CN107812340A - A kind of anti-resume combustion environment-friendly type water-based extinguishing agent - Google Patents
A kind of anti-resume combustion environment-friendly type water-based extinguishing agent Download PDFInfo
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- CN107812340A CN107812340A CN201711234568.XA CN201711234568A CN107812340A CN 107812340 A CN107812340 A CN 107812340A CN 201711234568 A CN201711234568 A CN 201711234568A CN 107812340 A CN107812340 A CN 107812340A
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Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0064—Gels; Film-forming compositions
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The invention discloses a kind of anti-resume combustion environment-friendly type water-based extinguishing agent, it is made up of the component of following parts by weight：5 20 parts of ammonium carbonate, 10 45 parts of APP, 10 30 parts of sodium metasilicate, 1 10 parts of foaming agent, 0.5 5 parts of polyethylene glycol, 15 parts of thickener, 4 10 parts of compound antifreezing agent, 55 80 parts of water；The one kind of the foaming agent in aliphatic alcohol polyethenoxy ether carboxylate, imidazoline amophoteric surface active agent, biosurfactant；The compound antifreezing agent is inorganic salts and polyalcohol in molar ratio 1:3‑1:9 compound compounds.Raw material of the present invention is all using environment-friendly materials, not fluorochemical, nontoxic, odorlessness, pollution-free；Fire retardant is added, effectively prevents fire spreading, fire extinguishing effectiveness height；Using green surfactant as foaming agent, foaminess is good, effectively completely cuts off contact of the comburant with air, accelerates blow-off velocity；Using inorganic salts and polyalcohol compound antifreezer, the freezing point of extinguishing chemical can be made to be reduced to 30 DEG C.
Description
Technical field
The invention belongs to fire-fighting equipment technical field, and in particular to a kind of extinguishing chemical, more particularly to a kind of anti-resume combustion environmental protection
Type water-based extinguishing agent.
Background technology
Fire is most frequently, most generally threatens one of major casualty of public security and social development.Water is most economical
Natural extinguishing chemical, be usually used in put out a fire to save life and property building, forest and stacking fire.But water good fluidity, easily in fire extinguishing procedure be lost in and
Water loading power very little, it is impossible to the fire of the effective vertical surface combustible that protects and put out a fire to save life and property.Flue gas, water can not be suppressed during above-water method
Rifle jet can increase by tens times of strong toxic smoke in the scene of a fire and flow to the powerful dense smoke air-flow of interior of building, easily in corridor
Formed " smokestack ", make personnel escape difficult.Therefore, it is necessary to add some additives in water to improve the extinguishing property of water, water
It is that extinguishing chemical arises at the historic moment.
Therefore, need badly develop a kind of fire extinguishing effectiveness suitable for transmission line forest fire it is high, can anti-resume combustion environment-friendly type fire extinguishing
Agent.
The content of the invention
It is an object of the invention to provide a kind of anti-resume combustion environment-friendly type water-based extinguishing agent, its is environmentally friendly, and fire extinguishing effectiveness is high,
Fire scene temperature can quickly be cooled down.
To achieve these goals, the present invention adopts the following technical scheme that：A kind of anti-resume combustion environment-friendly type water-based extinguishing agent, by
The component composition of following parts by weight：Super absorbent resin 6-8 parts, diammonium hydrogen phosphate 10-45 parts, disodium hydrogen phosphate 10-30 parts, three
Polyphosphate sodium 15-20 parts, biosurfactant 2-4 parts, hc-surfactant 1-2 parts, polyethylene glycol 4-6 parts, thickener
3-5 parts, calcium chloride 1-2 parts, isopropanol 6-10 parts, water 120-150 parts.
Preferably, a kind of anti-resume combustion environment-friendly type water-based extinguishing agent, is made up of the component of following parts by weight：Super absorbent resin
7 parts, 35 parts of diammonium hydrogen phosphate, 20 parts of disodium hydrogen phosphate, 16 parts of sodium tripolyphosphate, 3 parts of biosurfactant, hydrocarbon surface live
1.5 parts of agent of property, 5 parts of polyethylene glycol, 4 parts of thickener, 1.5 parts of calcium chloride, 8 parts of isopropanol, 130 parts of water.
Preferably, the biosurfactant is selected from marine alga glycolipid, rhamnolipid, cellobiose ester, sophorolipid, phosphatide
In one kind.
Preferably, the hc-surfactant is selected from lauryl sodium sulfate, neopelex, imidazoline type
One kind in surfactant, betaine type amphoteric surfactant.
Preferably, the thickener is selected from sodium carboxymethylcellulose, polyacrylamide or xanthans.
Wherein, super absorbent resin has water retention.
Wherein, decomposed after diammonium hydrogen phosphate is heated and produce ammonia and vapor, ammonia can play physical isolation fire extinguishing
Effect, vapor can put out a fire.
Wherein, it is decomposed to form phosphorus pentoxide vitreous film under disodium hydrogen phosphate, sodium tripolyphosphate high temperature and is covered in combustion
Burn thing surface, contact of the isolation comburant with air.
Wherein, sodium metasilicate can also play preferable fire retardation, improve the anti-resume combustion ability after fire extinguishing.
Wherein, biosurfactant, the main function of hc-surfactant are to produce a large amount of foams, completely cut off comburant
Contact with air, collaboration reduce the surface tension of water, the mixture of extinguishing chemical is extended shape rapidly on comburant surface
Into moisture film, accelerate coverage speed, play the purpose of quick extinguishing.
Wherein, the effect of polyethylene glycol be sprawl, anti-burning.
Wherein, the effect of thickener is to increase the viscosity of extinguishing chemical, reduces the wasting of resources and efficiency caused by water loss
Reduce.
Wherein, the compound condensation point for being used as antifreezing agent, extinguishing chemical being reduced in cold climates of calcium chloride, isopropanol.
The preparation method of above-mentioned anti-resume combustion environment-friendly type water-based extinguishing agent, comprises the steps：(1) by the phosphorus of the parts by weight
The sour ammonium of hydrogen two, disodium hydrogen phosphate, sodium tripolyphosphate are dissolved in the water of the parts by weight, obtain mixture A；(2) successively by described in
Biosurfactant, hc-surfactant, polyethylene glycol, calcium chloride, the isopropanol of parts by weight add said mixture A
In, stir to obtain mixture B；(3) thickener of the parts by weight is added, stir to obtain water-based extinguishing agent.
Beneficial effects of the present invention are as follows：
1st, addition super absorbent resin can strengthen the water holding capacity of extinguishing chemical.
2nd, compounded using diammonium hydrogen phosphate, disodium hydrogen phosphate, sodium tripolyphosphate by three as fire retardant, can be effective
Fire spreading is prevented, avoids reviving, fire extinguishing effectiveness is high；
3rd, using biosurfactant and hc-surfactant, compounded by both, effectively reduce aqueous solution surface
Tension force and interfacial tension, and foam, water membrane and foam protective layer are formed in fuel surface, reaches the purpose of quick extinguishing.
Embodiment
Embodiment 1
A kind of anti-resume combustion environment-friendly type water-based extinguishing agent, is made up of the component of following parts by weight：Super absorbent resin 6-8 parts,
Diammonium hydrogen phosphate 10-45 parts, disodium hydrogen phosphate 10-30 parts, sodium tripolyphosphate 15-20 parts, biosurfactant 2-4 parts, carbon
Hydrogen surfactant 1-2 parts, polyethylene glycol 4-6 parts, thickener 3-5 parts, calcium chloride 1-2 parts, isopropanol 6-10 parts, water 120-
150 parts.
The preparation method of above-mentioned anti-resume combustion environment-friendly type water-based extinguishing agent, comprises the steps：(1) by the carbon of the parts by weight
Sour ammonium, APP, sodium metasilicate are dissolved in the water of the parts by weight, obtain mixture A；(2) successively by the fat of the parts by weight
Fat alcohol polyethenoxy ether carboxylate, polyethylene glycol, guar gum are added in said mixture A, and stir to obtain mixture B；(3) again
Sodium chloride, the ethylene glycol of the parts by weight are added, stir to obtain extinguishing chemical.
Embodiment 2
A kind of anti-resume combustion environment-friendly type water-based extinguishing agent, is made up of the component of following parts by weight：7 parts of super absorbent resin, phosphorus
Sour 35 parts of two ammonium of hydrogen, 20 parts of disodium hydrogen phosphate, 16 parts of sodium tripolyphosphate, 3 parts of biosurfactant, hc-surfactant
1.5 parts, 5 parts of polyethylene glycol, 4 parts of thickener, 1.5 parts of calcium chloride, 8 parts of isopropanol, 130 parts of water.
The preparation method of above-mentioned anti-resume combustion environment-friendly type water-based extinguishing agent, comprises the steps：(1) by the carbon of the parts by weight
Sour ammonium, APP, sodium metasilicate are dissolved in the water of the parts by weight, obtain mixture A；(2) successively by the miaow of the parts by weight
Oxazoline amphoteric surfactant, polyethylene glycol, Sodium Polyacrylate are added in said mixture A, and stir to obtain mixture B；(3)
Calcium chloride, the propane diols of the parts by weight are added, stir to obtain extinguishing chemical.
Embodiment 3
A kind of anti-resume combustion environment-friendly type water-based extinguishing agent, is made up of the component of following parts by weight：Super absorbent resin 6-8 parts,
Diammonium hydrogen phosphate 10-45 parts, disodium hydrogen phosphate 10-30 parts, sodium tripolyphosphate 15-20 parts, biosurfactant 2-4 parts, carbon
Hydrogen surfactant 1-2 parts, polyethylene glycol 4-6 parts, thickener 3-5 parts, calcium chloride 1-2 parts, isopropanol 6-10 parts, water 120-
150 parts.
The preparation method of above-mentioned anti-resume combustion environment-friendly type water-based extinguishing agent, comprises the steps：(1) by the carbon of the parts by weight
Sour ammonium, APP, sodium metasilicate are dissolved in the water of the parts by weight, obtain mixture A；(2) successively by the sea of the parts by weight
Algae glycolipid, polyethylene glycol, sodium hydroxyethyl cellulose are added in said mixture A, and stir to obtain mixture B；(3) institute is added
Magnesium chloride, the glycerine of parts by weight are stated, stir to obtain extinguishing chemical.
Embodiment 4
A kind of anti-resume combustion environment-friendly type water-based extinguishing agent, is made up of the component of following parts by weight：18 parts of ammonium carbonate, APP
25 parts, 20 parts of sodium metasilicate, 5 parts of phosphatidase 2,3 parts of polyethylene glycol, 3.5 parts of xanthans, 1 part of sodium carbonate, 6 parts of ethylene glycol, 70 parts of water.
The preparation method of above-mentioned anti-resume combustion environment-friendly type water-based extinguishing agent, comprises the steps：(1) by the carbon of the parts by weight
Sour ammonium, APP, sodium metasilicate are dissolved in the water of the parts by weight, obtain mixture A；(2) successively by the phosphorus of the parts by weight
Fat, polyethylene glycol, xanthans are added in said mixture A, and stir to obtain mixture B；(3) carbon of the parts by weight is added
Sour sodium, ethylene glycol, stir to obtain extinguishing chemical.
Embodiment 5
A kind of anti-resume combustion environment-friendly type water-based extinguishing agent, is made up of the component of following parts by weight：20 parts of ammonium carbonate, APP
10 parts, 30 parts of sodium metasilicate, 30 parts of cellobiose ester, 5 parts of polyethylene glycol, 2 parts of sodium cellulose glycolate, 1 part of potassium carbonate, propane diols
5 parts, 60 parts of water.
The preparation method of above-mentioned anti-resume combustion environment-friendly type water-based extinguishing agent, comprises the steps：(1) by the carbon of the parts by weight
Sour ammonium, APP, sodium metasilicate are dissolved in the water of the parts by weight, obtain mixture A；(2) successively by the fibre of the parts by weight
Tie up two sugar esters, polyethylene glycol, sodium cellulose glycolate to add in said mixture A, stir to obtain mixture B；(3) add
Potassium carbonate, the propane diols of the parts by weight, stir to obtain extinguishing chemical.
Anti- resume combustion environment-friendly type water-based extinguishing agent product obtained by above-described embodiment 1-5 is qualified through examining.By above-mentioned 5 implementations
The extinguishing chemical stoste that example obtains is diluted with water 20 times, is filled in fire extinguisher and carries out live fire-extinguishing test.It is fine to test same day weather
It is bright, overdo 4 minutes burning times, obtain result of the test and see the table below：
Fire-extinguishing test result form
Claims (5)
1. a kind of anti-resume combustion environment-friendly type water-based extinguishing agent, it is characterised in that be made up of the component of following parts by weight：High-hydroscopicity tree
Fat 6-8 parts, diammonium hydrogen phosphate 10-45 parts, disodium hydrogen phosphate 10-30 parts, sodium tripolyphosphate 15-20 parts, biosurfactant
2-4 parts, hc-surfactant 1-2 parts, polyethylene glycol 4-6 parts, thickener 3-5 parts, calcium chloride 1-2 parts, isopropanol 6-10 parts,
Water 120-150 parts.
2. anti-resume combustion environment-friendly type water-based extinguishing agent according to claim 1, it is characterised in that by the component of following parts by weight
Composition：7 parts of super absorbent resin, 35 parts of diammonium hydrogen phosphate, 20 parts of disodium hydrogen phosphate, 16 parts of sodium tripolyphosphate, biological surface are lived
3 parts of agent of property, 1.5 parts of hc-surfactant, 5 parts of polyethylene glycol, 4 parts of thickener, 1.5 parts of calcium chloride, 8 parts of isopropanol, water 130
Part.
3. anti-resume combustion environment-friendly type water-based extinguishing agent according to claim 1 or 2, it is characterised in that the biological surface is lived
The one kind of property agent in marine alga glycolipid, rhamnolipid, cellobiose ester, sophorolipid, phosphatide.
4. anti-resume combustion environment-friendly type water-based extinguishing agent according to claim 1 or 2, it is characterised in that live on the hydrocarbon surface
Property agent be selected from lauryl sodium sulfate, neopelex, Imidazoline Surfactants, betaine type amphoteric surfactant
In one kind.
5. anti-resume combustion environment-friendly type water-based extinguishing agent according to claim 1 or 2, it is characterised in that the thickener is selected from
Sodium carboxymethylcellulose, polyacrylamide or xanthans.
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108421194A (en) * | 2018-04-24 | 2018-08-21 | 厦门泰消防科技开发有限公司 | A kind of environment-friendly type water-based extinguishing agent |
| CN108434645A (en) * | 2018-04-10 | 2018-08-24 | 公安部天津消防研究所 | A kind of attached type water based fire suppressant for vertical plane solid fire |
| CN108947579A (en) * | 2018-09-20 | 2018-12-07 | 扬州工业职业技术学院 | A kind of novel light, resistance to compression, insulating foam concrete segment |
| CN110152232A (en) * | 2019-06-26 | 2019-08-23 | 厦门一泰消防科技开发有限公司 | Extinguishing chemical and preparation method thereof based on magnetization and chelating technology |
| CN110433442A (en) * | 2019-07-17 | 2019-11-12 | 湖南省湘电试研技术有限公司 | A kind of vaporization prevention high-efficiency fire-extinguishant for helicopter fire extinguishing |
| CN110711339A (en) * | 2019-11-13 | 2020-01-21 | 徐州金港起重机制造有限公司 | Water-based fire extinguishing agent capable of extinguishing gasoline fire |
| CN110917553A (en) * | 2019-12-06 | 2020-03-27 | 国网湖南省电力有限公司 | Temperature-sensitive evaporation-preventing water-based extinguishing agent |
| CN110975216A (en) * | 2019-12-20 | 2020-04-10 | 厦门市兆泰云智能科技有限公司 | Fire extinguishing material suitable for extinguishing electric vehicle fire |
| CN111075499A (en) * | 2019-12-12 | 2020-04-28 | 山东科技大学 | Phosphorus-silicon synergistic fire prevention and extinguishing foam gel and preparation method thereof |
| CN111905318A (en) * | 2020-07-24 | 2020-11-10 | 辽宁工程技术大学 | Novel hydrogel coal field fire prevention and extinguishing material and use method thereof |
| CN112957649A (en) * | 2021-02-05 | 2021-06-15 | 茂名职业技术学院 | Sodium hydrosulfite fire suppression liquid fire extinguishing agent and corresponding slow-release sodium hydrosulfite |
| CN113663272A (en) * | 2021-09-04 | 2021-11-19 | 成都迪沃航空科技有限公司 | Novel fire extinguishing agent |
| GB2595589A (en) * | 2020-05-27 | 2021-12-01 | Firexo Group Ltd | Fire extinguishing composition for large fires |
| CN114042283A (en) * | 2018-11-26 | 2022-02-15 | 宁夏万汇云合消防科技有限公司 | Novel high-molecular water-based extinguishing agent and preparation method thereof |
| CN114112957A (en) * | 2021-11-26 | 2022-03-01 | 浙江夸克生物科技有限公司 | Adiponectin determination kit and application thereof |
| US11964178B2 (en) | 2018-08-09 | 2024-04-23 | Carrier Corporation | Fire extinguishing composition and method of making |
| CN117942525A (en) * | 2024-01-29 | 2024-04-30 | 无锡联盾特种防护有限公司 | Environment-friendly water-based extinguishing agent and preparation method thereof |
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| CN108434645B (en) * | 2018-04-10 | 2020-07-31 | 应急管理部天津消防研究所 | Attached water-based fire extinguishing agent for vertical surface solid fire |
| CN108434645A (en) * | 2018-04-10 | 2018-08-24 | 公安部天津消防研究所 | A kind of attached type water based fire suppressant for vertical plane solid fire |
| CN108421194A (en) * | 2018-04-24 | 2018-08-21 | 厦门泰消防科技开发有限公司 | A kind of environment-friendly type water-based extinguishing agent |
| US11964178B2 (en) | 2018-08-09 | 2024-04-23 | Carrier Corporation | Fire extinguishing composition and method of making |
| CN108947579A (en) * | 2018-09-20 | 2018-12-07 | 扬州工业职业技术学院 | A kind of novel light, resistance to compression, insulating foam concrete segment |
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| CN110152232A (en) * | 2019-06-26 | 2019-08-23 | 厦门一泰消防科技开发有限公司 | Extinguishing chemical and preparation method thereof based on magnetization and chelating technology |
| CN110433442A (en) * | 2019-07-17 | 2019-11-12 | 湖南省湘电试研技术有限公司 | A kind of vaporization prevention high-efficiency fire-extinguishant for helicopter fire extinguishing |
| CN110711339A (en) * | 2019-11-13 | 2020-01-21 | 徐州金港起重机制造有限公司 | Water-based fire extinguishing agent capable of extinguishing gasoline fire |
| CN110917553B (en) * | 2019-12-06 | 2021-06-15 | 国网湖南省电力有限公司 | Temperature-sensitive evaporation-preventing water-based extinguishing agent |
| CN110917553A (en) * | 2019-12-06 | 2020-03-27 | 国网湖南省电力有限公司 | Temperature-sensitive evaporation-preventing water-based extinguishing agent |
| CN111075499A (en) * | 2019-12-12 | 2020-04-28 | 山东科技大学 | Phosphorus-silicon synergistic fire prevention and extinguishing foam gel and preparation method thereof |
| CN110975216A (en) * | 2019-12-20 | 2020-04-10 | 厦门市兆泰云智能科技有限公司 | Fire extinguishing material suitable for extinguishing electric vehicle fire |
| GB2595589A (en) * | 2020-05-27 | 2021-12-01 | Firexo Group Ltd | Fire extinguishing composition for large fires |
| GB2595589B (en) * | 2020-05-27 | 2022-12-21 | Firexo Cotm Ltd | Fire extinguishing composition for large fires |
| CN111905318A (en) * | 2020-07-24 | 2020-11-10 | 辽宁工程技术大学 | Novel hydrogel coal field fire prevention and extinguishing material and use method thereof |
| CN112957649A (en) * | 2021-02-05 | 2021-06-15 | 茂名职业技术学院 | Sodium hydrosulfite fire suppression liquid fire extinguishing agent and corresponding slow-release sodium hydrosulfite |
| CN113663272A (en) * | 2021-09-04 | 2021-11-19 | 成都迪沃航空科技有限公司 | Novel fire extinguishing agent |
| CN114112957A (en) * | 2021-11-26 | 2022-03-01 | 浙江夸克生物科技有限公司 | Adiponectin determination kit and application thereof |
| CN117942525A (en) * | 2024-01-29 | 2024-04-30 | 无锡联盾特种防护有限公司 | Environment-friendly water-based extinguishing agent and preparation method thereof |
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