CN105131768A - Indoor air purification emulsion paint - Google Patents

Indoor air purification emulsion paint Download PDF

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Publication number
CN105131768A
CN105131768A CN201510551858.1A CN201510551858A CN105131768A CN 105131768 A CN105131768 A CN 105131768A CN 201510551858 A CN201510551858 A CN 201510551858A CN 105131768 A CN105131768 A CN 105131768A
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China
Prior art keywords
indoor air
powder
air purification
emulsion paint
parts
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Pending
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CN201510551858.1A
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Chinese (zh)
Inventor
祝秀凤
戴宇钧
汪鹏程
孙巨福
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TIANCHANG YINHU PAINT Co Ltd
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TIANCHANG YINHU PAINT Co Ltd
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Priority to CN201510551858.1A priority Critical patent/CN105131768A/en
Publication of CN105131768A publication Critical patent/CN105131768A/en
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Abstract

The invention discloses indoor air purification emulsion paint. The indoor air purification emulsion paint is prepared from silicone acrylic emulsion, pure acrylic emulsion, modified diatom ooze, light calcium carbonate, superfine talcum powder, nanometer titania, silane coupling agents KH-560, hydroxyethyl cellulose, sodium tripolyphosphate, dispersant SN-5040, propylene glycol, wetting agents AP-680, antifoaming agents, mildew preventive, alcohol ester-12, propylene glycol monomethyl ether, AMP-95 and deionized water. According to the indoor air purification emulsion paint, harmful ingredients in indoor air can be absorbed, negative ions can be continuously released for a long time, the air can be freshened, and environmental protection and health can be achieved.

Description

A kind of indoor air purification emulsion paint
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of indoor air purification emulsion paint.
Background technology
Along with people produce and the modernization more of mode of life, more work and sports entertainment all can carry out in indoor, and shopping also need not be gone into the street every day, and suitable kryptoclimate makes people often need not arrive outdoors, like this, most of activity time of people is all spent in indoor.Add up according to investigations, people every day on average nearly more than 80% time spend in indoor, have even up to more than 93%.Therefore, the relation of IAQ (indoor air quality) and HUMAN HEALTH is just more tight, and people also just pay attention to IAQ (indoor air quality) more.Although compared with outdoor, in room air, objectionable constituent (comprising formaldehyde, benzene, ammonia etc.) concentration is often lower, because people spend in indoor for a long time, in air objectionable constituent and human contact chronic, therefore its accumulation Exposure is very high.The weak crowd such as especially old, young, sick, residual, Abwehrkraft des Koepers is lower, outdoors chance less, and therefore, the quality of IAQ (indoor air quality) directly has influence on their healthy state.
Wherein, negative ion is a kind of negative oxygen ion be highly profitable to HUMAN HEALTH be present in air.A people needs about 13,000,000,000 negative ions every day, and our room, office, the environment such as public place of entertainment, can only provide 1 ~ 2,000,000,000 negative ion, the huge contrast between this supply and demand, often easily cause pneumonia, the respiratory diseases such as trachitis.And existing indoor paint is more weak to objectionable constituent adsorption in the air of indoor, and some product even also discharges the volatile organic matter such as formaldehyde, benzene,toluene,xylene, serious harm HUMAN HEALTH.Therefore develop one and can not only adsorb objectionable constituent in room air, and the wall coating of permanent constantly anion releasing, family room can be become natural ecological environment, reach the air condition that virgin forest, natural waterfall, Gold Coast, green open country etc. emulate naturally, its benefit is self-evident.
Summary of the invention
The present invention proposes a kind of indoor air purification emulsion paint, it can not only adsorb objectionable constituent in room air, can also for a long time continuous anion releasing, fresh air, environment protection health.
The present invention proposes a kind of indoor air purification emulsion paint, its raw material comprises by weight: organosilicon crylic acid latex 40-56 part, pure-acrylic emulsion 10-20 part, modification diatom ooze 35-45 part, light calcium carbonate 8-15 part, superfine talcum powder 3-6 part, nano titanium oxide 5-10 part, silane coupling agent KH-5600.5-1.5 part, Natvosol 0.5-1 part, tripoly phosphate sodium STPP 1-2 part, dispersion agent SN-50400.3-0.5 part, propylene glycol 3-5 part, wetting agent AP-6800.05-0.1 part, defoamer 0.2-0.4 part, mould inhibitor 0.1-0.5 part, alcohol ester 12 0.5-1 part, propylene glycol monomethyl ether 0.2-0.5 part, AMP-950.4-0.8 part, deionized water 65-80 part.
In a particular embodiment, the weight part of organosilicon crylic acid latex can 41, 42, 43, 44, 45, 46, 47, 48, 49, 51, 52, 53, 54, 55, the weight part of pure-acrylic emulsion can be 11, 12, 13, 14.4, 15, 15.3, 16, 16.8, 17, 18, 19, the weight part of modification diatom ooze can be 36, 36.8, 37, 38, 39, 40, 41.7, 42, 43.5, 44, the weight part of light calcium carbonate can be 8.6, 9.1, 9.7, 10.5, 11, 12.4, 13, 13.5, 14.3, the weight part of superfine talcum powder can be 3.6, 4.1, 4.7, 5.5, 5.8, the weight part of nano titanium oxide can be 5.5, 5.8, 6, 6.3, 7, 7.5, 8, 8.6, 9.1, 9.7 part.
Preferably, the preparation method of described modification diatom ooze comprises: after the stirring and evenly mixing that diatomite 30-45 part of particle diameter < 60um, negative ion powder 10-15 part added water by weight, add sierozem power 10-15 part, redispersable latex powder 2-4 part, treated starch cakingagent 2-5 part, insulated and stirred 0.5-1h at 30-40 DEG C, filter, washing, dries and obtains described modification diatom ooze; Preferably, described negative ion powder is that the rare earth element powder of 3-4:1 and tourmaline powder form by quality proportioning.
Preferably, in described diatomite, the content of amorphous silicon di-oxide is more than 80%.
Preferably, the preparation method of described treated starch cakingagent comprises: tapioca (flour) adds in the aqueous ethanolic solution of 80-90wt%, caustic soda is added under stirring, quaternization 20-30min at 30-40 DEG C, add boric acid again, stir 30-50min at 50-120 DEG C, obtain described treated starch cakingagent, wherein the weight proportion of tapioca (flour), caustic soda, boric acid is 1:0.1-0.3:0.03-0.05.
Preferably, described redispersable latex powder is one or more in polyacrylic ester rubber powder, ethylene-vinyl acetate copolymer rubber powder, poly-sbr powder.
Preferably, described defoamer is mineral oil antifoam agent or organic-silicon-modified defoamer.
Preferably, the weight proportion of SN-5040 dispersion agent and wetting agent AP-680 is 5-6:1.
A kind of preparation method of described indoor air purification emulsion paint, comprise: by tripoly phosphate sodium STPP, after deionized water mixing, 3-5min is disperseed under 300-400r/min rotating speed, add dispersion agent SN-5040, wetting agent AP-680, defoamer and mould inhibitor, 2-4min is disperseed under 600-800r/min rotating speed, add modification diatom ooze again, light calcium carbonate, superfine talcum powder, nano titanium oxide, silane coupling agent KH-560, alcohol ester 12 and propylene glycol, 35-40min is disperseed under 1800-2200r/min speed, add organosilicon crylic acid latex again, pure-acrylic emulsion, Natvosol, propylene glycol monomethyl ether and AMP-95, under 800-1000r/min speed, disperse 15-20min even to mixing liquid.
In the present invention, organosilicon crylic acid latex is added in described indoor air purification emulsion paint, and combine with pure-acrylic emulsion, while improve the water tolerance of film, sticking power, water absorbability and flexibility, also can better the mineral filler such as coating modification diatom ooze, light calcium carbonate, superfine talcum powder, nano titanium oxide, be conducive to being formed the paint film of densification continuously, modification diatom ooze is by selecting load negative ion powder in diatomite, be equipped with rubber powder, gelatinous material etc., the surfaces such as diatomite are become entangled in again by treated starch cakingagent, form a kind of homogeneous mixture thus, except adding diatom ooze film forming stability, the modification diatom ooze obtained thus, not only can control negative ion powder slowly to anion releasing particle in air, the structure of its uniqueness had " binding molecule sieve " simultaneously, significantly improve the gas sweetening performance of diatom ooze, effectively free in absorbed air objectionable impurities, and by its oxygenolysis, in addition the silane coupling agent KH-560 added further increases the stability in coating such as light calcium carbonate, superfine talcum powder, the composite diatom ooze of nano titanium oxide can improve the purification efficiency of formaldehyde, alcohol ester 12, propylene glycol monomethyl ether are as film coalescence aid, and its superior solubility, is conducive to film stable, even, the composite stable storing performance that effectively can improve coating of the dispersion agent SN-5040 of specified proportion and wetting agent AP-680, and film is stable, good weatherability, tripoly phosphate sodium STPP, Vltra tears, as the composite use of thickening material, are conducive to obtaining more stable network structure, improve the stability of system.
In the present invention, while the lasting anion releasing of described indoor air purification emulsion paint, also harmful material adsorbed or reduce activity, thus the Air quality environment of safe occupancy life is provided, described coating also has excellent weathering resistance, water tolerance, contamination resistance and tack simultaneously, long-term exposure does not ftracture under air, do not peel off, not shedding, nondiscoloration, durable in use, safety non-toxic, pollution-free, be applicable to indoor wall decorations.
Embodiment
Embodiment 1
In the present embodiment, a kind of indoor air purification emulsion paint, its raw material comprises by weight: organosilicon crylic acid latex 40 parts, pure-acrylic emulsion 20 parts, modification diatom ooze 35 parts, light calcium carbonate 15 parts, superfine talcum powder 3 parts, nano titanium oxide 10 parts, silane coupling agent KH-5600.5 part, Natvosol 1 part, tripoly phosphate sodium STPP 1 part, dispersion agent SN-50400.5 part, propylene glycol 3 parts, wetting agent AP-6800.1 part, defoamer 0.2 part, mould inhibitor 0.5 part, alcohol ester 12 parts, propylene glycol monomethyl ether 0.5 part, AMP-950.4 part, deionized water 80 parts;
The preparation method of described modification diatom ooze comprises: by weight by after 30 parts, the diatomite of particle diameter < 60um, negative ion powder 15 parts of stirring and evenly mixings that add water, add sierozem power 10 parts, polyacrylic ester rubber powder 4 parts, treated starch cakingagent 2 parts, insulated and stirred 0.5h at 40 DEG C, filter, washing, dries and obtains described modification diatom ooze; Wherein, described negative ion powder is that the rare earth element powder of 4:1 and tourmaline powder form by quality proportioning; In described diatomite, the content of amorphous silicon di-oxide is more than 80%; The preparation method of described treated starch cakingagent comprises: added by tapioca (flour) in the aqueous ethanolic solution of 80wt%, caustic soda is added under stirring, quaternization 20min at 40 DEG C, add boric acid again, 30min is stirred at 120 DEG C, obtain described treated starch cakingagent, wherein the weight proportion of tapioca (flour), caustic soda, boric acid is 1:0.3:0.03; Described defoamer is mineral oil antifoam agent.
Embodiment 2
In the present embodiment, a kind of indoor air purification emulsion paint, its raw material comprises by weight: organosilicon crylic acid latex 56 parts, pure-acrylic emulsion 10 parts, modification diatom ooze 45 parts, light calcium carbonate 8 parts, superfine talcum powder 6 parts, nano titanium oxide 5 parts, silane coupling agent KH-5601.5 part, Natvosol 0.5 part, tripoly phosphate sodium STPP 2 parts, dispersion agent SN-50400.3 part, propylene glycol 5 parts, wetting agent AP-6800.05 part, defoamer 0.4 part, mould inhibitor 0.1 part, alcohol ester 12 parts, propylene glycol monomethyl ether 0.2 part, AMP-950.8 part, deionized water 65 parts;
The preparation method of described modification diatom ooze comprises: by weight by after 45 parts, the diatomite of particle diameter < 60um, negative ion powder 10 parts of stirring and evenly mixings that add water, add sierozem power 15 parts, ethylene-vinyl acetate copolymer rubber powder 2 parts, treated starch cakingagent 5 parts, insulated and stirred 1h at 30 DEG C, filter, washing, dries and obtains described modification diatom ooze; Wherein, described negative ion powder is that the rare earth element powder of 3:1 and tourmaline powder form by quality proportioning; In described diatomite, the content of amorphous silicon di-oxide is more than 80%; The preparation method of described treated starch cakingagent comprises: added by tapioca (flour) in the aqueous ethanolic solution of 90wt%, caustic soda is added under stirring, quaternization 30min at 30 DEG C, add boric acid again, 50min is stirred at 50 DEG C, obtain described treated starch cakingagent, wherein the weight proportion of tapioca (flour), caustic soda, boric acid is 1:0.1:0.05; Described defoamer is organic-silicon-modified defoamer.
Embodiment 3
In the present embodiment, a kind of indoor air purification emulsion paint, its raw material comprises by weight: organosilicon crylic acid latex 48 parts, pure-acrylic emulsion 15 parts, modification diatom ooze 40 parts, light calcium carbonate 11 parts, superfine talcum powder 4 parts, nano titanium oxide 7 parts, silane coupling agent KH-5601.0 part, Natvosol 0.7 part, tripoly phosphate sodium STPP 1.5 parts, dispersion agent SN-50400.4 part, propylene glycol 4 parts, wetting agent AP-6800.07 part, defoamer 0.3 part, mould inhibitor 0.3 part, alcohol ester 12 parts, propylene glycol monomethyl ether 0.3 part, AMP-950.6 part, deionized water 70 parts;
The preparation method of described modification diatom ooze comprises: by weight by after 35 parts, the diatomite of particle diameter < 60um, negative ion powder 12 parts of stirring and evenly mixings that add water, add sierozem power 12 parts, poly-sbr powder 3 parts, treated starch cakingagent 3 parts, insulated and stirred 0.7h at 35 DEG C, filter, washing, dries and obtains described modification diatom ooze; Wherein, described negative ion powder is that the rare earth element powder of 3.5:1 and tourmaline powder form by quality proportioning; In described diatomite, the content of amorphous silicon di-oxide is more than 80%; The preparation method of described treated starch cakingagent comprises: added by tapioca (flour) in the aqueous ethanolic solution of 85wt%, caustic soda is added under stirring, quaternization 25min at 35 DEG C, add boric acid again, 40min is stirred at 85 DEG C, obtain described treated starch cakingagent, wherein the weight proportion of tapioca (flour), caustic soda, boric acid is 1:0.2:0.04; Described defoamer is mineral oil antifoam agent.
Embodiment 4
In the present embodiment, a kind of indoor air purification emulsion paint, its raw material comprises by weight: organosilicon crylic acid latex 50 parts, pure-acrylic emulsion 16 parts, modification diatom ooze 42 parts, light calcium carbonate 12 parts, superfine talcum powder 5 parts, nano titanium oxide 8 parts, silane coupling agent KH-5601.2 part, Natvosol 0.8 part, tripoly phosphate sodium STPP 1.6 parts, dispersion agent SN-50400.4 part, propylene glycol 4 parts, wetting agent AP-6800.08 part, defoamer 0.3 part, mould inhibitor 0.3 part, alcohol ester 12 parts, propylene glycol monomethyl ether 0.4 part, AMP-950.7 part, deionized water 75 parts;
The preparation method of described modification diatom ooze comprises: by weight by after 40 parts, the diatomite of particle diameter < 60um, negative ion powder 13 parts of stirring and evenly mixings that add water, add sierozem power 13 parts, redispersable latex powder 3 parts, treated starch cakingagent 4 parts, insulated and stirred 0.8h at 36 DEG C, filter, washing, dries and obtains described modification diatom ooze; Wherein, described negative ion powder is that the rare earth element powder of 3.6:1 and tourmaline powder form by quality proportioning; In described diatomite, the content of amorphous silicon di-oxide is more than 80%; The preparation method of described treated starch cakingagent comprises: added by tapioca (flour) in the aqueous ethanolic solution of 86wt%, adds caustic soda under stirring, quaternization 24min at 36 DEG C, then adds boric acid, stirs 45min at 90 DEG C, obtains described treated starch cakingagent,
Wherein the weight proportion of tapioca (flour), caustic soda, boric acid is 1:0.2:0.04; Described redispersable latex powder is two kinds of compositions of polyacrylic ester rubber powder, ethylene-vinyl acetate copolymer rubber powder; Described defoamer is organic-silicon-modified defoamer.
The preparation method of the indoor air purification emulsion paint described in above-described embodiment 1-4, comprise: by tripoly phosphate sodium STPP, after deionized water mixing, 3-5min is disperseed under 300-400r/min rotating speed, add dispersion agent SN-5040, wetting agent AP-680, defoamer and mould inhibitor, 2-4min is disperseed under 600-800r/min rotating speed, add modification diatom ooze again, light calcium carbonate, superfine talcum powder, nano titanium oxide, silane coupling agent KH-560, alcohol ester 12 and propylene glycol, 35-40min is disperseed under 1800-2200r/min speed, add organosilicon crylic acid latex again, pure-acrylic emulsion, Natvosol, propylene glycol monomethyl ether and AMP-95, under 800-1000r/min speed, disperse 15-20min even to mixing liquid.
The performance test results of the indoor air purification emulsion paint that above-described embodiment 1-4 obtains is as shown in the table:
In the present invention, organosilicon crylic acid latex is added in described indoor air purification emulsion paint, and combine with pure-acrylic emulsion, while improve the water tolerance of film, sticking power, water absorbability and flexibility, also can better the mineral filler such as coating modification diatom ooze, light calcium carbonate, superfine talcum powder, nano titanium oxide, be conducive to being formed the paint film of densification continuously, modification diatom ooze is by selecting load negative ion powder in diatomite, be equipped with rubber powder, gelatinous material etc., the surfaces such as diatomite are become entangled in again by treated starch cakingagent, form a kind of homogeneous mixture thus, except adding diatom ooze film forming stability, the modification diatom ooze obtained thus, not only can control negative ion powder slowly to anion releasing particle in air, the structure of its uniqueness had " binding molecule sieve " simultaneously, significantly improve the gas sweetening performance of diatom ooze, effectively free in absorbed air objectionable impurities, and by its oxygenolysis, in addition the silane coupling agent KH-560 added further increases the stability in coating such as light calcium carbonate, superfine talcum powder, the composite diatom ooze of nano titanium oxide can improve the purification efficiency of formaldehyde, alcohol ester 12, propylene glycol monomethyl ether are as film coalescence aid, and its superior solubility, is conducive to film stable, even, the composite stable storing performance that effectively can improve coating of the dispersion agent SN-5040 of specified proportion and wetting agent AP-680, and film is stable, good weatherability, tripoly phosphate sodium STPP, Vltra tears, as the composite use of thickening material, are conducive to obtaining more stable network structure, improve the stability of system.
In the present invention, while the lasting anion releasing of described indoor air purification emulsion paint, also harmful material adsorbed or reduce activity, thus the Air quality environment of safe occupancy life is provided, described coating also has excellent weathering resistance, water tolerance, contamination resistance and tack simultaneously, long-term exposure does not ftracture under air, do not peel off, not shedding, nondiscoloration, durable in use, safety non-toxic, pollution-free, be applicable to indoor wall decorations.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (8)

1. an indoor air purification emulsion paint, it is characterized in that, its raw material comprises by weight: organosilicon crylic acid latex 40-56 part, pure-acrylic emulsion 10-20 part, modification diatom ooze 35-45 part, light calcium carbonate 8-15 part, superfine talcum powder 3-6 part, nano titanium oxide 5-10 part, silane coupling agent KH-5600.5-1.5 part, Natvosol 0.5-1 part, tripoly phosphate sodium STPP 1-2 part, dispersion agent SN-50400.3-0.5 part, propylene glycol 3-5 part, wetting agent AP-6800.05-0.1 part, defoamer 0.2-0.4 part, mould inhibitor 0.1-0.5 part, alcohol ester 12 0.5-1 part, propylene glycol monomethyl ether 0.2-0.5 part, AMP-950.4-0.8 part, deionized water 65-80 part.
2. indoor air purification emulsion paint according to claim 1, it is characterized in that, the preparation method of described modification diatom ooze comprises: after the stirring and evenly mixing that diatomite 30-45 part of particle diameter < 60um, negative ion powder 10-15 part added water by weight, add sierozem power 10-15 part, redispersable latex powder 2-4 part, treated starch cakingagent 2-5 part, insulated and stirred 0.5-1h at 30-40 DEG C, filter, washing, dry and obtain described modification diatom ooze; Preferably, described negative ion powder is that the rare earth element powder of 3-4:1 and tourmaline powder form by quality proportioning.
3. indoor air purification emulsion paint according to claim 2, is characterized in that, in described diatomite, the content of amorphous silicon di-oxide is more than 80%.
4. the indoor air purification emulsion paint according to Claims 2 or 3, it is characterized in that, the preparation method of described treated starch cakingagent comprises: added by tapioca (flour) in the aqueous ethanolic solution of 80-90wt%, caustic soda is added under stirring, quaternization 20-30min at 30-40 DEG C, then add boric acid, stir 30-50min at 50-120 DEG C, obtain described treated starch cakingagent, wherein the weight proportion of tapioca (flour), caustic soda, boric acid is 1:0.1-0.3:0.03-0.05.
5. the indoor air purification emulsion paint according to any one of claim 2-4, is characterized in that, described redispersable latex powder is one or more in polyacrylic ester rubber powder, ethylene-vinyl acetate copolymer rubber powder, poly-sbr powder.
6. indoor air purification emulsion paint according to any one of claim 1-5, is characterized in that, described defoamer is mineral oil antifoam agent or organic-silicon-modified defoamer.
7. indoor air purification emulsion paint according to any one of claim 1-6, is characterized in that, the weight proportion of SN-5040 dispersion agent and wetting agent AP-680 is 5-6:1.
8. the preparation method of an indoor air purification emulsion paint according to any one of claim 1-7, it is characterized in that, comprise: by tripoly phosphate sodium STPP, after deionized water mixing, 3-5min is disperseed under 300-400r/min rotating speed, add dispersion agent SN-5040, wetting agent AP-680, defoamer and mould inhibitor, 2-4min is disperseed under 600-800r/min rotating speed, add modification diatom ooze again, light calcium carbonate, superfine talcum powder, nano titanium oxide, silane coupling agent KH-560, alcohol ester 12 and propylene glycol, 35-40min is disperseed under 1800-2200r/min speed, add organosilicon crylic acid latex again, pure-acrylic emulsion, Natvosol, propylene glycol monomethyl ether and AMP-95, under 800-1000r/min speed, disperse 15-20min even to mixing liquid.
CN201510551858.1A 2015-09-01 2015-09-01 Indoor air purification emulsion paint Pending CN105131768A (en)

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CN105838121A (en) * 2016-06-07 2016-08-10 赵广全 Waterborne thin-coating diatom mud
CN107673656A (en) * 2017-11-21 2018-02-09 广西吉顺能源科技有限公司 A kind of heat insulating inner wall water proof type diatom ooze and preparation method
CN107857506A (en) * 2017-11-21 2018-03-30 广西吉顺能源科技有限公司 A kind of heat insulating inner wall antimicrobial form diatom ooze and preparation method
CN107879667A (en) * 2017-11-21 2018-04-06 广西吉顺能源科技有限公司 A kind of heat insulating inner wall Anti-radiation type diatom ooze and preparation method
CN108219559A (en) * 2017-12-26 2018-06-29 深圳光天建材有限公司 Multi-functional environment-protection water nano diatom ooze and preparation method thereof
CN108948930A (en) * 2018-06-11 2018-12-07 阜南县中信柳木工艺品有限公司 A kind of preparation method of cool feeling wicker plaiting article cap
CN109897485A (en) * 2019-01-31 2019-06-18 苏州百联节能科技股份有限公司 A kind of self-cleaning environmental protection coating material of novel heat-insulation

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105838121A (en) * 2016-06-07 2016-08-10 赵广全 Waterborne thin-coating diatom mud
CN107673656A (en) * 2017-11-21 2018-02-09 广西吉顺能源科技有限公司 A kind of heat insulating inner wall water proof type diatom ooze and preparation method
CN107857506A (en) * 2017-11-21 2018-03-30 广西吉顺能源科技有限公司 A kind of heat insulating inner wall antimicrobial form diatom ooze and preparation method
CN107879667A (en) * 2017-11-21 2018-04-06 广西吉顺能源科技有限公司 A kind of heat insulating inner wall Anti-radiation type diatom ooze and preparation method
CN108219559A (en) * 2017-12-26 2018-06-29 深圳光天建材有限公司 Multi-functional environment-protection water nano diatom ooze and preparation method thereof
CN108948930A (en) * 2018-06-11 2018-12-07 阜南县中信柳木工艺品有限公司 A kind of preparation method of cool feeling wicker plaiting article cap
CN109897485A (en) * 2019-01-31 2019-06-18 苏州百联节能科技股份有限公司 A kind of self-cleaning environmental protection coating material of novel heat-insulation

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Application publication date: 20151209