CN104650638A - Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint and preparation method thereof - Google Patents

Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint and preparation method thereof Download PDF

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Publication number
CN104650638A
CN104650638A CN201310599339.3A CN201310599339A CN104650638A CN 104650638 A CN104650638 A CN 104650638A CN 201310599339 A CN201310599339 A CN 201310599339A CN 104650638 A CN104650638 A CN 104650638A
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China
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agent
bamboo charcoal
emulsion paint
paint
suju
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CN201310599339.3A
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Chinese (zh)
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刘汉斌
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Individual
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C09D5/025—Preservatives, e.g. antimicrobial agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate

Abstract

The invention belongs to the technical field of chemical paint and relates to Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint and a preparation method thereof. The Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint comprises, by weight, 10-15% of deionized water, 0.5-1% of a potassium salt dispersant, 0.2% of a wetting agent without APEO (alkylphenol), 0.1-0.15% of an antiseptic, 0.15% of an antifoaming agent, 14-18% of rutile-type titanium dioxide, 8% of heavy calcium carbonate, 7% of calcined kaolin, 5% of wollastonite, 0.3% of a sodium-based anti-settling agent, 3% of fine salt bamboo charcoal, 20-25% of modified emulsion paint, 0.2% of a complexing agent, 0.2% of an antifoaming agent, 0.05% of a film forming assistant, 0.05% of a leveling agent and 0.05% of a thickening agent. The Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint has no smell and no pollution, is green and environmentally friendly, prevents wall mould generation, adopts a fine salt bamboo charcoal technology, and has a good adsorption capability and an air purification capability.

Description

A kind of speed occupies clean taste emulsion paint of bamboo charcoal antibacterial and preparation method thereof
technical field
The invention belongs to technical field of chemical paint, particularly a kind of speed occupies clean taste emulsion paint of bamboo charcoal antibacterial and preparation method thereof.
background technology
along with the quickening of social step, people enter allegro animation, and the moment embodies the importance of time, as the saying goes: time is gold.In the life step that this is compact, the requirement of house is also entered in fast pace, expedite the emergence of a series of if wedding room, fast house etc. are can move in the novel house form into feature fast.But along with the quickening of step, house does not but often reach the desirable effect of moving in rapidly required by oneself.Its basic reason to be exactly house need the ventilation of a very long time to blow away after finishing again indoor just fitted up comprise emulsion paint, peculiar smell that household comes out.In this context by thousands of time experiments finally indoor the essential problem of environment set out and have developed a kind of New-type latex paint solved the problem.
summary of the invention
The present invention overcomes deficiency of the prior art, provides a kind of speed to occupy the clean taste emulsion paint of bamboo charcoal antibacterial.
The technical solution adopted in the present invention is:
A kind of speed occupies the clean taste emulsion paint of bamboo charcoal antibacterial, the weight percent of the concrete component of described emulsion paint is: 10%-15% deionization, 0.5%-1% sylvite dispersion agent, 0.2% do not contain wetting agent, the 0.1%-0.15% sanitas of APEO (alkylphenol), the titanium dioxide of 0.15% defoamer, 14%-18% rutile-type, 8% water-ground limestone, 7% calcined kaolin, 5% wollastonite, 0.3% sodium base anti-settling agent, 3% fine salt bamboo charcoal, the paint of 20%-25% modified emulsion, 0.2% complexing agent, 0.2% defoamer, 0.05% film coalescence aid, 0.05% flow agent, 0.05% thickening material.
The invention also discloses the preparation method that described speed occupies the clean taste emulsion paint of bamboo charcoal antibacterial, comprise the following steps:
(1) add in the deionized water of 10%-15% the sylvite dispersion agent of 0.5%-1%, about 0.2% not containing the wetting agent of APEO (alkylphenol), the sanitas of 0.1%-0.15%, the defoamer of 0.15, adds the titanium dioxide of the rutile-type of 14%-18%, 8% water-ground limestone, 7% calcined kaolin, 5% wollastonite;
(2) high speed dispersion, shredder grinding is entered after dispersion 30min, fineness is squeezed in paint mixing kettle after reaching 20 orders, the fine salt bamboo charcoal of about 3% is added after the sodium base anti-settling agent adding 0.3% fully dissolves, slowly be stirred to the modified emulsion paint adding 20%-25% evenly, the defoamer of 0.2% is added after the complexing agent adding 0.2% slowly stirs, slowly stir, after adding 0.05% film coalescence aid, stir, add 0.05% flow agent, 0.05% thickening material is modulated, modulation terminates that rear detection is qualified for salely dispatches from the factory.
Sterilant in the present invention is Sol company of Britain last word, the derivative of isothiazolinone, green, environmental protection, degradation cycle are short, and be close to nontoxic, fanout free region to human body, the sanitas that can be used for makeup uses, more can to environment.
The sylvite dispersion agent used in the present invention is not containing VOC, and dispersion effect is remarkable, and the Emulsion combination in film process easily and in coating, not h substance, also can not move outside, and is retained in paint film firmly, this product is the derivative of sylvite, and dispersion efficiency is high and nontoxic, not to environment.
Wetting agent is in the present invention imported product, containing APEO (alkylphenol), meeting national requirements for environmental protection, is green.
Titanium dioxide in the present invention is the imported product of rutile-type, du pont company, titanium dioxide particle surface processes further, whiteness is high, purity is good, and have extraordinary stability, ultraviolet-resistant capacity is extremely strong, do not discharge toxic substance, because stability itself, generally do not send out into reaction with other material, acid-and base-resisting effective.
Have the filler (water-ground limestone, calcined kaolin, wollastonite) used all to be through outstanding process in the present invention, chemical property tends towards stability, not containing other heavy metal, nontoxic, pollution-free.
The fine salt bamboo charcoal used in the present invention obtains in heat, and intrinsic colour is just near-white, and so just can be any painting color used, whitewash is no exception, and addition also can strengthen and not affect the color of coating.Tiny and the uniform particles of this fine salt bamboo charcoal particle, can be easy to each corner being just dispersed in coating uniformly, and all can not have influence on the decorative effect of coating paint film and the planeness of paint film in construction and after construction in coating.This fine salt bamboo-carbon fibre is plentiful, and filtration capacity is distinguished, can absorb the peculiar smell in room, filtrated air, is adsorbed on firmly among bamboo charcoal by harmful gas, has reached the effect of protection.
Emulsion in the present invention is acrylic acid modified emulsion, and through nucleocapsid, a series of abundant reaction such as crosslinked, the later stage, to the absorption of emulsion monomer, allows the VOC of emulsion well below the limitation of International Environmental Protection qualification certification.This kind of modified emulsion moderate in grain size, enhance the parcel ability of emulsion to dye, filler, emulsion possesses certain elasticity, extremely small bubble can be produced in stirring, the water resistance of emulsion and acid-proof alkaline brilliance, also improve the yellowing resistance energy of emulsion simultaneously, add the work-ing life of coating.
The complexing agent used in the present invention self is macromole, the spilling so can not volatilize, it carries out complex reaction by little functional group such as the hydrogen bond etc. of its own band to volatile VOC material remaining in coating, is that it can not volatilize, and the more perfect emulsion network of some side chain complexings composition of emulsion, dye, filler can be allowed to be wrapped in firmly among paint film, this complexing agent is organic macromolecule, nontoxic, easily decomposes, not to environment, do not produce toxic substance.
Full effect dry film sterilant in the present invention is effect body of wall and paint film being played to bactericidal after drying varniss, prevent mushroom from growing, combine firmly with paint film after this series bactericidal agent drying, the constraint of paint film can not be pulled out because of the impact of other materials such as water, air, its timeliness that effectively control bacterium is antibacterial is 5-7, can not to naturally impacting.
Defoamer in the present invention is external import, not easily occurs the phenomenon such as orange peel, flake, and defoaming effect is remarkable, and this defoamer itself is not containing VOC, nontoxic, nuisanceless.
Flow agent in the present invention is external import, has fabulous improvement, coating can be allowed to form very smooth paint film, thus make the decoration ability of paint film stronger the levelling property of paint film and sag resistance.
Beneficial effect of the present invention:
The tasteless pollution free green environment protection of the present invention, closed body of wall inside contacts with room air, and prevent body of wall from producing mould, or the mould produced is killed, grow the indoor a large amount of oxygen of consumption while destroying body of wall cause indoor anoxic and prevent mould from process of growth, discharging a large amount of obnoxious flavoures to prevent mould, so adopt the pointed removing of all kinds of mould and suppression.The peculiar smell produced for indoor furniture and other reason and toxic gas are removed, and adopt fine salt bamboo charcoal technology, high adsorption capacity, the ability purified air is remarkable.
embodiment
Embodiment 1:
A kind of speed occupies the clean taste emulsion paint of bamboo charcoal antibacterial, the weight percent of the concrete component of described emulsion paint is: 12% deionization, 0.6% sylvite dispersion agent, 0.2% do not contain wetting agent, 0.12% sanitas of APEO (alkylphenol), the titanium dioxide of 0.15% defoamer, 16% rutile-type, 8% water-ground limestone, 7% calcined kaolin, 5% wollastonite, 0.3% sodium base anti-settling agent, 3% fine salt bamboo charcoal, 23% modified emulsion paint, 0.2% complexing agent, 0.2% defoamer, 0.05% film coalescence aid, 0.05% flow agent, 0.05% thickening material.
Preparation method comprises the following steps:
(1) add in the deionized water of 12% the sylvite dispersion agent of 0.6%, about 0.2% not containing the wetting agent of APEO (alkylphenol), the sanitas of 0.12%, the defoamer of 0.15, adds the titanium dioxide of the rutile-type of 16%, 8% water-ground limestone, 7% calcined kaolin, 5% wollastonite;
(2) high speed dispersion, shredder grinding is entered after dispersion 30min, fineness is squeezed in paint mixing kettle after reaching 20 orders, the fine salt bamboo charcoal of about 3% is added after the sodium base anti-settling agent adding 0.3% fully dissolves, slowly be stirred to the modified emulsion paint adding 23% evenly, the defoamer of 0.2% is added after the complexing agent adding 0.2% slowly stirs, slowly stir, after adding 0.05% film coalescence aid, stir, add 0.05% flow agent, 0.05% thickening material is modulated, modulation terminates that rear detection is qualified for salely dispatches from the factory.

Claims (2)

1. a speed occupies the clean taste emulsion paint of bamboo charcoal antibacterial, it is characterized in that the weight percent of the concrete component of described emulsion paint is: 10%-15% deionization, 0.5%-1% sylvite dispersion agent, 0.2% containing the wetting agent of APEO (alkylphenol), 0.1%-0.15% sanitas, 0.15% defoamer, the titanium dioxide of 14%-18% rutile-type, 8% water-ground limestone, 7% calcined kaolin, 5% wollastonite, 0.3% sodium base anti-settling agent, 3% fine salt bamboo charcoal, the paint of 20%-25% modified emulsion, 0.2% complexing agent, 0.2% defoamer, 0.05% film coalescence aid, 0.05% flow agent, 0.05% thickening material.
2. speed according to claim 1 occupies a preparation method for the clean taste emulsion paint of bamboo charcoal antibacterial, it is characterized in that comprising the following steps:
(1) add in the deionized water of 10%-15% the sylvite dispersion agent of 0.5%-1%, about 0.2% not containing the wetting agent of APEO (alkylphenol), the sanitas of 0.1%-0.15%, the defoamer of 0.15, adds the titanium dioxide of the rutile-type of 14%-18%, 8% water-ground limestone, 7% calcined kaolin, 5% wollastonite;
(2) high speed dispersion, shredder grinding is entered after dispersion 30min, fineness is squeezed in paint mixing kettle after reaching 20 orders, the fine salt bamboo charcoal of about 3% is added after the sodium base anti-settling agent adding 0.3% fully dissolves, slowly be stirred to the modified emulsion paint adding 20%-25% evenly, the defoamer of 0.2% is added after the complexing agent adding 0.2% slowly stirs, slowly stir, after adding 0.05% film coalescence aid, stir, add 0.05% flow agent, 0.05% thickening material is modulated, modulation terminates that rear detection is qualified for salely dispatches from the factory.
CN201310599339.3A 2013-11-25 2013-11-25 Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint and preparation method thereof Pending CN104650638A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310599339.3A CN104650638A (en) 2013-11-25 2013-11-25 Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310599339.3A CN104650638A (en) 2013-11-25 2013-11-25 Suju bamboo charcoal antibiosis peculiar smell-removal emulsion paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN104650638A true CN104650638A (en) 2015-05-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867334A (en) * 2017-03-08 2017-06-20 颐中（青岛）实业有限公司 A kind of VAE emulsions response type is except formaldehyde interiro wall latex paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867334A (en) * 2017-03-08 2017-06-20 颐中（青岛）实业有限公司 A kind of VAE emulsions response type is except formaldehyde interiro wall latex paint and preparation method thereof

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Application publication date: 20150527