CN104667474B - A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant - Google Patents
A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant Download PDFInfo
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- CN104667474B CN104667474B CN201510147771.8A CN201510147771A CN104667474B CN 104667474 B CN104667474 B CN 104667474B CN 201510147771 A CN201510147771 A CN 201510147771A CN 104667474 B CN104667474 B CN 104667474B
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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- Emergency Management (AREA)
- Fireproofing Substances (AREA)
- Fire-Extinguishing Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, it is related to a kind of fire-extinguishing composite, more particularly to a kind of fire-extinguishing composite for producing gas phase.Its purpose is to provide one kind, under 65 DEG C of high temperature and 50 DEG C of cold-resistant low temperature climatic conditions to store every physical and chemical index for a long time constant, the needs of each liquid and solid fire can be effectively put out, there is environmentally friendly, efficient, explosion-proof, fire-retardant, cold-resistant multi-functional water-based extinguishing agent.The water-based extinguishing agent of the present invention includes diethylene glycol ether, alkyl phenol Polyoxyalkylene ethers, sulfurio benzo thiazole, phosphate amine salt, fluorocarbon surfactant, calcium carbonate, magnesium stearate, antimony oxide, carboxymethyl cellulose and pure water.The water-based extinguishing agent of the present invention prepares easy, good extinguishing effect, holding time length.The present invention is used for fire-fighting domain.
Description
Technical field
The present invention relates to a kind of fire-extinguishing composite, more particularly to a kind of fire-extinguishing composite for producing gas phase.
Background technology
Fire-fighting domain existing water-based extinguishing agent in China's can not meet the low temperature climate bar that resisted cold 65 degree of high temperature -50 degree
A classes (solid) fire, B classes (gasoline) liquid fire and alcohol solvent fire, the powered fire of E classes are effectively put out under part, f classes are eaten
The fire extinguishing of energy high quality is using needs in oil, and effective shelf-life durations of extinguishing chemical and use range of putting out a fire are limited.
The content of the invention
The present invention is in order to solve the above technical problems, and providing a kind of in 65 DEG C of high temperature and -50 DEG C of cold-resistant low temperature gas
Store that every physical and chemical index is constant under the conditions of marquis for a long time, can effectively put out the needs of each liquid and solid fire, there is environmental protection, high
Effect, explosion-proof, fire-retardant, cold-resistant multi-functional water-based extinguishing agent.
A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, includes following components by mass fraction：
Diethylene glycol ether：1.8-2.3 parts,
Alkyl phenol Polyoxyalkylene ethers：1.2-1.8 part：
Sulfurio benzo thiazole：0.3-0.8 parts,
Phosphate amine salt：3.6-5.2 parts,
Fluorocarbon surfactant：2.2-3.6 parts,
Calcium carbonate：0.6-1.2 parts,
Magnesium stearate：0.03-0.06 parts,
Antimony oxide：3.2-3.8 part；
Carboxymethyl cellulose：1.8-3.2 parts,
Pure water complements to 100 parts.
Further, a kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, include by mass fraction following
Component：
Diethylene glycol ether：1.9-2.2 parts,
Alkyl phenol Polyoxyalkylene ethers 1.3-1.7 parts,
Sulfurio benzo thiazole：0.4-0.7 parts,
Phosphate amine salt：3.9-4.9 parts,
Fluorocarbon surfactant：2.4-3.3 parts,
Calcium carbonate：0.8-1.1 parts,
Magnesium stearate：0.04-0.05 parts,
Antimony oxide：3.3-3.7 part；
Carboxymethyl cellulose：2.0-3.0 parts,
Pure water complements to 100 parts.
Further, a kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, by mass fraction include with
Lower component：
Diethylene glycol ether：2.0-2.1 parts,
Alkyl phenol Polyoxyalkylene ethers：1.4-1.6 parts,
Sulfurio benzo thiazole：0.5-0.6 parts,
Phosphate amine salt：4.2-4.6 parts,
Fluorocarbon surfactant：2.7-3.0 parts,
Calcium carbonate：0.9-1.0 parts,
Magnesium stearate：0.04-0.05 parts,
Antimony oxide：3.4-3.6 part；
Carboxymethyl cellulose：2.4-2.7 parts,
Pure water complements to 100 parts.
The multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention, its extinguishing mechanism are as follows：
L, extinguishing chemical is sprayed onto solid burning article flame, transient absorption heat, is at once vapor, and thermal decomposition is interrupted, flame
Terminate immediately.
2nd, extinguishing chemical is sprayed to the surface of liquid comburant, liquid not only rapid expanding, and form foam and film forming breast
Change layer, flame is interrupted with air insulated and put out a fire.
The multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention has below beneficial to effect compared with prior art
Fruit：
L, its Main Ingredients and Appearance of the water-based extinguishing agent of the present invention is pollution-free degradable compound, thus will not cause ring
Pollute in border.
2nd, water-based extinguishing agent of the invention, is not used by high/low temperature climatic environment not only and is limited, while has explosion-proof, resistance
Combustion, the function of cooling.
3rd, water-based extinguishing agent of the invention is 5 times of national standard extinguishing grade, is ABC dry powder extinguisher extinguishing grades
10 times.
4th, by GB17835-2008 standards, it is specified that testing each physical and chemical index not after water-based extinguishing agent of the invention stores 10 years
Become, the constant problem of use quality can not be stored for a long time by having broken through China's water-based extinguishing agent.
Embodiment
A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present invention is made by following examples further
Explanation.
Embodiment
A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant of the present embodiment, each raw material in table 1 is well mixed,
Obtain product of the present invention.
Using above method, the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant is prepared according to the component proportion of table 1.
The proportioning of each component in the embodiment 1-6 of table 1
| Embodiment | 1 | 2 | 3 | 4 | 5 | 6 |
| Diethylene glycol ether (kg) | 1.8 | 2.2 | 2.3 | 1.9 | 2.0 | 2.1 |
| Alkyl phenol Polyoxyalkylene ethers (kg) | 1.3 | 1.7 | 1.8 | 1.4 | 1.2 | 1.6 |
| Sulfurio benzo thiazole (kg) | 0.5 | 0.8 | 0.3 | 0.6 | 0.7 | 0.4 |
| Phosphate amine salt (kg) | 4.6 | 3.6 | 4.2 | 3.9 | 5.2 | 4.9 |
| Fluorocarbon surfactant (kg) | 3.0 | 3.3 | 3.6 | 2.4 | 2.2 | 2.7 |
| Calcium carbonate (kg) | 0.8 | 0.9 | 0.6 | 1.2 | 1.0 | 1.1 |
| Magnesium stearate (kg) | 0.05 | 0.03 | 0.06 | 0.04 | 0.05 | 0.03 |
| Antimony oxide (kg) | 3.7 | 3.3 | 3.6 | 3.2 | 3.4 | 3.8 |
| Carboxymethyl cellulose (kg) | 1.8 | 3.2 | 2.7 | 2.0 | 2.4 | 3.0 |
| Pure water (kg) | 82.45 | 80.97 | 80.84 | 83.36 | 81.85 | 80.37 |
The physical and chemical index for embodiment 1-6 being made product according to GB 17835-2008 detects, and the results are shown in Table 2.
The physical and chemical index of product is made in the embodiment 1-6 of table 2
As seen from the above table, water-based extinguishing agent of the invention meets national standard, can not be by domestic high/low temperature climatic environment
The limitation used, while there is explosion-proof, fire-retardant, cooling function fire extinguishing.Make fire extinguishing examination for the 5th article by the standards of GB17835-2008
Test, pool shape diameter 2.4m, the ㎡ of food tray area 4.52, fuel 93# gasoline, amount of fuel 100L, only need 2L extinguishing chemicals, be country
5 times of standard fire suppression rank, it is 10 times of ABC dry powder extinguisher extinguishing grades.After the water-based extinguishing agent of the present invention stores 10 years,
It is detected again, the results are shown in Table 2, it is known that, its physicochemical property does not change substantially.
Although the foregoing describing the embodiment of the present invention, it will be appreciated by those of skill in the art that these
It is merely illustrative of, protection scope of the present invention is defined by the appended claims.Those skilled in the art is not carrying on the back
On the premise of principle and essence from the present invention, various changes or modifications can be made to these embodiments, but these are changed
Protection scope of the present invention is each fallen within modification.
Claims (3)
1. a kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant, it is characterised in that include following components by mass fraction：
Diethylene glycol ether：1.8-2.3 parts,
Alkyl phenol Polyoxyalkylene ethers：1.2-1.8 part：
Sulfurio benzo thiazole：0.3-0.8 parts,
Phosphate amine salt：3.6-5.2 parts,
Fluorocarbon surfactant：2.2-3.6 parts,
Calcium carbonate：0.6-1.2 parts,
Magnesium stearate：0.03-0.06 parts,
Antimony oxide：3.2-3.8 part；
Carboxymethyl cellulose：1.8-3.2 parts,
Pure water complements to 100 parts.
2. the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant according to claim 1, it is characterised in that：By mass parts
Number includes following components：
Diethylene glycol ether：1.9-2.2 parts,
Alkyl phenol Polyoxyalkylene ethers 1.3-1.7 parts,
Sulfurio benzo thiazole：0.4-0.7 parts,
Phosphate amine salt：3.9-4.9 parts,
Fluorocarbon surfactant：2.4-3.3 parts,
Calcium carbonate：0.8-1.1 parts,
Magnesium stearate：0.04-0.05 parts,
Antimony oxide：3.3-3.7 part；
Carboxymethyl cellulose：2.0-3.0 parts,
Pure water complements to 100 parts.
3. the multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant according to claim 2, it is characterised in that：By mass parts
Number includes following components：
Diethylene glycol ether：2.0-2.1 parts,
Alkyl phenol Polyoxyalkylene ethers：1.4-1.6 parts,
Sulfurio benzo thiazole：0.5-0.6 parts,
Phosphate amine salt：4.2-4.6 parts,
Fluorocarbon surfactant：2.7-3.0 parts,
Calcium carbonate：0.9-1.0 parts,
Magnesium stearate：0.04-0.05 parts,
Antimony oxide：3.4-3.6 part；
Carboxymethyl cellulose：2.4-2.7 parts,
Pure water complements to 100 parts.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510147771.8A CN104667474B (en) | 2015-03-31 | 2015-03-31 | A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant |
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| CN201510147771.8A CN104667474B (en) | 2015-03-31 | 2015-03-31 | A kind of multi-functional water-based extinguishing agent of environment-friendly high-efficiency explosion-proof flame-retardant |
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| CN104667474A CN104667474A (en) | 2015-06-03 |
| CN104667474B true CN104667474B (en) | 2018-02-23 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105797301B (en) * | 2016-04-20 | 2019-01-29 | 四川瑞思可消防科技有限公司 | A kind of pollution-free water-based extinguishing agent |
| CN106377863B (en) * | 2016-10-14 | 2019-12-06 | 浙江环亚消防新材料股份有限公司 | Water-based extinguishing agent and preparation method thereof |
| CN106730565B (en) * | 2016-12-15 | 2018-06-26 | 浙江睦田消防科技开发有限公司 | Extinguishing chemical and preparation method thereof |
| CN113214542B (en) * | 2021-05-18 | 2022-05-20 | 湖南娄底华星锑业有限公司 | Composite antimony trioxide flame retardant and preparation method thereof |
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| JP2010200928A (en) * | 2009-03-03 | 2010-09-16 | Iej:Kk | Method for extinguishing fire due to combustible liquid and fire extinguishing composition |
| JP6032896B2 (en) * | 2012-01-20 | 2016-11-30 | 利宏 伊藤 | Two-component mixed fire extinguisher |
| WO2014115036A2 (en) * | 2013-01-22 | 2014-07-31 | Miraculum Applications AB | Flame retardant and fire extinguishing product for fires in liquids |
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| CN101366999A (en) * | 2007-08-15 | 2009-02-18 | 中瑞华特（北京）高新技术开发有限公司 | Water system extinguishing agent |
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