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention is further described.
Embodiment
The multi-functional water-based extinguishing agent of a kind of environment-friendly high-efficiency explosion-proof flame-retardant of the present embodiment, mixes raw material each in table 1, namely obtains product of the present invention.
Adopt above method, prepare the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant according to the component proportion of table 1.
The proportioning of each component in table 1 embodiment 1-6
Embodiment | 1 | 2 | 3 | 4 | 5 | 6 |
Diethylene glycol ether (kg) | 1.8 | 2.2 | 2.3 | 1.9 | 2.0 | 2.1 |
Alkyl phenol Polyoxyalkylene ethers (kg) | 1.3 | 1.7 | 1.8 | 1.4 | 1.2 | 1.6 |
Sulfurio benzo thiazole (kg) | 0.5 | 0.8 | 0.3 | 0.6 | 0.7 | 0.4 |
Phosphate amine salt (kg) | 4.6 | 3.6 | 4.2 | 3.9 | 5.2 | 4.9 |
Fluorocarbon surfactant (kg) | 3.0 | 3.3 | 3.6 | 2.4 | 2.2 | 2.7 |
Calcium carbonate (kg) | 0.8 | 0.9 | 0.6 | 1.2 | 1.0 | 1.1 |
Dolomol (kg) | 0.05 | 0.03 | 0.06 | 0.04 | 0.05 | 0.03 |
Antimony oxide (kg) | 3.7 | 3.3 | 3.6 | 3.2 | 3.4 | 3.8 |
Carboxymethyl cellulose (kg) | 1.8 | 3.2 | 2.7 | 2.0 | 2.4 | 3.0 |
Pure water (kg) | 82.45 | 80.97 | 80.84 | 83.36 | 81.85 | 80.37 |
According to GB 17835-2008, the physical and chemical index that embodiment 1-6 obtains product is detected, the results are shown in Table 2.
Table 2 embodiment 1-6 obtains the physical and chemical index of product
As seen from the above table, water-based extinguishing agent of the present invention meets national standard, the restriction that can not use by domestic high/low temperature climatic environment, has function fire extinguishing that is explosion-proof, fire-retardant, cooling simultaneously.By GB17835-2008 standard the 5th row culture fire-extinguishing test, pool shape diameter 2.4m, food tray area 4.52 ㎡, fuel 93# gasoline, amount of fuel 100L, only needs 2L extinguishing chemical, is 5 times of national standard extinguishing grade, is 10 times of ABC dry powder extinguisher extinguishing grade.Water-based extinguishing agent of the present invention detects it after storing 10 years again, the results are shown in Table 2, known, and its physicochemical property does not change substantially.
Although the foregoing describe the specific embodiment of the present invention, it will be understood by those of skill in the art that these only illustrate, protection scope of the present invention is defined by the appended claims.Those skilled in the art, under the prerequisite not deviating from principle of the present invention and essence, can make various changes or modifications to these embodiments, but these change and amendment all falls into protection scope of the present invention.
Claims (3)
1. the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant, is characterized in that, comprises following component by mass fraction:
Diethylene glycol ether: 1.8-2.3 part,
Alkyl phenol Polyoxyalkylene ethers: 1.2-1.8 part:
Sulfurio benzo thiazole: 0.3-0.8 part,
Phosphate amine salt: 3.6-5.2 part,
Fluorocarbon surfactant: 2.2-3.6 part,
Calcium carbonate: 0.6-1.2 part,
Dolomol: 0.03-0.06 part,
Antimony oxide: 3.2-3.8 part;
Carboxymethyl cellulose: 1.8-3.2 part,
Pure water complements to 100 parts.
2. the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant according to claim 1, is characterized in that: comprise following component by mass fraction:
Diethylene glycol ether: 1.9-2.2 part,
Alkyl phenol Polyoxyalkylene ethers 1.3-1.7 part,
Sulfurio benzo thiazole: 0.4-0.7 part,
Phosphate amine salt: 3.9-4.9 part,
Fluorocarbon surfactant: 2.4-3.3 part,
Calcium carbonate: 0.8-1.1 part,
Dolomol: 0.04-0.05 part,
Antimony oxide: 3.3-3.7 part;
Carboxymethyl cellulose: 2.0-3.0 part,
Pure water complements to 100 parts.
3. the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant according to claim 2, is characterized in that: comprise following component by mass fraction:
Diethylene glycol ether: 2.0-2.1 part,
Alkyl phenol Polyoxyalkylene ethers: 1.4-1.6 part,
Sulfurio benzo thiazole: 0.5-0.6 part,
Phosphate amine salt: 4.2-4.6 part,
Fluorocarbon surfactant: 2.7-3.0 part,
Calcium carbonate: 0.9-1.0 part,
Dolomol: 0.04-0.05 part,
Antimony oxide: 3.4-3.6 part;
Carboxymethyl cellulose: 2.4-2.7 part,
Pure water complements to 100 parts.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105797301A (en) * | 2016-04-20 | 2016-07-27 | 四川瑞思可消防科技有限公司 | Pollution-free water-series extinguishant |
CN106377863A (en) * | 2016-10-14 | 2017-02-08 | 浙江环亚消防新材料股份有限公司 | Water-based extinguishing agent and preparing method |
CN106730565A (en) * | 2016-12-15 | 2017-05-31 | 浙江睦田消防科技开发有限公司 | Extinguishing chemical and preparation method thereof |
CN113214542A (en) * | 2021-05-18 | 2021-08-06 | 湖南娄底华星锑业有限公司 | Composite antimony trioxide flame retardant and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN106730565A (en) * | 2016-12-15 | 2017-05-31 | 浙江睦田消防科技开发有限公司 | Extinguishing chemical and preparation method thereof |
CN113214542A (en) * | 2021-05-18 | 2021-08-06 | 湖南娄底华星锑业有限公司 | Composite antimony trioxide flame retardant and preparation method thereof |
CN113214542B (en) * | 2021-05-18 | 2022-05-20 | 湖南娄底华星锑业有限公司 | Composite antimony trioxide flame retardant and preparation method thereof |
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